CN104970016A - Attractant of tomicus yunnanensis - Google Patents
Attractant of tomicus yunnanensis Download PDFInfo
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- CN104970016A CN104970016A CN201410133344.XA CN201410133344A CN104970016A CN 104970016 A CN104970016 A CN 104970016A CN 201410133344 A CN201410133344 A CN 201410133344A CN 104970016 A CN104970016 A CN 104970016A
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- australene
- attractant
- verbenol
- cis
- yunnan
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- 239000005667 attractant Substances 0.000 title claims abstract description 54
- 230000031902 chemoattractant activity Effects 0.000 title claims abstract description 53
- 241000346024 Tomicus yunnanensis Species 0.000 title abstract 5
- WONIGEXYPVIKFS-UHFFFAOYSA-N (+)-cis-Verbenol Natural products CC1=CC(O)C2C(C)(C)C1C2 WONIGEXYPVIKFS-UHFFFAOYSA-N 0.000 claims abstract description 62
- WONIGEXYPVIKFS-YIZRAAEISA-N (1s,2s,5s)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@@H]2C(C)(C)[C@H]1C2 WONIGEXYPVIKFS-YIZRAAEISA-N 0.000 claims abstract description 42
- SLKPBCXNFNIJSV-HNNXBMFYSA-N Cuparene Chemical compound C1=CC(C)=CC=C1[C@@]1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-HNNXBMFYSA-N 0.000 claims abstract description 36
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims abstract description 36
- WONIGEXYPVIKFS-VGMNWLOBSA-N (1r,2s,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-VGMNWLOBSA-N 0.000 claims abstract description 20
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims abstract description 18
- SLKPBCXNFNIJSV-UHFFFAOYSA-N cuparene Natural products C1=CC(C)=CC=C1C1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-UHFFFAOYSA-N 0.000 claims abstract description 18
- WVRVMHCZDFFAFB-UHFFFAOYSA-N epsilon-Cuprenene Natural products C1=CC(C)=CCC1C1(C)C(C)(C)CCC1 WVRVMHCZDFFAFB-UHFFFAOYSA-N 0.000 claims abstract description 18
- BQOFWKZOCNGFEC-BDAKNGLRSA-N (+)-Delta3-carene Chemical compound C1C(C)=CC[C@H]2C(C)(C)[C@@H]12 BQOFWKZOCNGFEC-BDAKNGLRSA-N 0.000 claims abstract description 10
- 229930006713 (+)-car-3-ene Natural products 0.000 claims abstract description 10
- BQOFWKZOCNGFEC-UHFFFAOYSA-N Delta3-Carene Natural products C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 claims abstract description 10
- HEVGGTGPGPKZHF-UHFFFAOYSA-N 1-(1,2-dimethyl-3-methylidenecyclopentyl)-4-methylbenzene Chemical compound CC1C(=C)CCC1(C)C1=CC=C(C)C=C1 HEVGGTGPGPKZHF-UHFFFAOYSA-N 0.000 claims description 32
- RXBQNMWIQKOSCS-UHFFFAOYSA-N Myrthenol Natural products C1C2C(C)(C)C1CC=C2CO RXBQNMWIQKOSCS-UHFFFAOYSA-N 0.000 claims description 26
- RXBQNMWIQKOSCS-IUCAKERBSA-N [(1s,5r)-6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl]methanol Chemical compound C1[C@@H]2C(C)(C)[C@H]1CC=C2CO RXBQNMWIQKOSCS-IUCAKERBSA-N 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 6
- WONIGEXYPVIKFS-HRDYMLBCSA-N (1r,2r,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-HRDYMLBCSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 241000238631 Hexapoda Species 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 6
- CRPUJAZIXJMDBK-DTWKUNHWSA-N (+)-camphene Chemical compound C1C[C@@H]2C(=C)C(C)(C)[C@H]1C2 CRPUJAZIXJMDBK-DTWKUNHWSA-N 0.000 abstract description 4
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 abstract description 4
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 abstract description 4
- CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 abstract description 4
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 abstract description 4
- 238000011282 treatment Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000012544 monitoring process Methods 0.000 abstract description 3
- 229940099369 (+)- limonene Drugs 0.000 abstract description 2
- GRWFGVWFFZKLTI-RKDXNWHRSA-N (+)-α-pinene Chemical compound CC1=CC[C@H]2C(C)(C)[C@@H]1C2 GRWFGVWFFZKLTI-RKDXNWHRSA-N 0.000 abstract description 2
- 229960003595 (-)- limonene Drugs 0.000 abstract description 2
- CRPUJAZIXJMDBK-BDAKNGLRSA-N (-)-camphene Chemical compound C1C[C@H]2C(=C)C(C)(C)[C@@H]1C2 CRPUJAZIXJMDBK-BDAKNGLRSA-N 0.000 abstract description 2
