Explosion-proof early warning lithium battery
Technical field
The present invention relates to a kind of lithium battery, especially, is a kind of lithium battery with step-down, explosion prevention function.
Background technology
Compared to traditional lead acid accumulator, lithium battery has obvious advantage, and its energy Ratios is higher, longer service life, rated voltage are higher, self-discharge rate is lower, and quality is lighter simultaneously, more energy-conserving and environment-protective, plurality of advantages makes lithium battery be widely used in each corner of life; But still there is potential safety hazard in current lithium battery, lithium battery by use in recent years in, often report that lithium battery explodes in charging process; The explosion cause of lithium battery is roughly divided into three kinds: external short circuit, internal short-circuit, over-charging of battery; Its direct explosion cause is that battery short circuit result in internal temperature and raises, and the electrolyte in battery is heated vaporization, makes cell expansion, and then produces and explode; Percentage of batteries even can make electrolyte burn, and causes serious security incident.
Summary of the invention
For the problems referred to above, the invention provides a kind of explosion-proof early warning lithium battery, this lithium battery can send warning when expanded by heating, simultaneously can step-down automatically, effectively prevents battery explosion.
For solving the problem, the technical solution adopted in the present invention is: this explosion-proof early warning lithium battery includes housing, battery core and explosion-proof parts; Described explosion-proof parts include the pedestal being fixed on housing lower surface; Described pedestal is provided with one can around point film rotating shaft of own axis; Described point of film rotating shaft is arranged with the translation rotating cylinder that internal perisporium is carved with spiral, and described translation rotating cylinder only can along described point of film rotating shaft upper and lower translation under the restriction of spacing pole; The fluid-tight sheet be fixed in described point film rotating shaft is installed at the nozzle of described translation rotating cylinder; The closed cavity of described fluid-tight sheet, translation rotating cylinder and point film rotating shaft makeup ring tubular, is filled with inert gas in described closed cavity; Flexible point of film blade is evenly equipped with in the top circumference of described point of film rotating shaft; Be covered with the Explosion-proof cap coaxial with described point of film rotating shaft at described point of film blade upper cover, the caping of described Explosion-proof cap exposes housing upper surface, and described Explosion-proof cap is fixed on housing by adhesive; The lid neck of described Explosion-proof cap puts in described housing along dividing the axis of film rotating shaft; Described lid neck offers decompression hole, the postive stop baffle be fixed on described lid neck is also installed in the below of described decompression hole.
The invention has the beneficial effects as follows: when producing, by selecting the adhesive of different firmness, the bonding firmness namely between adjustable Explosion-proof cap and housing, and then the maximum pressure that regulating cell inside can allow; In battery charge and discharge process, inside battery can produce certain heat, and the pressure in battery has increase by a small margin; But because a point film blade is covered by Explosion-proof cap, described caping and a point film blade contact, under the restriction of frictional force, point film blade keeps inactive state, is that elastic bending state is housed in Explosion-proof cap with time-division film blade.
When there is the abnormalities such as short circuit when battery, the temperature of inside battery rises fast, and electrolyte is heated vaporization, and the pressure of inside battery increases fast; When pressure exceedes safety value, described Explosion-proof cap is backed down, and Explosion-proof cap is along axis upward sliding, and the caping of Explosion-proof cap does not contact with a point film blade, and frictional force disappears; Now described decompression hole exposes the upper surface of housing, and the electrolyte of vaporization sheds in housing, and battery pressure reduces, and then prevents battery explosion; Liquid electrolyte may be had form liquid film at decompression hole place while the electrolyte of vaporization sheds, and then decompression hole is blocked, now battery recovers air-tight state again, pressure in battery increases again, the pressure increased makes the contraction of gas in translation rotating cylinder, volume in translation rotating cylinder reduces, and described translation rotating cylinder moves down; Along with moving down of translation rotating cylinder, described fluid-tight sheet rotates along the spiral of translation rotating cylinder, and then drive point film rotating shaft and point film blade rotation, when point film blade is through decompression hole, film blade is divided to be stretched by elastic bending state, point film blade stretches out from decompression hole and is broken by the liquid film bullet getting lodged in decompression hole, thus enables the decompression hole electrolyte of carburation by spraying, step-down again.
Delicate structure of the present invention, can step-down automatically when inside battery pressure exceedes critical value, and can effectively prevent electrolyte from blocking decompression hole, make pressure all-the-time stable in battery in controlled range, there will not be the situation that dropping valve is plugged, therefore use safer.
As preferably, two described explosion-proof parts are installed the upper and lower surface of described housing is rotational symmetric; When battery expands, the gas sprayed in described explosion-proof parts can make battery produce turning moment, is convenient to battery and departs from from charger, to realize open circuit; Eruption power conversion can be become rotation function simultaneously, reduce the scope that battery is jet, blast involves, make battery safer.
As preferably, each described point film blade is made up of two parallel springing sheets; Gas, when spraying from decompression hole, drives the vibration of springing sheet, and make lithium battery produce buzz, reminding user battery charging state is abnormal.
As preferably, described caping is made by transparent material; So that observe the state of point film blade.
As further preferably, described point of film blade scribbles fine silver layer; A point film blade for original-pack battery is silvery white in color, and the battery inferior through reclaiming, and because a point film blade exposes mistake in atmosphere, the oxidized or sulfuration of fine silver layer, can show black; Therefore the quality of battery tentatively can be judged by observing point film blade.
Accompanying drawing explanation
Fig. 1 is the stereochemical structure simplified schematic diagram of this explosion-proof early warning lithium battery embodiment.
Fig. 2 is side structure schematic diagram embodiment illustrated in fig. 1.
Fig. 3 be embodiment illustrated in fig. 1 in the structure for amplifying schematic diagram of explosion-proof parts when battery is normal.
Fig. 4 be embodiment illustrated in fig. 1 in point structure for amplifying schematic diagram of film blade when battery is normal.
Fig. 5 be embodiment illustrated in fig. 1 in the structure for amplifying schematic diagram of explosion-proof parts when battery is abnormal.
Fig. 6 be embodiment illustrated in fig. 1 in point film blade structure for amplifying schematic diagram when battery is abnormal.
Embodiment
Embodiment
In embodiment shown in Fig. 1 to Fig. 6, this explosion-proof early warning lithium battery includes housing 1, battery core and explosion-proof parts; Two described explosion-proof parts are installed the upper and lower surface of described housing 1 is rotational symmetric; Described explosion-proof parts include the pedestal 2 being fixed on housing 1 lower surface; Described pedestal 2 is provided with one can around point film rotating shaft 3 of own axis; Described point of film rotating shaft 3 is arranged with the translation rotating cylinder 4 that internal perisporium is carved with spiral, and described translation rotating cylinder 4 only can along described point of film rotating shaft 3 upper and lower translation under the restriction of spacing pole 41; The fluid-tight sheet 42 be fixed in described point film rotating shaft 3 is installed at the nozzle of described translation rotating cylinder 4; The closed cavity of described fluid-tight sheet 42, translation rotating cylinder 4 and point film rotating shaft 3 makeup ring tubular, is filled with inert gas in described closed cavity; Flexible point of film blade 5 is evenly equipped with in the top circumference of described point of film rotating shaft 3; Each described point of film blade 5 is made up of two parallel springing sheets; Described point of film blade 5 scribbles fine silver layer; Be covered with the Explosion-proof cap 6 coaxial with described point of film rotating shaft 3 at described point of film blade 5 upper cover, the caping 61 that described Explosion-proof cap 6 is transparent exposes housing 1 upper surface, and described Explosion-proof cap 6 is fixed on housing 1 by adhesive; The lid neck 62 of described Explosion-proof cap 6 puts in described housing 1 along dividing the axis of film rotating shaft 3; Described lid neck 62 offers decompression hole 621, the postive stop baffle be fixed on described lid neck 62 is also installed in the below of described decompression hole 621.
When producing, by selecting the adhesive of different firmness, the bonding firmness namely between adjustable Explosion-proof cap 6 and housing 1, and then the maximum pressure that regulating cell inside can allow; In battery charge and discharge process, inside battery can produce certain heat, and the pressure in battery has increase by a small margin; But because a point film blade 5 is covered by Explosion-proof cap 6, described caping 61 contacts with a point film blade 5, under the restriction of frictional force, a point film blade 5 keeps inactive state, is housed in Explosion-proof cap 6 with time-division film blade 5 in elastic bending state; In original-pack battery, described point of film blade 5 forms silvery white owing to having scribbled fine silver layer; After battery is opened, the oxidized or sulfuration of fine silver layer, presents black, and the color of observing point film blade 5 through transparent caping 61 tentatively can judge whether battery is original-pack battery.
When there is the abnormalities such as short circuit when battery, the temperature of inside battery rises fast, and electrolyte is heated vaporization, and the pressure of inside battery increases fast; When pressure exceedes safety value, described Explosion-proof cap 6 is backed down, and Explosion-proof cap 6 is along axis upward sliding, and the caping 61 of Explosion-proof cap 6 does not contact with a point film blade 5, and frictional force disappears; Now described decompression hole 621 exposes the upper surface of housing 1, and the electrolyte of vaporization sheds in housing 1, and battery pressure reduces, and then prevents battery explosion; Liquid electrolyte may be had form liquid film at decompression hole 621 place while the electrolyte of vaporization sheds, and then decompression hole 621 is blocked, now battery recovers air-tight state again, pressure in battery increases again, the pressure increased makes the contraction of gas in translation rotating cylinder 4, volume in translation rotating cylinder 4 reduces, and described translation rotating cylinder 4 moves down; Along with moving down of translation rotating cylinder 4, described fluid-tight sheet 42 rotates along the spiral of translation rotating cylinder 4, and then drive point film rotating shaft 3 and a point film blade 5 to rotate, when point film blade 5 is through decompression hole 621, film blade 5 is divided to be stretched by elastic bending state, point film blade 5 stretches out from decompression hole 621 and is broken by the liquid film bullet getting lodged in decompression hole 621, thus makes decompression hole 621 can the electrolyte of carburation by spraying, step-down again.
In addition, gas, when spraying from decompression hole 621, will drive springing sheet to vibrate, and make lithium battery produce buzz, reminding user battery charging state is abnormal; Simultaneously, due to two rotational symmetric upper and lower surfaces being arranged on described housing 1 of described explosion-proof parts, therefore when battery expands, the gas sprayed in described explosion-proof parts can make battery produce turning moment, be convenient to battery depart from from charger, to realize open circuit; Eruption power conversion can be become rotation function simultaneously, reduce the scope that battery is jet, blast involves, make battery safer.
Delicate structure of the present invention, can step-down automatically when inside battery pressure exceedes critical value, and can effectively prevent electrolyte from blocking decompression hole 621, make pressure all-the-time stable in battery in controlled range, there will not be the situation that dropping valve is plugged, therefore use safer; There is abnormality alarm function simultaneously, and easily can distinguish that battery is good and bad, there is higher commercial value.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.