CN102557760A - Marble-like glass ceramic composite board and production process thereof - Google Patents

Marble-like glass ceramic composite board and production process thereof Download PDF

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Publication number
CN102557760A
CN102557760A CN2012100681672A CN201210068167A CN102557760A CN 102557760 A CN102557760 A CN 102557760A CN 2012100681672 A CN2012100681672 A CN 2012100681672A CN 201210068167 A CN201210068167 A CN 201210068167A CN 102557760 A CN102557760 A CN 102557760A
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CN
China
Prior art keywords
ceramic composite
glass ceramic
composite boards
parian
ground
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Pending
Application number
CN2012100681672A
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Chinese (zh)
Inventor
余罗群
吴启章
邹利敏
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GUANGDONG HIGH CRYTALLITE TECHNOLOGY Co Ltd
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GUANGDONG HIGH CRYTALLITE TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG HIGH CRYTALLITE TECHNOLOGY Co Ltd filed Critical GUANGDONG HIGH CRYTALLITE TECHNOLOGY Co Ltd
Priority to CN2012100681672A priority Critical patent/CN102557760A/en
Publication of CN102557760A publication Critical patent/CN102557760A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a marble-like glass ceramic composite board and a production process thereof. The production process is characterized by comprising the following steps of: a, preparing the following components by weight percent: 1.5%-2% of ground coat, 0.1%-1.0% of fancy glaze, 84%-86% of blank and 10%-12% of transparent glass frit; b, feeding the blank into a press machine for molding, and then drying to prepare a dry blank; c, coating the ground coat on the dry blank to form a ground coat layer; d, printing the fancy glaze on the ground coat layer to obtain a fancy glaze layer; e, carrying out first firing; f, spreading the transparent glass frit on the upper line of a semi-finished product obtained by the first firing; g, carrying out second firing so that the glass frit is molten, and cooling to obtain a glass ceramic composite board; h, polishing; and i, edging to form a finished product, packing and putting in storage. The marble-like glass ceramic composite board has fine grain similar to that of natural marble and simultaneously has the hierarchy feel and transparent feel of the natural marble, thus the marble-like glass ceramic composite boar has good popularization value.

