CN102719092B - Composite reinforced nylon composition and preparation method thereof - Google Patents
Composite reinforced nylon composition and preparation method thereof Download PDFInfo
- Publication number
- CN102719092B CN102719092B CN201210232969.2A CN201210232969A CN102719092B CN 102719092 B CN102719092 B CN 102719092B CN 201210232969 A CN201210232969 A CN 201210232969A CN 102719092 B CN102719092 B CN 102719092B
- Authority
- CN
- China
- Prior art keywords
- glass fibre
- carbon fiber
- composite
- nano imvite
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
The invention relates to a composite reinforced nylon composition. The composite reinforced nylon composition consists of the following components in percentage by weight (wt%): 58.6 to 63.6 percent of nylon, 4 to 12 percent of carbon fiber, 15 to 20 percent of glass fiber, 3 to 5 percent of nano montmorillonite, 3 to 8 percent of toughening modifier and 0.4 to 6.4 percent of other auxiliaries. The other auxiliaries are a lubricating dispersing agent and an antioxidant. The invention also provides a preparation method of the composite reinforced nylon composition. Compared with the prior art, the composite reinforced nylon composition prepared by the preparation method disclosed by the invention has flat surface and high mechanical strength, has heat resistance, is conductive and has wide application range.
Description
Technical field
The present invention relates to a kind of nylon composite, specifically, is about a kind of composite enhancement nylon composition and method of making the same.
Background technology
The advantages such as polymeric amide has good physical strength and rigidity, and wear-resistant property is good are widely used in trolley part, mechanical part, electric field etc., become first of five large-engineering quantity of plastics, and a lot of application replaces traditional metallic substance.Simple glass fibre reinforced modified purer material improves the intensity, creep resistance, wear resistance etc. of material greatly, but still can not meet some to high temperature resistant, and heat-resisting, there is the applications of requirements at the higher level high strength aspect.Carbon fiber has the features such as light weight, tensile strength are high, wear-resistant, corrosion-resistant, creep resistance, conduction, heat transfer, and compared with glass fibre, modulus is high 35 times, because of but a kind of excellent strongthener obtaining high rigidity and high-strength nylon material.Because carbon fibre material is expensive, the application of pure carbon fiber strongthener is limited.Take glass fibre/carbon fiber composite reinforced material, and add organic nano imvite, the composite composition intensity of preparation is high, conduction, the excellent combination properties such as heat conduction, cost Equilibrium.
Chinese patent literature CN:1693365B, discloses a kind of enhancend friction type nylon composite materials and preparation technology.Chinese patent literature CN:101412845A, discloses a kind of high performance fiber reinforced nylon composite material and preparation method thereof.But yet there are no report about a kind of composite enhancement nylon composition and method of making the same.
Summary of the invention
The object of the invention is for deficiency of the prior art, a kind of composite enhancement nylon composition is provided.
Of the present invention again one object be that a kind of preparation method of composite enhancement nylon composition is provided.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of composite enhancement nylon composition, described composite enhancement nylon composition is made up of following compositions in weight percentage (wt%):
Nylon 58.6-63.6
Carbon fiber 4-12
Glass fibre 15-20
Nano imvite 3-5
Plasticized modifier 3-8
Other auxiliary agent 0.4-6.4
Other described auxiliary agent is lubrication dispersing agent and oxidation inhibitor.
Described nylon is nylon 6 or nylon66 fiber, and its limiting viscosity is 2.4-3.2Pa
*s.
Described carbon fiber belongs to amorphous carbon fiber, tensile modulus 24.0*10
3kgf/mm
2, Fibre diameter 7.0 μm, volume specific resistance 1.5*10
-3Ω cm.
Described glass fibre is alkali free glass fibre, and its surface is through silane coupling agent process.
Described nano imvite purity is 90%-98% polynite silico-aluminate, particle diameter 200-500 order, interlamellar spacing 1.9-2.1nm.
