CN104957144B - A kind of agricultural bactericidal composition - Google Patents
A kind of agricultural bactericidal composition Download PDFInfo
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- CN104957144B CN104957144B CN201510349970.7A CN201510349970A CN104957144B CN 104957144 B CN104957144 B CN 104957144B CN 201510349970 A CN201510349970 A CN 201510349970A CN 104957144 B CN104957144 B CN 104957144B
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- bactericidal composition
- fluxapyroxad
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Abstract
The invention discloses a kind of agricultural bactericidal compositions, and comprising effective constituents A and B and insecticides adjuvant, effective constituents A is fluxapyroxad, and effective component B is selected from one of Boscalid or thifluzamide;Effective constituents A and the weight ratio of B are 1:10~10:1, and weight percent is 1%~90% to the weight summation of effective constituents A and B in the composition;According to the actual application, the present composition can be prepared as one of aqueous emulsion, microemulsion, suspending agent, wettable powder, water dispersible granules, for preventing and treating powdery mildew of cucumber, powdery mildew of strawberry, gray mold of cucumber, grey mould fruit rot of strawberry, rice sheath blight disease.
Description
Technical field
It is with fluxapyroxad and Boscalid (or thifluzamide) is to have the present invention relates to a kind of agricultural bactericidal composition
Ingredient is imitated, for preventing and treating powdery mildew of cucumber, powdery mildew of strawberry, gray mold of cucumber, grey mould fruit rot of strawberry, rice sheath blight disease.
Background technique
The resistance problem of agricultural disease is a global problem, is always the emphasis class of agricultural science and technology worker concern
Topic.With the continuity year in year out of disease chemical prevention, the increase of Pesticide use amount and not scientifical use pesticide, germ
Resistance is got worse, and the germ type for generating resistance is increasing.Meanwhile high-intensitive use pesticide, lead to agricultural product pesticide
Exceeded, environmental pollution and the increase of peasant's drug cost etc. are remained, agricultural sustainable development is unfavorable for.Therefore, research and development efficiently,
Low toxicity, environmentally friendly bactericide agricultural chemicals have positive effect to agricultural sustainable development.
Fluxapyroxad, English name: fluxapyroxad is acid amide fungicides, main by inhibiting mitochondria amber
Amber acid esters dehydrogenase hinders tricarboxylic acid cycle, lacks amino acid, sugar, energy reduction, interferes the division and growth of cell, have
There are protection and therapeutic effect.It is efficient to gray mold, the powdery mildew of gourd, fruit and vegetable class crop, also there is higher work to fruit tree anthracnose
Property.
Boscalid, English name: boscalid, Boscalid is consistent with the fluxapyroxad mechanism of action, to melon, careless
The crop powdery mildews such as the certain kind of berries and gray mold are efficient.
Thifluzamide, English name: thifluzamide has very strong Uptake and translocation performance, can be with foliar spray, seed
The modes such as processing, soil treatment are applied, efficient to rice sheath blight disease, peanut sclerotium rolfsii.
The mixture of different pesticide species is the common methods for preventing and treating agricultural pest.It is screened, is filtered out by formulation of pesticide
Reasonable formula, can effectively improve practical control efficiency, reduce dosage, reduce cost, delay the generation of pest and disease damage drug resistance,
It is an important means of comprehensive agricultural management.The present inventor carries out the recipe determination of succinate dehydrogenase inhibitors class fungicide
Further investigation, it is found that it has apparent synergistic effect to a variety of fungies in a certain mix proportion range, after further study, complete
At the present invention.
The composition and application of fluxapyroxad and Boscalid (or thifluzamide) there is no report at present.
Summary of the invention
The technical problem to be solved by the present invention is to provide one kind efficiently, low toxicity and lasting period are long, can effectively prevent agriculture fungi
One kind of venereal disease evil contains the agricultural bactericidal composition of fluxapyroxad and Boscalid (or thifluzamide).
To solve the above problems, the technical scheme adopted by the invention is that: a kind of agricultural bactericidal composition, comprising effectively at
Divide A and B and insecticides adjuvant, effective constituents A is fluxapyroxad, and effective component B is in Boscalid or thifluzamide
It is a kind of;Effective constituents A and the weight ratio of B are 1:10~10:1, the weight summation of effective constituents A and B weight hundred in the composition
Divide than being 1%~90%.
According to the actual application, the present composition according to methods well known to those skilled in the art, can be prepared as
One of aqueous emulsion, microemulsion, suspending agent, wettable powder, water dispersible granules.
Auxiliary agent needed for the agricultural bactericidal composition also contains preparation pesticidal preparations, auxiliary agent are solvents, emulsifier, are total to
One of emulsifier, wetting agent, stabilizer, dispersing agent, thickener, pH adjusting agent, defoaming agent, antifreezing agent, filler etc. are several
The mixing of kind, is known substance, is common various auxiliary agents in pesticidal preparations, can be varied according to different situations, and
It is not particularly limited.
