CN105034467B - A kind of high-elastic fire-retardant warming flaky material of gluing flocking formula and its manufacture method - Google Patents
A kind of high-elastic fire-retardant warming flaky material of gluing flocking formula and its manufacture method Download PDFInfo
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- CN105034467B CN105034467B CN201510251649.5A CN201510251649A CN105034467B CN 105034467 B CN105034467 B CN 105034467B CN 201510251649 A CN201510251649 A CN 201510251649A CN 105034467 B CN105034467 B CN 105034467B
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- 239000000463 material Substances 0.000 title claims abstract description 58
- 238000010792 warming Methods 0.000 title claims abstract description 43
- 238000004026 adhesive bonding Methods 0.000 title claims abstract description 40
- 239000003063 flame retardant Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 269
- 239000000843 powder Substances 0.000 claims abstract description 126
- 239000011230 binding agent Substances 0.000 claims abstract description 101
- 238000001035 drying Methods 0.000 claims abstract description 94
- 210000004209 hair Anatomy 0.000 claims abstract description 70
- 239000011812 mixed powder Substances 0.000 claims abstract description 46
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 238000004804 winding Methods 0.000 claims abstract description 12
- 238000010410 dusting Methods 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims description 39
- 230000001070 adhesive effect Effects 0.000 claims description 39
- 230000005684 electric field Effects 0.000 claims description 11
- 230000008020 evaporation Effects 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 230000006855 networking Effects 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 210000001520 comb Anatomy 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000004753 textile Substances 0.000 abstract description 2
- 239000011810 insulating material Substances 0.000 description 11
- 238000009413 insulation Methods 0.000 description 11
- 230000003068 static effect Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 230000005686 electrostatic field Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000007664 blowing Methods 0.000 description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000005685 electric field effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920000592 inorganic polymer Polymers 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 229940074391 gallic acid Drugs 0.000 description 2
- 235000004515 gallic acid Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000001467 acupuncture Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003471 anti-radiation Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/025—Particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
- B32B2264/0264—Polyamide particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
- B32B2264/0278—Polyester particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Nonwoven Fabrics (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula and its manufacture method, belong to textile technology field.The upper strata fibre web of the high-elastic fire-retardant warming flaky material is with lower floor's fibre web inside sprinkled with thermal fusing powder and the mixed powder of fireproof powder, binder film, lower binder film is respectively coated with the opposite surface of lower floor's fibre web in upper strata fibre web, fine hair is clipped between upper strata fibre web and lower floor's fibre web, the two ends of fine hair are inserted among binder film, lower binder film respectively, are fixedly arranged at the surface of upper strata fibre web and lower floor's fibre web.Its preparation method comprises the following steps（1）It is prepared by fibre web,（2）The preparation of mixed powder,（3）Dusting,（4）Drying,（5）Gluing,（6）Electrostatic spinning,（7）Drying,（8）Inhale suede,（9）Fibre web is combined,（10）Drying,（11）Winding.Compared with prior art, warming flaky material produced by the present invention has anti-flaming function, elastic good, warmth retention property good.
Description
Technical field
The present invention relates to a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula and its manufacture method, belong to weaving neck
Domain.
Background technology
In past life, people are used with cotton, fiber crops, silk, hair and common terylene, polyamide fibre, acrylic fibers and staple fibre
Traditional heat insulating material Deng preparation is as heat insulating material, in these heat insulating materials, silk and wool warmth retention property preferably, but fiber
Easy breed bacteria, intolerant to damaging by worms, and silk is expensive, and wool fiber has peculiar smell, forming degree poor, by multiple working procedure plus
Cashmere price after work is more expensive, is limited to for many years using scope.With the development of living standard and science and technology, Ren Menkai
Beginning will just develop new heat insulating material, occur in that the chemical fibre insulation flocculus based on terylene, polypropylene fibre and the acrylic fibers, such as glue spraying
The far infrareds such as cotton, acupuncture cotton, space wadding, hot melting wool, melt-blown far infrared cotton, ultra-fine hot melting wool, down-like cotton.The master of heat transfer
Form is wanted to have heat transfer, three kinds of modes of heat radiation and thermal convection current.Material characteristicses and internal structure determine its heat under normal circumstances
The speed of conduction of velocity, material internal structure and outer shape determine the quality of its heat radiation and antiradiation performance, material shape
Its remains stationary air of shape and structures shape and the ability for preventing air flow.Traditional heat insulating material mainly passes through increase
Thickness and density carry out between increased fiber still air layer to improve thermal property.The thickness of usual material is bigger, density is smaller,
The warmth retention property of material is bigger, but if the density of material is too small, when causing the air therein to produce convection current, heat-insulating property on the contrary under
Drop, for clothes heat insulating material, thickness crosses conference and causes the volume ratio of clothes more too fat to move, is not easy to motion and lacks beautiful
Sense.Therefore, the exploitation of novel heat-preserving material becomes the main flow of heat insulating material research with research.The Novel heat-preservation developed in recent years
Material also has far-infrared warm material, sunlight heat accumulation thermal material, medium phase-changing and temperature-regulating material etc., and this kind of heat insulating material is not only abided by
Follow traditional heat-insulation warm keeping principle, and external heat can for example be absorbed by some other forms, store and to people
Body transmits to produce fuel factor, or solar energy, electric energy and chemical energy etc. is changed into heat energy to reach the purpose of heat-insulation warm keeping.