Described nano imvite carries out organic-treating, and its concrete treatment process is, nano imvite added polynite mass parts 30%-70% alkylation treatment agent, add acetone soln, ultra-sonic oscillation 1h, distilled water wash after centrifugation, dry.
Described nano imvite alkylation treatment agent is selected from the one in Gemini quaternary ammonium salt, Cetyl dimethyl betaine, Trimethyllaurylammonium bromide or Cetyltrimethylammonium bromide.
Described plasticized modifier is the oligopolymer of the graft polymerization of POE grafting unsaturated acid or acid anhydrides, for maleic anhydride graft POE, its melting index is 2g/10min, and percentage of grafting is 0.5-1%, can be selected from CMG9805(Rizhisheng New Technology Development Co., Ltd., Shanghai and produce).
Described lubrication dispersing agent and oxidation inhibitor weight ratio are 1:1, and lubrication dispersing agent is selected from silicone, and oxidation inhibitor is that HD98 and HD168 forms by weight 1:1 is composite.
For realizing above-mentioned second object, the technical scheme that the present invention takes is:
A preparation method for composite enhancement nylon composition, is characterized in that, the method comprises the following steps:
A () is got the raw materials ready according to following component and content weight percent (wt%), carbon fiber, glass fibre enter from glass fibre mouth;
Nylon 58.6-63.6
Carbon fiber 4-12
Glass fibre 15-20
Nano imvite 3-5
Plasticized modifier 3-8
Other auxiliary agent 0.4-6.4
B discharging after high-speed mixer and mixing 3-5min put into by above-mentioned raw material except glass fibre and carbon fiber by (), obtain mixture, then the processing temperature 240-260 DEG C of twin screw extruder is controlled, screw rod revolution 180-600 rev/min, mixture is placed in twin screw extruder, glass fibre and carbon fiber enter from glass fibre mouth, and extruding pelletization, obtains product.
The invention has the advantages that: compared with prior art, the composite reinforcing nylon material that the present invention obtains, surfacing, physical strength is high, heat-resisting, and conduction, has wide range of applications.
Embodiment
Below embodiment provided by the invention is elaborated.
embodiment 1,2,3
A kind of composite enhancement nylon preparation method of composition, comprises the following steps:
(1) get the raw materials ready according to the component in table 1 and content, carbon fiber, glass fibre enter from glass fibre mouth.
(2) above-mentioned raw material except glass fibre and carbon fiber is put into discharging after high-speed mixer and mixing 3-5min, obtain mixture, then the processing temperature 240-260 DEG C of twin screw extruder is controlled, screw rod revolution 180-600 rev/min, mixture is placed in twin screw extruder, glass fibre and carbon fiber enter from glass fibre mouth, and extruding pelletization, obtains product.
Table 1
| Raw material/wt% | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Nylon | 63.6 | 61.6 | 58.6 |
| Carbon fiber | 10 | 12 | 4 |
| Glass fibre | 20 | 15 | 20 |
| Nano imvite | 3 | 5 | 3 |
| Plasticized modifier | 3 | 3 | 8 |
| Other auxiliary agent | 0.4 | 3.4 | 6.4 |
It should be noted that:
Nylon66 fiber in embodiment 1, limiting viscosity is 2.4 Pa
*s; Nylon66 fiber in embodiment 2, limiting viscosity is 2.6 Pa
*s; Nylon 6 in embodiment 3, limiting viscosity is 3.2 Pa
*s.
Embodiment 1, embodiment 2, the carbon fiber in embodiment 3 is amorphous carbon fiber, tensile modulus 24.0*10
3kgf/mm
2, Fibre diameter 7.0 μm, volume specific resistance 1.5*10
-3Ω cm.
