CN104999725B - A kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material and its manufacture method - Google Patents
A kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material and its manufacture method Download PDFInfo
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- CN104999725B CN104999725B CN201510251750.0A CN201510251750A CN104999725B CN 104999725 B CN104999725 B CN 104999725B CN 201510251750 A CN201510251750 A CN 201510251750A CN 104999725 B CN104999725 B CN 104999725B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/025—Particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
- B32B2264/0264—Polyamide particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
- B32B2264/0278—Polyester particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Abstract
The present invention relates to a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material and its manufacture method, belong to textile technology field.The upper strata fibre web of the high-elastic heat insulation flaky material and the opposite surface of fibre web at the middle and upper levels be respectively coated binder film, in upper binder film, upper fine hair vertical is clipped in upper strata fibre web and at the middle and upper levels between fibre web, middle lower floor's fibre web lower binder film, lower binder film in being respectively coated with the opposite surface of lower floor's fibre web, lower fine hair vertical is clipped between middle lower floor's fibre web and lower floor's fibre web, and fibre web is consolidated with middle lower floor's fibre web at the middle and upper levels.Preparation method includes（1）It is prepared by fibre web,（2）Gluing,（3）Electrostatic spinning,（4）Drying,（5）Inhale suede,（6）Fibre web overlay film is consolidated,（7）Fibre web is combined,（8）Drying,（9）Winding steps.Compared with prior art, warming sheet elastic properties of materials produced by the present invention is good, warmth retention property is good.
Description
Technical field
The present invention relates to a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material and its manufacture method, belong to weaving neck
Domain.
Background technology
With the development of chemical fibres industry, the research and development of heat insulating material are from fur, silk, wool, cotton and plumage
The natural fibers such as suede turn to chemical fibre, occur in that the chemical fibre insulation flocculus based on terylene, polypropylene fibre and the acrylic fibers, such as glue spraying
The far infrareds such as cotton, acupuncture cotton, space wadding, hot melting wool, melt-blown far infrared cotton, ultra-fine hot melting wool, down-like cotton.With cotton, fiber crops,
The heat insulating material of the preparation such as silk, hair and common terylene, polyamide fibre, acrylic fibers and staple fibre is commonly referred to as traditional heat insulating material, this
In a little heat insulating materials, silk and wool warmth retention property preferably, but the easy breed bacteria of fiber, intolerant to damaging by worms, and silk price is high
Expensive, wool fiber has peculiar smell, forming degree poor, and the cashmere price after multiple working procedure is processed is more expensive, for many years using scope
Limited to.The demand of heat insulating material is improved constantly with the high development and people of science and technology, above-mentioned tradition guarantor
Warm material can not meet needs, and people, which begin one's study, develops new heat insulating material.The principal mode of heat transfer has hot biography
Lead, three kinds of modes of heat radiation and thermal convection current.Material characteristicses and internal structure determine the fast of its heat conduction velocity under normal circumstances
Slowly, material internal structure and outer shape determine the quality of its heat radiation and antiradiation performance, material shape and structures shape
Its remains stationary air and the ability for preventing air flow.Traditional heat insulating material depends on the thickness of heat insulating material
Still air layer between density increased fiber improves thermal property.The thickness of usual material is bigger, and density is smaller, material
Warmth retention property it is better, but if the density of material is too small, when causing the air therein to produce convection current, heat-insulating property declines on the contrary,
For clothes heat insulating material, thickness crosses conference and causes the volume ratio of clothes more too fat to move, is not easy to motion and lacks aesthetic feeling,
It is this that people can not be met by way of improving clothing heat insulation increasing the method for material thickness as people are to beautiful pursuit
Requirement to clothing function and aesthetic property.The exploitation of novel heat-preserving material is increasingly becoming the weight of various countries' research with research work
Point, and have become the main flow of heat insulating material research and development.Current people are by effectively blocking and reducing the side of calorie spread
Method improves warming effect, has been developed that many new heat insulating materials, such as pearl cotton wool flake, eider down wadding felt, ultra-fine hot melt
Cotton, melt-blown cotton and its composite heat insulation material etc..These new materials are either all in constantly improve mistake on fiber or technique
Cheng Zhong, they with its light weight, warming, good permeability, windproof, mould proof, mothproof, acid and alkali-resistance, can directly wash the advantages of it is extensive
Applied to production.The novel heat-preserving material developed in recent years also has far-infrared warm material, sunlight heat accumulation thermal material, medium phase
Become thermal control material etc., this kind of heat insulating material not only follows traditional heat-insulation warm keeping principle, and can pass through some other shapes
Formula, for example, absorb external heat, stores and fuel factor is produced to human body transmission, or by solar energy, electric energy and chemical energy
The purpose of heat-insulation warm keeping is reached etc. heat energy is changed into.For the more excellent insulation flocculus of processability, by electrostatic spinning skill
Art is also introduced into the preparation of insulation flocculus.Using static flocking technology preparation is combined with traditional insulation flocculus manufacture method
The existing document report of Novel heat-preservation flocculus, such as Chinese invention patent application publication No. CN102493128A, entitled one kind
The manufacture method of melt blowing warm retention wadding, this application case discloses a kind of manufacture method of melt blowing warm retention wadding, and heat-accumulation temperature-adjustment is short
Fiber is implanted in the middle of melt-blowing nonwoven by electrostatic field, and melt blowing warm retention wadding is made.This method, is to utilize electrostatic spinning
Technology, chopped fiber is implanted to inside non-woven webs, little to performance impacts such as the elasticity and bulkiness of insulation flocculus.People
Growth in the living standard, requirements at the higher level not only are proposed to the warming effect of heat insulating material, and to the elasticity of heat insulating material
Aspect it is also proposed strict requirements, therefore high-elastic heat insulation material of the research and development with warmth retention property becomes as original heat insulating material is substituted
Obtain very meaningful.
The content of the invention
It is an object of the invention to provide the warming flaky material that a kind of warmth retention property is good, elasticity is good and its manufacture method.
To achieve these goals, the technical scheme is that：A kind of gluing Multi-layer flocking formula high-elastic heat insulation sheet material
Material, it is characterised in that：Upper strata fibre web and the opposite surface of fibre web at the middle and upper levels be respectively coated binder film, in upper binder film,
Upper fine hair is clipped in upper strata fibre web and at the middle and upper levels between fibre web, the two ends of upper fine hair be respectively inserted into binder film, in upper bond
Among agent film, the surface and the surface of fibre web at the middle and upper levels of upper strata fibre web, middle lower floor's fibre web and the opposite table of lower floor's fibre web are fixedly arranged at
Face lower binder film, lower binder film in being respectively coated, lower fine hair are clipped between middle lower floor's fibre web and lower floor's fibre web, lower fine hair
Two ends among lower binder film, lower binder film, are fixedly arranged at the surface of middle lower floor's fibre web and lower floor's fibre web in being respectively inserted into, in
Upper strata fibre web is consolidated with middle lower floor's fibre web by one layer of hot melt film.
Described upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, lower floor's fibre web are that short-fibred mechanical combs networking or gas
Flow fibre web into the net.
Described upper binder film, in upper binder film, in the adhesive selected of lower binder film, lower binder film be viscous
Knotting strength is high, water-fastness, aging-resisting type adhesive.
Described upper binder film, in upper binder film, in lower binder film, lower binder film be shaped as bar shaped or lattice
Sub- shape, size is identical.
Described upper fine hair, the material of lower fine hair are polyester fiber or Fypro.
A kind of manufacture method of above-mentioned gluing Multi-layer flocking formula high-elastic heat insulation flaky material, it is characterised in that：This method bag
Include following steps：
（1）It is prepared by fibre web：Upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, lower floor's fibre web are prepared respectively；
（2）Gluing：Respectively upper strata fibre web, at the middle and upper levels fibre web, middle lower floor's fibre web, bonding is coated in the one side of lower floor's fibre web
Agent, upper binder film, in upper binder film, in lower binder film, lower binder film；
（3）Electrostatic spinning：It is coated with the surface of adhesive in fibre web at the middle and upper levels and middle lower floor's fibre web and carries out electrostatic spinning,
Upper fine hair, lower fine hair are implanted in the surface of fibre web, middle lower floor's fibre web at the middle and upper levels respectively；
（4）Drying：Drying is carried out to the fibre web at the middle and upper levels and middle lower floor's fibre web for having completed electrostatic spinning；
（5）Inhale suede：The fibre web at the middle and upper levels that drying is crossed and middle lower floor's fibre web carry out inhaling suede processing；
（6）Fibre web overlay film is consolidated：The fibre web at the middle and upper levels after suede processing will be inhaled does not have the one side phase of flocking with middle lower floor's fibre web
Mutually overlapping, and one layer of hot melt film of middle folder, fibre web will be consolidated with middle lower floor's fibre web at the middle and upper levels through Overheating Treatment；
（7）Fibre web is combined：Upper strata fibre web is had to the one side of upper binder film, is compounded on the flocked surface of fibre web at the middle and upper levels,
Lower floor's fibre web is had to the one side of lower binder film, on the flocked surface for being compounded in middle lower floor's fibre web；
（8）Drying：After fibre web is compound, drying is carried out；
（9）Winding：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
Due to using above technical scheme, gluing Multi-layer flocking formula high-elastic heat insulation flaky material of the invention, with following
Feature：
First, the present invention is implanted into fine hair chopped fiber using static flocking technology between multilayer fibre web, is formed between fibre web
Still air region, can not only improve warming effect, and compared with prior art, the space inside fibre web is big, same
Under conditions of sample thickness, the usage amount of fibrous material can be reduced, production cost is reduced.
2nd, because the two ends of fine hair are fixedly arranged on two layers of fibre web by adhesive phase, fine hair is shorter, in villus length direction
During stress, bending resistance is strong, and recovery is good, the warming flaky material of manufacture it is elastic good.
3rd, the hot melt film selected of the present invention is the hot melt net of Reticular breathable structure, be disclosure satisfy that between two layer web
Bonding it is compound while, it is ensured that the gas permeability of flaky material.
4th, the adhesive that the present invention is selected is water-fastness, aging-resisting type adhesive, disclosure satisfy that the requirement of clothes, adopts
Bar shaped or checker board glue spreading method are taken, the high resiliency of warming flaky material is being realized, while improving warmth retention property, it is ensured that
The gas permeability of flaky material, is the ideal material for substituting eider down, as filler, can be widely used for garment industry.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Fig. 2 is that fibre web carries out the structural representation after bar shaped gluing flocking at the middle and upper levels according to embodiment of the present invention.
Fig. 3 is that fibre web carries out the structural representation after checker board gluing flocking at the middle and upper levels according to embodiment of the present invention.
Embodiment
The present invention is described in further detail below in conjunction with the drawings and specific embodiments.
Referring to Fig. 1-Fig. 3.
Gluing Multi-layer flocking formula high-elastic heat insulation flaky material, including upper strata fibre web 1, upper binder film 4, in upper binder film
4,, fibre web 2, hot melt film 6, middle lower floor's fibre web 2 at the middle and upper levels,, in lower binder film 5, lower binder film 5,, lower floor's fibre web 1,, upper suede
Hair 3, lower fine hair 3,.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2,, lower floor's fibre web 1,Networking is combed for short-fibred mechanical
Or airlaid fibre web.Upper strata fibre web 1 and the opposite surface of fibre web 2 at the middle and upper levels be respectively coated binder film 4, in upper bond
Agent film 4,, upper fine hair 3 is clipped between upper strata fibre web 1 and at the middle and upper levels fibre web 2, and the two ends of upper fine hair 3 are respectively inserted into adhesive
Film 4, in upper binder film 4,Among, it is fixedly arranged at the surface and the surface of fibre web 2, middle lower floor's fibre web 2 at the middle and upper levels of upper strata fibre web 1,With
Lower floor's fibre web 1,Opposite surface lower binder film 5, lower binder film 5 in being respectively coated,, lower fine hair 3,It is clipped in middle lower floor's fibre web
2,With lower floor fibre web 1,Between, lower fine hair 3,Two ends be respectively inserted into lower binder film 5, lower binder film 5,Among, consolidation
In middle lower floor's fibre web 2,With lower floor fibre web 1,Surface, fibre web 2 and middle lower floor's fibre web 2 at the middle and upper levels,Consolidated by one layer of hot melt film 6
Together.Upper binder film 4, in upper binder film 4,Size it is identical, be shaped as bar shaped or lattice shape, be coated in
The position on the surface of layer fibre web 1 and the at the middle and upper levels surface of fibre web 2 is corresponding, lower binder film 5, lower binder film 5,Size it is complete
It is exactly the same, bar shaped or lattice shape are shaped as, middle lower floor's fibre web 2 is coated in,Surface and lower floor's fibre web 1,Surface position phase
Correspondence, is conducive to upper fine hair 3 and lower fine hair 3,Into vertical, the elasticity of warming flaky material is improved.In order to improve warming sheet
The performances such as the water resistance of material, upper binder film 4, in upper binder film 4,, in lower binder film 5, lower binder film 5,Select
Adhesive is that adhesion strength is high, water-fastness, aging-resisting type adhesive, and it is shaped as bar shaped or lattice shape, can increase guarantor
Still air in warm material, lifts warming effect.Upper fine hair 3 and lower fine hair 3,Material it is fine for polyester fiber or polyamide
Dimension.
The manufacture method of gluing Multi-layer flocking formula high-elastic heat insulation flaky material, this method comprises the following steps：
（1）It is prepared by fibre web：Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 are prepared respectively,, lower floor's fibre web 1,；
（2）Gluing：Respectively in upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2,, lower floor's fibre web 1,One side on apply
Be covered with binder film 4, in upper binder film 4,, in lower binder film 5, lower binder film 5,, upper binder film 4 is upper be bonded
Agent film 4,The identical bar shaped of form and dimension or lattice shape, be coated in the surface of upper strata fibre web 1 and fibre web 2 at the middle and upper levels
Position it is corresponding, be easy in electrostatic spinning, upper fine hair 3 into vertical, in lower binder film 5, lower binder film 5,Shape
Shape and the identical bar shaped of size or lattice shape, are coated in middle lower floor's fibre web 2,, lower floor's fibre web 1,Surface position it is relative
It should be easy in electrostatic spinning, lower fine hair 3,Into vertical；
（3）Electrostatic spinning：In fibre web 2 at the middle and upper levels and middle lower floor's fibre web 2,It is coated with progress electrostatic plant on the surface of adhesive
Suede, respectively by upper fine hair 3, lower fine hair 3,It is implanted in fibre web 2, middle lower floor's fibre web 2 at the middle and upper levels,Surface be in plumbness；
（4）Drying：Fibre web at the middle and upper levels 2 and middle lower floor's fibre web 2 to having completed electrostatic spinning,Carry out drying, in upper bond
Agent film 4,The moisture evaporation of lower binder film 5, upper fine hair 3 and lower fine hair 3 with,It is fixedly arranged at fibre web 2 at the middle and upper levels and middle lower floor's fibre web
2,Surface；
（5）Inhale suede：The fibre web at the middle and upper levels 2 that drying is crossed and middle lower floor's fibre web 2,Carry out inhale suede processing, in being scattered on
Layer fibre web 2 and middle lower floor's fibre web 2,There is no the position of application of adhesive on surface and not by the upper fine hair of adhesive secure bond
3 with lower fine hair 3,Sop up, make fibre web 2 at the middle and upper levels and middle lower floor's fibre web 2,Surface neat and tidy；
（6）Fibre web overlay film is consolidated：Fibre web at the middle and upper levels 2 and middle lower floor's fibre web 2 after suede processing will be inhaled,There is no the one side of flocking
It is superimposed with each other, and one layer of hot melt film 6 of middle folder, will fibre web 2 and middle lower floor's fibre web 2 at the middle and upper levels through Overheating Treatment,It is consolidated；
（7）Fibre web is combined：Under electrostatic field, upper strata fibre web 1 is had to the one side of upper binder film 4, in being compounded on
On the flocked surface of layer fibre web 2, by lower floor's fibre web 1,There is lower binder film 5,One side, be compounded in middle lower floor's fibre web 2,Flocked surface
On, upper fine hair 3 and lower fine hair 3,In the erectility stretched；
（8）Drying：After fibre web is compound, drying is carried out；
（9）Winding：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
Embodiment 1
Bar shaped gluing flocking formula machinery networking high-elastic heat insulation flaky material and preparation method thereof：
Referring to Fig. 1, Fig. 2, gluing Multi-layer flocking formula high-elastic heat insulation flaky material, including upper strata fibre web 1, upper binder film 4,
In upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor's fibre web 2 ', in lower binder film 5, lower binder film 5 ', under
Layer fibre web 1 ', upper fine hair 3, lower fine hair 3 '.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', lower floor's fibre web 1 ' are fineness
For 3D, the hollow polyester fibre and fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is low for 110 DEG C
Melting-point fibers, compare 80% according to weight:20% carries out shredding mixing, and the fibre web prepared is combed by short-fibred mechanical.Upper strata
Fibre web 1 and the opposite surface of fibre web 2 at the middle and upper levels be respectively coated binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in
Layer fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 be respectively inserted into binder film 4, in upper binder film 4 ' it
In, it is fixedly arranged at the surface and the surface of fibre web 2 at the middle and upper levels of upper strata fibre web 1, middle lower floor's fibre web 2 ' and the opposite table of lower floor's fibre web 1 '
Face lower binder film 5, lower binder film 5 ' in being respectively coated, lower fine hair 3 ' be clipped in middle lower floor's fibre web 2 ' and lower floor's fibre web 1 ' it
Between, the two ends of lower fine hair 3 ' among lower binder film 5, lower binder film 5 ', are fixedly arranged at middle lower floor's fibre web in being respectively inserted into
2 ' be 5D from fineness with the surface of lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', and length is 1.5mm polyester staple fiber.In
Upper strata fibre web 2 is consolidated with middle lower floor fibre by the EVA hot-melt adhesive nethike embrane that one layer of melting temperature is 110 DEG C, upper adhesive
Film 4, in the upper size of binder film 4 ' it is identical, be shaped as bar shaped, be coated in the surface and fibre web 2 at the middle and upper levels of upper strata fibre web 1
Surface position it is corresponding, in lower binder film 5, lower binder film 5 ' size it is identical, be shaped as bar shaped, be coated in
The position on the surface of middle lower floor's fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is adhesion strength
High, water-fastness, ageing-resistant polyacrylate static flocking adhesive.
The manufacture method of gluing Multi-layer flocking formula high-elastic heat insulation flaky material, this method comprises the following steps：
（1）It is prepared by fibre web：Using mechanical carding method into the net, prepare respectively upper strata fibre web 1, at the middle and upper levels fibre web 2, under
Layer fibre web 2 ', lower floor's fibre web 1 '；
（2）Gluing：Respectively upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', apply in the one side of lower floor's fibre web 1 '
Adhesive is covered, width is formed for 1cm, thickness is 0.5mm, spacing distance is the upper viscous of the 1cm strip along breadth directional spreding
Mixture film 4, in upper binder film 4 ', in lower binder film 5, lower binder film 5 ', upper binder film 4 upper binder film 4 ' with
Form and dimension it is identical, the position for being coated in upper strata fibre web 1 with the surface of fibre web 2 at the middle and upper levels is corresponding, in lower bond
Agent film 5, lower binder film 5 ' form and dimension it is identical, be coated in middle lower floor's fibre web 2 ', the surface of lower floor's fibre web 1 '
Position is corresponding；
（3）Electrostatic spinning：Progress electrostatic plant on the surface of adhesive is coated with fibre web 2 at the middle and upper levels and middle lower floor's fibre web 2 '
Suede, is 50kV using rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field, respectively by upper suede
Hair 3, lower fine hair 3 ' are implanted in fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels
And the surface of lower fine hair 3 ' and middle lower floor's fibre web 2 ' is in plumbness；
（4）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 2 and middle lower floor's fibre web 2 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, and criteria thus the drying time is 3min, the water of drying upper binder film 4 ' lower binder film 5 with making
Divide evaporation, one end of upper fine hair 3 and lower fine hair 3 ' is fixedly arranged at fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels respectively；
（5）Inhale suede：The fibre web at the middle and upper levels 2 that drying is crossed and middle lower floor's fibre web 2 ' carry out inhaling suede processing, will be scattered in respectively
There is no the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on fibre web 2 and the middle surface of lower floor's fibre web 2 ' at the middle and upper levels and do not have
Sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 '；
（6）Fibre web overlay film is consolidated：Fibre web at the middle and upper levels 2 and middle one side of the lower floor's fibre web 2 ' without flocking after suede processing will be inhaled
It is superimposed with each other, and one layer of hot melt film 6 of middle folder, fibre web 2 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 2 ' through Overheating Treatment,
Hot pressing temperature is 160 DEG C, and pressure size is 2.5bar, and hot pressing time is 10min；
（7）Fibre web is combined：It is 50kV in rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high pressure
Under electric field action, upper strata fibre web 1 is had to the one side of adhesive, is compounded on the flocked surface of fibre web 2 at the middle and upper levels, by lower floor's fibre web 1 '
There is the one side of adhesive, on the flocked surface for being compounded in middle lower floor's fibre web 2 '；Upper fine hair 3 and lower fine hair 3 ' respectively with upper strata fibre web 1,
The surface of lower floor's fibre web 1 ' is vertical；
（8）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is
3min, drying makes binder film 4, the moisture evaporation of lower binder film 5 ', and one end of upper fine hair 3 is fixedly arranged at upper strata fibre web 1
Surface, one end of lower fine hair 3 ' is fixedly arranged at the surface of lower floor's fibre web 1 '；
（9）Winding：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
Embodiment 2
Checker board gluing flocking formula machinery networking high-elastic heat insulation flaky material and preparation method thereof：
Referring to Fig. 1, Fig. 3, gluing Multi-layer flocking formula high-elastic heat insulation flaky material, including upper strata fibre web 1, upper binder film 4,
In upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor's fibre web 2 ', in lower binder film 5, lower binder film 5 ', under
Layer fibre web 1 ', upper fine hair 3, lower fine hair 3 '.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', lower floor's fibre web 1 ' are fineness
For 3D, the hollow polyester fibre and fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is low for 110 DEG C
Melting-point fibers, compare 80% according to weight:20% carries out shredding mixing, and the fibre web prepared is combed by short-fibred mechanical.Upper strata
Fibre web 1 and the opposite surface of fibre web 2 at the middle and upper levels be respectively coated binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in
Layer fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 be respectively inserted into binder film 4, in upper binder film 4 ' it
In, it is fixedly arranged at the surface and the surface of fibre web 2 at the middle and upper levels of upper strata fibre web 1, middle lower floor's fibre web 2 ' and the opposite table of lower floor's fibre web 1 '
Face lower binder film 5, lower binder film 5 ' in being respectively coated, lower fine hair 3 ' be clipped in middle lower floor's fibre web 2 ' and lower floor's fibre web 1 ' it
Between, the two ends of lower fine hair 3 ' among lower binder film 5, lower binder film 5 ', are fixedly arranged at middle lower floor's fibre web in being respectively inserted into
2 ' be 5D from fineness with the surface of lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', and length is 1.5mm polyamide short fibre.
Fibre web 2 is consolidated with middle lower floor fibre by the EVA hot-melt adhesive nethike embrane that one layer of melting temperature is 110 DEG C at the middle and upper levels, upper bonding
Agent film 4, in the upper size of binder film 4 ' it is identical, be shaped as checker board, be coated in the surface of upper strata fibre web 1 and fine at the middle and upper levels
The position on the surface of net 2 is corresponding, in lower binder film 5, lower binder film 5 ' size it is identical, be shaped as checker board,
The position for being coated in the surface of middle lower floor's fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is viscous
High, water-fastness, the ageing-resistant polyacrylate static flocking adhesive of knotting strength.
The manufacture method of gluing Multi-layer flocking formula high-elastic heat insulation flaky material, this method comprises the following steps：
（1）It is prepared by fibre web：Using mechanical carding method into the net, prepare respectively upper strata fibre web 1, at the middle and upper levels fibre web 2, under
Layer fibre web 2 ', lower floor's fibre web 1 '；
（2）Gluing：Respectively upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', apply in the one side of lower floor's fibre web 1 '
Adhesive is covered, it is 1cm to be formed along breadth direction width, and thickness is 0.5mm, and spacing distance is 1cm, is along width length direction width
1cm, thickness for 0.5mm clathrate upper binder film 4, in upper binder film 4 ', in lower binder film 5, lower binder film
5 ', the form and dimension of upper binder film 4 upper binder film 4 ' with is identical, is coated in upper strata fibre web 1 and fibre at the middle and upper levels
The position on the surface of net 2 is corresponding, in lower binder film 5, lower binder film 5 ' form and dimension it is identical, in being coated in
Lower floor's fibre web 2 ', the surface of lower floor's fibre web 1 ' position it is corresponding；
（3）Electrostatic spinning：Progress electrostatic plant on the surface of adhesive is coated with fibre web 2 at the middle and upper levels and middle lower floor's fibre web 2 '
Suede, is 50kV using rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field, respectively by upper suede
Hair 3, lower fine hair 3 ' are implanted in fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels
And the surface of lower fine hair 3 ' and middle lower floor's fibre web 2 ' is in plumbness；
（4）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 2 and middle lower floor's fibre web 2 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, and criteria thus the drying time is 3min, the water of drying upper binder film 4 ' lower binder film 5 with making
Divide evaporation, one end of upper fine hair 3 and lower fine hair 3 ' is fixedly arranged at fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels respectively；
（5）Inhale suede：The fibre web at the middle and upper levels 2 that drying is crossed and middle lower floor's fibre web 2 ' carry out inhaling suede processing, will be scattered in respectively
There is no the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on fibre web 2 and the middle surface of lower floor's fibre web 2 ' at the middle and upper levels and do not have
Sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 '；
（6）Fibre web overlay film is consolidated：Fibre web at the middle and upper levels 2 and middle one side of the lower floor's fibre web 2 ' without flocking after suede processing will be inhaled
It is superimposed with each other, and one layer of hot melt film 6 of middle folder, fibre web 2 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 2 ' through Overheating Treatment,
Hot pressing temperature is 160 DEG C, and pressure size is 2.5bar, and hot pressing time is 10min；
（7）Fibre web is combined：It is 50kV in rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high pressure
Under electric field action, upper strata fibre web 1 is had to the one side of adhesive, is compounded on the flocked surface of fibre web 2 at the middle and upper levels, by lower floor's fibre web 1 '
There is the one side of adhesive, on the flocked surface for being compounded in middle lower floor's fibre web 2 '；Upper fine hair 3 and lower fine hair 3 ' respectively with upper strata fibre web 1,
The surface of lower floor's fibre web 1 ' is vertical；
（8）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is
3min, drying makes binder film 4, the moisture evaporation of lower binder film 5 ', and one end of upper fine hair 3 is fixedly arranged at upper strata fibre web 1
Surface, one end of lower fine hair 3 ' is fixedly arranged at the surface of lower floor's fibre web 1 '；
（9）Winding：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
Embodiment 3
Airlaid high-elastic heat insulation flaky material of bar shaped gluing flocking formula and preparation method thereof：
Referring to Fig. 1, Fig. 2, gluing Multi-layer flocking formula high-elastic heat insulation flaky material, including upper strata fibre web 1, upper binder film 4,
In upper binder film 4 ', at the middle and upper levels fibre web 2, hot melt film 6, middle lower floor's fibre web 2 ', in lower binder film 5, lower binder film 5 ', under
Layer fibre web 1 ', upper fine hair 3, lower fine hair 3 '.Upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', lower floor's fibre web 1 ' are fineness
For 3D, the hollow polyester fibre and fineness of the three-dimensional crimp that length is 51mm are 3D, and length is 51mm, and fusing point is low for 110 DEG C
Melting-point fibers, compare 80% according to weight:20% carries out shredding mixing, the fibre web prepared by short-fiber airlaid.Upper strata
Fibre web 1 and the opposite surface of fibre web 2 at the middle and upper levels be respectively coated binder film 4, in upper binder film 4 ', upper fine hair 3 is clipped in
Layer fibre web 1 and at the middle and upper levels between fibre web 2, the two ends of upper fine hair 3 be respectively inserted into binder film 4, in upper binder film 4 ' it
In, it is fixedly arranged at the surface and the surface of fibre web 2 at the middle and upper levels of upper strata fibre web 1, middle lower floor's fibre web 2 ' and the opposite table of lower floor's fibre web 1 '
Face lower binder film 5, lower binder film 5 ' in being respectively coated, lower fine hair 3 ' be clipped in middle lower floor's fibre web 2 ' and lower floor's fibre web 1 ' it
Between, the two ends of lower fine hair 3 ' among lower binder film 5, lower binder film 5 ', are fixedly arranged at middle lower floor's fibre web in being respectively inserted into
2 ' be 5D from fineness with the surface of lower floor's fibre web 1 ', upper fine hair 3, lower fine hair 3 ', and length is 1.5mm polyester staple fiber.In
Upper strata fibre web 2 is consolidated with middle lower floor fibre by the EVA hot-melt adhesive nethike embrane that one layer of melting temperature is 110 DEG C, upper adhesive
Film 4, in the upper size of binder film 4 ' it is identical, be shaped as bar shaped, be coated in the surface and fibre web 2 at the middle and upper levels of upper strata fibre web 1
Surface position it is corresponding, in lower binder film 5, lower binder film 5 ' size it is identical, be shaped as bar shaped, be coated in
The position on the surface of middle lower floor's fibre web 2 ' and the surface of lower floor's fibre web 1 ' is corresponding.The adhesive that adhesive is selected is adhesion strength
High, water-fastness, ageing-resistant polyacrylate static flocking adhesive.
