CN104996423B - The purposes and ethyl oleate acaricide of ethyl oleate - Google Patents
The purposes and ethyl oleate acaricide of ethyl oleate Download PDFInfo
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- CN104996423B CN104996423B CN201510351264.6A CN201510351264A CN104996423B CN 104996423 B CN104996423 B CN 104996423B CN 201510351264 A CN201510351264 A CN 201510351264A CN 104996423 B CN104996423 B CN 104996423B
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Abstract
The invention provides a kind of purposes of ethyl oleate and ethyl oleate acaricide, ethyl oleate is used to prepare acaricide, the ethyl oleate acaricide is made up of ethyl oleate with customary adjuvant, the quality of wherein ethyl oleate accounts for 0.05% the 99% of ethyl oleate acaricide quality, and customary adjuvant accounts for 1% 99.95%.The invention provides a kind of new harmonious acaricide to person poultry safety, environmentally friendly, the comprehensive regulation to ecological environmental protection, human health and disease all has far-reaching significance.
Description
Technical field
The present invention relates to a kind of acaricide of technical field of pesticide, in particular it relates to a kind of ethyl oleate acaricide and oil
The new application of acetoacetic ester.
Background technology
Phytophagous mites is found on the crops all over the world, it has, and small volume, breeding be fast, strong adaptability with
And the features such as be also easy to produce the resistance to the action of a drug, be it is generally acknowledged be difficult preventing and treating pest communities.It is used on the pesticide market of China at present
The most dependence on import of acaricide, the acaricidal expense of import accounts for the 88.8% of general import agricultural chemicals expense.And mite class is to crop
The loss caused, has obvious increase in Past 30 Years.Main cause is intensive monoculture and killed using non-specific
Worm agent.Secondly because the growth time of one generation of mite class is shorter, resistance can be produced to original acaricide rapidly.These desinsections
Often acaricidal activity is not high for agent, and mite class natural enemy has also been eliminated while mite class is killed.At present, the 3R problems of chemical pesticide are
Residual (Residue), resistance (Resistance) and pest resurgence (Resurgence) are generally paid close attention to by people, the mankind
Understanding to agricultural chemicals is also more and more deep, and the use of agricultural chemicals is not focused on killing off the insect pests, but more focuses on regulation.Therefore, use
Obligate acaricide turns into the major measure of preventing and treating phytophagous mites, and acaricidal development is inevitable towards efficient, wide spectrum, low toxicity, peace
Full biological pesticide and insect hormone type agricultural chemicals direction develops, and meets the demand in market.In terms of acaricidal research, both at home and abroad
Many scholars have made substantial amounts of work.
Ethyl oleate is a kind of fatty acid ester, is mainly used in the tough agent of lubricant, water repellent agent, resin, surfactant, doctor
Pharmaceutic adjuvant, the plasticizer of plastics, the preparation of ointment bases and other organic chemicals also serves as spices.Current ethyl oleate
The method for being mainly obtained by chemical synthesis, i.e., be made by ethanol and oleic acid through esterification or pass through another oleate
Ester exchange reaction is carried out together with ethanol to obtain.It can also obtain through refining and obtain from plant.In addition, ethyl oleate is as in honeybee body
A kind of pheromones, and the material can influence and adjust the behavior of honeybee in its internal content.
Found through being retrieved to existing technical literature, application report of the ethyl oleate in acaricide is prepared is there is no at present;
A kind of current also no and environment compatibility is good, harmonious acaricide to mammalian safe.
The content of the invention
Present invention aims at for deficiencies of the prior art, there is provided a kind of efficient, noresidue, production cost
Low, economical and practical, environment-friendly, high comprehensive performance ethyl oleate acaricide and application.
The present invention seeks to what is be achieved through the following technical solutions:
The present invention, which provides a kind of purposes of ethyl oleate, i.e. ethyl oleate, to be used to prepare acaricide.Wherein, the mite can be with
It is Tetranychus cinnabarinus, the plant evil mite such as Tetranychus urticae.
The present invention provides a kind of ethyl oleate acaricide, and the ethyl oleate acaricide is by ethyl oleate (i.e. bulk drug)
Constituted with customary adjuvant.The quality of wherein ethyl oleate accounts for the 0.05%-99% of ethyl oleate acaricide quality, and customary adjuvant is accounted for
The 1%-99.95% of ethyl oleate acaricide quality.
