CN105023858B - A kind of LED component and its manufacturing method of integrated graphene temperature sensing - Google Patents

A kind of LED component and its manufacturing method of integrated graphene temperature sensing Download PDF

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CN105023858B
CN105023858B CN201510308515.2A CN201510308515A CN105023858B CN 105023858 B CN105023858 B CN 105023858B CN 201510308515 A CN201510308515 A CN 201510308515A CN 105023858 B CN105023858 B CN 105023858B
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temperature sensor
temperature
graphene
led
light emitting
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CN105023858A (en
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周玉刚
李家明
张�荣
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Nanjing University
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Nanjing University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16151Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/16221Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/16225Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48225Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/48227Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/49Structure, shape, material or disposition of the wire connectors after the connecting process of a plurality of wire connectors
    • H01L2224/491Disposition
    • H01L2224/49105Connecting at different heights
    • H01L2224/49107Connecting at different heights on the semiconductor or solid-state body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73257Bump and wire connectors

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Led Device Packages (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Led Devices (AREA)

Abstract

The invention discloses a kind of LED component and its manufacturing method of integrated graphene temperature sensing, which includes LED light emitting device and temperature sensor on chip.Temperature sensor is a kind of graphene device.LED light emitting device and temperature sensor use back-to-back stacked on top structure, and top is LED light emitting device, and lower section is temperature sensor.The junction temperature of LED light emitting device can be monitored by graphene film resistance variation with temperature in measuring temperature senser element.Integrated graphene temperature sensing LED component provided by the invention can not only in real time, the accurate, junction temperature of reflection LED component stablized, and can effectively improve the heat dissipation of the light emission rate and the entire device of improvement of LED light emitting device.

