CN105038985A - Natural rose essential oil micro-emulsion and preparation method thereof - Google Patents
Natural rose essential oil micro-emulsion and preparation method thereof Download PDFInfo
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- CN105038985A CN105038985A CN201510408249.0A CN201510408249A CN105038985A CN 105038985 A CN105038985 A CN 105038985A CN 201510408249 A CN201510408249 A CN 201510408249A CN 105038985 A CN105038985 A CN 105038985A
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Abstract
The invention discloses a natural rose essential oil micro-emulsion and a preparation method thereof. The invention relates to the field of food, medicine, and cosmetic material and additive. The natural rose essential oil micro-emulsion is composed of the following components, by weight: 5-10% of natural rose essential oil, 20-30% of an emulsifier, 5-10% of a co-emulsifier, and 50-70% of water. The oil-in-water micro-emulsion provided by the invention is clear and transparent, and has good stability and good water solubility. The rose essential oil micro-emulsion can be widely used in a water soluble system of cosmetics, alcohol, beverages, healthcare foods and medicines, and has a good market prospect.
Description
Technical field
The present invention relates to a kind of natural rose essential microemulsion and preparation method thereof, belong to food, medicine, cosmetic ingredients and additive agent field.
Background technology
Flos Rosae Rugosae quintessence oil is a kind of natural rare spice extracted from Rosaceae roseleaf, is described as " liquid golden ".Its elegant fragrance is strong, quality is pure.Medicinally slow down fatigue, tranquilizing and allaying excitement, pressure of releiving, also have and regulate human body incretion balance, make the bright and clean moist beauty and health care functions of skin, be subject to the favor of human consumer's especially female consumer.Therefore, the multiplex auxiliary material doing luxury food, makeup and daily chemical products of natural rose essential, has wide market outlook.
Flos Rosae Rugosae quintessence oil is insoluble in water, its use time exist absorption rate low, have the shortcomings such as stimulation to stomach and intestine.In addition, because Flos Rosae Rugosae quintessence oil has good volatility, in production and storage and transport process, a lot of composition easily loses and is oxidized, and brings inconvenience to its storage and use.Micro-embedded technology is one of effective means addressed these problems, and micro-embedded technology mainly comprises microcapsulary and micro-emulsion technology.Microcapsulary is by natural rose essential solidification; well protection and Co ntrolled release effect are served to natural rose essential; but Protein denaturation process is loaded down with trivial details, and cost is higher, and traditional microcapsule exist usually in solid form; can not use in liquid foodstuff, makeup, medicine; particle diameter is comparatively large, and its bioavailability is not very high, when addition is less; also be unfavorable for realizing being uniformly distributed in the product, limit its application.
Summary of the invention
The present invention, in order to make up the deficiencies in the prior art, provides the good and natural rose essential microemulsion with good aqueous solubility and preparation method thereof of a kind of clear, storage stability.
Described natural rose essential microemulsion, its composition is counted with percent mass: natural rose essential 5%-10%, emulsifying agent 20%-30%, assistant for emulsifying agent 5%-10%, water 50%-70%.
Described emulsifying agent is selected from one in following material or its mixture: tween 80 (Tween80), polyoxyethylene laurel ether 58 (Brij58).
Described assistant for emulsifying agent elects ethanol as.
Described natural rose essential microemulsion is O/W type microemulsion, and particle diameter is 2nm-200nm.
In one embodiment of the invention, described natural rose essential microemulsion, its composition is counted with percent mass: natural rose essential 5%, emulsifying agent 20%, assistant for emulsifying agent 10%, water 65%.
In one embodiment of the invention, the preparation method of described natural rose essential microemulsion is as follows:
1) by formula, emulsifying agent and assistant for emulsifying agent are mixed;
2) in step 1) add Flos Rosae Rugosae quintessence oil in emulsifier mixture, at temperature 25-40 DEG C, under stirring velocity 1500-3000r/min condition, constant temperature stirs 10-20min mixing;
3) in step 2) add water in the mixture that obtains, at temperature 25-40 DEG C, under stirring velocity 1500-3000r/min condition, constant temperature stirs 15-30min mixing, obtained described Flos Rosae Rugosae quintessence oil microemulsion.