- 229930006714 (-)-camphene Natural products 0.000 abstract description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-β-pinene Chemical compound C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 abstract description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 abstract description 2
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 abstract description 2
- -1 (-)-Myrteneol Chemical compound 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- 238000000034 method Methods 0.000 description 20
- 238000012360 testing method Methods 0.000 description 10
- 240000001987 Pyrus communis Species 0.000 description 7
- 235000014443 Pyrus communis Nutrition 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 241000545593 Scolytinae Species 0.000 description 4
- 150000003505 terpenes Chemical class 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 230000036039 immunity Effects 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 239000003620 semiochemical Substances 0.000 description 2
- WUOACPNHFRMFPN-VIFPVBQESA-N (R)-(+)-alpha-terpineol Chemical compound CC1=CC[C@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-VIFPVBQESA-N 0.000 description 1
- NVZULJTUMCKVQR-UHFFFAOYSA-N C1C(C)=CCC2C(C)(C)C12.C1C(C)=CCC2C(C)(C)C12 Chemical compound C1C(C)=CCC2C(C)(C)C12.C1C(C)=CCC2C(C)(C)C12 NVZULJTUMCKVQR-UHFFFAOYSA-N 0.000 description 1
- 102100033538 Clusterin-associated protein 1 Human genes 0.000 description 1
- 101000945057 Danio rerio Clusterin-associated protein 1 homolog Proteins 0.000 description 1
- 101000945060 Homo sapiens Clusterin-associated protein 1 Proteins 0.000 description 1
- 235000005205 Pinus Nutrition 0.000 description 1
- 241000218602 Pinus <genus> Species 0.000 description 1
- 241000546225 Tomicus Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003016 pheromone Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
Abstract
The invention discloses an attractant of tomicus yunnanensis. The attractant comprises one or more of the following components: S-(-)-alpha-pinene, 1R-(+)-alpha-pinene, myrcene, (+)-camphene, (-)-camphene, alpha-terpinene, (+)-3-carene, (1s)-(-)-beta-pinene, (-)-limonene, (+)-limonene, (-)-Myrteneol, (s)-cis-verbenol, (-)-trans-verbenol and Cuparene. According to the attractant disclosed by the invention, the attractant containing a host and polypide volatile matter is utilized for attract tomicus yunnanensis massively, so that the tomicus yunnanensis is gathered in a certain device and then is killed; the attractant has the advantages of low cost, high efficiency, complete environmental friendliness, safety to people and livestock, incapability of generating drug resistance to insects and the like, so that the traditional passive chemical prevention and treatment can be replaced by active biological prevention and treatment; meanwhile, the aims of monitoring and forecasting the forestry insect pests can be achieved according to the amount of tomicus yunnanensis in the attractant.
Description
Technical field
The present invention relates to terpenes and monoterpenol as the application of Yunnan tangent epiderivative attractant and a kind of Yunnan tangent epiderivative attractant.
Background technology
Yunnan tangent epiderivative (Tomicus yunn α nensis Kirkendall and Faccoli) is a kind of important trunk borer, mainly occurs in the areas such as Chinese Yunnan and Sichuan, the multiple kind of harm Pinus.But up to the present, few about Yunnan tangent epiderivative Research Literature at home and abroad, and mainly concentrate on biology, Tropical area etc.According to applicant's investigation, as follows in Yunnan prevention and control bark beetle major measure at present: 1. to strengthen quarantine.Forbid to harm the allocation and transportation of wood, the nursery stock that prevents from being injured is diffused into by epidemic-stricken area that other is local.2. wood of harming is cleared up.For preventing insect pest from spreading, all for woodland wood of being injured being felled, and under the supervision of technical staff, carries out medicament fumigating or burn process.3. trap-tree trapping.In sample ground, bark beetle Burst Regions, Stochastic choice is injured trap-tree cuting down, and be placed in woodland, investigation newly invades hole count, finally processes trap-tree.4. chemical control.The method is carry out punching moth medicine to the wood of being injured of woodland.