Embodiment 1, embodiment 2, the glass fibre in embodiment 3 is alkali free glass fibre, and its surface is through silane coupling agent process, and the present embodiment 1,2, be selected from the alkali-free glass fiber that megalith group produces in 3, the concrete trade mark is ER14-1000-988A
Nano imvite purity in embodiment 1 is 90% polynite silico-aluminate, particle diameter 250 order, interlamellar spacing 2.1nm; The preparation method of nano imvite is as follows: nano imvite, carry out organic-treating, concrete treatment process is, nano imvite is added polynite mass parts 30% alkylation treatment agent, then the acetone soln of nano imvite mass parts 100 times is added, ultra-sonic oscillation 1h, distilled water wash after centrifugation, drying, described alkylation treatment agent is Cetyl dimethyl betaine.Nano imvite purity in embodiment 2 is 95% polynite silico-aluminate, particle diameter 500 order, interlamellar spacing 2.0nm; The preparation method of nano imvite is as follows: nano imvite, carry out organic-treating, concrete treatment process is, nano imvite is added polynite mass parts 70% alkylation treatment agent, add nano imvite mass parts 100 times of acetone solns, ultra-sonic oscillation 1h, distilled water wash after centrifugation, drying, described alkylation treatment agent is Cetyltrimethylammonium bromide.Nano imvite purity in embodiment 3 is 98% polynite silico-aluminate, particle diameter 200 order, interlamellar spacing 1.9nm.The preparation method of nano imvite is as follows: nano imvite, carry out organic-treating, concrete treatment process is, nano imvite is added polynite mass parts 45% alkylation treatment agent, add nano imvite mass parts 100 times of acetone solns, ultra-sonic oscillation 1h, distilled water wash after centrifugation, drying, described alkylation treatment agent is Trimethyllaurylammonium bromide.
Embodiment 1, embodiment 2, the plasticized modifier in embodiment 3 is that maleic anhydride graft POE(is CMG9805) its melting index is 2g/10min, percentage of grafting is 0.8%.
Lubrication dispersing agent (silicone) in embodiment 1 auxiliary agent is 2:1 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio; Lubrication dispersing agent (silicone) in embodiment 2 auxiliary agent is 1:1 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio; Lubrication dispersing agent (silicone) in embodiment 3 auxiliary agent is 1:2 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio.
Embodiment 1 Raw puts into discharging after high-speed mixer and mixing 3min, the processing temperature of twin screw extruder 260 DEG C, screw rod revolution 180 revs/min; Embodiment 2 Raw puts into discharging after high-speed mixer and mixing 5min, the processing temperature of twin screw extruder 240 DEG C, screw rod revolution 600 revs/min; Embodiment 3 Raw puts into discharging after high-speed mixer and mixing 4min, the processing temperature of twin screw extruder 250 DEG C, screw rod revolution 400 revs/min.
The sample 1-3 obtained according to embodiment 1-3, carries out performance test comparison, adopts iso standard, and test performance contrast is as shown in table 2.
Table 2
| Item | Unit | Condition | Sample 1 | Sample 2 | Sample 3 |
| Tensile strength | MPa | ISO 527 | 140 | 160 | 135 |
| Flexural strength | MPa | ISO 178 | 210 | 220 | 200 |
| Modulus in flexure | MPa | ISO 178 | 8000 | 9000 | 7800 |
| Shock strength | KJ/M 2 | ISO 179 | 8.5 | 9.0 | 9.6 |
| Density | g/㎝ 3 | ISO 1183 | 1.35 | 1.36 | 1.35 |
| Content | ISO 3451 | 33 | 35 | 33 | |
| Volume resistance | Ω · cm | ASTM D257 | 10 2 | 10 2 | 10 2 |
| Thermal distortion | ℃ | ISO 75 | 248 | 250 | 246 |
contrast experiment
Comparative example nylon composite preparation method, comprises the following steps:
(1) get the raw materials ready according to the component in table 3 (comparative example 1, comparative example 2, comparative example 3) and content, carbon fiber, glass fibre enter from glass fibre mouth.
(2) above-mentioned raw material except glass fibre and carbon fiber is put into discharging after high-speed mixer and mixing 3-5min, obtain mixture, then the processing temperature 240-260 DEG C of twin screw extruder is controlled, screw rod revolution 180-600 rev/min, mixture is placed in twin screw extruder, glass fibre and carbon fiber enter from glass fibre mouth, and extruding pelletization, obtains product.
