CN107513773A - A kind of glass fibre - Google Patents
A kind of glass fibre Download PDFInfo
- Publication number
- CN107513773A CN107513773A CN201710759259.8A CN201710759259A CN107513773A CN 107513773 A CN107513773 A CN 107513773A CN 201710759259 A CN201710759259 A CN 201710759259A CN 107513773 A CN107513773 A CN 107513773A
- Authority
- CN
- China
- Prior art keywords
- parts
- heavy metal
- glass fibre
- powders
- ethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of glass fibre, is made up of the raw material of following parts by weight：40 70 parts of polyethylene powders, 10 20 parts of lemon diethyl phthalates, 15 parts of chopped strands, 24 parts of di-iron trioxides, 20 40 parts of heavy metal compounds, 26 parts of terephthalic acid (TPA)s, 15 parts of phosphorous acid, 13 parts of terylene chips, 24 parts of ethylene glycol, 13 parts of zinc oxide, 4 10 parts of barium titanate powders, 13 parts of coupling agents, 13 parts of cumyl peroxides.The present invention is copolymerized, the not only function with radiation proof, and have every feature of terylene concurrently using terylene as carrier with heavy metal compound：Simple production process, cost are cheap, durable, elasticity is good, is unlikely to deform, is corrosion-resistant, insulate, be well-pressed etc..
Description
Technical field
The invention belongs to polyester fiber field, and in particular to a kind of glass fibre.
Background technology
With the development of battlefield surroundings, in order to improve the battlefield survival of tactical missile, effectively compacting, destruction enemy's air defense
Or early warning system, the flying speed of guided missile is more and more faster, and range is more and more remote, therefore tactical missile starts to propose more weight
Add the requirement of harshness, existing tactical missile antenna house uses ceramic material mostly, because the density of material in itself is larger and material
Toughness is poor, thus the weight of product is compared with use of the polymer matrix composites in antenna house, being greatly lowered antenna house
Weight；It is continuous with " ecological awareness " but most polymer matrix composites heat resistances are poor, thus the scope used is smaller
Enhancing, people increasingly pay attention to environmental protection, hygiene and health, wherein, processing characteristics is excellent, is used for various industrial products
It is typically by glass fibers that plastics pollution on the environment has turned into the problem of general concern, particularly fibre reinforced composites
Dimension, carbon fiber etc. are formed with plastic composition, and waste treatment is more difficult, and production environment is severe, and very big burden is added to environment, because
This, natural fiber such as bamboo, fiber crops, lumber fibre etc. because its have it is light, inexpensive, be easy to get, biodegradable, environmentally safe etc.
Feature causes the interest of people's development and application, although fiberglass surfacing is typically all surface-treated with coupling agent, due to
Polypropylene is non-polar polymer material, poor with the interfacial adhesion strength of glass fibre, even if generally use adds part acid anhydrides
The polypropylene of grafting improves interfacial adhesion strength, but raising of the glass fibre modification to Properties of Polypropylene is still limited.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of glass fibre.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of glass fibre, its innovative point are：
It is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 part lemons diethyl phthalate, 1-5 parts chopped strand, 2-
4 parts of di-iron trioxides, 20-40 parts heavy metal compound, 2-6 parts terephthalic acid (TPA), 1-5 parts phosphorous acid, 1-3 parts terylene chips,
2-4 parts ethylene glycol, 1-3 parts zinc oxide, 4-10 parts barium titanate powder, 1-3 parts coupling agent, 1-3 part cumyl peroxides.
Further, it is made up of the raw material of following parts by weight：It is 40 parts of polyethylene powders, 10 parts of lemon diethyl phthalates, 1 part short
Cut fiber, 2 parts of di-iron trioxides, 20 parts of heavy metal compounds, 2 parts of terephthalic acid (TPA)s, 1 part of phosphorous acid, 1 part of terylene chips, 2 parts
Ethylene glycol, 1 part of zinc oxide, 4 parts of barium titanate powders, 1 part of coupling agent, 1 part of cumyl peroxide.
Further, it is made up of the raw material of following parts by weight：It is 70 parts of polyethylene powders, 20 parts of lemon diethyl phthalates, 5 parts short
Cut fiber, 4 parts of di-iron trioxides, 40 parts of heavy metal compounds, 6 parts of terephthalic acid (TPA)s, 5 parts of phosphorous acid, 3 parts of terylene chips, 4 parts
Ethylene glycol, 3 parts of zinc oxide, 10 parts of barium titanate powders, 3 parts of coupling agents, 3 parts of cumyl peroxides.
Further, it is made up of the raw material of following parts by weight：It is 55 parts of polyethylene powders, 15 parts of lemon diethyl phthalates, 3 parts short
Cut fiber, 3 parts of di-iron trioxides, 30 parts of heavy metal compounds, 4 parts of terephthalic acid (TPA)s, 3 parts of phosphorous acid, 2 parts of terylene chips, 3 parts
Ethylene glycol, 2 parts of zinc oxide, 7 parts of barium titanate powders, 2 parts of coupling agents, 2 parts of cumyl peroxides.
Beneficial effects of the present invention are as follows：The present invention is copolymerized using terylene as carrier with heavy metal compound, is not only had anti-
The function of radiation, and have every feature of terylene concurrently：Simple production process, cost are cheap, durable, elasticity is good, are not easy
Deformation, corrosion-resistant, insulation, well-pressed etc..
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of glass fibre, it is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 parts citric acid two
Ethyl ester, 1-5 parts chopped strand, 2-4 parts di-iron trioxide, 20-40 parts heavy metal compound, 2-6 parts terephthalic acid (TPA), 1-5 parts
Phosphorous acid, 1-3 parts terylene chips, 2-4 parts ethylene glycol, 1-3 parts zinc oxide, 4-10 parts barium titanate powder, 1-3 parts coupling agent, 1-3 parts
Cumyl peroxide.
