CN107383556A - A kind of environmental-friendly glass fiber - Google Patents
A kind of environmental-friendly glass fiber Download PDFInfo
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- CN107383556A CN107383556A CN201710762059.8A CN201710762059A CN107383556A CN 107383556 A CN107383556 A CN 107383556A CN 201710762059 A CN201710762059 A CN 201710762059A CN 107383556 A CN107383556 A CN 107383556A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of environmental-friendly glass fiber, is made up of the raw material of following parts by weight：40 70 parts of polyethylene powders, 10 20 parts of terephthalic acid (TPA)s, 15 parts of fatty acid polyglycol glycol ethers, 24 parts of di-iron trioxides, 20 40 parts of silane couplers, 26 parts of bisphenol-type epoxy resins, 15 parts of phosphorous acid, 13 parts of triethyl citrates, 24 parts of ethylene glycol, 13 parts of bamboo fiber felts, 4 10 parts of barium titanate powders, 13 parts of soda ash, 13 parts of quick limes, 46 parts of zinc oxide, 13 parts of bechilites, 24 parts of maleic anhydride inoculated polypropylenes.The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and increase the dielectric constant of the formula by barium titanate powder, the preparation method of this kind of composite, technique is simple, it can implement on conventional equipment, this kind of composite has good intensity, rigidity and impact flexibility simultaneously, and technique is simple, cost is low, production efficiency is high.
Description
Technical field
The invention belongs to polyester fiber field, and in particular to a kind of environmental-friendly glass fiber.
Background technology
With the development of battlefield surroundings, in order to improve the battlefield survival of tactical missile, effectively compacting, destruction enemy's air defense
Or early warning system, the flying speed of guided missile is more and more faster, and range is more and more remote, therefore tactical missile starts to propose more weight
Add the requirement of harshness, existing tactical missile antenna house uses ceramic material mostly, because the density of material in itself is larger and material
Toughness is poor, thus the weight of product is compared with use of the polymer matrix composites in antenna house, being greatly lowered antenna house
Weight；It is continuous with " ecological awareness " but most polymer matrix composites heat resistances are poor, thus the scope used is smaller
Enhancing, people increasingly pay attention to environmental protection, hygiene and health, wherein, processing characteristics is excellent, is used for various industrial products
It is typically by glass fibers that plastics pollution on the environment has turned into the problem of general concern, particularly fibre reinforced composites
Dimension, carbon fiber etc. are formed with plastic composition, and waste treatment is more difficult, and production environment is severe, and very big burden is added to environment, because
This, natural fiber such as bamboo, fiber crops, lumber fibre etc. because its have it is light, inexpensive, be easy to get, biodegradable, environmentally safe etc.
Feature causes the interest of people's development and application, although fiberglass surfacing is typically all surface-treated with soda ash, due to poly-
Propylene is non-polar polymer material, poor with the interfacial adhesion strength of glass fibre, even if generally use adds part acid anhydrides and connect
The polypropylene of branch improves interfacial adhesion strength, but raising of the glass fibre modification to Properties of Polypropylene is still limited.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of environmental-friendly glass fiber.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of environmental-friendly glass fiber, its innovative point
It is：It is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 parts terephthalic acid (TPA), 1-5 part fatty acid polyglycols
Glycol ether, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 parts bisphenol-type epoxy resin, 1-5 parts phosphorous acid, 1-
3 parts of triethyl citrates, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 parts barium titanate powder, 1-3 parts soda ash, 1-3 parts life stone
Ash, 4-6 parts zinc oxide, 1-3 parts bechilite, 2-4 part maleic anhydride inoculated polypropylenes.
Further, it is made up of the raw material of following parts by weight：40 parts of polyethylene powders, 10 parts of terephthalic acid (TPA)s, 1 part of fat
Acid polyethylene glycol ether, 2 parts of di-iron trioxides, 20 parts of silane couplers, 2 parts of bisphenol-type epoxy resins, 1 part of phosphorous acid, 1 portion of lemon
Triethylenetetraminehexaacetic acid ester, 2 parts of ethylene glycol, 1 part of bamboo fiber felt, 4 parts of barium titanate powders, 1 part of soda ash, 1 part of quick lime, 4 parts of zinc oxide, 1 part of boron
Calcium stone, 2 parts of maleic anhydride inoculated polypropylenes.