Description

A kind of LED component and its manufacturing method of integrated graphene temperature sensing
Technical field
The present invention relates to a kind of luminescent device and production methods, more particularly, to a kind of integrated graphene temperature sensing LED light emitting device and its manufacturing method.
Background technology
Light emitting diode (light-emitting-diode, LED) is solid-state lighting cold light source of new generation, efficiency is high, Long lifespan, voltage is low, simple in structure, small, light-weight, fast response time, the features such as anti-seismic performance is good and spectrum is full-color, make It is obtained to be widely used in the various occasions such as backlight, display, traffic light and room lighting.Especially general In terms of illumination, LED has apparent advantage than conventional light source, will become next-generation lighting source.
Constantly universal with the application of LED, the integrity problem of LED is an important factor for restricting its development always, especially It is the junction temperature measurement problem closely bound up with LED luminance and service life.
Different from traditional heat radiation light source, LED is a kind of electroluminescent device, it directly converts electrical energy into luminous energy. But for the power-type LED of current technology maturation, electro-optical efficiency only has 30% or so, remaining 70% or so energy It is wholly converted into thermal energy, the junction temperature of LED is caused to increase.The raising of junction temperature can lead to the acceleration of semiconductor defect proliferation and package material The problems such as material is degenerated, the photoelectric characteristic so as to cause device constantly changes and decaying.By the real-time monitoring to junction temperature, favorably In more accurately analyzing LED failure phenomenon and mechanism, knot caused by LED reliabilities, and monitoring protection improper use is improved Temperature is excessively high, is conducive to the life and reliability for improving LED.
The prior art generally feeds back LED's using the external temperature sensor for measuring specific position in encapsulation or lamps and lanterns Operating temperature.Patent if Authorization Notice No. is CN203118989U discloses a kind of LED encapsulation method for realizing that junction temperature is controllable. In that patent, a temperature sensor is placed inside package lens near the LED chip realize temperature feedback.But due to by The radiating condition of encapsulation influences, and measured temperature is not actual temperature (virtual junction temperature meeting higher) at LED junction.Since heat passes Defeated to need the regular hour, external temperature sensor can not reflect LED chip junction temperature at this time in real time.Another known technology Be using LED itself as temperature sensor, it is anti-by the forward voltage monitored under normal drive current or under low current Reflect junction temperature size.However, under normal drive current, LED will produce self-heating effect, this will influence temperature measurement accuracy;Small Under electric current driving, since in LED operation state and test mode transfer process, junction temperature quickly reduces, this will also influence temperature The accuracy of measurement.
Invention content
In order to overcome the shortcomings and deficiencies of the prior art described above, the present invention provides a kind of integrated graphene temperature sensing LED component.
Meanwhile the present invention also provides the manufacturing methods of the LED component of the integrated graphene temperature sensing.
A kind of LED component of integrated graphene temperature sensing includes LED light emitting device and temperature sensor on chip; The temperature sensor is a kind of graphene device.
The LED light emitting device and temperature sensor use back-to-back stacked on top structure, and top is with formal dress The LED light emitting device of chip structure, lower section are temperature sensors;Temperature sensor lower surface is fixed on heat-radiating substrate simultaneously And its electrode is electrically connected with the wiring on substrate.
The structure of the temperature sensor includes graphene film, two or more metal film electrodes.
The substrate of the LED light emitting device is insulation or highly resistant material, including sapphire or silicon carbide.
The number of plies of the graphene film includes one layer, one kind in two layers or multilayer.
The metal film electrode material includes one kind or combinations thereof in Pt, Al, Ag, Ni, Ti, Au.
The interval width of two metal film electrode be much smaller than chip width, preferably 10-100 μm.
A kind of LED component production method of integrated graphene temperature sensing includes the following steps:
LED light emitting device is prepared on substrate;
In substrate back preparation temperature senser element;
Temperature sensor is connected with heat-radiating substrate.
The making step of the temperature sensor is
(1) graphene film is transferred to the back side of substrate;
(2) the deposited metal membrane electrode on the graphene film, and carve and break in the intermediate corrosion of the metal film electrode, The metal film electrode of partition is respectively formed the positive and negative polarities of temperature sensor;
(3) in sample surfaces deposit passivation layer, and it is lithographically formed mask, mask is removed after corrosion and passivation layer, expose metal foil The contact hole of membrane electrode;
The making step that the temperature sensor is connected with heat-radiating substrate is
(1) insulating layer and circuit layer are made respectively on heat-radiating substrate;
(2) use flip chip bonding or reflow method, by the positive and negative polarities of temperature sensor respectively on heat-radiating substrate Circuit layer corresponds to engagement.
Compared with prior art, the invention has the advantages that:
1, temperature sensor and LED light emitting device are integrated in same semiconductor core on piece, the two devices are mutually electric Independent, the measurement of junction temperature does not influence the normal work of LED.Since temperature sensor leans on LED light emitting device close, and temperature Senser element is spent between LED light emitting device and heat-radiating substrate, therefore temperature sensor is sent out with LED within the extremely short time The temperature of optical device reaches balance.This temperature sensor can in real time, accurately monitor the junction temperature of LED light emitting device.
2, since graphene has good thermal stability, this contributes to the stable work in work of temperature sensor.