For the more excellent insulation flocculus of processability, static flocking technology is also introduced into the preparation of insulation flocculus.Utilize
Static flocking technology is combined with traditional insulation flocculus manufacture method and prepares the existing document report of Novel heat-preservation flocculus.Such as middle promulgated by the State Council
A kind of bright patent application publication CN102493128A, entitled manufacture method of melt blowing warm retention wadding, this application case is public
A kind of manufacture method of melt blowing warm retention wadding has been opened, heat-accumulation temperature-adjustment chopped fiber has been implanted in melt-blowing nonwoven by electrostatic field
Between, melt blowing warm retention wadding is made.This method, is to utilize static flocking technology, chopped fiber is implanted in non-woven webs
Portion, it is little to performance impacts such as the elasticity and bulkiness of insulation flocculus.In daily life, fire safety is that people attach great importance to
The problem of, the common textile overwhelming majority is inflammable or flammable, and disaster is easily become when running into the disasters such as fire
Promoter, and take and fire-retardant mechanism is introduced in insulation flocculus, it can significantly delay and avoid the condition of a fire from caused may endangering.Present
Insulation flocculus product in, can realize high resiliency, bulkiness, warmth retention property and with fire resistance insulation flocculus relatively lack
Weary, therefore, preparing a kind of high-elastic fire-retardant insulation flocculus has realistic meaning.
The content of the invention
It is an object of the invention to provide the fire-retardant warming flaky material that a kind of warmth retention property is good, elasticity is good and its manufacturer
Method.
To achieve these goals, the technical scheme is that：A kind of high-elastic fire-retardant warming sheet material of gluing flocking formula
Material, it is characterised in that：Respectively sprinkled with thermal fusing powder and the mixed powder of fireproof powder inside upper strata fibre web and lower floor's fibre web, upper strata fibre web with
The opposite surface of lower floor's fibre web is respectively coated binder film, lower binder film, fine hair be clipped in upper strata fibre web and lower floor's fibre web it
Between, the two ends of fine hair are inserted among binder film, lower binder film respectively, are fixedly arranged at the table of upper strata fibre web and lower floor's fibre web
Face.
Described upper strata fibre web, lower floor's fibre web are that short-fibred mechanical combs networking or airlaid fibre web.
Described thermal fusing powder and the mixed powder of fireproof powder are the thermal fusing powder that fusing point is low, rheological property is preferable, adhesion strength is high
The mixture being mixed with heat endurance is good, fire resistance is good fireproof powder.
The adhesive that described upper binder film and lower binder film are selected is adhesion strength is high, water-fastness, aging-resisting type
Adhesive.
Described upper binder film and lower binder film are shaped as bar shaped or checker board, and size is identical.
The material of described fine hair is polyester fiber or Fypro.
A kind of manufacture method of the high-elastic fire-retardant warming flaky material of above-mentioned gluing flocking formula, it is characterised in that：This method bag
Include following steps：
（1）It is prepared by fibre web：Upper strata fibre web, lower floor's fibre web are prepared respectively；
（2）The preparation of mixed powder：Thermal fusing powder is uniformly mixed with fireproof powder, the mixing of thermal fusing powder and fireproof powder is prepared
Powder；
（3）Dusting：The mixed powder of thermal fusing powder and fireproof powder is spread inside upper strata fibre web, lower floor's fibre web respectively；
（4）Drying：Drying is carried out to the upper strata fibre web sprinkled with thermal fusing powder and the mixed powder of fireproof powder, lower floor's fibre web respectively；
（5）Gluing：The application of adhesive on the opposite surface of upper strata fibre web, lower floor's fibre web, forms bar shaped or grid respectively
The upper binder film and lower binder film of shape；
（6）Electrostatic spinning：It is coated with upper strata fibre web on the surface of binder film and carries out electrostatic spinning, fine hair is implanted in
The surface of upper strata fibre web；
（7）Drying：Drying is carried out to the upper strata fibre web for having completed electrostatic spinning；
（8）Inhale suede：The upper strata fibre web that drying is crossed carries out inhaling suede processing；
（9）Fibre web is combined：The upper strata fibre web that suction suede is crossed is with being coated with lower floor's fibre web that adhesive forms lower binder film
It is combined；
（10）Drying：After fibre web is compound, drying is carried out；
（11）Winding：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
Due to using above technical scheme, the high-elastic fire-retardant warming flaky material of gluing flocking formula of the invention, with following
Feature：
First, the present invention is implanted into fine hair chopped fiber using static flocking technology between two layers of fibre web, is formed between fibre web
Still air region, can not only improve warming effect, and compared with prior art, the space inside fibre web is big, same
Under conditions of sample thickness, the usage amount of fibrous material can be reduced, production cost is reduced.
