CN104842595B - A kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method - Google Patents
A kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method Download PDFInfo
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- CN104842595B CN104842595B CN201510251731.8A CN201510251731A CN104842595B CN 104842595 B CN104842595 B CN 104842595B CN 201510251731 A CN201510251731 A CN 201510251731A CN 104842595 B CN104842595 B CN 104842595B
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- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
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- 239000012943 hotmelt Substances 0.000 claims abstract description 167
- 238000001035 drying Methods 0.000 claims abstract description 79
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 67
- 210000004209 hair Anatomy 0.000 claims abstract description 51
- 238000007731 hot pressing Methods 0.000 claims abstract description 49
- 239000007921 spray Substances 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
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- 238000007596 consolidation process Methods 0.000 claims description 13
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- 230000014759 maintenance of location Effects 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 7
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/30—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
- B32B2260/023—Two or more layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method, belong to textile technology field.Each layer fibre web internal spray of the high-elastic antibacterial thermal insulating flaky material has antiseptic, upper strata fibre web and fibre web at the middle and upper levels, middle lower floor's fibre web surface opposite with lower floor fibre web consolidate corresponding flocked film base material respectively, and upper strata fine hair, undercoat are clipped among it respectively.It is consolidated at the middle and upper levels between fibre web and middle lower floor's fibre web with hot melt film.Its preparation method includes（1）Prepare before flocking,（2）It is prepared by fibre web,（3）Spray antiseptic,（4）Drying,（5）Hot pressing overlay film,（6）Gluing,（7）Electrostatic spinning,（8）Drying,（9）Inhale suede,（10）Fibre web overlay film consolidates,（11）Fibre web is compound,（12）Drying,（13）Winding.Compared with prior art, warming flaky material produced by the present invention has antibacterial functions, elasticity is good, warmth retention property is good.
Description
Technical field
The present invention relates to a kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method, belong to weaving
Field.
Background technology
In past life, people are used with cotton, fiber crops, silk, hair and common terylene, polyamide fibre, acrylic fibers and staple fibre
Traditional heat insulating material Deng preparation is as heat insulating material, and in these heat insulating materials, silk and wool warmth retention property are preferable, but fiber
Easy breed bacteria, intolerant to damaging by worms, and silk is expensive, and wool fiber has that peculiar smell, forming degree are poor, by multiple working procedure plus
Cashmere price after work is more expensive, and use range is limited to for many years.With the development of living standard and science and technology, Ren Menkai
Beginning will just develop new heat insulating material, occur by the chemical fibre insulation flocculus based on terylene, polypropylene fibre and acrylic fibers, such as glue spraying
The far infrareds such as cotton, acupuncture cotton, space wadding, hot melting wool, melt-blown far infrared cotton, ultra-fine hot melting wool, down-like cotton.The master of heat transfer
Form is wanted to have three kinds of heat transfer, heat radiation and thermal convection current modes.Material characteristicses and internal structure determine its heat under normal circumstances
The speed of conduction of velocity, material internal structure and outer shape determine the quality of its heat radiation and antiradiation performance, material shape
Its remains stationary air of shape and structures shape and the ability for preventing air flow.Traditional heat insulating material mainly passes through increase
Thickness and density carry out between increased fiber still air layer to improve thermal property.The thickness of usual material is bigger, density is smaller,
The warmth retention property of material is bigger, but if the density of material is too small, when causing the air therein to produce convection current, heat-insulating property on the contrary under
Drop, for clothes heat insulating material, thickness crosses conference and causes the volume ratio of clothes more too fat to move, is not easy to motion and lacks beautiful
Sense.Therefore, the exploitation of novel heat-preserving material becomes the main flow of heat insulating material research with research.The Novel heat-preservation developed in recent years
Material also has far-infrared warm material, sunlight heat accumulation thermal material, medium phase-changing and temperature-regulating material etc., and this kind of heat insulating material is not only abided by
Traditional heat-insulation warm keeping principle is followed, and can be by some other forms, such as absorb external heat, stored and to people
Body transmission changes into heat energy to reach the purpose of heat-insulation warm keeping to produce fuel factor, or by solar energy, electric energy and chemical energy etc..
For the more excellent insulation flocculus of processability, static flocking technology is also introduced into the preparation of insulation flocculus.Utilize
Static flocking technology is combined with traditional insulation flocculus manufacture method and prepares the existing document report of Novel heat-preservation flocculus.Such as middle promulgated by the State Council
Bright patent application publication CN102493128A, a kind of entitled manufacture method of melt blowing warm retention wadding, this application case are public
A kind of manufacture method of melt blowing warm retention wadding has been opened, heat-accumulation temperature-adjustment chopped fiber has been implanted in melt-blowing nonwoven by electrostatic field
Between, melt blowing warm retention wadding is made.This method, it is to utilize static flocking technology, chopped fiber is implanted in non-woven webs
Portion, it is little to performance impacts such as the elasticity of insulation flocculus and bulkinesses.In daily life, bacterium is ubiquitous, excessive bacterium
The problem of skin disease, respiratory infectious disease etc. can be caused, and invasion and attack of the common textile to bacterium are no too many anti-
Shield acts on.In present insulation flocculus product, high resiliency, bulkiness, warmth retention property and the guarantor with anti-microbial property can be realized
Warm flocculus compares shortage, and therefore, preparing a kind of high-elastic antibacterial thermal insulating flocculus has realistic meaning.
The content of the invention
It is an object of the invention to provide the antibacterial thermal insulating flaky material that a kind of warmth retention property is good, elasticity is good and its manufacturer
Method.
To achieve these goals, the technical scheme is that：A kind of high-elastic antibacterial thermal insulating piece of thin-film multilayer flocking formula
Shape material, it is characterised in that：Upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, antiseptic is sprayed with respectively inside lower floor's fibre web,
Upper strata fibre web and the opposite surface of fibre web at the middle and upper levels respectively with hot melt film, in upper hot melt film consolidation go up flocked film base material, in
Upper flocked film base material, upper strata fine hair be clipped in flocked film base material, between upper flocked film base material, upper flocked film base material
With in the opposite surface of upper flocked film base material be respectively coated upper binder film, in upper binder film, the both ends point of upper strata fine hair
Cha Ru upper binder film, among upper binder film, be fixedly arranged at flocked film base material, in upper flocked film base material table
Flocked film base under during hot melt film, lower hot melt film consolidate down during face, middle lower floor's fibre web and the opposite surface of lower floor's fibre web are used respectively
Material, lower flocked film base material, undercoat is in being clipped between lower flocked film base material, lower flocked film base material, in lower flocking it is thin
Film base material lower binder film, lower binder film in being respectively coated with the opposite surface of lower flocked film base material, the two of undercoat
End is in inserting among lower binder film, lower binder film respectively, lower flocked film base material in being fixedly arranged at, lower flocked film base material
Surface, it is consolidated at the middle and upper levels between fibre web and middle lower floor's fibre web with hot melt film.
Described upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, lower floor's fibre web are that short-fibred mechanical combs networking or gas
Flow fibre web into the net.
Described antiseptic is good anti-bacterial effect, water-fastness antiseptic.
Described upper flocked film base material, in upper flocked film base material, in lower flocked film base material, lower flocked film base
Material, upper hot melt film, in upper hot melt film, in lower hot melt film, lower hot melt film be shaped as bar shaped or checker board, size is identical.
Described upper binder film, in upper binder film, in the adhesive selected of lower binder film, lower binder film be viscous
High, water-fastness, aging-resisting type the adhesive of knotting strength.
Described upper strata fine hair and the material of undercoat are polyester fiber or Fypro.