Description

A kind of parian glass ceramic composite boards and production technique thereof
Technical field
The present invention relates to the ceramic technology field, relate to a kind of parian glass ceramic composite boards and production technique thereof in particular.
Background technology
Glass ceramic composite boards is called glass-ceramic clad plate again, is the high-grade green building finishing material of just successfully developing and introducing to the market in a large number in the recent period.At present; The existing glass ceramic clad plate comprises Watch glass layer 1 and bottom commentaries on classics base layer 2; As shown in Figure 1, the product of imitating natural marble material is less, and most of white or coloured crystallization frit or multiple crystallization frit of adopting combines distributing technique to decorate; Fidelity to stone material is not high, does not have fine grain and the gradation sense and the exquisitely carved sense of natural marble material yet.
Summary of the invention
The object of the invention is exactly that provide for the deficiency that solves prior art a kind of possesses the gradation sense of lithotome and the parian glass ceramic composite boards of exquisitely carved sense simultaneously.
Another object of the present invention provides a kind of production technique of parian glass ceramic composite boards, and the glass ceramic composite boards that utilizes this technology to make possesses the fine grain of approximate natural marble material, possesses the gradation sense and the exquisitely carved sense of lithotome simultaneously; Pattern is between glass coating and the ceramic layer, can be protected, and avoids direct wearing and tearing; Keep the integrity of product pattern and sense naturally for a long time; Prolong the work-ing life of product, and because of the effect of covering of pattern, product is more attractive in appearance.
The present invention adopts following technical solution to realize above-mentioned purpose: a kind of parian glass ceramic composite boards; It is characterized in that; It comprises glass coating, fancy glaze layer, cover coat and the adobe layer that distributes successively from top to bottom, and the thickness of fancy glaze layer is 0.1-0.3mm.
A kind of production technique of parian glass ceramic composite boards is characterized in that it comprises the steps:
A, preparation ground-coat enamel, fancy glaze, blank and transparent glass frit, more than each component (by weight percentage) proportioning: ground-coat enamel is 1.5%~2%, and fancy glaze is 0.1%~1.0%, and blank is 84%~86%, and the transparent glass frit is 10%~12%;
B, blank is sent to press-molding after, drying makes dry body;
C, dry body are executed ground-coat enamel, form ground glaze layer;
D, on ground glaze layer printing glaze, obtain the fancy glaze layer;
E, the first time burn till;
F, the work in-process after burning till are for the first time reached the standard grade to spread and are spilt the transparent glass frit;
G, the second time burn till, and make glass frit melt, and cooling obtains glass ceramic composite boards;
H, polishing;
I, edging form finished product, packaging and warehousing.
As further specifying of such scheme, in said process step a, said transparent glass frit is 14~200 orders.
Preferably, in said process step c, dry body is executed ground-coat enamel, and ground-coat enamel proportion is 1.72~1.90 g/m3, glaze amount 560~660g/m 2
Preferably, in said process step d, through any mode printing glaze in silk screen printing, roller printing and the spray ink Printing.
Preferably, in said process step e, burn till through 1200 ℃~1260 ℃ high temperature.
Preferably, in said process step f, spill the transparent glass frit through the form shop of dry type cloth.
Preferably, in said process step g, firing temperature is 1090 ℃~1125 ℃.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The production technique of the parian glass ceramic composite boards that the present invention adopts compared with prior art, through any mode printing glaze in silk screen printing, roller printing or the spray ink Printing, the glass ceramic composite boards that makes possesses the fine grain of approximate natural marble material; Possess the gradation sense and the exquisitely carved sense of lithotome simultaneously, pattern is between glass coating and the ceramic layer, can be protected; Avoid direct wearing and tearing; Keep the integrity of product pattern and sense naturally for a long time, the work-ing life of prolongation product, and because of the effect of covering of pattern; Make glass coating can reach the visual no bubble apart from 0.8m, product is more attractive in appearance.
Description of drawings
Fig. 1 is the structural representation of known glass ceramic composite boards;
Fig. 2 is a structural representation of the present invention.
Description of reference numerals: 1, glass coating 2, adobe layer 3, glass coating 4, fancy glaze layer 5, cover coat 6, adobe layer.
Embodiment
For those skilled in the art can understand technical scheme provided by the present invention better, set forth below in conjunction with specific embodiment.
As shown in Figure 2, a kind of parian glass ceramic composite boards of the present invention comprises the glass coating 3, fancy glaze layer 4, cover coat 5 and the adobe layer 6 that distribute successively from top to bottom, and generally speaking, the thickness of fancy glaze layer is 0.1-0.3mm.
The production technique of parian glass ceramic composite boards provided by the invention comprises the steps:
The production technique of parian glass ceramic composite boards comprises the steps:
(1) preparation ground-coat enamel, fancy glaze, blank and transparent glass frit;
(2) blank is sent to press-molding after, drying makes dry body;
(3) dry body is executed ground-coat enamel, and ground-coat enamel proportion is 1.72~1.90 g/m 3, glaze amount 560~660g/m 2
(4) through any mode printing glaze in silk screen printing, roller printing or the spray ink Printing;
(5) going into kiln burns till through 1200 ℃~1260 ℃ high temperature for the first time;
(6) work in-process that burn till through the first time are reached the standard grade to spread and are spilt the transparent glass frit;
(7) go into kiln and burn till through 1090 ℃~1125 ℃ second time, make glass frit melt, cooling obtains glass ceramic composite boards;
(8) polishing;
(9) edging forms finished product, packaging and warehousing.
Parian glass ceramic composite boards provided by the invention comprises ground-coat enamel, fancy glaze, blank and transparent glass frit, and ground-coat enamel is 1.5%~2%; Fancy glaze is 0.1%~1.0%; Said blank is 81%~83%; Said transparent glass frit is 15%~17%.More than each component be weight proportion.
Embodiment 1
The prescription of the parian glass ceramic composite boards that present embodiment provides is following:
The component of blank is shown in table one:
Table one
Component Potassium felspar sand Albite Kaolin Quartzy Burn talcum
Content 40% 30% 20% 5% 5%
More than each component be weight proportion.The weight proportion of the moisture content of blank is 6%.
The component of ground-coat enamel is shown in table two:
Table two
Component Potassium felspar sand Albite Calcined kaolin Quartzy Burn talcum Wollastonite Zirconium silicate
Content 30% 20% 8% 12% 6% 14% 10%
More than each component be weight proportion.
The component of fancy glaze is shown in table three:
Table three
More than each component be weight proportion.
The component of transparent glass frit is shown in table four:
Table four
Component Silicon-dioxide Aluminum oxide Quicklime Sodium oxide, potassium oxide, Lithium Oxide 98min, boron oxide sum Other
Content 67% 13% 5% 8% 7%
More than each component be weight proportion.
Embodiment 2
The prescription of the parian glass ceramic composite boards that present embodiment provides is following:
The component of blank is shown in table five:
Table five
Component Potassium felspar sand Albite Kaolin Quartzy Burn talcum
Content 45% 25% 22% 4% 4%
More than each component be weight proportion.The weight proportion of the moisture content of blank is 6%.
The component of ground-coat enamel is shown in table six:
Table six
More than each component be weight proportion.
The component of fancy glaze is shown in table seven:
Table seven
More than each component be weight proportion.
The component of transparent glass frit is shown in table eight:
Table eight
Component Silicon-dioxide Aluminum oxide Quicklime Sodium oxide, potassium oxide, Lithium Oxide 98min, boron oxide sum Other
Content 58% 11% 4% 16% 11%
More than each component be weight proportion.
Embodiment 3
The prescription of the parian glass ceramic composite boards that present embodiment provides is following:
The component of blank is shown in table nine:
Table nine
Component Potassium felspar sand Albite Kaolin Quartzy Burn talcum
Content 35% 30% 25% 6% 4%
More than each component be weight proportion.The weight proportion of the moisture content of blank is 6%.
The component of ground-coat enamel is shown in table ten:
Table ten
More than each component be weight proportion.
The component of fancy glaze is shown in table ten one:
Table ten one
More than each component be weight proportion.
The component of transparent glass frit is shown in table ten two:
Table ten two
Component Silicon-dioxide Aluminum oxide Quicklime Sodium oxide, potassium oxide, Lithium Oxide 98min sum Boron oxide Other
Content 62% 10% 5% 10% 8% 5%
More than each component be weight proportion.
Embodiment 4
The prescription of the parian glass ceramic composite boards that present embodiment provides is following:
The component of blank is shown in table ten three:
Table ten three
Component Potassium felspar sand Albite Kaolin Quartzy Burn talcum
Content 35% 35% 20% 5% 5%
More than each component be weight proportion.The weight proportion of the moisture content of blank is 6%.
The component of ground-coat enamel is shown in table ten four:
Table ten four
More than each component be weight proportion.
The component of fancy glaze is shown in table ten five:
Table ten five
More than each component be weight proportion.
The component of transparent glass frit is shown in table ten six:
Table ten six
Component Silicon-dioxide Aluminum oxide Quicklime Sodium oxide, potassium oxide, Lithium Oxide 98min sum Boron oxide Other
Content 58% 8% 5% 8% 11% 10%
More than each component be weight proportion.
Terepthaloyl moietie among above-mentioned four embodiment in the fancy glaze prescription can substitute with glycerine.
The production technique of parian glass ceramic composite boards provided by the present invention compared with prior art, through any mode printing glaze in silk screen printing, roller printing or the spray ink Printing, the glass ceramic composite boards that makes possesses the fine grain of approximate natural marble material; Possess the gradation sense and the exquisitely carved sense of lithotome simultaneously, pattern makes product color abundant through the refraction action of the thick glass-ceramic layer of 2~3mm and the specular reflection effect on sytull top layer; Decorative pattern is natural and tripping, has certain stereoeffect concurrently, and pattern is between glass coating and the ceramic layer; Can be protected, avoid direct wearing and tearing, keep the integrity of product pattern and sense naturally for a long time; Prolong the work-ing life of product; And because of the effect of covering of pattern, make glass coating can reach the visual no bubble apart from 0.8m, product is more attractive in appearance.
Above-described only is preferred implementation of the present invention, should be pointed out that for the person of ordinary skill of the art, under the prerequisite that does not break away from the invention design, can also make some distortion and improvement, and these all belong to protection scope of the present invention.