But cleaning wood of harming can leak and cuts down and cause large batch of pine tree to be forced to cut down and to remove.The effect of trap-tree trapping is poor.Punching moth medicine pollutes the environment, and destroys the balance of forest ecosystem, affects its bio-diversity.The Forest Tourism Resources in Yunnan is very abundant, and local government and forest department attach great importance to the prevention and control of trunk borer, but up to the present, production never has the method for relatively reasonable, more effective Supervise prevention and cure.
Along with the fast development of chemiecology, utilize the infochemical of insect to carry out prevention and control bark beetle and obtained good certification abroad.The method has efficiently, environmental friendliness, location are strong.In order to prevent and treat this worm better, emphasis of the present invention is studied for its semiochemicals, and have developed attractant formula.
Summary of the invention
The object of this invention is to provide by the application as Yunnan tangent epiderivative attractant of terpenes and terpenol.
Another object of the present invention be to provide a kind of have efficient, environmentally friendly, to person poultry safety, the attractant that do not make insect develop immunity to drugs.
For achieving the above object, the present invention takes following technical scheme:
S-(-)-australene (S-(-)-α-pinene), 1R-(+)-australene (1R-(+)-α-pinene), laurene (myrcene), (+)-amphene ((+)-camphene), (-)-amphene ((-)-camphene), α-terpinene (α-terpinene), (+)-3-carene ((+)-3-carene), (1S)-(-)-nopinene ((1s)-(-)-β-pinene), (-)-citrene ((-)-limonene), (+)-citrene ((+)-limonene), (-)-myrtenol ((-)-Myrtenol), (S)-cis-verbenol (s)-cis-verbenol, one or more application as Yunnan tangent epiderivative attractant in (-)-trans-verbenol ((-)-trans-verbenol) and cuparene (Cuparene).
The present invention utilizes the volatile matter of host and polypide as attractant, a large amount of Yunnan tangent epiderivative can be attracted, make it be gathered in certain device to be killed again, have cost low, efficient, completely environmentally friendly, to person poultry safety, do not make the advantages such as insect develops immunity to drugs, in the past passive chemical control is made to become biological control initiatively, simultaneously can also according to tangent epiderivative quantity in Yunnan in trapper number, reach the object of monitoring and forecast forestry insect pest.
A kind of Yunnan tangent epiderivative attractant, this attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, the volume ratio of (-)-myrtenol and cuparene is: 5-10:1-3:1-3:1-3:0.2-0.5:0.05-0.1:1-5:0.01-0.1:0.01-0.1: 0.01-0.1:0.05-0.3.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene is: 8:1:1.5:1.6:0.36:0.07:3.75:0.03:0.07:0.07:0.13.
A kind of Yunnan tangent epiderivative attractant, this attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 30-50:10-20:5-10:5-10:2-6:0.1-0.5:0.01-0.1:0.05-0.3:0.05-0.3:0.01-0.05:0.005-0.15:0.01-0.05:0.1-1, wherein, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene is: 39:14:9:7:3:0.35:0.05:0.18:0.16:0.03:0.01:0.03:0.5; Wherein, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of Yunnan tangent epiderivative attractant, this attractant is made up of S-(-)-australene and (s)-cis-verbenol, and described S-(-)-australene, cis-verbenol volume ratio is 25-100:0.075-0.5; Wherein, described S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, (s)-cis-verbenol is 50:0.125; Wherein, described S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
The constituent of a kind of Yunnan tangent epiderivative attractant, be made up of S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol, described S-(-)-australene, (s)-cis-verbenol, the volume ratio of (-)-trans-verbenol is 25-100:0.075-0.5:0.075-0.5; Wherein, described S-(-)-australene, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, described S-(-)-australene, (s)-cis-verbenol and (-)-trans-verbenol, its ratio is respectively 50ml:0.125cm
3: 0.125ml.
A kind of Yunnan tangent epiderivative attractant, this attractant is made up of S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene, and the volume ratio of described S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene is 25-100:0.1-1:0.075-0.5; Wherein, described S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene is 50:0.5:0.125; Wherein, described S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of Yunnan tangent epiderivative attractant, this attractant is made up of S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is 25-100:25-100:0.075-0.5; Wherein, described S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is 50:50:0.125; Wherein, described S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Advantage of the present invention is:
1, lure Yunnan tangent epiderivative more much lower than traditional chemical pest control cost with the infochemical of host and polypide, the terpenes preparation (offering on the net: 7800 yuan/ton) of domestic Production in Chemical Plant is comparatively at a low price external, and 10mi terpenes (amounting to about 0.08 yuan) can use 2 first quarter moons continuously.The method economical and effective, can save a large amount of manpower and materials.