The manufacture method of gluing Multi-layer flocking formula high-elastic heat insulation flaky material, this method comprises the following steps：
（1）It is prepared by fibre web：Using airlaid method, upper strata fibre web 1 is prepared respectively, fibre web 2, middle lower floor are fine at the middle and upper levels
Net 2 ', lower floor's fibre web 1 '；
（2）Gluing：Respectively upper strata fibre web 1, at the middle and upper levels fibre web 2, middle lower floor's fibre web 2 ', apply in the one side of lower floor's fibre web 1 '
Adhesive is covered, width is formed for 1cm, thickness is 0.5mm, spacing distance is the upper viscous of the 1cm strip along breadth directional spreding
Mixture film 4, in upper binder film 4 ', in lower binder film 5, lower binder film 5 ', upper binder film 4 upper binder film 4 ' with
Form and dimension it is identical, the position for being coated in upper strata fibre web 1 with the surface of fibre web 2 at the middle and upper levels is corresponding, in lower bond
Agent film 5, lower binder film 5 ' form and dimension it is identical, be coated in middle lower floor's fibre web 2 ', the surface of lower floor's fibre web 1 '
Position is corresponding；
（3）Electrostatic spinning：Progress electrostatic plant on the surface of adhesive is coated with fibre web 2 at the middle and upper levels and middle lower floor's fibre web 2 '
Suede, is 50kV using rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field, respectively by upper suede
Hair 3, lower fine hair 3 ' are implanted in fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels, and make the surface of fine hair 3 and fibre web 2 at the middle and upper levels
And the surface of lower fine hair 3 ' and middle lower floor's fibre web 2 ' is in plumbness；
（4）Drying：Drying, drying mode are carried out to the fibre web at the middle and upper levels 2 and middle lower floor's fibre web 2 ' for having completed electrostatic spinning
For hot blast drying, temperature is 160 DEG C, and criteria thus the drying time is 3min, the water of drying upper binder film 4 ' lower binder film 5 with making
Divide evaporation, one end of upper fine hair 3 and lower fine hair 3 ' is fixedly arranged at fibre web 2, the surface of middle lower floor's fibre web 2 ' at the middle and upper levels respectively；
（5）Inhale suede：The fibre web at the middle and upper levels 2 that drying is crossed and middle lower floor's fibre web 2 ' carry out inhaling suede processing, will be scattered in respectively
There is no the upper fine hair 3 on the position of application of adhesive, lower fine hair 3 ' on fibre web 2 and the middle surface of lower floor's fibre web 2 ' at the middle and upper levels and do not have
Sopped up by the upper fine hair 3 of adhesive secure bond, lower fine hair 3 '；
（6）Fibre web overlay film is consolidated：Fibre web at the middle and upper levels 2 and middle one side of the lower floor's fibre web 2 ' without flocking after suede processing will be inhaled
It is superimposed with each other, and one layer of hot melt film 6 of middle folder, fibre web 2 it will be consolidated at the middle and upper levels with middle lower floor's fibre web 2 ' through Overheating Treatment,
Hot pressing temperature is 160 DEG C, and pressure size is 2.5bar, and hot pressing time is 10min；
（7）Fibre web is combined：It is 50kV in rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high pressure
Under electric field action, upper strata fibre web 1 is had to the one side of adhesive, is compounded on the flocked surface of fibre web 2 at the middle and upper levels, by lower floor's fibre web 1 '
There is the one side of adhesive, on the flocked surface for being compounded in middle lower floor's fibre web 2 '；Upper fine hair 3 and lower fine hair 3 ' respectively with upper strata fibre web 1,
The surface of lower floor's fibre web 1 ' is vertical；
（8）Drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is
3min, drying makes binder film 4, the moisture evaporation of lower binder film 5 ', and one end of upper fine hair 3 is fixedly arranged at upper strata fibre web 1
Surface, one end of lower fine hair 3 ' is fixedly arranged at the surface of lower floor's fibre web 1 '；
（9）Winding：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
Claims (6)
1. a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material, it is characterised in that：Upper strata fibre web (1) and fibre web at the middle and upper levels
(2) opposite surface be respectively coated binder film (4), in upper binder film (4 '),Electrostatic spinningUpper fine hair (3) is clipped in
Layer fibre web (1) and at the middle and upper levels between fibre web (2), upper fine hair (3)In plumbness,Two ends are respectively inserted into binder film
(4) in, among upper binder film (4 '), the surface and the surface of fibre web (2), middle lower floor at the middle and upper levels of upper strata fibre web (1) are fixedly arranged at
Fibre web (2 ') lower binder film (5), lower binder film (5 ') in being respectively coated with the opposite surface of lower floor's fibre web (1 '),Electrostatic is planted SuedeLower fine hair (3 ') is clipped between middle lower floor's fibre web (2 ') and lower floor's fibre web (1 '), lower fine hair (3 ')In plumbness,Two
End among lower binder film (5), lower binder film (5 '), is fixedly arranged at middle lower floor's fibre web (2 ') and lower floor's fibre web in being respectively inserted into
The surface of (1 '), at the middle and upper levels fibre web (2) be consolidated with middle lower floor's fibre web (2 ') by one layer of hot melt film (6).
2. a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material as claimed in claim 1, it is characterised in that：Described is upper
Layer fibre web (1), at the middle and upper levels fibre web (2), middle lower floor's fibre web (2 '), lower floor's fibre web (1 ') are that short-fibred mechanical combs networking or air-flow
Fibre web into the net.
3. a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material as claimed in claim 1, it is characterised in that：Described is upper
Binder film (4), in upper binder film (4 '), in the adhesive selected of lower binder film (5), lower binder film (5 ') to bond
Intensity is high, water-fastness, aging-resisting type adhesive.
4. a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material as claimed in claim 1, it is characterised in that：Described is upper
Binder film (4), in upper binder film (4 '), in lower binder film (5), lower binder film (5 ') be shaped as bar shaped or grid
Shape, size is identical.