Table 3
| Raw material/wt% | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Nylon | 63.6 | 61.6 | 58.6 | 63.6 | 61.6 | 58.6 |
| Carbon fiber | 10 | 12 | 4 | 10 | 14 | 6 |
| Glass fibre | 20 | 15 | 20 | 22 | 18 | 21 |
| Nano imvite | 3 | 5 | 3 | |||
| Plasticized modifier | 3 | 3 | 8 | 4 | 3 | 8 |
| Other auxiliary agent | 0.4 | 3.4 | 6.4 | 0.4 | 3.4 | 6.4 |
It should be noted that:
Nylon66 fiber in comparative example 1, limiting viscosity is 2.4 Pa
*s; Nylon66 fiber in comparative example 2, limiting viscosity is 2.6 Pa
*s; Nylon 6 in comparative example 3, limiting viscosity is 3.2 Pa
*s.
Comparative example 1, comparative example 2, the carbon fiber in comparative example 3 is amorphous carbon fiber, tensile modulus 24.0*10
3kgf/mm
2, Fibre diameter 7.0 μm, volume specific resistance 1.5*10
-3Ω cm.
Comparative example 1, comparative example 2, the glass fibre in comparative example 3 is alkali free glass fibre, and its surface is through silane coupling agent process, and this comparative example 1,2, is selected from the alkali-free glass fiber ER14-1000-988A that megalith group produces in 3.
Comparative example 1, comparative example 2, the plasticized modifier in comparative example 3 is that maleic anhydride graft POE(is CMG9805) its melting index is 2g/10min, percentage of grafting is 0.8%.
Lubrication dispersing agent (silicone) in comparative example 1 auxiliary agent is 2:1 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio; Lubrication dispersing agent (silicone) in comparative example 2 auxiliary agent is 1:1 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio; Lubrication dispersing agent (silicone) in comparative example 3 auxiliary agent is 1:2 with oxidation inhibitor (HD98 and HD168 forms by weight 1:1 is composite) weight ratio.
Comparative example 1 Raw puts into discharging after high-speed mixer and mixing 3min, the processing temperature of twin screw extruder 260 DEG C, screw rod revolution 180 revs/min; Comparative example 2 Raw puts into discharging after high-speed mixer and mixing 5min, the processing temperature of twin screw extruder 240 DEG C, screw rod revolution 600 revs/min; Comparative example 3 Raw puts into discharging after high-speed mixer and mixing 4min, the processing temperature of twin screw extruder 250 DEG C, screw rod revolution 400 revs/min.
The sample 4-6 obtained according to comparative example 1-3, carries out performance test comparison, adopts iso standard, and test performance contrast is as shown in table 4.
Table 4
| Item | Unit | Condition | Sample 1 | Sample 2 | Sample 3 | Sample 4 | Sample 5 | Sample 6 |
| Tensile strength | MPa | ISO 527 | 140 | 160 | 135 | 145 | 165 | 140 |
| Flexural strength | MPa | ISO 178 | 210 | 220 | 200 | 220 | 220 | 210 |
| Modulus in flexure | MPa | ISO 178 | 8000 | 9000 | 7800 | 8000 | 9000 | 6800 |
| Shock strength | KJ/M 2 | ISO 179 | 8.5 | 9.0 | 9.6 | 8.6 | 9.1 | 9.7 |
| Density | g/㎝ 3 | ISO 1183 | 1.35 | 1.36 | 1.35 | 1.34 | 1.36 | 1.34 |
| Content | ISO 3451 | 33 | 35 | 33 | 33 | 35 | 33 | |
| Volume resistance | Ω · cm | ASTM D257 | 10 2 | 10 2 | 10 2 | 10 2 | 10 2 | 10 2 |
| Thermal distortion | ℃ | ISO 75 | 248 | 250 | 246 | 238 | 240 | 236 |
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the inventive method; can also make some improvement and supplement, these improve and supplement and also should be considered as protection scope of the present invention.