2, the use of attractant is not subject to seasonal restrictions and can Long-Time Service, and sprouting wings whole time period of harm at Yunnan tangent epiderivative can trapping pests, and chemical control and the killed wood of cleaning need to implement at a certain special time period, too early or cross all impact effects in evening.Therefore, the present invention is trying to explore and putting into practice frontier science and technology, has important scientific value and social value.
3, the present invention utilizes and attracts Yunnan tangent epiderivative in a large number containing host and polypide semiochemicals, make it be gathered in certain device to be killed again, there is efficient, complete environmental friendliness, to person poultry safety, do not make the advantages such as insect develops immunity to drugs, make in the past passive chemical control become biological control initiatively.
4, according to the number of tangent epiderivative quantity in Yunnan in trapper, reach the object of monitoring and forecast forestry insect pest.
Accompanying drawing explanation
Fig. 1 is that the different formulations of embodiment 1 on average traps spirogram table (in January, 2011, large pear tree village carried out testing experiment in Qujing) to the female male worm of Yunnan tangent epiderivative.
Fig. 2 is that the different disposal of embodiment 2 on average traps spirogram table (large pear tree village, in January, 2012 Qujing proceeds testing experiment) to the female worm of Yunnan tangent epiderivative.
Fig. 3 is that the different disposal of embodiment 2 on average traps spirogram table (large pear tree village, in January, 2012 Qujing proceeds testing experiment) to Yunnan tangent epiderivative male worm.
Fig. 4 is that the different disposal of embodiment 2 on average traps spirogram table (large pear tree village, in January, 2012 Qujing proceeds testing experiment) to Yunnan tangent epiderivative.
Embodiment
Yunnan of the present invention tangent epiderivative attractant is in large pear tree village, Yue Zhou town, Qilin District, the Qujing City of Yunnan Province public welfare forest testing experiment result of continuous 2 years.The purity of compound used therefor and manufacturer are in table 1
The sample purity of table 1 main volatile standard items and manufacturer
Note: * (s)-page-verbenol is solid, and unit is cm
3, the unit of all the other compounds is ml.Lower same.
Embodiment 1
1 in January, 2011, in Qujing, large pear tree village carries out in test, and according to host's volatile matter and bark beetle pheromone analysis result, (its numbering is respectively A to be configured with 3 kinds of attractant formulas, B, C), and establish the blank (numbering D) of an extension trapper.The concrete proportioning of formula is in table 2.
The mixed liquor of 40mL is loaded the slowly-releasing bottle (three one-tenth, Xiaodian District, Shanxi province Taiyuan city plastic molding and processing plant produces) of 100mL, the release rate of this slowly-releasing bottle s-(-)-australene s-(-)-α-pinene 20 DEG C time is about 50mg/d.The wide 37cm of trapper height 81em (middle prompt four directions, Beijing), bottom has a plastic collection bottle, and slowly-releasing bottle is fixed on trapper bottom.Trapper hangs between the pine tree of woodland Yunnan, bottom is liftoff 1.5m, interval 40m.Often process repetition 5 times, investigated once trapping amount every 5 days, and trapper is exchanged at random.
The different disposal of table 22011 field test in year December
D is the contrast without formula,
Note: * (s)-cis-verbenol is solid, and unit is cm
3, the unit of all the other compounds is ml.Lower same.
As shown in Figure 1, said method is adopted to lure the collection female worm of Yunnan tangent epiderivative 68 (F=10.74 altogether; Df=3,8; P=0.004), male worm 44 (F=9.27; Df=3,8; P=0.006).From female worm, process C trapping amount is significantly greater than process A and B, and all process are all significantly greater than blank D.From male worm, process C trapping amount is significantly greater than treatments B, and treatments B is significantly greater than blank.Female and male ratio in each process no significant difference (Mann-Whitney U detects, P>0.251).Whole experimental period, the female and male ratio of ordinary bending was respectively 1.67 (A, n=24), 1.57 (B, n=27), 1.70 (C, n=41), 1.82 (D, n=45), and 1.50 (F, n=8).
