CN104987656A - Formula of glass fiber composite - Google Patents

Formula of glass fiber composite Download PDF

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Publication number
CN104987656A
CN104987656A CN201510373621.9A CN201510373621A CN104987656A CN 104987656 A CN104987656 A CN 104987656A CN 201510373621 A CN201510373621 A CN 201510373621A CN 104987656 A CN104987656 A CN 104987656A
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CN
China
Prior art keywords
parts
glass fiber
formula
coupling agent
fiber composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510373621.9A
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Chinese (zh)
Inventor
徐大治
王新武
张勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI DANFENG ELECTRONIC MATERIAL Co Ltd
Original Assignee
ANHUI DANFENG ELECTRONIC MATERIAL Co Ltd
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Application filed by ANHUI DANFENG ELECTRONIC MATERIAL Co Ltd filed Critical ANHUI DANFENG ELECTRONIC MATERIAL Co Ltd
Priority to CN201510373621.9A priority Critical patent/CN104987656A/en
Publication of CN104987656A publication Critical patent/CN104987656A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a formula of a glass fiber composite, and relates to the field of glass fiber. The composite comprises the following raw materials by weight: 12 to 13 parts of EW-200 glass fiber plain cloth, 14 to 16 parts of phenolic resin, 10 to 12 parts of barium titanate powder, 9 to 12 parts of a coupling agent, 7 to 9 parts of bamboo fiber felt, 6 to 8 parts of triethyl citrate, 3 to 5 parts of polypropylene powder, 7 to 9 parts of epoxidized soybean oil, 12 to 13 parts of bisphenol epoxy resin, 15 to 18 parts of dicumyl peroxide, 14 to 16 parts of maleic anhydride grafted polypropylene, and 20 to 25 parts of glass fiber. The glass fiber composite prepared according to the formula is light in weight, high in strength, and high-temperature resistant; due to the addition of barium titanate powder, the dielectric constant of the glass fiber composite is improved. The preparation method of the glass fiber composite is simple in process, and can be carried out on conventional equipment; the glass fiber composite is excellent in strength, rigidity and impact strength; the process is simple; the cost is low; the production efficiency is high.

Description

A kind of formula of glass fiber compound material
Technical field
The present invention relates to glass fibre field, be specifically related to a kind of formula of glass fiber compound material.
Background technology
Along with the development of battlefield surroundings, in order to improve the battlefield survival of tactical missile, effective compacting, destruction enemy air defense or early warning system, the flight velocity of guided missile is more and more faster, range is more and more far away, therefore tactical missile starts to propose harsher requirement to weight, existing tactical missile radome adopts stupalith mostly, density due to material itself is comparatively large and toughness of material is poor, thus the weight of product comparatively, the use of polymer matrix composites in radome, significantly can reduce the weight of radome, but most polymer matrix composites heat resistance is poor, thus the scope used is less, along with the continuous enhancing of " ecological awareness ", people are to environment protection, hygiene and health are more and more paid attention to, wherein, processing characteristics is excellent, the plastics pollution on the environment being used to various mechanicals has become the problem of general concern, particularly fibre reinforced composites are normally by glass fibre, carbon fibers etc. form with plastic composition, waste treatment is more difficult, production environment is severe, very large burden is added to environment, therefore, natural fiber is as bamboo, fiber crops, lumber fibres etc. have light weight because of it, inexpensive, be easy to get, biodegradable, the features such as environmentally safe cause the interest of people's Application and Development, although fiberglass surfacing generally all carries out surface treatment with coupling agent, but because polypropylene is non-polar polymer material, poor with the interfacial adhesion strength of glass fibre, the acid anhydride-grafted polypropylene raising interfacial adhesion strength of part is added even if usually adopt, but glass fibre modification is still limited to the raising of Properties of Polypropylene.
Summary of the invention
Problem to be solved by this invention is to provide a kind of material light weight, and intensity is high, resistant to elevated temperatures glass fiber compound material.
To achieve these goals, the technical scheme that the present invention takes is the formula of a kind of glass fiber compound material provided, described composite-material formula is made up of the component of following weight fraction: EW-200 glass fibre plain 12-13 part, resol 14-16 part, barium titanate powder 10-12 part, coupling agent 9-12 part, bamboo fiber felt 7-9 part, triethyl citrate 6-8 part, polypropylene powder 3-5 part, epoxy soybean oil 7-9 part, bisphenol-type epoxy resin 12-13 part, dicumyl peroxide 15-18 part, maleic anhydride inoculated polypropylene 14-16 part, glass fibre 20-25 part.
Preferably, the formula of a kind of glass fiber compound material according to claim 1, described composite-material formula is made up of the component of following weight fraction: EW-200 glass fibre plain 12 parts, 16 parts, resol, barium titanate powder 10 parts, coupling agent 12 parts, bamboo fiber felt 8 parts, triethyl citrate 7 parts, polypropylene powder 4 parts, epoxy soybean oil 8 parts, bisphenol-type epoxy resin 12 parts, dicumyl peroxide 17 parts, maleic anhydride inoculated polypropylene 15 parts, 23 parts, glass fibre.
Preferably, described coupling agent is silane coupling agent, titanate coupling agent or aluminate coupling agent.
Adopt technical scheme of the present invention, the formula of a kind of glass fiber compound material of the present invention, high and the resistant to elevated temperatures advantage of the obtained glass fiber compound material material light weight of described formula, intensity, and the specific inductivity of this formula is increased by barium titanate powder, the preparation method of this kind of matrix material, technique is simple, and conventional equipment can be implemented, this kind of matrix material has good intensity, rigidity and impelling strength simultaneously, and technique is simple, cost is low, production efficiency is high.
Embodiment
The technique means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with embodiment, setting forth the present invention further.
embodiment 1:
A formula for glass fiber compound material, described composite-material formula is made up of the component of following weight fraction: EW-200 glass fibre plain 12 parts, 16 parts, resol, barium titanate powder 10 parts, coupling agent 12 parts, bamboo fiber felt 8 parts, triethyl citrate 7 parts, polypropylene powder 4 parts, epoxy soybean oil 8 parts, bisphenol-type epoxy resin 12 parts, dicumyl peroxide 17 parts, maleic anhydride inoculated polypropylene 15 parts, 23 parts, glass fibre.
Based on above-mentioned, the formula of a kind of glass fiber compound material of the present invention, high and the resistant to elevated temperatures advantage of the obtained glass fiber compound material material light weight of described formula, intensity, and the specific inductivity of this formula is increased by barium titanate powder, the preparation method of this kind of matrix material, technique is simple, and conventional equipment can be implemented, this kind of matrix material has good intensity, rigidity and impelling strength simultaneously, and technique is simple, cost is low, production efficiency is high.
Obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.