Further, it is made up of the raw material of following parts by weight：70 parts of polyethylene powders, 20 parts of terephthalic acid (TPA)s, 5 parts of fat
Acid polyethylene glycol ether, 4 parts of di-iron trioxides, 40 parts of silane couplers, 6 parts of bisphenol-type epoxy resins, 5 parts of phosphorous acid, 3 portions of lemons
Triethylenetetraminehexaacetic acid ester, 4 parts of ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of barium titanate powders, 3 parts of soda ash, 3 parts of quick limes, 6 parts of zinc oxide, 3 parts of boron
Calcium stone, 4 parts of maleic anhydride inoculated polypropylenes.
Further, it is made up of the raw material of following parts by weight：55 parts of polyethylene powders, 15 parts of terephthalic acid (TPA)s, 3 parts of fat
Acid polyethylene glycol ether, 3 parts of di-iron trioxides, 30 parts of silane couplers, 4 parts of bisphenol-type epoxy resins, 3 parts of phosphorous acid, 2 portions of lemons
Triethylenetetraminehexaacetic acid ester, 3 parts of ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of barium titanate powders, 2 parts of soda ash, 2 parts of quick limes, 5 parts of zinc oxide, 2 parts of boron
Calcium stone, 3 parts of maleic anhydride inoculated polypropylenes.
Beneficial effects of the present invention are as follows：The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and passes through barium titanate powder
Increase the dielectric constant of the formula, the preparation method of this kind of composite, technique is simple, can implement on conventional equipment, together
When this kind of composite there is good intensity, rigidity and impact flexibility, and technique is simple, cost is low, production efficiency is high.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of environmental-friendly glass fiber, it is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 parts are right
Phthalic acid, 1-5 part fatty acid polyglycols glycol ether, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 part bisphenol types
Epoxy resin, 1-5 parts phosphorous acid, 1-3 parts triethyl citrate, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 part barium titanates
Powder, 1-3 parts soda ash, 1-3 parts quick lime, 4-6 parts zinc oxide, 1-3 parts bechilite, 2-4 part maleic anhydride inoculated polypropylenes.
Embodiment 1
A kind of environmental-friendly glass fiber, it is made up of the raw material of following parts by weight：40 parts of polyethylene powders, 10 parts of terephthalic acid (TPA)s, 1
Part fatty acid polyglycol glycol ether, 2 parts of di-iron trioxides, 20 parts of silane couplers, 2 parts of bisphenol-type epoxy resins, 1 part of phosphorous acid, 1
Part triethyl citrate, 2 parts of ethylene glycol, 1 part of bamboo fiber felt, 4 parts of barium titanate powders, 1 part of soda ash, 1 part of quick lime, 4 parts of zinc oxide,
1 part of bechilite, 2 parts of maleic anhydride inoculated polypropylenes.
Embodiment 2
A kind of environmental-friendly glass fiber, it is made up of the raw material of following parts by weight：70 parts of polyethylene powders, 20 parts of terephthalic acid (TPA)s, 5
Part fatty acid polyglycol glycol ether, 4 parts of di-iron trioxides, 40 parts of silane couplers, 6 parts of bisphenol-type epoxy resins, 5 parts of phosphorous acid, 3
Part triethyl citrate, 4 parts of ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of barium titanate powders, 3 parts of soda ash, 3 parts of quick limes, 6 parts of oxidations
Zinc, 3 parts of bechilites, 4 parts of maleic anhydride inoculated polypropylenes.
Embodiment 3
A kind of environmental-friendly glass fiber, it is made up of the raw material of following parts by weight：55 parts of polyethylene powders, 15 parts of terephthalic acid (TPA)s, 3
Part fatty acid polyglycol glycol ether, 3 parts of di-iron trioxides, 30 parts of silane couplers, 4 parts of bisphenol-type epoxy resins, 3 parts of phosphorous acid, 2
Part triethyl citrate, 3 parts of ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of barium titanate powders, 2 parts of soda ash, 2 parts of quick limes, 5 parts of zinc oxide,
2 parts of bechilites, 3 parts of maleic anhydride inoculated polypropylenes.