Claims (2)
1. a composite enhancement nylon composition, it is characterized in that, described composite enhancement nylon composition is made up of following compositions in weight percentage: nylon66 fiber 63.6%, amorphous carbon fiber 10%, glass fibre 20%, nano imvite 3%, plasticized modifier 3%, other auxiliary agents 0.4%; Described nylon66 fiber limiting viscosity is 2.4PaS; It is 24.0 × 10 that described amorphous carbon fiber draws high modulus
3kgf/mm
2, Fibre diameter is 7.0 μm, and volume specific resistance is 1.5 × 10
-3Ω cm; Described glass fibre is the megalith group production trade mark is the alkali-free glass fiber of ER14-1000-988A, and surface is through silane coupling agent process; Described nano imvite purity is the polynite silico-aluminate of 90%, particle diameter 250 order, and interlamellar spacing is 2.1nm; Described nano imvite preparation method is as follows: nano imvite is added polynite mass parts 30% alkylation treatment agent, adds polynite mass parts 100 times of acetone solns, ultrasonic oscillation 1h, distilled water wash after centrifugation, dry; Described alkylation treatment agent is Cetyl dimethyl betaine; Described plasticized modifier is maleic anhydride graft POE, and its melting index is 2g/10min, and percentage of grafting is 0.8%; Described auxiliary agent is silicone, HD98, HD168 form by weight 4:1:1 is composite.
2. the preparation method of composite enhancement nylon composition according to claim 1, it is characterized in that, the method comprises the following steps:
A () is got the raw materials ready according to component according to claim 1 and content weight percent (wt%); B discharging after high-speed mixer and mixing 3-5min put into by above-mentioned raw material except glass fibre and carbon fiber by (), obtain mixture, then the processing temperature 240-260 DEG C of twin screw extruder is controlled, screw rod revolution 180-600 rev/min, mixture is placed in twin screw extruder, glass fibre and carbon fiber enter from glass fibre mouth, and extruding pelletization, obtains product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232969.2A CN102719092B (en) | 2012-07-06 | 2012-07-06 | Composite reinforced nylon composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232969.2A CN102719092B (en) | 2012-07-06 | 2012-07-06 | Composite reinforced nylon composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102719092A CN102719092A (en) | 2012-10-10 |
| CN102719092B true CN102719092B (en) | 2015-06-03 |
Family
ID=46944973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210232969.2A Expired - Fee Related CN102719092B (en) | 2012-07-06 | 2012-07-06 | Composite reinforced nylon composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102719092B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924994B (en) * | 2012-11-13 | 2014-01-08 | 汕头市东和机械有限公司 | Abrasion-resistant agents and preparation method thereof |
| CN103788643B (en) * | 2014-01-27 | 2016-08-17 | 上海日之升新技术发展有限公司 | High antiknock Compressive Strength fiberglass reinforced hydrolysis PA66 material and preparation method thereof |
| CN104292828A (en) * | 2014-09-30 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | Reinforced nylon 66 composite material and preparation method thereof |
| CN104513475A (en) * | 2014-12-19 | 2015-04-15 | 广东奇德新材料股份有限公司 | High-performance nanometer PA6 nano-composite material |
| CN104974506A (en) * | 2015-07-29 | 2015-10-14 | 苏州新区华士达工程塑胶有限公司 | Nylon reinforced office chair eight-claw pedestal plastic |
| CN106009647A (en) * | 2016-07-12 | 2016-10-12 | 蚌埠高华电子股份有限公司 | Glass fiber reinforcement nylon heat conduction composite material for LED lamp and preparing method thereof |
| CN107118547A (en) * | 2017-05-12 | 2017-09-01 | 昆山茂高塑胶科技有限公司 | A kind of high filling enhancing automobile engine cover plate PP Pipe Compound |
| CN109777093A (en) * | 2018-12-27 | 2019-05-21 | 安徽旭升新材料有限公司 | For making the carbon fiber and 6 composite material of modified Pa 6 of unmanned plane propeller |