3, graphene film with extraordinary translucency and the high optical reflectance metal film electrode deposited on it Light absorption can be reduced, the light emission rate for improving LED is conducive to.
4, graphene and metal film electrode all have good lateral thermal conductivity, and metal film electrode and heat-radiating substrate It is in direct contact.This helps to reduce LED active areas to the thermal resistance of heat-radiating substrate, increases the heat dissipation characteristics of LED.
5, LED light emitting device and temperature sensor stacked on top, do not increase device size additionally.
Description of the drawings
Fig. 1 is the structural schematic diagram of the LED component of integrated graphene temperature sensing of the present invention.
100:LED light emitting device;200:Temperature sensor;101:P-type electrode;102:N-type electrode;103:P-type is partly led Body layer;104:Active layer;105:N type semiconductor layer;106:Substrate;201:Graphene film;202:Metal film electrode;203: Passivation layer;301:Heat-radiating substrate;302:Substrate insulating layer;303:Substrate circuit layer;401、402:The electrode of LED light emitting device connects Line end;403、404:The electrode terminal of temperature sensor;501:Salient point.
Specific implementation mode
The invention will be further described with reference to the accompanying drawings and examples.
Referring to Fig. 1, it is the structural schematic diagram of the LED component of integrated graphene temperature sensing of the present invention.The device Include LED light emitting device 100 and temperature sensor 200 on the chip of part.The temperature sensor 200 is a kind of graphene device Part.LED light emitting device 100 and temperature sensor 200 use back-to-back stacked on top structure, and mutually electrically independent, top It is the LED light emitting device 100 with formal dress chip structure, lower section is temperature sensor 200.200 following table of temperature sensor Face is fixed on heat-radiating substrate 301 and its electrode is electrically connected with the wiring on substrate.
The structure of the temperature sensor 200 includes graphene film 201, two metal film electrodes 202, passivation layer 203. LED can be monitored in real time by the 201 resistance value variation with temperature relationship of graphene film in measuring temperature senser element 200 The junction temperature of luminescent device 100.The resistance value of graphene film is linear as the temperature increases in 300-500K temperature ranges to drop It is low.When 300K, resistance value size is about 0.2-5 × 10^5 Ω, and resistance-temperature coefficient is about 150-350 Ω/K.
The production method of the LED component of the integrated graphene temperature sensing of the present embodiment, comprises the following steps:
(1) MOCVD technologies are used, n type semiconductor layer 105, active layer 104 and p-type is grown successively on substrate 106 and partly leads Body layer 103.The material of the substrate 106 is sapphire or silicon carbide;
(2) ICP lithographic techniques are used, are etched down in n type semiconductor layer 105 from the side of p type semiconductor layer 103, Table top is formed in the side of n type semiconductor layer 105;
(3) sputtering technology is used, prepares on p type semiconductor layer 103 and respectively LED on the table top of n type semiconductor layer 105 The P-type electrode 101 and N-type electrode 102 of luminescent device 100;
(4) one temporary base is connected with the wafer upper surface comprising LED light emitting device 100 by photosensitive resin.It is this Photosensitive resin can play cementation by the method solidified resin of ultraviolet light.
(5) by the 106 thinning back side grinding and polishing of wafer substrate comprising LED light emitting device 100, retain substrate thickness about 100μm;
(6) graphene film 201 is transferred to the back side of substrate 106;The number of plies of the graphene film 201 can be single Layer or multilayer;
(7) the deposited metal membrane electrode 202 on the graphene film 201, and carved in the intermediate corrosion of the metallic film Disconnected, the metal film electrode 202 of partition is respectively formed the positive and negative polarities of temperature sensor 200.Among metal film electrode 202 The width of etching be much smaller than chip width, preferably 10-100 μm;202 material of metal film electrode be Pt, Al, One kind in Ag, Ni, Ti, Au or combinations thereof;
(8) passivation layer 203 is formed in sample surfaces deposition silica, and is lithographically formed mask, gone after corrosion and passivation layer Mask exposes the contact hole of metal film electrode;203 material of the passivation layer is alternatively aluminium oxide or aluminium nitride;
(9) with corrosive liquid by LED light emitting device 100 resin and temporary base remove, temporary base can be sharp again With reduction waste;
(10) divide, detach disk, obtain the chip such as LED light emitting device 100 in figure.
(11) insulating layer 302 and circuit layer 303 are made respectively on heat-radiating substrate 301, using flip chip bonding or Reflow Soldering side Method connects the positive and negative polarities of temperature sensor 200 by the way that salient point 501 is corresponding with the circuit layer of heat-radiating substrate 301 303 respectively It closes, and electrode terminal 403 and 404 corresponding on heat-radiating substrate 301 is electrically connected respectively;
(12) by Wire Bonding Technology, by the positive and negative electrode 101 of LED light emitting device 100 and 102 respectively with heat-radiating substrate Corresponding electrode terminal 401 and 402 is correspondingly connected on 301.
The LED component for the integrated graphene temperature sensing completed according to an embodiment of the invention can utilize graphene temperature Spend graphene film resistance variation with temperature relationship in senser element in real time, the junction temperature of accurate measurements LED component.Due to stone Black alkene has good thermal stability, this helps to improve the job stability of temperature sensor.And the height of graphene is thoroughly Light, the high reflectance of high heat conduction characteristic and metallic film, high heat conduction characteristic contribute to the thermal resistance for reducing entire LED component, increase Its light emission rate.
Particular embodiments described above has carried out further the purpose of the present invention, technical solution and advantageous effect It is described in detail, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, All within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the present invention's Within protection domain.