Embodiment 1
A kind of glass fibre, it is made up of the raw material of following parts by weight：It is 40 parts of polyethylene powders, 10 parts of lemon diethyl phthalates, 1 part short
Cut fiber, 2 parts of di-iron trioxides, 20 parts of heavy metal compounds, 2 parts of terephthalic acid (TPA)s, 1 part of phosphorous acid, 1 part of terylene chips, 2 parts
Ethylene glycol, 1 part of zinc oxide, 4 parts of barium titanate powders, 1 part of coupling agent, 1 part of cumyl peroxide.
Embodiment 2
A kind of glass fibre, it is made up of the raw material of following parts by weight：It is 70 parts of polyethylene powders, 20 parts of lemon diethyl phthalates, 5 parts short
Cut fiber, 4 parts of di-iron trioxides, 40 parts of heavy metal compounds, 6 parts of terephthalic acid (TPA)s, 5 parts of phosphorous acid, 3 parts of terylene chips, 4 parts
Ethylene glycol, 3 parts of zinc oxide, 10 parts of barium titanate powders, 3 parts of coupling agents, 3 parts of cumyl peroxides.
Embodiment 3
A kind of glass fibre, it is made up of the raw material of following parts by weight：It is 55 parts of polyethylene powders, 15 parts of lemon diethyl phthalates, 3 parts short
Cut fiber, 3 parts of di-iron trioxides, 30 parts of heavy metal compounds, 4 parts of terephthalic acid (TPA)s, 3 parts of phosphorous acid, 2 parts of terylene chips, 3 parts
Ethylene glycol, 2 parts of zinc oxide, 7 parts of barium titanate powders, 2 parts of coupling agents, 2 parts of cumyl peroxides.
The present invention is copolymerized, the not only function with radiation proof, and have concurrently and wash using terylene as carrier with heavy metal compound
Every feature of synthetic fibre：Simple production process, cost are cheap, durable, elasticity is good, are unlikely to deform, are corrosion-resistant, insulate, be well-pressed
Deng.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (4)
- A kind of 1. glass fibre, it is characterised in that：It is made up of the raw material of following parts by weight：40-70 parts polyethylene powders, 10-20 Part lemon diethyl phthalate, 1-5 parts chopped strand, 2-4 parts di-iron trioxide, 20-40 parts heavy metal compound, 2-6 parts are to benzene two Formic acid, 1-5 parts phosphorous acid, 1-3 parts terylene chips, 2-4 parts ethylene glycol, 1-3 parts zinc oxide, 4-10 parts barium titanate powder, 1-3 parts are even Join agent, 1-3 part cumyl peroxides.
- A kind of 2. glass fibre according to claim 1, it is characterised in that：It is made up of the raw material of following parts by weight：40 parts Polyethylene powders, 10 parts of lemon diethyl phthalates, 1 part of chopped strand, 2 parts of di-iron trioxides, 20 parts of heavy metal compounds, 2 parts it is right Phthalic acid, 1 part of phosphorous acid, 1 part of terylene chips, 2 parts of ethylene glycol, 1 part of zinc oxide, 4 parts of barium titanate powders, 1 part of coupling agent, 1 part Cumyl peroxide.
- A kind of 3. glass fibre according to claim 1, it is characterised in that：It is made up of the raw material of following parts by weight：70 parts Polyethylene powders, 20 parts of lemon diethyl phthalates, 5 parts of chopped strands, 4 parts of di-iron trioxides, 40 parts of heavy metal compounds, 6 parts it is right Phthalic acid, 5 parts of phosphorous acid, 3 parts of terylene chips, 4 parts of ethylene glycol, 3 parts of zinc oxide, 10 parts of barium titanate powders, 3 parts of coupling agents, 3 parts Cumyl peroxide.
- A kind of 4. glass fibre according to claim 1, it is characterised in that：It is made up of the raw material of following parts by weight：55 parts Polyethylene powders, 15 parts of lemon diethyl phthalates, 3 parts of chopped strands, 3 parts of di-iron trioxides, 30 parts of heavy metal compounds, 4 parts it is right Phthalic acid, 3 parts of phosphorous acid, 2 parts of terylene chips, 3 parts of ethylene glycol, 2 parts of zinc oxide, 7 parts of barium titanate powders, 2 parts of coupling agents, 2 parts Cumyl peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710759259.8A CN107513773A (en) | 2017-08-30 | 2017-08-30 | A kind of glass fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710759259.8A CN107513773A (en) | 2017-08-30 | 2017-08-30 | A kind of glass fibre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107513773A true CN107513773A (en) | 2017-12-26 |
Family
ID=60724464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710759259.8A Pending CN107513773A (en) | 2017-08-30 | 2017-08-30 | A kind of glass fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107513773A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264268A (en) * | 2014-09-18 | 2015-01-07 | 海安县华荣化纤有限公司 | Anti-neutron radiation polyester fiber preparation method |
| CN104987656A (en) * | 2015-07-01 | 2015-10-21 | 安徽丹凤电子材料股份有限公司 | Formula of glass fiber composite |
-
2017
- 2017-08-30 CN CN201710759259.8A patent/CN107513773A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264268A (en) * | 2014-09-18 | 2015-01-07 | 海安县华荣化纤有限公司 | Anti-neutron radiation polyester fiber preparation method |
| CN104987656A (en) * | 2015-07-01 | 2015-10-21 | 安徽丹凤电子材料股份有限公司 | Formula of glass fiber composite |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171226 |