A kind of manufacture method of the high-elastic antibacterial thermal insulating flaky material of above-mentioned thin-film multilayer flocking formula, it is characterised in that：The party
Method comprises the following steps：
（1）Prepare before flocking：By upper flocked film base material, in upper flocked film base material, upper hot melt film, in upper hot melt film system
The standby shape into the bar shaped of size identical or grid；Will in lower flocked film base material, lower flocked film base material, in lower heat
Film, lower hot melt film are prepared into the shape of the bar shaped of size identical or grid；
（2）It is prepared by fibre web：Upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, lower floor's fibre web are prepared respectively；
（3）Spray antiseptic：Respectively under a certain pressure to upper strata fibre web, fibre web, middle lower floor's fibre web, lower floor's fibre web at the middle and upper levels
Antiseptic is sprayed respectively；
（4）Drying：Respectively to being sprayed with the upper strata fibre web of antiseptic, fibre web, middle lower floor's fibre web, lower floor's fibre web progress at the middle and upper levels
Drying；
（5）Hot pressing overlay film：Upper flocked film base material is coated on the fibre web of upper strata together with upper hot melt film, and makes hot melt
For film between upper flocked film base material and upper strata fibre web, hot pressing melts hot melt film, and upper flocked film base material is fixedly arranged at
On layer fibre web；Will in upper flocked film base material in together with upper hot melt film coated at the middle and upper levels on fibre web, and upper hot melt film in making
Flocked film base material and at the middle and upper levels between fibre web in, hot pressing upper hot melt film melting in making, will in upper flocked film base material consolidate
Knot is at the middle and upper levels on fibre web；Will in lower flocked film base material in together with lower hot melt film coated on middle lower floor's fibre web, and make
Lower hot melt film is lower between flocked film base material and middle lower floor's fibre web in, hot pressing lower hot melt film melting in making, will in lower flocking it is thin
Film base material is fixedly arranged on middle lower floor's fibre web；Lower flocked film base material is coated on lower floor's fibre web together with lower binder film, and
Make lower binder film between lower flocked film base material and lower floor's fibre web, hot pressing melts lower binder film, by lower flocked film
Base material is fixedly arranged on lower floor's fibre web；
（6）Gluing：Respectively the upper flocked film base material being fixedly arranged on the fibre web of upper strata, be fixedly arranged at the middle and upper levels on fibre web in
Upper flocked film base material, lower flocked film base material, the lower flocking being fixedly arranged on lower floor's fibre web in being fixedly arranged on middle lower floor's fibre web
Applied on the surface of film substrate be covered with binder film, in upper binder film, in lower binder film, lower binder film；
（7）Electrostatic spinning：Electrostatic spinning is carried out on the surface of the fibre web at the middle and upper levels after gluing, middle lower floor's fibre web respectively,
By upper strata fine hair, undercoat be implanted in respectively fibre web at the middle and upper levels and in upper flocked film base material, middle lower floor's fibre web and in lower flocking
The surface of film substrate；
（8）Drying：Drying is carried out to the fibre web at the middle and upper levels and middle lower floor's fibre web for having completed electrostatic spinning；
（9）Inhale suede：The fibre web at the middle and upper levels and middle lower floor's fibre web that drying is crossed carry out inhaling suede processing；
（10）Fibre web overlay film consolidates：The fibre web at the middle and upper levels after suede is handled and middle lower floor's fibre web, which will be inhaled, does not have the one side phase of flocking
Mutually overlapping, and middle folder hot melt film, fibre web will be consolidated with middle lower floor's fibre web at the middle and upper levels through Overheating Treatment；
（11）Fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web after hot pressing overlay film, gluing is crossed with inhaling suede respectively
Carry out it is compound, lower floor's fibre web and inhale middle lower floor's fibre web for crossing of suede carry out it is compound；
（12）Drying：After fibre web is compound, drying is carried out；
（13）Winding：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
Due to using above technical scheme, the high-elastic antibacterial thermal insulating flaky material of gluing flocking formula of the invention, have following
Feature：
First, the present invention is implanted into fine hair chopped fiber using static flocking technology between two layers of fibre web, between two layers of fibre web
Still air region is formed, can not only improve warming effect, and compared with prior art, the space inside fibre web is big,
Under conditions of same thickness, the usage amount of fibrous material can be reduced, reduces production cost.
2nd, the present invention selects the antiseptic of good anti-bacterial effect, and fibre web is sprayed into the form of spraying, can realize warming sheet
The antibacterial requirement of material, while also ensure gas permeability, the warmth retention property of material, and to human body and environmental nonpollution.
3rd, fine hair is shorter, and in villus length direction during stress, bending resistance is strong, and recovery is good, the warming sheet of manufacture
Material it is elastic good.
4th, the hot melt film selected of the present invention is the hot melt net of Reticular breathable structure, be disclosure satisfy that between two layer web
Bonding it is compound while, ensure the gas permeability of flaky material.
5th, because the both ends of fine hair are fixedly arranged on film by adhesive, and film is consolidated with fibre web, after flocking
Height of naps can be consistent, obtained warming sheet material surface is smooth, and appearance is good.Film is bar shaped or grid
Shape, the high resiliency of warming flaky material is being realized, while improving warmth retention property, it is ensured that the gas permeability of flaky material,
It is the ideal material for substituting eider down, as filler, can be widely used for garment industry.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
Fig. 2 is that fibre web carries out the structural representation after strip film flocking at the middle and upper levels according to embodiment of the present invention.
Fig. 3 is that fibre web carries out the structural representation after checker board film flocking at the middle and upper levels according to embodiment of the present invention.
Embodiment
The present invention is described in further detail below in conjunction with the drawings and specific embodiments.
Referring to Fig. 1-Fig. 3.