The present invention expects light, the high and resistant to elevated temperatures advantage of intensity, and increases the dielectric constant of the formula by barium titanate powder,
The preparation method of this kind of composite, technique is simple, can implement on conventional equipment, while this kind of composite has very well
Intensity, rigidity and impact flexibility, and technique is simple, cost is low, production efficiency is high.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (4)
- A kind of 1. environmental-friendly glass fiber, it is characterised in that：It is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 parts terephthalic acid (TPA), 1-5 part fatty acid polyglycols glycol ether, 2-4 parts di-iron trioxide, 20-40 parts silane coupler, 2-6 Part bisphenol-type epoxy resin, 1-5 parts phosphorous acid, 1-3 parts triethyl citrate, 2-4 parts ethylene glycol, 1-3 parts bamboo fiber felt, 4-10 Part barium titanate powder, 1-3 parts soda ash, 1-3 parts quick lime, 4-6 parts zinc oxide, 1-3 parts bechilite, the grafting of 2-4 parts maleic anhydride are poly- Propylene.
- A kind of 2. environmental-friendly glass fiber according to claim 1, it is characterised in that：By the raw material structure of following parts by weight Into：40 parts of polyethylene powders, 10 parts of terephthalic acid (TPA)s, 1 part of fatty acid polyglycol glycol ether, 2 parts of di-iron trioxides, 20 parts of silane idols Join agent, 2 parts of bisphenol-type epoxy resins, 1 part of phosphorous acid, 1 part of triethyl citrate, 2 parts of ethylene glycol, 1 part of bamboo fiber felt, 4 parts of titaniums Sour barium powder, 1 part of soda ash, 1 part of quick lime, 4 parts of zinc oxide, 1 part of bechilite, 2 parts of maleic anhydride inoculated polypropylenes.
- A kind of 3. environmental-friendly glass fiber according to claim 1, it is characterised in that：By the raw material structure of following parts by weight Into：70 parts of polyethylene powders, 20 parts of terephthalic acid (TPA)s, 5 parts of fatty acid polyglycol glycol ethers, 4 parts of di-iron trioxides, 40 parts of silane idols Join agent, 6 parts of bisphenol-type epoxy resins, 5 parts of phosphorous acid, 3 parts of triethyl citrates, 4 parts of ethylene glycol, 3 parts of bamboo fiber felts, 10 parts of titaniums Sour barium powder, 3 parts of soda ash, 3 parts of quick limes, 6 parts of zinc oxide, 3 parts of bechilites, 4 parts of maleic anhydride inoculated polypropylenes.
- A kind of 4. environmental-friendly glass fiber according to claim 1, it is characterised in that：By the raw material structure of following parts by weight Into：55 parts of polyethylene powders, 15 parts of terephthalic acid (TPA)s, 3 parts of fatty acid polyglycol glycol ethers, 3 parts of di-iron trioxides, 30 parts of silane idols Join agent, 4 parts of bisphenol-type epoxy resins, 3 parts of phosphorous acid, 2 parts of triethyl citrates, 3 parts of ethylene glycol, 2 parts of bamboo fiber felts, 7 parts of titaniums Sour barium powder, 2 parts of soda ash, 2 parts of quick limes, 5 parts of zinc oxide, 2 parts of bechilites, 3 parts of maleic anhydride inoculated polypropylenes.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710762059.8A CN107383556A (en) | 2017-08-30 | 2017-08-30 | A kind of environmental-friendly glass fiber |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710762059.8A CN107383556A (en) | 2017-08-30 | 2017-08-30 | A kind of environmental-friendly glass fiber |
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| CN107383556A true CN107383556A (en) | 2017-11-24 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987656A (en) * | 2015-07-01 | 2015-10-21 | 安徽丹凤电子材料股份有限公司 | Formula of glass fiber composite |
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- 2017-08-30 CN CN201710762059.8A patent/CN107383556A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987656A (en) * | 2015-07-01 | 2015-10-21 | 安徽丹凤电子材料股份有限公司 | Formula of glass fiber composite |
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Application publication date: 20171124 |
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