| CN110894356A (en) * | 2019-11-29 | 2020-03-20 | 苏州润佳高分子材料有限公司 | High-strength modified nylon material for automobile |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974666A (en) * | 2005-11-18 | 2007-06-06 | Ems化学股份公司 | Reinforced polyamide moulding materials |
| CN102391643A (en) * | 2011-09-07 | 2012-03-28 | 上海日之升新技术发展有限公司 | High temperate-resistant nanometer fire resistance-enhanced PA6 composite material and preparation method thereof |
| CN102417727A (en) * | 2011-11-24 | 2012-04-18 | 上海日之升新技术发展有限公司 | High and low temperature-resistant cycling glass fiber reinforcement polyamide 66 (PA66) composite material and production method thereof |
-
2012
- 2012-07-06 CN CN201210232969.2A patent/CN102719092B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974666A (en) * | 2005-11-18 | 2007-06-06 | Ems化学股份公司 | Reinforced polyamide moulding materials |
| CN102391643A (en) * | 2011-09-07 | 2012-03-28 | 上海日之升新技术发展有限公司 | High temperate-resistant nanometer fire resistance-enhanced PA6 composite material and preparation method thereof |
| CN102417727A (en) * | 2011-11-24 | 2012-04-18 | 上海日之升新技术发展有限公司 | High and low temperature-resistant cycling glass fiber reinforcement polyamide 66 (PA66) composite material and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102719092A (en) | 2012-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102719092B (en) | Composite reinforced nylon composition and preparation method thereof | |
| CN101230193B (en) | High-strength basalt fibre reinforced nylon composition and preparation method thereof | |
| CN108164820A (en) | A kind of plant fiber/PP composite materials and preparation method thereof | |
| CN113025039A (en) | Polyphenylene sulfide composite material and preparation method thereof | |
| CN102051045B (en) | High-rigidity glass fiber reinforced PA6/ABS composite material | |
| CN108165003A (en) | A kind of high content of glass fiber enhancing high-temperature nylon composite material and preparation method thereof | |
| CN103834161A (en) | High-temperature resistant semi aromatic nylon composite material and preparation method thereof | |
| CN103102682A (en) | Graphene reinforcing and toughening nylon resin and preparation method thereof | |
| CN106589927A (en) | Fiber blend reinforced nylon composite material and preparation method thereof | |
| CN102532869A (en) | Heat-conducting antistatic carbon fiber modified polyamide composite material and preparation method thereof | |
| CN102604353B (en) | Glass fiber reinforced polycarbonate composite material and preparation method thereof | |
| CN103937093A (en) | Long glass fiber reinforced polypropylene composite material and preparation method | |
| CN106589581A (en) | Special material for wind wheels of air conditioners and preparation method for special material | |
| CN105440642A (en) | Modified polycarbonate engineering plastic and preparation method of modified polycarbonate engineering plastic | |
| CN104559146A (en) | Whisker reinforced thermally conductive plastic material and preparation method thereof | |
| CN106751761A (en) | High rigidity high glaze carbon fiber reinforced polyamide composite material and preparation method thereof | |
| CN103980707A (en) | Toughened polyether-imide composite material and preparation method thereof | |
| CN103408927A (en) | Composite fiber modified nylon material and preparation method thereof | |
| CN103724952A (en) | PET/PPO (Polyethylene terephthalate/poly-p-phenylene oxide) alloy material and preparation method thereof | |
| CN104672828A (en) | PC (polycarbonate) abrasion resistant master batches | |
| CN104045981B (en) | PET/ polyester alloy that a kind of heat conduction carbon fibre strengthens and preparation method thereof | |
| CN104163983A (en) | Ramie fiber-reinforced polypropylene composite material and preparation process thereof | |
| CN105153631B (en) | A kind of coating modified fibre reinforced ABS resin composite material and preparation method | |
| CN108396402B (en) | High-toughness polyester staple fiber and preparation method thereof | |
| CN104419135A (en) | Carbon fiber-reinforced PBT and PET alloy |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150603 Termination date: 20160706 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |