CN105036806A - Manufacturing method of imitation Sanpu mountain gneissic granite stone line ceramic - Google Patents
Manufacturing method of imitation Sanpu mountain gneissic granite stone line ceramic Download PDFInfo
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- CN105036806A CN105036806A CN201510438607.2A CN201510438607A CN105036806A CN 105036806 A CN105036806 A CN 105036806A CN 201510438607 A CN201510438607 A CN 201510438607A CN 105036806 A CN105036806 A CN 105036806A
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- stone
- sanpu
- gneissic
- ceramic
- oxide
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- 239000000919 ceramic Substances 0.000 title claims abstract description 43
- 239000004575 stone Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000010438 granite Substances 0.000 title abstract 7
- 238000000034 method Methods 0.000 claims abstract description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 10
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 9
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 8
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 8
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 4
- 241000218225 Trema Species 0.000 claims description 12
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 12
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 210000003298 dental enamel Anatomy 0.000 abstract description 12
- 230000000007 visual effect Effects 0.000 abstract description 5
- 238000009826 distribution Methods 0.000 abstract description 4
- 238000010304 firing Methods 0.000 abstract 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 230000009466 transformation Effects 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- IUYLTEAJCNAMJK-UHFFFAOYSA-N cobalt(2+);oxygen(2-) Chemical compound [O-2].[Co+2] IUYLTEAJCNAMJK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 238000009377 nuclear transmutation Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 241000207961 Sesamum Species 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 210000001161 mammalian embryo Anatomy 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 241001466460 Alveolata Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
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- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a manufacturing method of imitation Sanpu mountain gneissic granite stone line ceramic. The method is easy to operate, and during the firing process, kiln transformation occurs on an enamel layer to form the imitation Sanpu mountain gneissic granite stone line ceramic. The method comprises the steps that chromophore materials containing stannic dioxide, zirconium dioxide, nickel oxide, cobaltous oxide, chromic oxide, ferric oxide, manganese dioxide and antimony oxide are prepared, glaze slip with 45-52 wt% of total solid content is prepared by being mixed with transparent basic glaze, and firing is conducted on a glazed ceramic body to obtain an imitation Sanpu mountian gneissic granite stone line ceramic product. According to the manufacturing method of the imitation Sanpu mountian gneissic granite stone line ceramic, the kiln transformation occurs on the enamel layer during the firing process, color spots with colors such as ash black and white appear on the enamel layer of a fired ceramic product, the shade and the distribution state of the color spots are similar to Sanpu mountain gneissic granite, and the visual effect of the appearance of the Sanpu mountain gneissic granite is achieved. Glazing in one time is adopted, the labor cost is greatly reduced, and the production efficiency is improved.
Description
Technical field
The present invention relates to the manufacture method of pottery, particularly relate to the manufacture method of the ceramic with bag appearance effect.
Background technology
The ceramic with stone textures effect, owing to having special appreciation effect, is subject to the favor of human consumer, has the wide market space as vase, ornaments, apparatus or collectibles.Therefore, it becomes a developing direction of decorating ceramic products.
Chinese invention patent application prospectus CN1218020A proposes a kind of method forming marble pattern on pottery, first one high-density is provided, viscosity is little, the ground-coat enamel of high-consistency, then proportion is little, viscosity is large, the cover-coat enamel of low denseness is slowly poured in ground-coat enamel, due to the drop of two kinds of glaze proportions and viscosity, cover-coat enamel does not decompose immediately in ground-coat enamel, and float on the top layer of ground-coat enamel, then paddling glaze paint makes it produce marble grain, then biscuiting embryo part is dipped in glaze to roll and turns around, muffle painting is made to be overlying on embryo, fire in high temperature after completing glazing program and namely produce marble grain.The method operation is difficult to control, and reproducibility is poor, and yield rate is low, and is difficult to form the natural color spot that can not form stone.
The pottery disclosed in CN1241497A, CN1424190A, CN1546294A, CN1727147A, CN1887558A and CN101585210A with bag top layer adopts mechanical means that one or more mill bases are dispersed in biscuit of ceramics surface, burns till rear ceramic surface display plurality of color pulp color to embody stone speckle.But these method complicated operations, and due to speckle too regular, imitative stone effect is poor.
CN1923747A thinks, is wrapped in by pigment in frit, can form stone imitation pattern glazed ceramic after burning till, but due to pigment patch too small, occur stone material pattern and natural stone gap larger.
CN101066890A thinks, ceramic paste preforms is executed one deck ground-coat enamel, prepare ground-coat enamel base, pick containing alveolate color glaze by ground-coat enamel base surface, form marbling because color glaze slurry bubble vanishes, this method applicability can be strong, the ceramic product of type complexity can be applicable to, but color spot is single, surface of ceramic products planeness is poor, far away with natural stone textures gap.
In the association request CN2010105902776 of applicant, propose a kind ofly occur transmutation at sintering procedure glaze layer and form the process for preparing ceramic of Indian red bag, preparation is containing tindioxide, zirconium dioxide, first glaze slip of nickel oxide and cobalt oxide, containing cobalt oxide, nickel oxide, chromium sesquioxide, second glaze slip of ferric oxide and Manganse Dioxide, containing tindioxide, zirconium dioxide, 3rd glaze slip of nickel oxide and weisspiessglanz, ceramic body executes the first glaze slip successively, second glaze slip and the 3rd glaze slip, fire rear ceramic glaze layer and occur transmutation, the color spot such as grey black and white is there is at glaze layer, the color spot depth is close with sesame stone with distribution situation, there is sesame stone apparent visual effect.But production process needs to configure multiple glaze slip, repeatedly glazing, effort of taking a lot of work, cost also improves thus.
Summary of the invention
The object of the present invention is to provide a kind of operation simple and easy, occur transmutation at sintering procedure glaze layer and form the process for preparing ceramic of Sang Pu Leaf of Diels Trema stone bag.
The method comprises the following steps:
A. preparation is by weight percentage containing tindioxide 7.7-9.1%, zirconium dioxide 52.6-55.4%, nickel oxide 5.1-7.4%, cobalt oxide 5.2-6.8%, chromium sesquioxide 4.2-4.8%, ferric oxide 5.4-6.6%, Manganse Dioxide 11.4-12.6%, the color base material of weisspiessglanz 1.8-2.2%, add water grinding;
B. in the ratio of color base material and transparent parent glaze weight ratio 20 ︰ 100 the color base material after grinding mixed with transparent parent glaze and again grind, add water and be made into the glaze slip of total solid content 45-52wt%;
C. on ceramic body, above-mentioned glaze slip is executed, glazed thickness 0.03-0.12mm after dry;
D. the ceramic body after glazing is fired: intensification per hour 180-200 DEG C 200-800 DEG C time; intensification per hour 90-100 DEG C when 800-1100 DEG C; intensification per hour 50-60 DEG C when 1100-1280 DEG C; 0.5-1 hour is incubated when arriving 1280 ~ 1290 DEG C; cease fire and lower the temperature, after cooling, ceramic body becomes imitative Sang Pu Leaf of Diels Trema stone stone-texture ceramic goods.
In the present invention, transparent parent glaze is the normal transparent glaze used in ceramic industry, or becomes frit.
In step, the weight percentage of color base material is tindioxide 8.4%, zirconium dioxide 54.6%, nickel oxide 6.2%, cobalt oxide 6.1%, chromium sesquioxide 4.5%, ferric oxide 6.2%, Manganse Dioxide 12%, weisspiessglanz 2%.
In step C, sintering procedure is when temperature is 800-900 DEG C, reduction mode is adopted to fire, i.e. increasing fuel consumption but do not increase air flow quantity, in kiln, fuel burns under anoxic condition, in addition other temperature range adopts mode of oxidizing to fire, i.e. fuel perfect combustion under the sufficient state of oxygen.
There is transmutation at sintering process glaze layer in the present invention, the ceramic after burning till occurs the color spot such as grey black and white at glaze layer, and the color spot depth is close with Sang Pu Leaf of Diels Trema stone with distribution situation, has the apparent visual effect of Sang Pu Leaf of Diels Trema stone.Compared with CN2010105902776 patent, adopt a glazing, greatly save cost of labor, enhance productivity.
Accompanying drawing explanation
Fig. 1 is the ceramic surface appearance effects figure that the method for embodiment 1 makes.
Fig. 2 is the local surfaces appearance effect figure of Fig. 1 ceramic.
Embodiment
Embodiment 1
By tindioxide 8.4 grams, zirconium dioxide 54.6 grams, nickel oxide 6.2 grams, cobalt oxide 6.1 grams, chromium sesquioxide 4.5 grams, ferric oxide 6.2 grams, Manganse Dioxide 12 grams, weisspiessglanz 2 grams mixing, add 50 grams of water grindings, adding 500 grams of transparent parent glazes, adding water 300 grams and continue grinding, add water and be made into the glaze slip of solid content 48-50wt%
Dried ceramic body is dipped in above-mentioned glaze slip, takes out dry, control dry after glazed thickness 0.03-0.12mm, as defective, can glazing be once again.Also spray pattern glazing can be adopted.
Ceramic body after glazing is fired: slowly heat when starting, make the moisture slow evaporation in ceramic body, ceramic body is prevented to be out of shape, heat and can be elevated to 80 DEG C after 1 hour, add high flame gradually afterwards, 200 DEG C are elevated to after 1 hour, intensification per hour 200 DEG C between 200-800 DEG C, after temperature is elevated to 800 DEG C, between 800-900 DEG C, reduction mode is adopted to fire, i.e. increasing fuel consumption but do not increase air flow quantity, fuel incomplete combustion under anoxic condition in kiln, after 1 hour, temperature is elevated to 900 DEG C, increase air flow quantity afterwards, complete combustion of fuel in kiln, intensification per hour 100 DEG C between 900-1100 DEG C, intensification per hour 60 DEG C between 1100-1280 DEG C, 0.5 hour is incubated when arriving 1290 DEG C, cease fire and lower the temperature, kiln is opened after cool to room temperature, ceramic body becomes imitative Sang Pu Leaf of Diels Trema stone stone-texture ceramic goods.
This ceramic apparent visual effect as depicted in figs. 1 and 2, Fig. 2 is the local surfaces outside drawing of chi 1 ︰ 1 in proportion, from Fig. 1 and Fig. 2, the multiple color spot such as grey black and white is there is at glaze layer, the color spot depth is close with Sang Pu Leaf of Diels Trema stone with distribution situation, has the apparent visual effect of clear and definite Sang Pu Leaf of Diels Trema stone.
Claims (3)
1. a manufacture method for imitative Sang Pu Leaf of Diels Trema stone stone-texture ceramic, is characterized in that, comprise the following steps:
A. preparation is by weight percentage containing tindioxide 7.7-9.1%, zirconium dioxide 52.6-55.4%, nickel oxide 5.1-7.4%, cobalt oxide 5.2-6.8%, chromium sesquioxide 4.2-4.8%, ferric oxide 5.4-6.6%, Manganse Dioxide 11.4-12.6%, the color base material of weisspiessglanz 1.8-2.2%, add water grinding;
B. in the ratio of color base material and transparent parent glaze weight ratio 20 ︰ 100 the color base material after grinding mixed with transparent parent glaze and again grind, add water and be made into the glaze slip of total solid content 45-52wt%;
C. on ceramic body, above-mentioned glaze slip is executed, glazed thickness 0.03-0.12mm after dry;
D. the ceramic body after glazing is fired: intensification per hour 180-200 DEG C 200-800 DEG C time; intensification per hour 90-100 DEG C when 800-1100 DEG C; intensification per hour 50-60 DEG C when 1100-1280 DEG C; 0.5-1 hour is incubated when arriving 1280 ~ 1290 DEG C; cease fire and lower the temperature, after cooling, ceramic body becomes imitative Sang Pu Leaf of Diels Trema stone stone-texture ceramic goods.
2. imitate the manufacture method of Sang Pu Leaf of Diels Trema stone stone-texture ceramic according to claim 1, it is characterized in that, in step, the weight percentage of color base material is tindioxide 8.4%, zirconium dioxide 54.6%, nickel oxide 6.2%, cobalt oxide 6.1%, chromium sesquioxide 4.5%, ferric oxide 6.2%, Manganse Dioxide 12%, weisspiessglanz 2%.
3. imitate the manufacture method of Sang Pu Leaf of Diels Trema stone stone-texture ceramic according to claim 1, it is characterized in that, in step D, sintering procedure, when temperature is 800-900 DEG C, adopts reduction mode to fire, and other temperature range in addition adopts mode of oxidizing to fire.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510438607.2A CN105036806B (en) | 2015-07-24 | 2015-07-24 | A kind of manufacture method of imitative Sang Pu Folium Trematis Dielsianae stone stone-texture ceramic |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510438607.2A CN105036806B (en) | 2015-07-24 | 2015-07-24 | A kind of manufacture method of imitative Sang Pu Folium Trematis Dielsianae stone stone-texture ceramic |
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| Publication Number | Publication Date |
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| CN105036806A true CN105036806A (en) | 2015-11-11 |
| CN105036806B CN105036806B (en) | 2017-03-15 |
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| CN201510438607.2A Active CN105036806B (en) | 2015-07-24 | 2015-07-24 | A kind of manufacture method of imitative Sang Pu Folium Trematis Dielsianae stone stone-texture ceramic |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102001867A (en) * | 2010-12-07 | 2011-04-06 | 陈晓晖 | Manufacturing method of imitated sesame stone ceramic |
| CN102557760A (en) * | 2012-03-15 | 2012-07-11 | 广东高微晶科技有限公司 | Marble-like glass ceramic composite board and production process thereof |
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2015
- 2015-07-24 CN CN201510438607.2A patent/CN105036806B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102001867A (en) * | 2010-12-07 | 2011-04-06 | 陈晓晖 | Manufacturing method of imitated sesame stone ceramic |
| CN102557760A (en) * | 2012-03-15 | 2012-07-11 | 广东高微晶科技有限公司 | Marble-like glass ceramic composite board and production process thereof |
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| CN105036806B (en) | 2017-03-15 |
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Effective date of registration: 20160706 Address after: 515646 Guangdong Province, Chaozhou city Chaoan District Feng Tang Shuang Gang Tang Bian Applicant after: Chaozhou porcelain industry Co., Ltd. Address before: 515064 Guangdong city of Chaozhou province Chaoan County Feng Tang Zhen Shuang Gang Lu Tang Bian porcelain porcelain industrial park Chaozhou City porcelain industry Co. Ltd. Applicant before: Chen Xiaohui |
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