Preferably, the customary adjuvant refers to one or more in solubilizer, synergist, emulsifying agent, bleeding agent etc..
Preferably, the solubilizer is neopelex, Potassium dodecylbenzenesulfonate, polysorbate, poly- second two
Alcohol, sorbierite polyoxy ether, lignosulfonates, tea seed cake, take gleditsia sinensis etc. it is all in one or more;Emulsifying agent is sapn
Class, Tweens, ethylene glycol esters, propane diols esters and/or polyethylene glycol type nonionic surfactant etc.;Synergist is tea soap
Element, APEO etc.;Bleeding agent is azone etc..
Weigh ethyl oleate solvent according to aforementioned proportion to dissolve, selection adds various auxiliary materials, e.g., solubilizer, synergist,
Emulsifying agent, bleeding agent etc., according to various techniques, are made various forms of acaricides, for example:Pulvis, it is missible oil, suspending agent, dry
Suspending agent, emulsifiable concentrate, sustained release agent, aqueous emulsion, spray etc..Wherein, solvent can be water, ethanol, methanol, acetone, cyclohexanone,
One or more in all organic solvents such as petroleum ether, petroleum aromatic, purified petroleum benzin, ethyl acetate, toluene, dimethylbenzene.
The present invention provides a kind of acaricidal application of above-mentioned ethyl oleate, is specially:Added water under stirring at normal temperature
In ethyl oleate acaricide, it is diluted to after ethyl oleate i.e. bulk drug accounts for 0.5-40wt% concentration and be spray applied.
Compared with prior art, the present invention has following beneficial effect:
The invention provides a kind of new harmonious acaricide to person poultry safety, environmentally friendly, to ecological environmental protection,
The comprehensive regulation of human health and disease all has far-reaching significance.Compared with traditional agricultural chemicals, the present invention has following spy
Point and advantage:
(1) ethyl oleate is a kind of natural products, with nontoxic, the features such as degradable, is for people, animal and ecological environment
Friendly, it is safe;
(2) ethyl oleate source is easy, it is possible to use esterification is synthesized, and can also directly be extracted from plant, method
It is simple and easy to apply, large-scale industrial production can be carried out;
(3) present invention is to find that ethyl oleate has mite killing bioactivity first, and is configured to acaricide first, is passed through
Experiment, to Tetranychus cinnabarinus preventive effect up to 98.2%.
Embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that to the ordinary skill of this area
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1
Ethyl oleate 20g is weighed, is dissolved with 22g ethanol solutions, 26g Tween-80s, dissolving, according to common process, system is added
Into ethyl oleate acaricide of the present invention, then it is diluted with water in made ethyl oleate acaricide, makes ethyl oleate, i.e. raw material
The concentration of medicine is 6%.Finally, the ethyl oleate acaricide after dilution is subjected to indoor biological determination of activity, side to Tetranychus cinnabarinus
The tetranychid that method is surveyed in SOP according to national southern pesticides discovery center life soaks stem infusion process and carried out.Each processing is investigated after 24 hours
Life or death borer population, its preventive effect is 84.3%.
Embodiment 2
Ethyl oleate 54g is weighed, is dissolved with 420g ethyl acetate, the 203g such as emulsifying agent are added wherein, according to conventional work
Skill, is made ethyl oleate acaricide of the present invention, is then diluted with water in made ethyl oleate acaricide, makes ethyl oleate,
I.e. the concentration of bulk drug is 1%.Finally, the ethyl oleate acaricide after dilution is carried out into indoor biological activity to Tetranychus cinnabarinus to survey
Fixed, the tetranychid that method is surveyed in SOP according to national southern pesticides discovery center life soaks stem infusion process and carried out.Investigated everywhere after 24 hours
The life or death borer population of reason, its preventive effect is 78.6%.
Embodiment 3
Ethyl oleate 90g is weighed, is dissolved with 7g ethanol, the grade 4g of emulsifier span -20 is added wherein, according to conventional work
Skill, is made ethyl oleate acaricide of the present invention, is then diluted with water in made ethyl oleate acaricide, makes ethyl oleate i.e.