Claims (3)

1. the formula of a glass fiber compound material, it is characterized in that, described composite-material formula is made up of the component of following weight fraction: EW-200 glass fibre plain 12-13 part, resol 14-16 part, barium titanate powder 10-12 part, coupling agent 9-12 part, bamboo fiber felt 7-9 part, triethyl citrate 6-8 part, polypropylene powder 3-5 part, epoxy soybean oil 7-9 part, bisphenol-type epoxy resin 12-13 part, dicumyl peroxide 15-18 part, maleic anhydride inoculated polypropylene 14-16 part, glass fibre 20-25 part.
2. the formula of a kind of glass fiber compound material according to claim 1, it is characterized in that, described composite-material formula is made up of the component of following weight fraction: EW-200 glass fibre plain 12 parts, 16 parts, resol, barium titanate powder 10 parts, coupling agent 12 parts, bamboo fiber felt 8 parts, triethyl citrate 7 parts, polypropylene powder 4 parts, epoxy soybean oil 8 parts, bisphenol-type epoxy resin 12 parts, dicumyl peroxide 17 parts, maleic anhydride inoculated polypropylene 15 parts, 23 parts, glass fibre.
3. the formula of a kind of glass fiber compound material according to claim 1, is characterized in that, described coupling agent is silane coupling agent, titanate coupling agent or aluminate coupling agent.
CN201510373621.9A 2015-07-01 2015-07-01 Formula of glass fiber composite Pending CN104987656A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510373621.9A CN104987656A (en) 2015-07-01 2015-07-01 Formula of glass fiber composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510373621.9A CN104987656A (en) 2015-07-01 2015-07-01 Formula of glass fiber composite

Publications (1)

Publication Number Publication Date
CN104987656A true CN104987656A (en) 2015-10-21

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CN201510373621.9A Pending CN104987656A (en) 2015-07-01 2015-07-01 Formula of glass fiber composite

Country Status (1)