Flos Rosae Rugosae quintessence oil microemulsion provided by the invention is thermodynamic stable system, has storage-stable, discharges the features such as even, and its nano level molecule makes it to be easy to realize Targeting delivery.Microemulsion is transparent or semitransparent, and particle diameter is 2nm ~ 200nm, has low-viscosity, isotropy.It also has can filtration sterilization, and storage stability is good, and preparation technology is simple, is convenient to the advantages such as suitability for industrialized production.Use Flos Rosae Rugosae quintessence oil microemulsion to replace Flos Rosae Rugosae quintessence oil can also improve the solvability of natural rose essential, improve stability, broaden application scope, make it easy to storage and transport.
Accompanying drawing explanation
Fig. 1 is the storage rate change in embodiment 1 in natural rose essential microemulsion storage.
Fig. 2 is the transmittance change in embodiment 1 in natural rose essential microemulsion storage.
Embodiment
Storage rate: steam distillation measures the total content of Flos Rosae Rugosae quintessence oil in Flos Rosae Rugosae quintessence oil micro emulsion: joined in 500mL round-bottomed flask by the Flos Rosae Rugosae quintessence oil micro emulsion of 20mL, measuring concentration is 1mgmL
-1sodium chloride solution 150mL pour in flask, shake up, carry out atmospheric steam distillation 3h, read its volume (being accurate to 0.1mL).Storage rate/%=(volume of the volume/Flos Rosae Rugosae quintessence oil micro emulsion of Flos Rosae Rugosae quintessence oil) × 100%.
Spectrophotometry micro emulsion transmittance: at a wavelength of 800 nm, measure Flos Rosae Rugosae quintessence oil micro emulsion transmittance, blank sample is emulsifying agent, the water mixture of corresponding proportion.Survey three groups of Duplicate Samples, average.
Embodiment 1
Get tween 80 (Tween80) 20g, dehydrated alcohol 10g, mix and make blending emulsifiers, add Flos Rosae Rugosae quintessence oil 5g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 15min mixing, add water 65g again, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 20min obtain Flos Rosae Rugosae quintessence oil microemulsion, this microemulsion median size 77nm, clear, good stability; Store that storage rate after 12 months is 95.1%, transmittance is 97.3%, compared with time initial with storage, there is no considerable change.
Embodiment 2
Get Brij5820g, dehydrated alcohol 10g, mixes and makes blending emulsifiers, adds Flos Rosae Rugosae quintessence oil 5g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 15min mixing, then add water 65g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 20min and obtain Flos Rosae Rugosae quintessence oil microemulsion, this microemulsion median size 63nm, clarifies bright, good stability; Store that storage rate after 12 months is 96.9%, transmittance is 98.8%, compared with time initial with storage, there is no considerable change.
Embodiment 3
Get tween 80 and each 10g of Brij58, dehydrated alcohol 10g, mixes and makes blending emulsifiers, adds Flos Rosae Rugosae quintessence oil 5g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 15min mixing, then add water 65g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 20min and obtain Flos Rosae Rugosae quintessence oil microemulsion, this microemulsion median size 35nm, clarifies bright, good stability; Store that storage rate after 12 months is 98.7%, transmittance is 99.4%, compared with time initial with storage, there is no considerable change.
Embodiment 4
Get 20g emulsifying agent CremophorRH40, dehydrated alcohol 10g, mix and make blending emulsifiers, add Flos Rosae Rugosae quintessence oil 5g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 15min mixing, add water 65g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 20min and obtain Flos Rosae Rugosae quintessence oil microemulsion, this microemulsion median size 156nm, with embodiment 1,2,3 prepare micro emulsion comparing result as shown in the table.
The change of the different embodiment microemulsions of table 1 storage rate and transmittance after 12 months
Microemulsion prepared by embodiment 4, stores that storage rate after 12 months is only 64.5%, transmittance is 60.2%, obvious decline compared with embodiment 1,2,3, poor stability.
Embodiment 5
Get 20g emulsifying agent TritonX-114, dehydrated alcohol 10g, mix and make blending emulsifiers, add Flos Rosae Rugosae quintessence oil 5g, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 15min mixing, add water 65g again, under temperature 30 DEG C, stirring velocity 3000r/min condition, stir 20min and obtain Flos Rosae Rugosae quintessence oil microemulsion, this microemulsion median size 179nm, with embodiment 1,2,3 prepare micro emulsion comparing result as shown in the table.
The change of the different embodiment microemulsions of table 2 storage rate and transmittance after 12 months
Microemulsion prepared by embodiment 5, stores that storage rate after 12 months is only 56.8%, transmittance is 50.3%, obvious decline compared with embodiment 1,2,3, poor stability.
Embodiment 6 is prepared containing the essence of Flos Rosae Rugosae quintessence oil micro emulsion
Flos Rosae Rugosae quintessence oil microemulsion 1.0%, glycyrrhiza glabra 1.0%, green tea extract 2.0%, glycerine 4.0%, vitamin C glycoside 2.0%, butyleneglycol 3.0%, carbomer receives 1.5%, ethyl Hyaluronic Acid 1.0%, complexon ii four sodium 0.25%, Phenoxyethanol 0.5%, deionized water adds to 100%.
Although the present invention with preferred embodiment openly as above; but it is also not used to limit the present invention, any person skilled in the art, without departing from the spirit and scope of the present invention; all can do various changes and modification, what therefore protection scope of the present invention should define with claims is as the criterion.
Claims (8)
1. a natural rose essential microemulsion, is characterized in that, its composition is counted with percent mass: natural rose essential 5%-10%, emulsifying agent 20%-30%, assistant for emulsifying agent 5%-10%, water 50%-70%.
2. natural rose essential microemulsion according to claim 1, is characterized in that, described emulsifying agent is selected from one in following material or its mixture: tween 80, polyoxyethylene laurel ether 58.
3. natural rose essential microemulsion according to claim 1, is characterized in that, described assistant for emulsifying agent is ethanol.
4. natural rose essential microemulsion according to claim 1, is characterized in that, be O/W type microemulsion, particle diameter is 2nm-200nm.
5., according to the arbitrary described natural rose essential microemulsion of claim 1-4, it is characterized in that, its composition is counted with percent mass: natural rose essential 5%, emulsifying agent 20%, assistant for emulsifying agent 10%, water 65%.
6. natural rose essential microemulsion according to claim 1, it is characterized in that, preparation process comprises:
1) by formula, emulsifying agent and assistant for emulsifying agent are mixed;
2) to step 1) add Flos Rosae Rugosae quintessence oil in emulsifier mixture, temperature 25-40 DEG C, constant temperature stirs 10-20min mixing under stirring velocity 1500-3000r/min condition;
3) to step 2) add water in the mixture that obtains, temperature 25-40 DEG C, constant temperature stirs 15-30min mixing, obtained Flos Rosae Rugosae quintessence oil microemulsion under stirring velocity 1500-3000r/min condition.
7. prepare a method for the arbitrary described natural rose essential microemulsion of claim 1-4, it is characterized in that, comprise the following steps:
1) by formula, emulsifying agent and assistant for emulsifying agent are mixed;
2) to step 1) add Flos Rosae Rugosae quintessence oil in emulsifier mixture, temperature 25-40 DEG C, constant temperature stirs 10-20min mixing under stirring velocity 1500-3000r/min condition;
3) to step 2) add water in the mixture that obtains, temperature 25-40 DEG C, constant temperature stirs 15-30min mixing, obtained Flos Rosae Rugosae quintessence oil microemulsion under stirring velocity 1500-3000r/min condition.