Embodiment 2
In January, 2012, in Qujing, large pear tree village proceeds testing experiment.Be provided with 9 process altogether, be attractant formula, numbering is respectively C, E, F, G, K, L, M.The C that wherein fills a prescription is the optimum formula filtered out from embodiment 1, is processed in contrast in this experiment; Other formula is the new formula formed on C fills a prescription basis, and its composition and ratio are in table 3.Each process repetition 5 times, woodland implementation method is with embodiment 1.
The different disposal of table 32012 field test in year January
As shown in Figure 2, Figure 3 and Figure 4, this test lures tangent epiderivative female male worm in Yunnan to be respectively 335 and 246 altogether.The female male worm of Yunnan tangent epiderivative lured of process C, E, F and G obviously processes more than H, I, J, K and L five that (female worm F=7.890, df=8,36, P=0.0001, be shown in Fig. 2; Male worm F=24.788, df=8,36, P=0.0001, be shown in Fig. 3).C, E, G trapping amount to female worm is significantly higher than F, and E, F, G trapping amount to male worm is significantly higher than C.Merged by female male worm, obtain Fig. 4, C, E, F and G comprehensive attracting action to the female male worm of Yunnan tangent epiderivative processes apparently higher than H, I, J, K and L five, and E, G are significantly higher than C.The neutral ratio of each process also no significant difference (Mann-Whitney U detects, P >=0.114).The female and male ratio of the Yunnan tangent epiderivative of whole experimental period collection is respectively 0.7 (C, n=118), 0.6 (E, n=153), 0.5 (F, n=131), 0.7 (G, n=142), 1 (H, n=48), 1.2 (I, n=49), 1 (J, n=63), 0.8 (K, n=47), 0.8 (L, n=50).
Claims (12)
1. a Yunnan tangent epiderivative attractant, it is characterized in that, described attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, the volume ratio of (-)-myrtenol and cuparene is: 5-10:1-3:1-3:1-3:0.2-0.5:0.05-0.1:1-5:0.01-0.1:0.01-0.1: 0.01-0.1:0.05-0.3.
2. Yunnan tangent epiderivative attractant according to claim 1, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene is: 8:1:1.5:1.5:0.3:0.07:3.75:0.03:0.07:0.07:0.13.
3. a Yunnan tangent epiderivative attractant, is characterized in that, described attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 30-50:10-20:5-10:5-10:2-6:0.1-0.5:0.01-0.1:0.05-0.3:0.05-0.3:0.01-0.05:0.005-0.15:0.01-0.05:0.1-1, wherein, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are all in units of m1, and (S)-cis-verbenol is solid, with cm
3for unit.
4. Yunnan tangent epiderivative attractant according to claim 3, it is characterized in that, S-(-)-australene in described attractant, 1R-(+)-australene, laurene, (+)-amphene, (-)-amphene, α-terpinene, (+)-3-carene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 39:14:9:7:3:0.35:0.05:0.18:0.16:0.03:0.01:0.03:0.5.
5. a Yunnan tangent epiderivative attractant, it is characterized in that, described attractant is made up of S-(-)-australene and (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, cis-verbenol is 25-100:0.075-0.5; Wherein, described S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
6. Yunnan tangent epiderivative attractant according to claim 5, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, (s)-cis-verbenol is 50:0.125.
7. the constituent of a Yunnan tangent epiderivative attractant, it is characterized in that, described attractant is made up of S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol, described S-(-)-australene, (s)-cis-verbenol, the volume ratio of (-)-trans-verbenol is 25-100:0.075-0.5:0.075-0.5; Wherein, described S-(-)-australene, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
8. Yunnan tangent epiderivative attractant according to claim 7, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, (s)-cis-verbenol and (-)-trans-verbenol is 50ml:0.125cm
3: 0.125ml.
9. a Yunnan tangent epiderivative attractant, it is characterized in that, described attractant is made up of S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene, and the volume ratio of described S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene is 25-100:0.1-1:0.075-0.5; Wherein, described S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
10. Yunnan tangent epiderivative attractant according to claim 9, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, (-)-myrtenol, (S)-cis-verbenene is 50:0.5:0.125.
11. 1 kinds of Yunnan tangent epiderivative attractants, it is characterized in that, described attractant is made up of S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is 25-100:25-100:0.075-0.5; Wherein, described S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
12. according to tangent epiderivative attractant in Yunnan described in claim 11, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is 50:50:0.125.
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