The high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, including upper strata fibre web 1, upper hot melt film 2, upper flocked film
Base material 3, upper binder film 4, upper strata fine hair 5, in upper binder film 4,, in upper flocked film base material 3,, in upper hot melt film 2,, in
Upper strata fibre web 6, hot melt film 10, middle lower floor's fibre web 6,, in lower hot melt film 7, in lower flocked film base material 8, in lower binder film 9,
Undercoat 5,, lower binder film 9,, lower flocked film base material 8,, lower hot melt film 7,, lower floor's fibre web 1,, antiseptic 11,11,、12、
12,.Upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6,, lower floor's fibre web 1,For short-fibred mechanical comb networking or air-flow into
The fibre web of net.The antiseptic 11 of the chitosan-containing of the internal spray good anti-bacterial effect of upper strata fibre web 1, the at the middle and upper levels internal spray of fibre web 6
The antiseptic 11 of the chitosan-containing of good anti-bacterial effect,, middle lower floor's fibre web 6,The antibacterial of the chitosan-containing of internal spray good anti-bacterial effect
Agent 12,, lower floor's fibre web 1,The antiseptic 12 of the chitosan-containing of internal spray good anti-bacterial effect, chitosan can influence bacterial activity,
Good antibacterial effect is obtained, obtains good antibacterial effect, and chitosan has preferable wash durability.Upper strata fibre web
1 with the opposite surface of fibre web 6 at the middle and upper levels respectively with hot melt film 2, in go up hot melt film 2,Flocked film base material 3 in consolidation, on
Flocked film base material 3,, upper strata fine hair 5 be clipped in flocked film base material 3, in upper flocked film base material 3,Between, upper flocked film
The upper flocked film base material 3 with of base material 3,Opposite surface be respectively coated binder film 4, in upper binder film 4,, upper strata fine hair
5 both ends insert respectively binder film 4, in upper binder film 4,Among, be fixedly arranged at flocked film base material 3, in upper flocking
Film substrate 3,Surface.Middle lower floor's fibre web 6,With lower floor fibre web 1,Opposite surface lower hot melt film 7, lower hot melt film in using respectively
7,Lower flocked film base material 8, lower flocked film base material 8 in consolidation,, undercoat 5,Lower flocked film base material 8, lower plant in being clipped in
Suede film substrate 8,Between, in lower flocked film base material 8 and lower flocked film base material 8,Opposite surface is lower in being respectively coated to be bonded
Agent film 9, lower binder film 9,, undercoat 5,Both ends insert respectively in lower binder film 9, lower binder film 9,Among, consolidation
Lower flocked film base material 8, lower flocked film base material 8 in,Surface.Upper hot melt film 2, in upper hot melt film 2,, in lower hot melt film 7,
Lower hot melt film 7,, upper flocked film base material 3, in upper flocked film base material 3,, in lower flocked film base material 8, lower flocked film base material
8,Be shaped as bar shaped or checker board, size is identical.Upper binder film 4, in upper binder film 4,, in lower binder film 9, lower viscous
Mixture film 9,The adhesive of selection is high, water-fastness, aging-resisting type the adhesive of adhesion strength.Upper strata fine hair 5 and undercoat 5,
Material be polyester fiber or Fypro.Fibre web 6 and middle lower floor's fibre web 6 at the middle and upper levels,Between with hot melt film 10 be fixedly arranged at one
Rise.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, this method comprise the following steps：
（1）Prepare before flocking：By upper flocked film base material 3, in upper flocked film base material 3,, upper hot melt film 2, in upper heat
Film 2,It is prepared into the shape of the bar shaped of shape size identical or grid；Lower flocked film base material 8, lower flocked film base material by
8,, in lower hot melt film 7, lower hot melt film 7,It is prepared into the shape of the bar shaped of shape size identical or grid；
（2）It is prepared by fibre web：Using the method for combing networking or air lay, upper strata fibre web 1, at the middle and upper levels fibre are prepared respectively
Net 6, middle lower floor's fibre web 6,, lower floor's fibre web 1,；
（3）Spray antiseptic：Difference uniformly sprays antiseptic 11 to upper strata fibre web 1 under a certain pressure, to fibre web 6 at the middle and upper levels
Uniformly sprinkling antiseptic 11,, to middle lower floor's fibre web 6,Uniformly sprinkling antiseptic 12,, to lower floor's fibre web 1,Uniformly sprinkling antiseptic
12, make antiseptic 11,11,、12,, 12 can as far as possible be evenly distributed in upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6,、
Lower floor's fibre web 1,Inside, obtain good anti-microbial property after being easy to drying；
（4）Drying：Respectively to being sprayed with antiseptic 11,11,、12,, 12 upper strata fibre web 1, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6,, lower floor's fibre web 1,Carry out drying；
（5）Hot pressing overlay film：Upper flocked film base material 3 is coated on upper strata fibre web 1 together with upper hot melt film 2, and made
For hot melt film 2 between upper flocked film base material 3 and upper strata fibre web 1, hot pressing melts hot melt film 2, by upper flocked film base material 3
It is fixedly arranged on upper strata fibre web 1；The upper flocked film base material 3 by,The upper hot melt film 2 with,It is coated in together at the middle and upper levels on fibre web 6, and
Upper hot melt film 2 in making,Flocked film base material 3 in,Between fibre web 6 at the middle and upper levels, hot pressing upper hot melt film 2 in making,Melting, will
In upper flocked film base material 3,It is fixedly arranged at the middle and upper levels on fibre web 6；Lower flocked film base material 8 applies in together with lower hot melt film 7 by
Overlay on middle lower floor's fibre web 6,On, and hot melt film 7 lower flocked film base material 8 and middle lower floor's fibre web 6 in are descended in making,Between, hot pressing makes
In lower hot melt film 7 melt, lower flocked film base material 8 is fixedly arranged at middle lower floor's fibre web 6 by,On；By lower flocked film base material 8,With under
Binder film 9,Lower floor's fibre web 1 is coated in together,On, and make lower binder film 9,In lower flocked film base material 8,With lower floor fibre web 1,
Between, hot pressing makes lower binder film 9,Melting, by lower flocked film base material 8,It is fixedly arranged at lower floor's fibre web 1,On；
（6）Gluing：Respectively in the upper flocked film base material 3 being fixedly arranged on upper strata fibre web 1, be fixedly arranged at the middle and upper levels on fibre web 6
In upper flocked film base material 3,, be fixedly arranged at middle lower floor's fibre web 6,On in lower flocked film base material 8, be fixedly arranged at lower floor's fibre web 1,
On lower flocked film base material 8,Surface on apply be covered with binder film 4, in upper binder film 4,, in lower binder film 9, lower viscous
Mixture film 9,；
（7）Electrostatic spinning：Fibre web at the middle and upper levels 6 after gluing, middle lower floor's fibre web 6 respectively,Surface on carry out electrostatic plant
Suede, by upper strata fine hair 5, undercoat 5,Be implanted in respectively fibre web 6 at the middle and upper levels and in upper flocked film base material 3,, middle lower floor's fibre web 6,
The surface of lower flocked film base material 8 in and；
（8）Drying：To the fibre web at the middle and upper levels 6 for having completed electrostatic spinning and middle lower floor's fibre web 6,Carry out drying, in upper bond
Agent film 4,, in lower binder film 9 moisture evaporation, the upper flocked film base material 3 in consolidating of upper strata fine hair 5,Surface, undercoat
5,The surface of lower flocked film base material 8 in consolidation；
（9）Inhale suede：The fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 that drying is crossed,, carry out inhaling suede processing.On in being scattered in
Layer fibre web 6, middle lower floor's fibre web 6,Surface on and not by the upper strata fine hair 5 of adhesive secure bond, undercoat 5,Sop up,
Make fibre web 6, middle lower floor's fibre web 6 at the middle and upper levels,Surface neat and tidy, the fine hair after flocking is neat；
（10）Fibre web overlay film consolidates：The fibre web at the middle and upper levels 6 after suede is handled and middle lower floor's fibre web 6 will be inhaled,There is no the one of flocking