The concentration of bulk drug is 38%.Finally, the ethyl oleate acaricide after dilution is carried out to Tetranychus cinnabarinus using indoor pot method
It is raw to survey, the death rate is counted after 24 hours, its preventive effect is 98.2%.
Embodiment 4
Ethyl oleate 204g is weighed, is dissolved with 52g methanol, wherein addition emulsifier tween -245, the 84g such as Arlacel-20,
According to common process, ethyl oleate acaricide of the present invention is made, is then diluted with water, makes in made ethyl oleate acaricide
Ethyl oleate is that the concentration of bulk drug is 23%.Finally, the ethyl oleate acaricide after dilution is used indoor to Tetranychus cinnabarinus
Pot-culture method is carried out giving birth to survey, and the death rate is counted after 24 hours, and its preventive effect is 96.3%.
Embodiment 5
Ethyl oleate 480g is weighed, 267g petroleum ether dissolutions are used, emulsifying agent, synergist, solubilizer etc. are added wherein auxiliary
Expect 213g, according to common process, ethyl oleate acaricide of the present invention is made, is then added water in made ethyl oleate acaricide
Dilution, it is 15% to make the ethyl oleate i.e. concentration of bulk drug.Finally, the ethyl oleate acaricide after dilution is adopted to Tetranychus cinnabarinus
Field plot experiment carries out field control effectiveness test, the death rate is counted after 48 hours, preventive effect reaches 94.1%.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (2)
1. a kind of purposes of ethyl oleate, it is characterised in that be used to ethyl oleate prepare acaricide, the mite is Tetranychus cinnabarinus
Or Tetranychus urticae;
The ethyl oleate acaricide is made up of ethyl oleate with customary adjuvant, and the quality of wherein ethyl oleate accounts for ethyl oleate
The 0.05%-99% of acaricide quality, customary adjuvant accounts for the 1%-99.95% of ethyl oleate acaricide quality;
The customary adjuvant refers to one or more in solubilizer, synergist, emulsifying agent, bleeding agent;
The solubilizer be neopelex, Potassium dodecylbenzenesulfonate, polysorbate, polyethylene glycol, sorbierite gather
Oxygen ether, lignosulfonates, tea seed cake, the one or more taken in gleditsia sinensis;The emulsifying agent is spans, Tweens, second two
It is one or more in alkoxide, propane diols esters and/or polyethylene glycol type nonionic surfactant;Synergist be Tea Saponin,
It is a kind of in APEO;Bleeding agent is azone;
The ethyl oleate acaricide is pulvis, missible oil, suspending agent, dry suspending agent, emulsifiable concentrate, sustained release agent, aqueous emulsion, spray
It is a kind of in form.
2. the purposes of ethyl oleate according to claim 1, it is characterised in that the ethyl oleate acaricide is in stirring at normal temperature
Under will add water, it is diluted to after ethyl oleate i.e. bulk drug accounts for 0.5-40wt% concentration and be spray applied.
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CN105613493A (en) * | 2016-02-24 | 2016-06-01 | 深圳百乐宝生物农业科技有限公司 | Application of propylene glycol monofatty acid ester as acaricide, acaricide and application of acaricide |
CN106305851A (en) * | 2016-08-18 | 2017-01-11 | 江苏绿洲园艺绿化有限公司 | Preparation method of pesticide used for magnolia tree |
CN109430295B (en) * | 2018-12-21 | 2021-05-18 | 佛山市高科合创科技有限公司 | Acaricide with tea seed oil as main raw material and preparation thereof |
CN109997850A (en) * | 2019-04-29 | 2019-07-12 | 广西壮族自治区农业科学院 | A kind of insecticide acaricide composition and preparation method thereof |
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JP2919280B2 (en) * | 1994-11-02 | 1999-07-12 | 武田薬品工業株式会社 | Wood pest control agent |
CN101856022B (en) * | 2010-06-11 | 2013-01-23 | 中国科学院动物研究所 | Application of ethyl oleate in prevention and control of bursaphelenchus xylophilus |
CN101870607B (en) * | 2010-06-13 | 2013-02-27 | 武汉海鼎化工有限公司 | Full-biodegradable anti-caking agent for compound fertilizer/blended fertilizer and preparation method thereof |
CN102283195A (en) * | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | Pesticide adjuvant and preparation method thereof |
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