8. natural rose essential microemulsion according to claim 1 is preparing the application in makeup, beverage, medicine.
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| CN106987313A (en) * | 2017-04-26 | 2017-07-28 | 鲜活果汁工业（昆山）有限公司 | The preparation method of lemon oil microemulsion |
| CN107937134A (en) * | 2017-12-13 | 2018-04-20 | 湖北中烟工业有限责任公司 | Preparation method for the sweet orange oil Microemulsions For Use of cigarette blending |
| CN108452358A (en) * | 2018-04-02 | 2018-08-28 | 福建路合环保科技有限公司 | Multi-functional drive taste agent based on plants essential oil |
| CN108498399A (en) * | 2018-05-16 | 2018-09-07 | 杭州千岛湖天鑫有限公司 | A kind of compound botanical extract with anti-corrosion effect and its application in cosmetics anti-corrosion |
| CN109843388A (en) * | 2016-06-01 | 2019-06-04 | 香奈儿香水美妆品公司 | The fragrance of aqueous microemulsion form |
| CN110833076A (en) * | 2019-11-22 | 2020-02-25 | 贵州省油料研究所 | Rosemary essential oil microemulsion for preventing and treating plant diseases and insect pests and preparation method thereof |
| CN111887264A (en) * | 2020-07-15 | 2020-11-06 | 上海驰纺材料科技有限公司 | Natural plant essential oil microemulsion antibacterial spray and preparation method thereof |
| CN114259893A (en) * | 2021-12-13 | 2022-04-01 | 云南中烟工业有限责任公司 | Preparation method of microemulsion spice with high stability and high utilization rate and application of microemulsion spice in improving cigarette tobacco quality |
| CN115006290A (en) * | 2022-06-15 | 2022-09-06 | 广州品赫化妆品有限公司 | Plant compound essential oil nanoemulsion and preparation method and application thereof |
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| CN109843388A (en) * | 2016-06-01 | 2019-06-04 | 香奈儿香水美妆品公司 | The fragrance of aqueous microemulsion form |
| CN106987313A (en) * | 2017-04-26 | 2017-07-28 | 鲜活果汁工业（昆山）有限公司 | The preparation method of lemon oil microemulsion |
| CN107937134A (en) * | 2017-12-13 | 2018-04-20 | 湖北中烟工业有限责任公司 | Preparation method for the sweet orange oil Microemulsions For Use of cigarette blending |
| CN107937134B (en) * | 2017-12-13 | 2021-04-02 | 湖北中烟工业有限责任公司 | Preparation method of sweet orange oil microemulsion for cigarette flavoring |
| CN108452358A (en) * | 2018-04-02 | 2018-08-28 | 福建路合环保科技有限公司 | Multi-functional drive taste agent based on plants essential oil |
| CN108498399A (en) * | 2018-05-16 | 2018-09-07 | 杭州千岛湖天鑫有限公司 | A kind of compound botanical extract with anti-corrosion effect and its application in cosmetics anti-corrosion |
| CN108498399B (en) * | 2018-05-16 | 2020-11-24 | 杭州千岛湖天鑫有限公司 | Compound plant extract with antiseptic effect and application thereof in cosmetic antiseptic |
| CN110833076A (en) * | 2019-11-22 | 2020-02-25 | 贵州省油料研究所 | Rosemary essential oil microemulsion for preventing and treating plant diseases and insect pests and preparation method thereof |
| CN111887264A (en) * | 2020-07-15 | 2020-11-06 | 上海驰纺材料科技有限公司 | Natural plant essential oil microemulsion antibacterial spray and preparation method thereof |
| CN114259893A (en) * | 2021-12-13 | 2022-04-01 | 云南中烟工业有限责任公司 | Preparation method of microemulsion spice with high stability and high utilization rate and application of microemulsion spice in improving cigarette tobacco quality |
| CN115006290A (en) * | 2022-06-15 | 2022-09-06 | 广州品赫化妆品有限公司 | Plant compound essential oil nanoemulsion and preparation method and application thereof |
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