Face is superimposed with each other, and middle folder hot melt film 10, will fibre web 6 and middle lower floor's fibre web 6 at the middle and upper levels through Overheating Treatment,It is consolidated；
（11）Fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web 1 after hot pressing overlay film, gluing is crossed with inhaling suede respectively
6 carry out compound, lower floor's fibre web 1,The middle lower floor's fibre web 6 crossed with inhaling suede,Carry out compound；
（12）Drying：After fibre web is compound, drying, upper binder film 4, lower binder film 9 are carried out,Moisture evaporation, upper strata
The other end of fine hair 5 is fixedly arranged at the surface of flocked film base material 3, undercoat 5,The other end be fixedly arranged at lower flocked film base
Material 8,Surface；
（13）Winding：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
Embodiment 1
High-elastic antibacterial thermal insulating flaky material of strip film flocking formula machinery networking and preparation method thereof：
Referring to Fig. 1, Fig. 2, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, including upper strata fibre web 1, upper hot melt film
2nd, upper flocked film base material 3, upper binder film 4, upper strata fine hair 5, in upper binder film 4 ', in upper flocked film base material 3 ', in
Upper hot melt film 2 ', at the middle and upper levels fibre web 6, hot melt film 10, middle lower floor's fibre web 6 ', in lower hot melt film 7, in lower flocked film base material 8, in
It is lower binder film 9, undercoat 5 ', lower binder film 9 ', lower flocked film base material 8 ', lower hot melt film 7 ', lower floor's fibre web 1 ', anti-
Microbial inoculum 11,11,、12、12,.Upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6 ', lower floor's fibre web 1 ' are that fineness is 3D, long
Spend the hollow polyester fibre of the three-dimensional crimp for 51mm and fineness is 3D, length 51mm, the low melting point that fusing point is 110 DEG C is fine
Dimension, according to weight than 80%:20% carries out shredding mixing, and the fibre web being prepared is combed by short-fibred mechanical.The fibre web 1 on upper strata
The antiseptic 11 containing chitosan is sprayed, fibre web 6 sprays the antiseptic 11 containing chitosan at the middle and upper levels,, the middle spray of lower floor's fibre web 6 '
Spill the antiseptic 12 containing chitosan,, lower floor's fibre web 1 ' spray the antiseptic 12 containing chitosan, upper strata fibre web 1 with the middle and upper levels
The opposite surface of fibre web 6 respectively with hot melt film 2, in the upper flocked film base material 3 of the upper consolidation of hot melt film 2 ', in upper flocked film base
Material 3 ', upper strata fine hair 5 be clipped in flocked film base material 3, between upper flocked film base material 3 ', upper flocked film base material 3 is with
The opposite surface of upper flocked film base material 3 ' be respectively coated binder film 4, in upper binder film 4 ', the both ends of upper strata fine hair 5
Insert respectively upper binder film 4, among upper binder film 4 ', be fixedly arranged at flocked film base material 3, in upper flocked film base material
3 ' surface.Middle lower floor's fibre web 6 ' in using in lower hot melt film 7, lower hot melt film 7 ' consolidation respectively with the opposite surface of lower floor's fibre web 1 '
Lower flocked film base material 8, lower flocked film base material 8 ', undercoat 5 ' lower flocked film base material 8, lower flocked film base in being clipped in
Between material 8 ', in lower flocked film base material 8 be respectively coated with the opposite surface of lower flocked film base material 8 ' in lower binder film 9,
Lower binder film 9 ', the both ends of undercoat 5 ' in inserting among lower binder film 9, lower binder film 9 ' respectively, in being fixedly arranged at
Lower flocked film base material 8, the surface of lower flocked film base material 8 '.Upper hot melt film 2, in upper hot melt film 2 ', in lower hot melt film 7, under
Hot melt film 7 ', upper flocked film base material 3, in upper flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material
8 ' the width that is shaped as is 1cm, and spacing distance is the 1cm bar shaped along breadth directional spreding.Upper flocked film base material 3, on
Flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material 8 ' be PET film base material.Upper strata fine hair 5 with
The material of undercoat 5 ' is that fineness is 5D, and length is 1.5mm polyester staple fiber.Fibre web 6 and middle lower floor's fibre web 6 ' at the middle and upper levels
Between be consolidated with hot melt film, upper hot melt film 2, in upper hot melt film 2 ', in lower hot melt film 7, lower hot melt film 7 ', fine at the middle and upper levels
Hot melt film between net 6 and middle lower floor's fibre web 6 ' is EVA hot-melt adhesive nethike embrane, and melting temperature is 110 DEG C.Adhesive is selected viscous
Mixture is high, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of adhesion strength.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, this method comprise the following steps：
（1）Prepare before flocking：By upper flocked film base material 3, in upper flocked film base material 3 ', upper hot melt film 2, in upper heat
Film 2 ' is prepared into shape size identical bar shape；Will in lower flocked film base material 8, lower flocked film base material 8 ', in lower heat
Melt film 7, lower hot melt film 7 ' are prepared into shape size identical bar shape；
（2）It is prepared by fibre web：Using method into the net is combed, upper strata fibre web 1 is prepared respectively, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6 ', lower floor's fibre web 1 '；
（3）Spray antiseptic：Difference uniformly sprays antiseptic 11 to upper strata fibre web 1 under a certain pressure, to fibre web 6 at the middle and upper levels
Uniformly sprinkling antiseptic 11,, to middle lower floor's fibre web 6,Uniformly sprinkling antiseptic 12,, to lower floor's fibre web 1,Uniformly sprinkling antiseptic
12, make antiseptic 11,11,、12,, 12 can as far as possible be evenly distributed in upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6,、
Lower floor's fibre web 1,Inside, obtain good anti-microbial property after being easy to drying；
（4）Drying：Respectively to being sprayed with antiseptic 11,11,、12,, 12 upper strata fibre web 1, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6,, lower floor's fibre web 1,Carry out drying；
（5）Hot pressing overlay film：Upper flocked film base material 3 is coated on upper strata fibre web 1 together with upper hot melt film 2, and made
For hot melt film 2 between upper flocked film base material 3 and upper strata fibre web 1, hot pressing melts hot melt film 2, by upper flocked film base material 3
It is fixedly arranged on upper strata fibre web 1；Upper flocked film base material 3 ' is coated at the middle and upper levels on fibre web 6 in together with upper hot melt film 2 ' by,
And in making upper hot melt film 2 ' on flocked film base material 3 ' with the middle and upper levels between fibre web 6, hot pressing upper melting of hot melt film 2 ' in making,
Upper flocked film base material 3 ' is fixedly arranged at the middle and upper levels on fibre web 6 by；Under lower flocked film base material 8 is in by together with hot melt film 7
Coated on middle lower floor's fibre web 6 ', and lower hot melt film 7 is warm between lower flocked film base material 8 and middle lower floor's fibre web 6 ' in making
Lower hot melt film 7 in making is pressed to melt, lower flocked film base material 8 is fixedly arranged on middle lower floor's fibre web 6 ' by；Upper flocked film base material 3 is solid
Tie upper strata fibre web 1, on flocked film base material 3 ' be fixedly arranged at fibre web 6 at the middle and upper levels position it is corresponding.By lower flocked film base
Material 8 ' together with lower binder film 9 ' coated on lower floor's fibre web 1 ', and make lower binder film 9 ' lower flocked film base material 8 ' with
Between lower floor's fibre web 1 ', hot pressing melts lower binder film 9 ', and lower flocked film base material 8 ' is fixedly arranged on lower floor's fibre web 1 ', in
It is also corresponding that lower flocked film base material 8 and lower flocked film base material 8 ' are fixedly arranged at middle lower floor's fibre web 6 ', the position of lower floor's fibre web 1 '.
Hot pressing temperature is 160 DEG C, pressure size 2.5bar, hot pressing time 10min；
（6）Gluing：Respectively in the upper flocked film base material 3 being fixedly arranged on upper strata fibre web 1, be fixedly arranged at the middle and upper levels on fibre web 6
In upper flocked film base material 3 ', be fixedly arranged on middle lower floor's fibre web 6 ' in lower flocked film base material 8, be fixedly arranged at lower floor's fibre web 1 '
On lower flocked film base material 8 ' surface on apply be covered with binder film 4, in upper binder film 4 ', in lower binder film 9, lower viscous
Mixture film 9 ', adhesive thickness 0.5mm；
（7）Electrostatic spinning：Electrostatic plant is carried out on the surface of the fibre web at the middle and upper levels 6 after gluing, middle lower floor's fibre web 6 ' respectively
Suede, the use of rated voltage is 50kV, output current 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field is by upper strata fine hair
5th, undercoat 5 ' be implanted in respectively fibre web 6 at the middle and upper levels and in upper flocked film base material 3 ', middle lower floor's fibre web 6 ' and in lower flocking it is thin
The surface of film base material 8, and upper strata fine hair 5, undercoat 5 ' is in straight configuration；
（8）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, criteria thus the drying time 3min, drying upper binder film 4 ' in making, in lower binder film 9 water
Point evaporation, the surface of the upper flocked film base material 3 ' in consolidating of upper strata fine hair 5, the lower flocked film base material 8 in consolidating of undercoat 5 '
Surface；
（9）Inhale suede：The fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' that drying is crossed, carry out inhaling suede processing.On in being scattered in
Layer fibre web 6, middle lower floor's fibre web 6 ' surface on and do not sopped up by upper strata fine hair 5, the undercoat 5 ' of adhesive secure bond；
（10）Fibre web overlay film consolidates：The fibre web at the middle and upper levels 6 after suede is handled and middle lower floor's fibre web 6 ', which will be inhaled, does not have the one of flocking
Face is superimposed with each other, and middle folder hot melt film 10, is 160 DEG C, pressure size 2.5bar by hot pressing temperature, hot pressing time is
10min hot-pressing processing, fibre web 6 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 6 '；
（11）Fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web 1 after hot pressing overlay film, gluing is crossed with inhaling suede respectively
6, lower floor's fibre web 1 ' is 50kV with inhaling middle lower floor's fibre web 6 ' for crossing of suede in rated voltage, output current 5mA, high voltage electric field interpolar
The distance 12cm lower progress of high voltage electric field effect is compound；
（12）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes binder film 4, the moisture evaporation of lower binder film 9 ', and the other end of upper strata fine hair 5 is fixedly arranged at flocking
The surface of film substrate 3, the other end of undercoat 5 ' are fixedly arranged at the surface of lower flocked film base material 8 '；
（13）Winding：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
Embodiment 2
High-elastic antibacterial thermal insulating flaky material of checker board film flocking formula machinery networking and preparation method thereof：
Referring to Fig. 1, Fig. 3, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, including upper strata fibre web 1, upper hot melt film
2nd, upper flocked film base material 3, upper binder film 4, upper strata fine hair 5, in upper binder film 4 ', in upper flocked film base material 3 ', in
Upper hot melt film 2 ', at the middle and upper levels fibre web 6, hot melt film 10, middle lower floor's fibre web 6 ', in lower hot melt film 7, in lower flocked film base material 8, in
It is lower binder film 9, undercoat 5 ', lower binder film 9 ', lower flocked film base material 8 ', lower hot melt film 7 ', lower floor's fibre web 1 ', anti-
Microbial inoculum 11,11,、12、12,.Upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6 ', lower floor's fibre web 1 ' are that fineness is 3D, long
Spend the hollow polyester fibre of the three-dimensional crimp for 51mm and fineness is 3D, length 51mm, the low melting point that fusing point is 110 DEG C is fine
Dimension, according to weight than 80%:20% carries out shredding mixing, and the fibre web being prepared is combed by short-fibred mechanical.The fibre web 1 on upper strata
The antiseptic 11 containing chitosan is sprayed, fibre web 6 sprays the antiseptic 11 containing chitosan at the middle and upper levels,, the middle spray of lower floor's fibre web 6 '
Spill the antiseptic 12 containing chitosan,, lower floor's fibre web 1 ' spray the antiseptic 12 containing chitosan, upper strata fibre web 1 with the middle and upper levels
The opposite surface of fibre web 6 respectively with hot melt film 2, in the upper flocked film base material 3 of the upper consolidation of hot melt film 2 ', in upper flocked film base
Material 3 ', upper strata fine hair 5 be clipped in flocked film base material 3, between upper flocked film base material 3 ', upper flocked film base material 3 is with
The opposite surface of upper flocked film base material 3 ' be respectively coated binder film 4, in upper binder film 4 ', the both ends of upper strata fine hair 5
Insert respectively upper binder film 4, among upper binder film 4 ', be fixedly arranged at flocked film base material 3, in upper flocked film base material
3 ' surface.Middle lower floor's fibre web 6 ' in using in lower hot melt film 7, lower hot melt film 7 ' consolidation respectively with the opposite surface of lower floor's fibre web 1 '
Lower flocked film base material 8, lower flocked film base material 8 ', undercoat 5 ' lower flocked film base material 8, lower flocked film base in being clipped in
Between material 8 ', in lower flocked film base material 8 be respectively coated with the opposite surface of lower flocked film base material 8 ' in lower binder film 9,
Lower binder film 9 ', the both ends of undercoat 5 ' in inserting among lower binder film 9, lower binder film 9 ' respectively, in being fixedly arranged at
Lower flocked film base material 8, the surface of lower flocked film base material 8 '.Upper hot melt film 2, in upper hot melt film 2 ', in lower hot melt film 7, under
Hot melt film 7 ', upper flocked film base material 3, in upper flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material
8 ' be shaped as along breadth direction width is 1cm, spacing distance 1cm, is 1cm, spacing distance 1cm along width length direction width
Checker board.Upper flocked film base material 3, in upper flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material
8 ' be PET film base material.The material of upper strata fine hair 5 and undercoat 5 ' is that fineness is 5D, and length is that 1.5mm polyamide is short
Fiber.Be consolidated at the middle and upper levels between fibre web 6 and middle lower floor's fibre web 6 ' with hot melt film, upper hot melt film 2, in upper hot melt film 2 ',
In lower hot melt film 7, lower hot melt film 7 ', the hot melt film at the middle and upper levels between fibre web 6 and middle lower floor's fibre web 6 ' be EVA hot-melt adhesive net
Film, melting temperature are 110 DEG C.The adhesive that adhesive is selected is high, water-fastness, the ageing-resistant polyacrylate of adhesion strength
Static flocking adhesive.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, this method comprise the following steps：
（1）Prepare before flocking：By upper flocked film base material 3, in upper flocked film base material 3 ', upper hot melt film 2, in upper heat
Film 2 ' is prepared into shape size identical checker board shape；Will in lower flocked film base material 8, lower flocked film base material 8 ', under
Hot melt film 7, lower hot melt film 7 ' are prepared into shape size identical checker board shape；
（2）It is prepared by fibre web：Using method into the net is combed, upper strata fibre web 1 is prepared respectively, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6 ', lower floor's fibre web 1 '；
（3）Spray antiseptic：Difference uniformly sprays antiseptic 11 to upper strata fibre web 1 under a certain pressure, to fibre web 6 at the middle and upper levels
Uniformly sprinkling antiseptic 11,, to middle lower floor's fibre web 6,Uniformly sprinkling antiseptic 12,, to lower floor's fibre web 1,Uniformly sprinkling antiseptic
12, make antiseptic 11,11,、12,, 12 can as far as possible be evenly distributed in upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6,、
Lower floor's fibre web 1,Inside, obtain good anti-microbial property after being easy to drying；
（4）Drying：Respectively to being sprayed with antiseptic 11,11,、12,, 12 upper strata fibre web 1, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6,, lower floor's fibre web 1,Carry out drying；
（5）Hot pressing overlay film：Upper flocked film base material 3 is coated on upper strata fibre web 1 together with upper hot melt film 2, and made
For hot melt film 2 between upper flocked film base material 3 and upper strata fibre web 1, hot pressing melts hot melt film 2, by upper flocked film base material 3
It is fixedly arranged on upper strata fibre web 1；Upper flocked film base material 3 ' is coated at the middle and upper levels on fibre web 6 in together with upper hot melt film 2 ' by,
And in making upper hot melt film 2 ' on flocked film base material 3 ' with the middle and upper levels between fibre web 6, hot pressing upper melting of hot melt film 2 ' in making,
Upper flocked film base material 3 ' is fixedly arranged at the middle and upper levels on fibre web 6 by；Under lower flocked film base material 8 is in by together with hot melt film 7
Coated on middle lower floor's fibre web 6 ', and lower hot melt film 7 is warm between lower flocked film base material 8 and middle lower floor's fibre web 6 ' in making
Lower hot melt film 7 in making is pressed to melt, lower flocked film base material 8 is fixedly arranged on middle lower floor's fibre web 6 ' by；Upper flocked film base material 3 is solid
Tie upper strata fibre web 1, on flocked film base material 3 ' be fixedly arranged at fibre web 6 at the middle and upper levels position it is corresponding.By lower flocked film base
Material 8 ' together with lower binder film 9 ' coated on lower floor's fibre web 1 ', and make lower binder film 9 ' lower flocked film base material 8 ' with
Between lower floor's fibre web 1 ', hot pressing melts lower binder film 9 ', and lower flocked film base material 8 ' is fixedly arranged on lower floor's fibre web 1 ', in
It is also corresponding that lower flocked film base material 8 and lower flocked film base material 8 ' are fixedly arranged at middle lower floor's fibre web 6 ', the position of lower floor's fibre web 1 '.
Hot pressing temperature is 160 DEG C, pressure size 2.5bar, hot pressing time 10min；
（6）Gluing：Respectively in the upper flocked film base material 3 being fixedly arranged on upper strata fibre web 1, be fixedly arranged at the middle and upper levels on fibre web 6
In upper flocked film base material 3 ', be fixedly arranged on middle lower floor's fibre web 6 ' in lower flocked film base material 8, be fixedly arranged at lower floor's fibre web 1 '
On lower flocked film base material 8 ' surface on apply be covered with binder film 4, in upper binder film 4 ', in lower binder film 9, lower viscous
Mixture film 9 ', adhesive thickness 0.5mm；
（7）Electrostatic spinning：Electrostatic plant is carried out on the surface of the fibre web at the middle and upper levels 6 after gluing, middle lower floor's fibre web 6 ' respectively
Suede, the use of rated voltage is 50kV, output current 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field is by upper strata fine hair
5th, undercoat 5 ' be implanted in respectively fibre web 6 at the middle and upper levels and in upper flocked film base material 3 ', middle lower floor's fibre web 6 ' and in lower flocking it is thin
The surface of film base material 8, and upper strata fine hair 5, undercoat 5 ' is in straight configuration；
（8）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, criteria thus the drying time 3min, drying upper binder film 4 ' in making, in lower binder film 9 water
Point evaporation, the surface of the upper flocked film base material 3 ' in consolidating of upper strata fine hair 5, the lower flocked film base material 8 in consolidating of undercoat 5 '
Surface；
（9）Inhale suede：The fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' that drying is crossed, carry out inhaling suede processing.On in being scattered in
Layer fibre web 6, middle lower floor's fibre web 6 ' surface on and do not sopped up by upper strata fine hair 5, the undercoat 5 ' of adhesive secure bond；
（10）Fibre web overlay film consolidates：The fibre web at the middle and upper levels 6 after suede is handled and middle lower floor's fibre web 6 ', which will be inhaled, does not have the one of flocking
Face is superimposed with each other, and middle folder hot melt film 10, is 160 DEG C, pressure size 2.5bar by hot pressing temperature, hot pressing time is
10min hot-pressing processing, fibre web 6 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 6 '；
（11）Fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web 1 after hot pressing overlay film, gluing is crossed with inhaling suede respectively
6, lower floor's fibre web 1 ' is 50kV with inhaling middle lower floor's fibre web 6 ' for crossing of suede in rated voltage, output current 5mA, high voltage electric field interpolar
The distance 12cm lower progress of high voltage electric field effect is compound；
（12）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes binder film 4, the moisture evaporation of lower binder film 9 ', and the other end of upper strata fine hair 5 is fixedly arranged at flocking
The surface of film substrate 3, the other end of undercoat 5 ' are fixedly arranged at the surface of lower flocked film base material 8 '；
（13）Winding：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
Embodiment 3
High-elastic antibacterial thermal insulating flaky material of strip film flocking formula air lay and preparation method thereof：
Referring to Fig. 1, Fig. 2, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, including upper strata fibre web 1, upper hot melt film
2nd, upper flocked film base material 3, upper binder film 4, upper strata fine hair 5, in upper binder film 4 ', in upper flocked film base material 3 ', in
Upper hot melt film 2 ', at the middle and upper levels fibre web 6, hot melt film 10, middle lower floor's fibre web 6 ', in lower hot melt film 7, in lower flocked film base material 8, in
It is lower binder film 9, undercoat 5 ', lower binder film 9 ', lower flocked film base material 8 ', lower hot melt film 7 ', lower floor's fibre web 1 ', anti-
Microbial inoculum 11,11,、12、12,.Upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6 ', lower floor's fibre web 1 ' are that fineness is 3D, long
Spend the hollow polyester fibre of the three-dimensional crimp for 51mm and fineness is 3D, length 51mm, the low melting point that fusing point is 110 DEG C is fine
Dimension, according to weight than 80%:20% carries out shredding mixing, the fibre web being prepared by short-fiber airlaid.The fibre web 1 on upper strata
The antiseptic 11 containing chitosan is sprayed, fibre web 6 sprays the antiseptic 11 containing chitosan at the middle and upper levels,, the middle spray of lower floor's fibre web 6 '
Spill the antiseptic 12 containing chitosan,, lower floor's fibre web 1 ' spray the antiseptic 12 containing chitosan, upper strata fibre web 1 with the middle and upper levels
The opposite surface of fibre web 6 respectively with hot melt film 2, in the upper flocked film base material 3 of the upper consolidation of hot melt film 2 ', in upper flocked film base
Material 3 ', upper strata fine hair 5 be clipped in flocked film base material 3, between upper flocked film base material 3 ', upper flocked film base material 3 is with
The opposite surface of upper flocked film base material 3 ' be respectively coated binder film 4, in upper binder film 4 ', the both ends of upper strata fine hair 5
Insert respectively upper binder film 4, among upper binder film 4 ', be fixedly arranged at flocked film base material 3, in upper flocked film base material
3 ' surface.Middle lower floor's fibre web 6 ' in using in lower hot melt film 7, lower hot melt film 7 ' consolidation respectively with the opposite surface of lower floor's fibre web 1 '
Lower flocked film base material 8, lower flocked film base material 8 ', undercoat 5 ' lower flocked film base material 8, lower flocked film base in being clipped in
Between material 8 ', in lower flocked film base material 8 be respectively coated with the opposite surface of lower flocked film base material 8 ' in lower binder film 9,
Lower binder film 9 ', the both ends of undercoat 5 ' in inserting among lower binder film 9, lower binder film 9 ' respectively, in being fixedly arranged at
Lower flocked film base material 8, the surface of lower flocked film base material 8 '.Upper hot melt film 2, in upper hot melt film 2 ', in lower hot melt film 7, under
Hot melt film 7 ', upper flocked film base material 3, in upper flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material
8 ' the width that is shaped as is 1cm, and spacing distance is the 1cm bar shaped along breadth directional spreding.Upper flocked film base material 3, on
Flocked film base material 3 ', in lower flocked film base material 8, lower flocked film base material 8 ' be PET film base material.Upper strata fine hair 5 with
The material of undercoat 5 ' is that fineness is 5D, and length is 1.5mm polyester staple fiber.Fibre web 6 and middle lower floor's fibre web 6 ' at the middle and upper levels
Between be consolidated with hot melt film, upper hot melt film 2, in upper hot melt film 2 ', in lower hot melt film 7, lower hot melt film 7 ', fine at the middle and upper levels
Hot melt film between net 6 and middle lower floor's fibre web 6 ' is EVA hot-melt adhesive nethike embrane, and melting temperature is 110 DEG C.Adhesive is selected viscous
Mixture is high, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of adhesion strength.
The manufacture method of the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, this method comprise the following steps：
（1）Prepare before flocking：By upper flocked film base material 3, in upper flocked film base material 3 ', upper hot melt film 2, in upper heat
Film 2 ' is prepared into shape size identical bar shape；Will in lower flocked film base material 8, lower flocked film base material 8 ', in lower heat
Melt film 7, lower hot melt film 7 ' are prepared into shape size identical bar shape；
（2）It is prepared by fibre web：Using the method for air lay, upper strata fibre web 1 is prepared respectively, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6 ', lower floor's fibre web 1 '；
（3）Spray antiseptic：Difference uniformly sprays antiseptic 11 to upper strata fibre web 1 under a certain pressure, to fibre web 6 at the middle and upper levels
Uniformly sprinkling antiseptic 11,, to middle lower floor's fibre web 6,Uniformly sprinkling antiseptic 12,, to lower floor's fibre web 1,Uniformly sprinkling antiseptic
12, make antiseptic 11,11,、12,, 12 can as far as possible be evenly distributed in upper strata fibre web 1, at the middle and upper levels fibre web 6, middle lower floor's fibre web 6,、
Lower floor's fibre web 1,Inside, obtain good anti-microbial property after being easy to drying；
（4）Drying：Respectively to being sprayed with antiseptic 11,11,、12,, 12 upper strata fibre web 1, fibre web 6, middle lower floor are fine at the middle and upper levels
Net 6,, lower floor's fibre web 1,Carry out drying；
（5）Hot pressing overlay film：Upper flocked film base material 3 is coated on upper strata fibre web 1 together with upper hot melt film 2, and made
For hot melt film 2 between upper flocked film base material 3 and upper strata fibre web 1, hot pressing melts hot melt film 2, by upper flocked film base material 3
It is fixedly arranged on upper strata fibre web 1；Upper flocked film base material 3 ' is coated at the middle and upper levels on fibre web 6 in together with upper hot melt film 2 ' by,
And in making upper hot melt film 2 ' on flocked film base material 3 ' with the middle and upper levels between fibre web 6, hot pressing upper melting of hot melt film 2 ' in making,
Upper flocked film base material 3 ' is fixedly arranged at the middle and upper levels on fibre web 6 by；Under lower flocked film base material 8 is in by together with hot melt film 7
Coated on middle lower floor's fibre web 6 ', and lower hot melt film 7 is warm between lower flocked film base material 8 and middle lower floor's fibre web 6 ' in making
Lower hot melt film 7 in making is pressed to melt, lower flocked film base material 8 is fixedly arranged on middle lower floor's fibre web 6 ' by；Upper flocked film base material 3 is solid
Tie upper strata fibre web 1, on flocked film base material 3 ' be fixedly arranged at fibre web 6 at the middle and upper levels position it is corresponding.By lower flocked film base
Material 8 ' together with lower binder film 9 ' coated on lower floor's fibre web 1 ', and make lower binder film 9 ' lower flocked film base material 8 ' with
Between lower floor's fibre web 1 ', hot pressing melts lower binder film 9 ', and lower flocked film base material 8 ' is fixedly arranged on lower floor's fibre web 1 ', in
It is also corresponding that lower flocked film base material 8 and lower flocked film base material 8 ' are fixedly arranged at middle lower floor's fibre web 6 ', the position of lower floor's fibre web 1 '.
Hot pressing temperature is 160 DEG C, pressure size 2.5bar, hot pressing time 10min；
（6）Gluing：Respectively in the upper flocked film base material 3 being fixedly arranged on upper strata fibre web 1, be fixedly arranged at the middle and upper levels on fibre web 6
In upper flocked film base material 3 ', be fixedly arranged on middle lower floor's fibre web 6 ' in lower flocked film base material 8, be fixedly arranged at lower floor's fibre web 1 '
On lower flocked film base material 8 ' surface on apply be covered with binder film 4, in upper binder film 4 ', in lower binder film 9, lower viscous
Mixture film 9 ', adhesive thickness 0.5mm；
（7）Electrostatic spinning：Electrostatic plant is carried out on the surface of the fibre web at the middle and upper levels 6 after gluing, middle lower floor's fibre web 6 ' respectively
Suede, the use of rated voltage is 50kV, output current 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field is by upper strata fine hair
5th, undercoat 5 ' be implanted in respectively fibre web 6 at the middle and upper levels and in upper flocked film base material 3 ', middle lower floor's fibre web 6 ' and in lower flocking it is thin
The surface of film base material 8, and upper strata fine hair 5, undercoat 5 ' is in straight configuration；
（8）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, criteria thus the drying time 3min, drying upper binder film 4 ' in making, in lower binder film 9 water
Point evaporation, the surface of the upper flocked film base material 3 ' in consolidating of upper strata fine hair 5, the lower flocked film base material 8 in consolidating of undercoat 5 '
Surface；
（9）Inhale suede：The fibre web at the middle and upper levels 6 and middle lower floor's fibre web 6 ' that drying is crossed, carry out inhaling suede processing.On in being scattered in
Layer fibre web 6, middle lower floor's fibre web 6 ' surface on and do not sopped up by upper strata fine hair 5, the undercoat 5 ' of adhesive secure bond；
（10）Fibre web overlay film consolidates：The fibre web at the middle and upper levels 6 after suede is handled and middle lower floor's fibre web 6 ', which will be inhaled, does not have the one of flocking
Face is superimposed with each other, and middle folder hot melt film 10, is 160 DEG C, pressure size 2.5bar by hot pressing temperature, hot pressing time is
10min hot-pressing processing, fibre web 6 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 6 '；
（11）Fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web 1 after hot pressing overlay film, gluing is crossed with inhaling suede respectively
6, lower floor's fibre web 1 ' is 50kV with inhaling middle lower floor's fibre web 6 ' for crossing of suede in rated voltage, output current 5mA, high voltage electric field interpolar
The distance 12cm lower progress of high voltage electric field effect is compound；
（12）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, criteria thus the drying time
For 3min, drying makes binder film 4, the moisture evaporation of lower binder film 9 ', and the other end of upper strata fine hair 5 is fixedly arranged at flocking
The surface of film substrate 3, the other end of undercoat 5 ' are fixedly arranged at the surface of lower flocked film base material 8 '；
（13）Winding：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
Claims (7)
- A kind of 1. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula, it is characterised in that：Sprayed inside upper strata fibre web (1) anti- Microbial inoculum (11), antiseptic (11 ') is sprayed inside fibre web (6) at the middle and upper levels, antiseptic (12 ') is sprayed inside middle lower floor's fibre web (6 '), Antiseptic (12) is sprayed inside lower floor's fibre web (1 '), upper strata fibre web (1) is with the opposite surface of fibre web (6) at the middle and upper levels respectively with heat Melt film (2), in flocked film base material (3) in upper hot melt film (2 ') consolidation, in go up flocked film base material (3 '), upper strata fine hair (5) Be clipped in flocked film base material (3), between upper flocked film base material (3 '), it is thin that upper flocked film base material (3) goes up flocking with The opposite surface of film base material (3 ') be respectively coated binder film (4), in upper binder film (4 '), upper strata fine hair (5)In stretching Straight state,Both ends insert respectively binder film (4), among upper binder film (4 '), be fixedly arranged at flocked film base material (3) surface of upper flocked film base material (3 ') in, during middle lower floor's fibre web (6 ') is used respectively with the opposite surface of lower floor's fibre web (1 ') Lower flocked film base material (8), lower flocked film base material (8 '), undercoat in lower hot melt film (7), lower hot melt film (7 ') consolidation (5 ') are lower between flocked film base material (8), lower flocked film base material (8 ') in being clipped in, in lower flocked film base material (8) and lower plant The opposite surface of suede film substrate (8 ') lower binder film (9), lower binder film (9 '), undercoat (5 ') in being respectively coatedPlace In straight configuration,Both ends are descended among binder film (9), lower binder film (9 ') in inserting respectively, lower flocked film in being fixedly arranged at Base material (8), the surface of lower flocked film base material (8 '), use hot melt film between fibre web (6) and middle lower floor's fibre web (6 ') at the middle and upper levels (10) it is consolidated.
- A kind of 2. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as claimed in claim 1, it is characterised in that：It is described Upper strata fibre web (1), at the middle and upper levels fibre web (6), middle lower floor's fibre web (6 '), lower floor's fibre web (1 ') be short-fibred mechanical comb networking or The fibre web of air lay.
- A kind of 3. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as claimed in claim 1, it is characterised in that：It is described Antiseptic (11) (11 ') (12) (12 ') for good anti-bacterial effect, water-fastness antiseptic.
- A kind of 4. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as claimed in claim 1, it is characterised in that：It is described Upper flocked film base material (3), in upper flocked film base material (3 '), in lower flocked film base material (8), lower flocked film base material (8 '), upper hot melt film (2), in upper hot melt film (2 '), in lower hot melt film (7), lower hot melt film (7 ') be shaped as bar shaped or grid Shape, size are identical.
- A kind of 5. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as claimed in claim 1, it is characterised in that：It is described Upper binder film (4), in upper binder film (4 '), in the adhesive selected of lower binder film (9), lower binder film (9 ') be High, water-fastness, aging-resisting type the adhesive of adhesion strength.
- A kind of 6. high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as claimed in claim 1, it is characterised in that：It is described The material of upper strata fine hair (5) and undercoat (5 ') be polyester fiber or Fypro.
- A kind of 7. manufacture of the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula as any one of claim 1-6 Method, it is characterised in that：This method comprises the following steps：(1) prepare before flocking：By upper flocked film base material (3), in upper flocked film base material (3 '), upper hot melt film (2), in upper heat Melt film (2 ') is prepared into the shape of the bar shaped of size identical or grid；Lower flocked film base material (8), lower flocked film base by Material (8 '), in lower hot melt film (7), lower hot melt film (7 ') be prepared into the shape of the bar shaped of size identical or grid；(2) prepared by fibre web：Upper strata fibre web (1), at the middle and upper levels fibre web (6), middle lower floor's fibre web (6 '), lower floor's fibre web are prepared respectively (1’)；(3) antiseptic is sprayed：Antiseptic (11) is sprayed to upper strata fibre web (1) under a certain pressure respectively, is sprayed to fibre web at the middle and upper levels (6) Antiseptic (11 ') is spilt, sprays antiseptic (12 '), lower floor's fibre web (1 ') sprinkling antiseptic (12) to middle lower floor's fibre web (6 ')；(4) drying：Respectively to being sprayed with the upper strata fibre web (1) of antiseptic (11), the fibre web at the middle and upper levels (6) of antiseptic (11 ') is sprayed with, Middle lower floor's fibre web (6 ') of antiseptic (12 ') is sprayed with, the lower floor's fibre web (1 ') for being sprayed with antiseptic (12) carries out drying；(5) hot pressing overlay film：Upper flocked film base material (3) is coated on upper strata fibre web (1) together with upper hot melt film (2), and made Upper hot melt film (2) is between upper flocked film base material (3) and upper strata fibre web (1), and hot pressing melts hot melt film (2), by upper plant Suede film substrate (3) is fixedly arranged on upper strata fibre web (1)；Upper flocked film base material (3 ') applies in together with upper hot melt film (2 ') by Overlay at the middle and upper levels on fibre web (6), and in making upper hot melt film (2 ') on flocked film base material (3 ') and fibre web (6) at the middle and upper levels it Between, hot pressing upper hot melt film (2 ') melting in making, upper flocked film base material (3 ') is fixedly arranged at the middle and upper levels on fibre web (6) by；By in Lower flocked film base material (8) is descended together with hot melt film (7) in and is coated on middle lower floor's fibre web (6 '), and descends hot melt film (7) in making Under between flocked film base material (8) and middle lower floor's fibre web (6 '), hot pressing lower hot melt film (7) melting in making, the lower flocking by Film substrate (8) is fixedly arranged on middle lower floor's fibre web (6 ')；Lower flocked film base material (8 ') is applied together with lower binder film (9 ') Overlay on lower floor's fibre web (1 '), and make lower binder film (9 ') between lower flocked film base material (8 ') and lower floor's fibre web (1 '), Hot pressing melts lower binder film (9 '), and lower flocked film base material (8 ') is fixedly arranged on lower floor's fibre web (1 ')；(6) gluing：Respectively the upper flocked film base material (3) on upper strata fibre web (1) is fixedly arranged at, be fixedly arranged at fibre web (6) at the middle and upper levels On in upper flocked film base material (3 '), be fixedly arranged on middle lower floor's fibre web (6 ') in lower flocked film base material (8), be fixedly arranged at down Applied on the surface of lower flocked film base material (8 ') on layer fibre web (1 ') be covered with binder film (4), in upper binder film (4 '), in Lower binder film (9), lower binder film (9 ')；(7) electrostatic spinning：Respectively the fibre web at the middle and upper levels (6) after gluing, middle lower floor's fibre web (6 ') surface on carry out electrostatic plant Suede, by upper strata fine hair (5), undercoat (5 ') be implanted in respectively fibre web (6) at the middle and upper levels and in upper flocked film base material (3 '), under Layer fibre web (6 ') and in lower flocked film base material (8) surface, and be in upper strata fine hair (5), undercoat (5 ') and stretch shape State；(8) drying：Drying is carried out to the fibre web at the middle and upper levels (6) and middle lower floor's fibre web (6 ') for having completed electrostatic spinning；(9) suede is inhaled：Fibre web at the middle and upper levels (6) that drying is crossed and middle lower floor's fibre web (6 ') are carried out to inhale suede processing；(10) fibre web overlay film consolidates：The fibre web at the middle and upper levels (6) after suede is handled and middle lower floor's fibre web (6 '), which will be inhaled, does not have the one of flocking Face is superimposed with each other, and middle folder hot melt film (10), fibre web (6) will be fixedly arranged at the middle and upper levels with middle lower floor's fibre web (6 ') through Overheating Treatment Together；(11) fibre web is compound：The fibre web at the middle and upper levels that the upper strata fibre web (1) after hot pressing overlay film, gluing is crossed with inhaling suede respectively (6) progress is compound, and middle lower floor's fibre web (6 ') that lower floor's fibre web (1 ') is crossed with suction suede is 50kV in rated voltage, and output current is 5mA, high voltage electric field anode-cathode distance the 12cm lower progress of high voltage electric field effect are compound；(12) drying：After fibre web is compound, drying is carried out, makes binder film (4), the moisture evaporation of lower binder film (9 '), on The other end of layer fine hair (5) is fixedly arranged at the surface of flocked film base material (3), and the other end of undercoat (5 ') is fixedly arranged at lower plant The surface of suede film substrate (8 ')；(13) wind：After drying, winding, the high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula is made.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510251731.8A CN104842595B (en) | 2015-05-18 | 2015-05-18 | A kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method |
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| CN201510251731.8A CN104842595B (en) | 2015-05-18 | 2015-05-18 | A kind of high-elastic antibacterial thermal insulating flaky material of thin-film multilayer flocking formula and its manufacture method |
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| CN2381484Y (en) * | 1999-05-26 | 2000-06-07 | 陈学清 | Thermal insulating composite flannelette |
| CN2439447Y (en) * | 2000-07-21 | 2001-07-18 | 上海菲常保暖制品开发应用有限公司 | Bacteriostasis, high strength of extension and super warm keeping composite material |
| US20060231188A1 (en) * | 2004-12-07 | 2006-10-19 | Wen Han C | Method for making artificial suede |
| CN1730804A (en) * | 2005-08-26 | 2006-02-08 | 上海汽车集团股份有限公司 | Antibacterial fabric and its preparation method |
| CN201950858U (en) * | 2010-10-22 | 2011-08-31 | 吴江天信勤丰纺织有限公司 | Waterproof dual-layer flocked fabric |
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