Claims (9)

1. a kind of LED component of integrated graphene temperature sensing, it is characterised in that:Include LED light emitting device and temperature on chip Spend senser element;The temperature sensor is a kind of graphene device, and the structure of the temperature sensor includes that graphene is thin Film, two or more metal film electrodes;
The LED light emitting device and temperature sensor use back-to-back stacked on top structure, and top is that have positive cartridge chip The LED light emitting device of structure, lower section are temperature sensors;Temperature sensor lower surface is fixed on heat-radiating substrate, and The electrode of the temperature sensor is electrically connected using inverted structure by the electrode terminal on salient point and heat-radiating substrate, institute Stating the positive and negative electrode of LED light emitting device, electrode terminal corresponding on heat-radiating substrate is correspondingly connected with respectively.
2. the LED component of integrated graphene temperature sensing according to claim 1, it is characterised in that:The LED light emitter The substrate of part is insulation or highly resistant material, including sapphire or silicon carbide.
3. the LED component of integrated graphene temperature sensing according to claim 1, it is characterised in that:The graphene is thin The number of plies of film includes one layer, one kind in two layers or multilayer.
4. the LED component of integrated graphene temperature sensing according to claim 1, it is characterised in that:The metallic film Electrode material includes one kind or combinations thereof in Pt, Al, Ag, Ni, Ti, Au.
5. the LED component of integrated graphene temperature sensing according to claim 1, it is characterised in that:It is two neighboring described The interval width of metal film electrode is much smaller than the width of chip.
6. the LED component of integrated graphene temperature sensing according to claim 5, it is characterised in that:It is two neighboring described The interval width of metal film electrode is 10-100 μm.
7. the production method of the LED component of the integrated graphene temperature sensing described in any one of claim 1-6, feature exist In including the following steps:
LED light emitting device is prepared on substrate;
In substrate back preparation temperature senser element;
Temperature sensor is connected with heat-radiating substrate.
8. the production method of the LED component of integrated graphene temperature sensing according to claim 7, which is characterized in that institute The making step for the temperature sensor stated is:
(1) graphene film is transferred to the back side of substrate;
(2) the deposited metal membrane electrode on the graphene film, and carve disconnected, partition in the intermediate corrosion of the metal film electrode Metal film electrode be respectively formed the positive and negative polarities of temperature sensor;
(3) in sample surfaces deposit passivation layer, and it is lithographically formed mask, mask is removed after corrosion and passivation layer, expose metallic film electricity The contact hole of pole.
9. the LED component production method of integrated graphene temperature sensing according to claim 8, which is characterized in that described The making step that is connected with heat-radiating substrate of temperature sensor be:
(1) insulating layer and circuit layer are made respectively on heat-radiating substrate;
(2) use flip chip bonding or reflow method, by the positive and negative polarities of temperature sensor respectively with the circuit on heat-radiating substrate The corresponding engagement of layer.
CN201510308515.2A 2015-06-05 2015-06-05 A kind of LED component and its manufacturing method of integrated graphene temperature sensing Active CN105023858B (en)

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CN105841739B (en) * 2016-03-25 2018-10-26 南方科技大学 Temperature Humidity Sensor and preparation method thereof, temperature/humidity measuring system
CN106783653B (en) * 2016-11-24 2019-06-07 天津津航计算技术研究所 Chip interior temperature monitoring apparatus based on multi-chip stacking technique
CN108336065A (en) * 2018-01-31 2018-07-27 韩德军 A kind of automatic temperature-adjusting control LED component
CN109920904B (en) * 2019-04-10 2023-11-10 黄山学院 Heat radiation structure of high-power GaN-based LED and processing technology
WO2023108487A1 (en) * 2021-12-15 2023-06-22 联嘉光电股份有限公司 Temperature-measurable vertical light-emitting diode grain structure and temperature measurement correction method therefor

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