2nd, the present invention is using fusing point is low, good rheological property, adhesion strength are high thermal fusing powder and heat endurance are good, anti-flammability
The mixture that the good fireproof powder of energy is mixed with, can realize the flame-retardancy requirements of warming flaky material, while also ensureing material
The gas permeability of material, warmth retention property, and to human body and environmental nonpollution.
3rd, because the two ends of fine hair are fixedly arranged on two layers of fibre web by adhesive phase, fine hair is shorter, in villus length direction
During stress, bending resistance is strong, and recovery is good, therefore the warming flaky material of manufacture is elastic good.
4th, the adhesive that the present invention is selected is water-fastness, aging-resisting type adhesive, disclosure satisfy that the requirement of clothes, adopts
Bar shaped or checker board glue spreading method are taken, the high resiliency of warming flaky material is being realized, while improving warmth retention property, it is ensured that
The gas permeability of flaky material, is the ideal material for substituting eider down, as filler, can be widely used for garment industry.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Fig. 2 is that the structural representation after bar shaped gluing flocking is carried out according to embodiment of the present invention upper strata fibre web.
Fig. 3 is that the structural representation after checker board gluing flocking is carried out according to embodiment of the present invention upper strata fibre web.
Embodiment
The present invention is described in further detail below in conjunction with the drawings and specific embodiments.
Referring to Fig. 1-Fig. 3.
The high-elastic fire-retardant warming flaky material of gluing flocking formula, including upper strata fibre web 1, upper binder film 4, fine hair 3, lower bonding
Agent film 4’, lower floor's fibre web 2, the mixed powder 5,5 of thermal fusing powder and fireproof powder,.Upper strata fibre web 1, lower floor's fibre web 2 are combed for short-fibred mechanical
Networking or airlaid fibre web are managed, is sprinkled with the mixed powder 5 of thermal fusing powder and fireproof powder, lower floor's fibre web 2 and spreads in fibre web 1 on upper strata
There is the mixed powder 5 of thermal fusing powder and fireproof powder,, upper strata fibre web 1 and the opposite surface of lower floor's fibre web 2 be respectively coated binder film 4,
Lower binder film 4’, fine hair 3 is clipped between upper strata fibre web 1 and lower floor's fibre web 2, and binder film is inserted at the two ends of fine hair 3 respectively
4th, lower binder film 4’Among, it is fixedly arranged at the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2.Upper binder film 4 and lower bonding
Agent film 4’Form and dimension identical bar shaped or lattice shape, be coated in surface and the lower floor's fibre web 2 of upper strata fibre web 1
The position on surface is corresponding, is easy to fine hair 3 into vertical, can increase the still air in heat insulating material, lifts warming effect,
Improve the elasticity of warming flaky material.In order to ensure the consolidation fastness of fine hair 3 and upper strata fibre web 1 and lower floor's fibre web 2, improve warming
The performances such as the water resistance of flaky material, upper binder film 4 and lower binder film 4’The adhesive of selection is that adhesion strength is high, water-fast
Wash, the adhesive of aging-resisting type.The material of fine hair 3 is polyester fiber or Fypro.The mixed powder of thermal fusing powder and fireproof powder
5、5,For fusing point is low, the thermal fusing powder that good rheological property, adhesion strength are high and heat endurance is good, fire resistance is good fireproof powder carry out
The mixture being mixed with, fireproof powder after thermal fusing powder heating melting by sticking to upper strata fibre web 1 with inside lower floor's fibre web 2, having
There is preferable water-wash resistance.
The manufacture method of the high-elastic fire-retardant warming flaky material of gluing flocking formula, this method comprises the following steps：
（1）It is prepared by fibre web：Upper strata fibre web 1, lower floor's fibre web 2 are prepared respectively；
（2）The preparation of mixed powder：Thermal fusing powder is uniformly mixed with fireproof powder, the mixing of thermal fusing powder and fireproof powder is prepared
Powder 5,5,；
（3）Dusting：The mixed powder 5 of thermal fusing powder and fireproof powder is spread inside upper strata fibre web 1 respectively, inside lower floor's fibre web 2
Spread the mixed powder 5 of thermal fusing powder and fireproof powder,；
（4）Drying：Respectively to the mixed powder 5,5 sprinkled with thermal fusing powder and fireproof powder,Upper strata fibre web 1, lower floor's fibre web 2 carries out
Drying, drying melts thermal fusing powder, bonds upper strata fibre web 1, lower floor's fibre web 2 and fireproof powder；
（5）Gluing：The application of adhesive on the opposite surface of upper strata fibre web 1, lower floor's fibre web 2, forms bar shaped or lattice respectively
The upper binder film 4 and lower binder film 4 of sub- shape’With lower binder film 4 ' in pairs, form and dimension is complete for upper binder film 4
Unanimously, the position for being coated in the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2 is also corresponding；
（6）Electrostatic spinning：It is coated with upper strata fibre web 1 on the surface of binder film 4 and carries out electrostatic spinning, by fine hair 3
The surface of upper strata fibre web 1 is implanted in, fine hair 3 is implanted in the surface of upper strata fibre web 1 in the presence of electrostatic field, and makes fine hair 3 and upper strata
The surface of fibre web 1 is in plumbness；
（7）Drying：Drying is carried out to the upper strata fibre web 1 for having completed electrostatic spinning, drying steams the moisture of binder film 4
Hair, fine hair 3 is fixedly arranged at the surface of upper strata fibre web 1；
（8）Inhale suede：The upper strata fibre web 1 that drying is crossed carries out inhaling suede processing, will be scattered on the surface of upper strata fibre web 1 and does not apply
Cover the fine hair 3 at the position of adhesive and do not sopped up by the fine hair 3 of adhesive secure bond；
（9）Fibre web is combined：The upper strata fibre web 1 that suction suede is crossed forms lower binder film 4 with being coated with adhesive’Lower floor it is fine
Net 2 is combined, and fine hair 3 is vertical with the surface of lower floor fibre web 2, and fine hair 3 is in the state stretched；
（10）Drying：After fibre web is compound, carry out drying, drying makes the moisture evaporation of lower binder film 4 ', fine hair 3 it is another
End is fixedly arranged at the surface of lower floor's fibre web 2；
（11）Winding：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
Embodiment 1
High-elastic fire-retardant warming flaky material of bar shaped gluing flocking formula machinery networking and preparation method thereof：
Referring to Fig. 1, Fig. 2, the high-elastic fire-retardant warming flaky material of gluing flocking formula, including upper strata fibre web 1, lower floor's fibre web 2, suede
Hair 3, upper binder film 4, lower binder film 4 ', the mixed powder 5,5 of thermal fusing powder and fireproof powder,.Upper strata fibre web 1, lower floor's fibre web 2 are
Fineness is 3D, and hollow polyester fibre and the fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is 110 DEG C
Low-melting fiber, according to percentage by weight 80%:20% carries out shredding mixing, and the fibre prepared is combed by short-fibred mechanical
Net.On upper strata sprinkled with thermal fusing powder and the mixed powder 5 of fireproof powder in fibre web 1, sprinkled with the mixed of thermal fusing powder and fireproof powder in lower floor's fibre web 2
Close powder 5,, the fusing point of thermal fusing powder is 110 DEG C, and fireproof powder is the fire-retardant pulvis of inorganic polymer bromine series nanometer grade, on upper strata fibre web 1 with
Binder film 4, lower binder film 4 ' is respectively coated in the opposite surface of lower floor's fibre web 2, and fine hair 3 is clipped in upper strata fibre web 1 and lower floor
Between fibre web 2, the two ends of fine hair 3 are respectively inserted among binder film 4, lower binder film 4 ', are fixedly arranged at upper strata fibre web 1
Surface and the surface of lower floor's fibre web 2, fine hair 3 are 5D from fineness, and length is 1.5mm polyester staple fiber.Upper binder film 4,
The form and dimension of lower binder film 4 ' is completely the same, is coated in the position on the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2
It is corresponding.The adhesive that upper binder film 4, lower binder film 4 ' are selected is high, water-fastness, the ageing-resistant polypropylene of adhesion strength
Esters of gallic acid static flocking adhesive.Upper binder film 4, lower binder film 4 ' are shaped as bar shaped.
The manufacture method of the high-elastic fire-retardant warming flaky material of gluing flocking formula, this method comprises the following steps：
（1）It is prepared by fibre web：Networking is combed using short-fibred mechanical and prepares upper strata fibre web 1, lower floor's fibre web 2 respectively；
（2）The preparation of mixed powder：Thermal fusing powder and fireproof powder are uniformly mixed, and prepare the mixed powder of thermal fusing powder and fireproof powder
5、5,；
（3）Dusting：The mixed powder 5 of thermal fusing powder and fireproof powder is spread inside upper strata fibre web 1 respectively, inside lower floor's fibre web 2
Spread the mixed powder 5 of thermal fusing powder and fireproof powder,；
（4）Drying：Respectively to the mixed powder 5,5 sprinkled with thermal fusing powder and fireproof powder,Upper strata fibre web 1, lower floor's fibre web 2 carries out
Drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min, and drying melts thermal fusing powder, bonds upper strata
Fibre web 1, lower floor's fibre web 2 and fireproof powder；
（5）Gluing：The upper strata fibre web 1 prepared, lower floor's fibre web 2 are fed into coating machine respectively, adhesive is coated in
The surface of layer fibre web 1, forms width for 1cm, and thickness is 0.5mm, and spacing distance is the 1cm bar along web width directional spreding
Upper binder film 4, the lower binder film 4 ' of shape.Upper binder film 4 and lower binder film 4 ' in pairs, form and dimension complete one
Cause, the position for being coated in the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2 is also corresponding；
（6）Electrostatic spinning：On upper strata, fibre web 1, which is coated with the surface of adhesive, carries out electrostatic spinning, uses rated voltage
For 50kV, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field makes fine hair 3 in the presence of electrostatic field,
The surface of upper strata fibre web 1 is implanted in, and the surface of fine hair 3 and upper strata fibre web 1 is in plumbness；
（7）Drying：Drying is carried out to the upper strata fibre web 1 for having completed electrostatic spinning, drying mode is hot blast drying, and temperature is
160 DEG C, criteria thus the drying time is 3min, and drying makes the moisture evaporation of binder film 4, and fine hair 3 is fixedly arranged at the surface of upper strata fibre web 1；
（8）Inhale suede：The upper strata fibre web 1 that drying is crossed carries out inhaling suede processing, will be scattered on the surface of upper strata fibre web 1 and does not apply
Cover the fine hair 3 at the position of adhesive and do not sopped up by the fine hair 3 of adhesive secure bond；
（9）Fibre web is combined：The upper strata fibre web 1 that suction suede is crossed and the lower floor's fibre web 2 for being coated with adhesive formation binder film
It is 50kV in rated voltage, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field effect is lower to be combined,
Fine hair 3 is vertical with the surface of lower floor fibre web 2, and fine hair 3 is in the state stretched；
（10）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes the moisture evaporation of lower binder film 4 ', and the other end of fine hair 3 is fixedly arranged at the surface of lower floor's fibre web 2；
（11）Winding：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
Embodiment 2
High-elastic fire-retardant warming flaky material of checker board gluing flocking formula machinery networking and preparation method thereof：
Referring to Fig. 1, Fig. 3, the high-elastic fire-retardant warming flaky material of gluing flocking formula, including upper strata fibre web 1, lower floor's fibre web 2, suede
Hair 3, upper binder film 4, lower binder film 4 ', the mixed powder 5,5 of thermal fusing powder and fireproof powder,.Upper strata fibre web 1, lower floor's fibre web 2 are
Fineness is 3D, and hollow polyester fibre and the fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is 110 DEG C
Low-melting fiber, according to percentage by weight 80%:20% carries out shredding mixing, and the fibre prepared is combed by short-fibred mechanical
Net.On upper strata sprinkled with thermal fusing powder and the mixed powder 5 of fireproof powder in fibre web 1, sprinkled with the mixed of thermal fusing powder and fireproof powder in lower floor's fibre web 2
Close powder 5,, the fusing point of thermal fusing powder is 110 DEG C, and fireproof powder is the fire-retardant pulvis of inorganic polymer bromine series nanometer grade, on upper strata fibre web 1 with
Binder film 4, lower binder film 4 ' is respectively coated in the opposite surface of lower floor's fibre web 2, and fine hair 3 is clipped in upper strata fibre web 1 and lower floor
Between fibre web 2, the two ends of fine hair 3 are respectively inserted among binder film 4, lower binder film 4 ', are fixedly arranged at upper strata fibre web 1
Surface and the surface of lower floor's fibre web 2, fine hair 3 are 5D from fineness, and length is 1.5mm Fypro.Upper binder film 4,
The form and dimension of lower binder film 4 ' is completely the same, is coated in the position on the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2
It is corresponding.The adhesive that upper binder film 4, lower binder film 4 ' are selected is high, water-fastness, the ageing-resistant polypropylene of adhesion strength
Esters of gallic acid static flocking adhesive.Upper binder film 4, lower binder film 4 ' are shaped as checker board, can increase in heat insulating material
Still air, lifts warming effect.
The manufacture method of the high-elastic fire-retardant warming flaky material of gluing flocking formula, this method comprises the following steps：
（1）It is prepared by fibre web：Networking is combed using short-fibred mechanical and prepares upper strata fibre web 1, lower floor's fibre web 2 respectively；
（2）The preparation of mixed powder：Thermal fusing powder and fireproof powder are uniformly mixed, and prepare the mixed powder of thermal fusing powder and fireproof powder
5、5,；
（3）Dusting：The mixed powder 5 of thermal fusing powder and fireproof powder is spread inside upper strata fibre web 1 respectively, inside lower floor's fibre web 2
Spread the mixed powder 5 of thermal fusing powder and fireproof powder,；
（4）Drying：Respectively to the mixed powder 5,5 sprinkled with thermal fusing powder and fireproof powder,Upper strata fibre web 1, lower floor's fibre web 2 carries out
Drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min, and drying melts thermal fusing powder, bonds upper strata
Fibre web 1, lower floor's fibre web 2 and fireproof powder；
（5）Gluing：The upper strata fibre web 1 prepared, lower floor's fibre web 2 are fed into coating machine respectively, adhesive is coated in
The surface of layer fibre web 1, it is 1cm to be formed along breadth direction width, and spacing distance is 1cm, is 1cm, interval along width length direction width
Distance is 1cm, and thickness is upper binder film 4, the lower binder film 4 ' of 0.5mm checker board.Upper binder film 4 and lower adhesive
In pairs, form and dimension is completely the same for film 4 ', is coated in the position on the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2 also phase
Correspondence；
（6）Electrostatic spinning：On upper strata, fibre web 1, which is coated with the surface of adhesive, carries out electrostatic spinning, uses rated voltage
For 50kV, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field makes fine hair 3 in the presence of electrostatic field,
The surface of upper strata fibre web 1 is implanted in, and the surface of fine hair 3 and upper strata fibre web 1 is in plumbness；
（7）Drying：Drying is carried out to the upper strata fibre web 1 for having completed electrostatic spinning, drying mode is hot blast drying, and temperature is
160 DEG C, criteria thus the drying time is 3min, and drying makes the moisture evaporation of binder film 4, and fine hair 3 is fixedly arranged at the surface of upper strata fibre web 1；
（8）Inhale suede：The upper strata fibre web 1 that drying is crossed carries out inhaling suede processing, will be scattered on the surface of upper strata fibre web 1 and does not apply
Cover the fine hair 3 at the position of adhesive and do not sopped up by the fine hair 3 of adhesive secure bond；
（9）Fibre web is combined：The upper strata fibre web 1 that suction suede is crossed and the lower floor's fibre web 2 for being coated with adhesive formation binder film
It is 50kV in rated voltage, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field effect is lower to be combined,
Fine hair 3 is vertical with the surface of lower floor fibre web 2, and fine hair 3 is in the state stretched；
（10）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes the moisture evaporation of lower binder film 4 ', and the other end of fine hair 3 is fixedly arranged at the surface of lower floor's fibre web 2；
（11）Winding：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
Embodiment 3
Airlaid high-elastic fire-retardant warming flaky material of bar shaped gluing flocking formula and preparation method thereof：
Referring to Fig. 1, Fig. 2, the high-elastic fire-retardant warming flaky material of gluing flocking formula, including upper strata fibre web 1, lower floor's fibre web 2, suede
Hair 3, upper binder film 4, lower binder film 4 ', the mixed powder 5,5 of thermal fusing powder and fireproof powder,.Upper strata fibre web 1, lower floor's fibre web 2 are
Fineness is 3D, and hollow polyester fibre and the fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is 110 DEG C
Low-melting fiber, according to percentage by weight 80%:20% carries out shredding mixing, is prepared by short-fiber airlaid machine
Fibre web.On upper strata sprinkled with thermal fusing powder and the mixed powder 5 of fireproof powder in fibre web 1, sprinkled with thermal fusing powder and fireproof powder in lower floor's fibre web 2
Mixed powder 5,, the fusing point of thermal fusing powder is 110 DEG C, and fireproof powder is the fire-retardant pulvis of inorganic polymer bromine series nanometer grade, the fibre web 1 on upper strata
Upper binder film 4, lower binder film 4 ' is respectively coated in opposite surface with lower floor fibre web 2, and fine hair 3 is clipped in upper strata fibre web 1 with
Between layer fibre web 2, the two ends of fine hair 3 are respectively inserted among binder film 4, lower binder film 4 ', are fixedly arranged at upper strata fibre web 1
Surface and lower floor's fibre web 2 surface, fine hair 3 from fineness be 5D, length be 1.5mm polyester staple fiber.Upper binder film
4th, the form and dimension of lower binder film 4 ' is completely the same, is coated in the position on the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2
Put corresponding.The adhesive that upper binder film 4, lower binder film 4 ' are selected is high, water-fastness, ageing-resistant poly- third of adhesion strength
Olefin(e) acid esters static flocking adhesive.Upper binder film 4, lower binder film 4 ' are shaped as bar shaped, can increase in heat insulating material
Still air, lifts warming effect.
The manufacture method of the high-elastic fire-retardant warming flaky material of gluing flocking formula, this method comprises the following steps：
（1）It is prepared by fibre web：Prepare upper strata fibre web 1, lower floor's fibre web 2 respectively using short-fiber airlaid；
（2）The preparation of mixed powder：Thermal fusing powder and fireproof powder are uniformly mixed, and prepare the mixed powder of thermal fusing powder and fireproof powder
5、5,；
（3）Dusting：The mixed powder 5 of thermal fusing powder and fireproof powder is spread inside upper strata fibre web 1 respectively, inside lower floor's fibre web 2
Spread the mixed powder 5 of thermal fusing powder and fireproof powder,；
（4）Drying：Respectively to the mixed powder 5,5 sprinkled with thermal fusing powder and fireproof powder,Upper strata fibre web 1, lower floor's fibre web 2 carries out
Drying, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is 3min, and drying melts thermal fusing powder, bonds upper strata
Fibre web 1, lower floor's fibre web 2 and fireproof powder；
（5）Gluing：The upper strata fibre web 1 prepared, lower floor's fibre web 2 are fed into coating machine respectively, adhesive is coated in
The surface of layer fibre web 1, forms width for 1cm, and thickness is 0.5mm, and spacing distance is the 1cm bar along web width directional spreding
Upper binder film 4, the lower binder film 4 ' of shape.Upper binder film 4 and lower binder film 4 ' in pairs, form and dimension complete one
Cause, the position for being coated in the surface of upper strata fibre web 1 and the surface of lower floor's fibre web 2 is also corresponding；
（6）Electrostatic spinning：On upper strata, fibre web 1, which is coated with the surface of adhesive, carries out electrostatic spinning, uses rated voltage
For 50kV, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field makes fine hair 3 in the presence of electrostatic field,
The surface of upper strata fibre web 1 is implanted in, and the surface of fine hair 3 and upper strata fibre web 1 is in plumbness；
（7）Drying：Drying is carried out to the upper strata fibre web 1 for having completed electrostatic spinning, drying mode is hot blast drying, and temperature is
160 DEG C, criteria thus the drying time is 3min, and drying makes the moisture evaporation of binder film 4, and fine hair 3 is fixedly arranged at the surface of upper strata fibre web 1；
（8）Inhale suede：The upper strata fibre web 1 that drying is crossed carries out inhaling suede processing, will be scattered on the surface of upper strata fibre web 1 and does not apply
Cover the fine hair 3 at the position of adhesive and do not sopped up by the fine hair 3 of adhesive secure bond；
（9）Fibre web is combined：The upper strata fibre web 1 that suction suede is crossed and the lower floor's fibre web 2 for being coated with adhesive formation binder film
It is 50kV in rated voltage, output current is 5mA, and high voltage electric field anode-cathode distance 12cm high voltage electric field effect is lower to be combined,
Fine hair 3 is vertical with the surface of lower floor fibre web 2, and fine hair 3 is in the state stretched；
（10）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes the moisture evaporation of lower binder film 4 ', and the other end of fine hair 3 is fixedly arranged at the surface of lower floor's fibre web 2；
（11）Winding：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
Claims (7)
1. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula, it is characterised in that：Thermal fusing powder is sprinkled with inside upper strata fibre web (1)
With the mixed powder (5) of fireproof powder, the internal mixed powder (5 ') for being sprinkled with thermal fusing powder and fireproof powder of lower floor's fibre web (2), upper strata fibre web (1)
Upper binder film (4), lower binder film (4 '), the fine hair (3) of electrostatic spinning is respectively coated in opposite surface with lower floor's fibre web (2)
It is clipped between upper strata fibre web (1) and lower floor's fibre web (2), fine hair (3) is in plumbness, and binder film is inserted at two ends respectively
(4), among lower binder film (4 '), it is fixedly arranged at the surface of upper strata fibre web (1) and lower floor's fibre web (2).
2. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula as claimed in claim 1, it is characterised in that：Described is upper
Layer fibre web (1), lower floor's fibre web (2) are that short-fibred mechanical combs networking or airlaid fibre web.
3. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula as claimed in claim 1, it is characterised in that：Described heat
The mixed powder (5,5 ') of molten powder and fireproof powder is the thermal fusing powder and heat endurance that fusing point is low, rheological property is preferable, adhesion strength is high
The mixture that the good fireproof powder of good, fire resistance is mixed with.
4. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula as claimed in claim 1, it is characterised in that：Described is upper
The adhesive that binder film (4) and lower binder film (4 ') are selected is adhesion strength is high, water-fastness, aging-resisting type adhesive.
5. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula as claimed in claim 1, it is characterised in that：Described is upper
Binder film (4) and lower binder film (4 ') are shaped as bar shaped or checker board, and size is identical.
6. a kind of high-elastic fire-retardant warming flaky material of gluing flocking formula as claimed in claim 1, it is characterised in that：Described suede
The material of hair (3) is polyester fiber or Fypro.
7. a kind of manufacturer of the high-elastic fire-retardant warming flaky material of gluing flocking formula as any one of claim 1-6
Method, it is characterised in that：This method comprises the following steps：
(1) prepared by fibre web：Upper strata fibre web (1), lower floor's fibre web (2) are prepared respectively；
(2) preparation of mixed powder：Thermal fusing powder is uniformly mixed with fireproof powder, the mixed powder of thermal fusing powder and fireproof powder is prepared
(5、5’)；
(3) dusting：The mixed powder (5) of thermal fusing powder and fireproof powder is spread inside upper strata fibre web (1) respectively, lower floor's fibre web (2) is internal
Spread the mixed powder (5 ') of thermal fusing powder and fireproof powder；
(4) drying：Upper strata fibre web (1) respectively to the mixed powder (5) sprinkled with thermal fusing powder and fireproof powder and sprinkled with thermal fusing powder and resistance
Mixed powder (5 ') lower floor fibre web (2) for firing powder carries out drying；
(5) gluing：The application of adhesive on the opposite surface of upper strata fibre web (1), lower floor's fibre web (2), forms bar shaped or lattice respectively
The upper binder film (4) and lower binder film (4 ') of sub- shape；
(6) electrostatic spinning：It is coated with upper strata fibre web (1) on the surface of upper binder film (4) and carries out electrostatic spinning, by fine hair
(3) surface of upper strata fibre web (1) is implanted in, and fine hair (3) is in plumbness；
(7) drying：Drying is carried out to the upper strata fibre web (1) for having completed electrostatic spinning；
(8) suede is inhaled：The upper strata fibre web (1) that drying is crossed carries out inhaling suede processing；
(9) fibre web is combined：It is 50kV in rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field
Under effect, lower floor's fibre web (2) that the upper strata fibre web (1) that suction suede is crossed forms lower binder film (4 ') with being coated with adhesive is carried out
Compound, fine hair (3) is vertical with the surface of lower floor's fibre web (2), and fine hair (3) is in the state stretched；
(10) drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is
3min, drying makes the moisture evaporation of lower binder film (4 '), and the other end of fine hair (3) is fixedly arranged at the surface of lower floor's fibre web (2)；
(11) wind：After drying, the high-elastic fire-retardant warming flaky material of gluing flocking formula is made in winding.
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| CN109130373A (en) * | 2018-07-27 | 2019-01-04 | 大连神润新材料有限公司 | The preparation method of the nonmetallic gadget material of nana intelligent automobile inside |
| CN109393881A (en) * | 2018-09-30 | 2019-03-01 | 苏州太湖雪丝绸股份有限公司 | A kind of silk quilt and preparation method thereof |
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| CN1257784A (en) * | 1998-12-21 | 2000-06-28 | 国碳科技股份有限公司 | Method for making fire-resistant fabrics and its products |
| JP2001226860A (en) * | 2000-02-14 | 2001-08-21 | Toyobo Co Ltd | Particle-containing nonwoven fabric and method for producing the same |
| CN102126312A (en) * | 2010-10-22 | 2011-07-20 | 苏州展华纺织有限公司 | Thermal insulation composite fabric |
| CN103287003A (en) * | 2012-02-23 | 2013-09-11 | 余兴东 | Multicolor flocked cloth and manufacturing method thereof |
| CN103692990A (en) * | 2013-12-16 | 2014-04-02 | 浙江华江科技发展有限公司 | Light fiber-reinforced thermoplastic plate used for high-performance passenger vehicle bottom protection plate and preparation technology thereof |
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| CN2704476Y (en) * | 2004-05-24 | 2005-06-15 | 朱克耐 | Leather-imitating composite cloth |
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| CN1257784A (en) * | 1998-12-21 | 2000-06-28 | 国碳科技股份有限公司 | Method for making fire-resistant fabrics and its products |
| JP2001226860A (en) * | 2000-02-14 | 2001-08-21 | Toyobo Co Ltd | Particle-containing nonwoven fabric and method for producing the same |
| CN102126312A (en) * | 2010-10-22 | 2011-07-20 | 苏州展华纺织有限公司 | Thermal insulation composite fabric |
| CN103287003A (en) * | 2012-02-23 | 2013-09-11 | 余兴东 | Multicolor flocked cloth and manufacturing method thereof |
| CN103692990A (en) * | 2013-12-16 | 2014-04-02 | 浙江华江科技发展有限公司 | Light fiber-reinforced thermoplastic plate used for high-performance passenger vehicle bottom protection plate and preparation technology thereof |
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