5. a kind of gluing Multi-layer flocking formula high-elastic heat insulation flaky material as claimed in claim 1, it is characterised in that：Described is upper
Fine hair (3), the material of lower fine hair (3 ') are polyester fiber or Fypro.
6. a kind of manufacturer of gluing Multi-layer flocking formula high-elastic heat insulation flaky material as any one of claim 1-5
Method, it is characterised in that：This method comprises the following steps：
(1) prepared by fibre web：Upper strata fibre web (1), at the middle and upper levels fibre web (2), middle lower floor's fibre web (2 '), lower floor's fibre web are prepared respectively
(1’)；
(2) gluing：Respectively in the one side of upper strata fibre web (1), at the middle and upper levels fibre web (2), middle lower floor's fibre web (2 '), lower floor's fibre web (1 ')
Upper painting be covered with binder film (4), in upper binder film (4 '), in lower binder film (5), lower binder film (5 ')；
(3) electrostatic spinning：Progress electrostatic plant on the surface of adhesive is coated with fibre web at the middle and upper levels (2) and middle lower floor's fibre web (2 ')
Suede, respectively by upper fine hair (3), lower fine hair (3 ') be implanted in fibre web (2) at the middle and upper levels, middle lower floor's fibre web (2 ') surface, and make suede
Hair (3), lower fine hair (3 ') are in plumbness；
(4) drying：Drying is carried out to the fibre web at the middle and upper levels (2) and middle lower floor's fibre web (2 ') for having completed electrostatic spinning；
(5) suede is inhaled：The fibre web at the middle and upper levels (2) that drying is crossed and middle lower floor's fibre web (2 ') carry out inhaling suede processing；
(6) fibre web overlay film is consolidated：Fibre web at the middle and upper levels (2) and middle one side of the lower floor's fibre web (2 ') without flocking after suede processing will be inhaled
It is superimposed with each other, and one layer of hot melt film (6) of middle folder, fibre web (2) it will be consolidated at the middle and upper levels with middle lower floor's fibre web (2 ') through Overheating Treatment
Together；
(7) fibre web is combined：It is 50kV in rated voltage, output current is 5mA, high voltage electric field anode-cathode distance 12cm high voltage electric field
Under effect, upper strata fibre web (1) is had to the one side of upper binder film (4), is compounded on the flocked surface of fibre web (2) at the middle and upper levels, by under
Layer fibre web (1 ') has on the one side of lower binder film (5 '), the flocked surface for being compounded in middle lower floor's fibre web (2 '), and upper fine hair (3) is with
Fine hair (3 ') is vertical with the surface of upper strata fibre web (1), lower floor's fibre web (1 ') respectively；
(8) drying：After fibre web is compound, drying is carried out, drying mode is hot blast drying, and temperature is 160 DEG C, and criteria thus the drying time is
3min, drying makes binder film (4), the moisture evaporation of lower binder film (5 '), and one end of upper fine hair (3) is fixedly arranged at upper strata fibre
The surface of net (1), one end of lower fine hair (3 ') is fixedly arranged at the surface of lower floor's fibre web (1 ')；
(9) wind：After drying, gluing Multi-layer flocking formula high-elastic heat insulation flaky material is made in winding.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2172160Y (en) * | 1993-09-15 | 1994-07-20 | 张耀芳 | Flocking wall decoration adhesive body |
| CN2381484Y (en) * | 1999-05-26 | 2000-06-07 | 陈学清 | Thermal insulating composite flannelette |
| JP2001226860A (en) * | 2000-02-14 | 2001-08-21 | Toyobo Co Ltd | Particle-containing nonwoven fabric and method for producing the same |
| CN201950858U (en) * | 2010-10-22 | 2011-08-31 | 吴江天信勤丰纺织有限公司 | Waterproof dual-layer flocked fabric |
| CN202480465U (en) * | 2011-12-19 | 2012-10-10 | 武汉优地贸易有限公司 | Flocking non-woven |
| CN103287003A (en) * | 2012-02-23 | 2013-09-11 | 余兴东 | Multicolor flocked cloth and manufacturing method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2704476Y (en) * | 2004-05-24 | 2005-06-15 | 朱克耐 | Leather-imitating composite cloth |
-
2015
- 2015-05-18 CN CN201510251750.0A patent/CN104999725B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2172160Y (en) * | 1993-09-15 | 1994-07-20 | 张耀芳 | Flocking wall decoration adhesive body |
| CN2381484Y (en) * | 1999-05-26 | 2000-06-07 | 陈学清 | Thermal insulating composite flannelette |
| JP2001226860A (en) * | 2000-02-14 | 2001-08-21 | Toyobo Co Ltd | Particle-containing nonwoven fabric and method for producing the same |
| CN201950858U (en) * | 2010-10-22 | 2011-08-31 | 吴江天信勤丰纺织有限公司 | Waterproof dual-layer flocked fabric |
| CN202480465U (en) * | 2011-12-19 | 2012-10-10 | 武汉优地贸易有限公司 | Flocking non-woven |
| CN103287003A (en) * | 2012-02-23 | 2013-09-11 | 余兴东 | Multicolor flocked cloth and manufacturing method thereof |
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