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CN (1) CN104987656A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295296A (en) * 2015-11-20 2016-02-03 陈雪琴 Polymeric self-repairing elastic mechanical material and preparation method thereof
CN106751431A (en) * 2016-12-22 2017-05-31 叶晓东 A kind of battery separator and preparation method thereof
CN107325384A (en) * 2017-08-30 2017-11-07 南通市华通纤维有限公司 A kind of high temperature resistant type glass fibre
CN107383556A (en) * 2017-08-30 2017-11-24 南通市华通纤维有限公司 A kind of environmental-friendly glass fiber
CN107383555A (en) * 2017-08-30 2017-11-24 南通市华通纤维有限公司 A kind of combined glass fibre
CN107399926A (en) * 2017-08-29 2017-11-28 南通市华通纤维有限公司 A kind of glass fiber compound
CN107474363A (en) * 2017-08-30 2017-12-15 南通市华通纤维有限公司 A kind of anti-acid glass fibre
CN107474364A (en) * 2017-08-30 2017-12-15 南通市华通纤维有限公司 A kind of new glass fibre
CN107502967A (en) * 2017-08-29 2017-12-22 南通市华通纤维有限公司 A kind of new composite polyester fiber
CN107513773A (en) * 2017-08-30 2017-12-26 南通市华通纤维有限公司 A kind of glass fibre
CN107603134A (en) * 2017-10-31 2018-01-19 安徽丹凤电子材料股份有限公司 A kind of glass fiber compound material
CN107686580A (en) * 2017-08-29 2018-02-13 南通市华通纤维有限公司 A kind of glass combination fiber
CN107815785A (en) * 2017-10-31 2018-03-20 安徽丹凤电子材料股份有限公司 A kind of preparation technology of glass fiber compound material
CN109206924A (en) * 2018-08-11 2019-01-15 铜山县恒丰机械有限公司 A kind of engineering machinery composite material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6213432A (en) * 1985-07-11 1987-01-22 Sumitomo Bakelite Co Ltd Epoxy resin composition
CN103726399A (en) * 2013-12-19 2014-04-16 陕西科技大学 Blend fiber-reinforced paper-based friction material and preparation method thereof
CN104387719A (en) * 2014-10-29 2015-03-04 陈精明 Fiber-reinforced phenolic resin-based composite material and preparation method thereof
CN104403262A (en) * 2014-11-06 2015-03-11 上海复合材料科技有限公司 High-dielectric low-loss phenolic glass fiber composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6213432A (en) * 1985-07-11 1987-01-22 Sumitomo Bakelite Co Ltd Epoxy resin composition
CN103726399A (en) * 2013-12-19 2014-04-16 陕西科技大学 Blend fiber-reinforced paper-based friction material and preparation method thereof
CN104387719A (en) * 2014-10-29 2015-03-04 陈精明 Fiber-reinforced phenolic resin-based composite material and preparation method thereof
CN104403262A (en) * 2014-11-06 2015-03-11 上海复合材料科技有限公司 High-dielectric low-loss phenolic glass fiber composite material and preparation method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107488330A (en) * 2015-11-20 2017-12-19 合肥智慧龙图腾知识产权股份有限公司 A kind of macromolecule selfreparing elastic mechanical material and preparation method thereof
CN105295296A (en) * 2015-11-20 2016-02-03 陈雪琴 Polymeric self-repairing elastic mechanical material and preparation method thereof
CN106751431A (en) * 2016-12-22 2017-05-31 叶晓东 A kind of battery separator and preparation method thereof
CN107686580A (en) * 2017-08-29 2018-02-13 南通市华通纤维有限公司 A kind of glass combination fiber
CN107502967A (en) * 2017-08-29 2017-12-22 南通市华通纤维有限公司 A kind of new composite polyester fiber
CN107399926A (en) * 2017-08-29 2017-11-28 南通市华通纤维有限公司 A kind of glass fiber compound
CN107383556A (en) * 2017-08-30 2017-11-24 南通市华通纤维有限公司 A kind of environmental-friendly glass fiber
CN107474364A (en) * 2017-08-30 2017-12-15 南通市华通纤维有限公司 A kind of new glass fibre
CN107474363A (en) * 2017-08-30 2017-12-15 南通市华通纤维有限公司 A kind of anti-acid glass fibre
CN107383555A (en) * 2017-08-30 2017-11-24 南通市华通纤维有限公司 A kind of combined glass fibre
CN107513773A (en) * 2017-08-30 2017-12-26 南通市华通纤维有限公司 A kind of glass fibre
CN107325384A (en) * 2017-08-30 2017-11-07 南通市华通纤维有限公司 A kind of high temperature resistant type glass fibre
CN107603134A (en) * 2017-10-31 2018-01-19 安徽丹凤电子材料股份有限公司 A kind of glass fiber compound material
CN107815785A (en) * 2017-10-31 2018-03-20 安徽丹凤电子材料股份有限公司 A kind of preparation technology of glass fiber compound material
CN109206924A (en) * 2018-08-11 2019-01-15 铜山县恒丰机械有限公司 A kind of engineering machinery composite material

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Application publication date: 20151021