Claims (9)

1. a parian glass ceramic composite boards is characterized in that, it comprises glass coating, fancy glaze layer, cover coat and the adobe layer that distributes successively from top to bottom.
2. a kind of parian glass ceramic composite boards according to claim 1 is characterized in that the thickness of said fancy glaze layer is 0.1-0.3mm.
3. the production technique of a parian glass ceramic composite boards is characterized in that, it comprises the steps:
A, preparation ground-coat enamel, fancy glaze, blank and transparent glass frit, more than each component (by weight percentage) proportioning: ground-coat enamel is 1.5%~2%, and fancy glaze is 0.1%~1.0%, and blank is 84%~86%, and the transparent glass frit is 10%~12%;
B, blank is sent to press-molding after, drying makes dry body;
C, dry body are executed ground-coat enamel, form ground glaze layer;
D, on ground glaze layer printing glaze, obtain the fancy glaze layer;
E, the first time burn till;
F, the work in-process after burning till are for the first time reached the standard grade to spread and are spilt the transparent glass frit;
G, the second time burn till, and make glass frit melt, and cooling obtains glass ceramic composite boards;
H, polishing;
I, edging form finished product, packaging and warehousing.
4. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step a, said transparent glass frit is 14~200 orders.
5. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step c, dry body is executed ground-coat enamel, and ground-coat enamel proportion is 1.72~1.90 g/m3, glaze amount 560~660g/m 2
6. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step d, through any mode printing glaze in silk screen printing, roller printing and the spray ink Printing.
7. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step e, burns till through 1200 ℃~1260 ℃ high temperature.
8. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step f, spills the transparent glass frit through the form shop of dry type cloth.
9. the production technique of parian glass ceramic composite boards according to claim 3 is characterized in that, in said process step g, firing temperature is 1090 ℃~1125 ℃.
CN2012100681672A 2012-03-15 2012-03-15 Marble-like glass ceramic composite board and production process thereof Pending CN102557760A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102775074A (en) * 2012-08-13 2012-11-14 广东金牌陶瓷有限公司 Method for producing microcrystal glass ceramics composite board
CN102838386A (en) * 2012-09-13 2012-12-26 广东高微晶科技有限公司 Manufacturing method of glass-ceramic composite plate
CN103342546A (en) * 2013-07-05 2013-10-09 广东博华陶瓷有限公司 Production method of ceramic tile
CN103770562A (en) * 2012-10-21 2014-05-07 罗祖敏 Ceramic surface simulation natural treatment process
CN104760130A (en) * 2015-04-16 2015-07-08 佛山市简一陶瓷有限公司 Ceramic tile material distribution and printing synchronous control system
CN105036806A (en) * 2015-07-24 2015-11-11 陈晓晖 Manufacturing method of imitation Sanpu mountain gneissic granite stone line ceramic
CN105669036A (en) * 2016-01-20 2016-06-15 广西丛欣实业有限公司 Multilayer colored crystallized glass ceramic tile
CN105731818A (en) * 2016-01-20 2016-07-06 广西丛欣实业有限公司 Layered microlite ceramic tile
CN108238783A (en) * 2016-12-27 2018-07-03 中磊企业集团装饰有限公司 A kind of production technology of artificial marble ceramic glazed thin plate
CN110744425A (en) * 2019-09-27 2020-02-04 湖南怀化永久轻建屋面科技开发有限公司 Polishing device for ceramic-like composite board and processing technology thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654378A (en) * 2008-08-19 2010-02-24 郑水泉 Ceramic glaze pattern-glazed brick and production method thereof
CN101691312A (en) * 2009-09-29 2010-04-07 河源万峰陶瓷有限公司 Technology for producing glass ceramic composite boards
CN101993255A (en) * 2010-09-17 2011-03-30 霍镰泉 Process for producing artificial marble ceramic tiles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101654378A (en) * 2008-08-19 2010-02-24 郑水泉 Ceramic glaze pattern-glazed brick and production method thereof
CN101691312A (en) * 2009-09-29 2010-04-07 河源万峰陶瓷有限公司 Technology for producing glass ceramic composite boards
CN101993255A (en) * 2010-09-17 2011-03-30 霍镰泉 Process for producing artificial marble ceramic tiles

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102775074A (en) * 2012-08-13 2012-11-14 广东金牌陶瓷有限公司 Method for producing microcrystal glass ceramics composite board
CN102838386A (en) * 2012-09-13 2012-12-26 广东高微晶科技有限公司 Manufacturing method of glass-ceramic composite plate
CN102838386B (en) * 2012-09-13 2014-03-26 广东高微晶科技有限公司 Manufacturing method of glass-ceramic composite plate
CN103770562A (en) * 2012-10-21 2014-05-07 罗祖敏 Ceramic surface simulation natural treatment process
CN103342546A (en) * 2013-07-05 2013-10-09 广东博华陶瓷有限公司 Production method of ceramic tile
CN104760130A (en) * 2015-04-16 2015-07-08 佛山市简一陶瓷有限公司 Ceramic tile material distribution and printing synchronous control system
CN104760130B (en) * 2015-04-16 2017-04-12 佛山市简一陶瓷有限公司 Ceramic tile material distribution and printing synchronous control system
CN105036806A (en) * 2015-07-24 2015-11-11 陈晓晖 Manufacturing method of imitation Sanpu mountain gneissic granite stone line ceramic
CN105669036A (en) * 2016-01-20 2016-06-15 广西丛欣实业有限公司 Multilayer colored crystallized glass ceramic tile
CN105731818A (en) * 2016-01-20 2016-07-06 广西丛欣实业有限公司 Layered microlite ceramic tile
CN108238783A (en) * 2016-12-27 2018-07-03 中磊企业集团装饰有限公司 A kind of production technology of artificial marble ceramic glazed thin plate
CN110744425A (en) * 2019-09-27 2020-02-04 湖南怀化永久轻建屋面科技开发有限公司 Polishing device for ceramic-like composite board and processing technology thereof

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