The agricultural bactericidal composition, for preventing and treating cucumber, powdery mildew of strawberry, rice sheath blight disease.
Bactericidal composition provided by the invention generallys use spray method use, also can according to need using agriculturally
Other of application use technology.
The method have the advantages that:
1, bactericidal composition provided by the invention shows apparent synergy or summation action within a certain ratio range,
Composition is significantly improved to the control efficiency of germ than single dose, reduces the dosage of pesticide, reduces times for spraying,
Drug cost is reduced, reduces pesticide to the adverse effect of ecological environment.
2, bactericidal composition provided by the invention, the combination of two kinds of effective ingredients expand fungicidal spectrum, a drug
It solves the problems, such as multiple diseases, compensates for defects and limitations when single dose uses.
3, bactericidal composition provided by the invention, drug effect play rapidly, and the lasting period is long, and use cost is low, easy to use, save
Shi Shengli, popularization and application have huge economic benefit and social benefit.
Specific embodiment
The technical scheme adopted by the invention is that: a kind of agricultural bactericidal composition includes effective constituents A and B and pesticide
Auxiliary agent, effective constituents A are fluxapyroxad, and effective component B is selected from one of Boscalid or thifluzamide;Effective constituents A
Be 1:10~10:1 with the weight ratio of B, the weight summation of effective constituents A and B in the composition weight percent be 1%~
90%.
In order to keep the objectives, technical solutions, and advantages of the present invention more concise, present invention following specific embodiments
It is illustrated, however, the present invention is by no means limited to these examples.The following is only the preferred embodiment of the present invention, is used only for
The description present invention, should not be understood as limiting the scope of the present invention.It should be pointed out that all in the spirit and principles in the present invention
Within any modifications, equivalent replacements, and improvements etc. done, should all be included in the protection scope of the present invention.Therefore, this hair
The scope of protection shall be subject to the appended claims for bright patent.
Content as described in the examples is weight percentage.
(1) preparation method of pesticidal preparations
Embodiment 1: the bactericidal composition is suspending agent, and each component percentage composition is respectively as follows:
Concrete operation step are as follows: first other auxiliary agents are mixed, shear-mixed is uniform in cutter, be then added effectively at
Divide A and effective component B, 2-3h is ground in ball crusher, is below 5mm a diameter, can be prepared by Bactericidal composite of the present invention
Object aqueous suspension formulations.
Embodiment 2: the bactericidal composition is aqueous emulsion, and each component percentage composition is respectively as follows:
Concrete operation step are as follows: first effective constituents A and effective component B, solvent, emulsifier are mixed, are dissolved into
For uniform oily phase.Part water and other auxiliary agents are mixed again, dissolution becomes uniform water phase.Then in a kettle
The oil phase is added to the aqueous phase while high-speed stirred, slowly adds water to and reaches phase inversion point, carries out high speed shear later, and residue is added
Water, shear about 30min, can be prepared by bactericidal composition water and milk agent formulation of the present invention.
Embodiment 3: the bactericidal composition is microemulsion, and each component percentage composition is respectively as follows:
Concrete operation step are as follows: effective constituents A and effective component B are completely dissolved with solvent and cosolvent, then added again
Enter other auxiliary agents, is uniformly mixed, is eventually adding water, after being sufficiently stirred, can be prepared by bactericidal composition microemulsion formulation of the present invention.
Embodiment 4: the bactericidal composition is wettable powder, and each component percentage composition is respectively as follows:
Concrete operation step are as follows: mix effective constituents A and effective component B, other auxiliary agents and filler, in a stirring kettle
It is sufficiently stirred, is uniformly mixed after being smashed by air jet mill, can be prepared by bactericidal composition wettable powder formulation of the present invention.
Embodiment 5: the bactericidal composition is water dispersible granules, and each component percentage composition is respectively as follows:
Concrete operation step are as follows: effective constituents A and effective component B, other auxiliary agents and filler are uniformly mixed, ultra micro is used
Airslide disintegrating mill crushes, and is added in fluidized-bed granulation dryer after being granulated, drying, sieve after mediating, can be prepared by this
Invention bactericidal composition water-dispersible grain agent formulation.
Auxiliary agent is selected from as described below in the above dosage form:
Solvent can be trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biology
One or more of diesel oil, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil etc..
It is poly- that emulsifier can be calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene
Ethylene oxide block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinethene, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan aliphatic ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, fatty acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
It is one or more of.
Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
One or more of amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrating agent can be one in sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Kind is several.
Dispersing agent can be formaldehyde condensate of sodium methylnaphthalene sulfonate, sodium lignin sulfonate, calcium lignosulfonate, to methoxy
Base fatty acyl anilinesulfonic acid, desugar and the sodium lignin sulfonate being classified, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid condensation polymer
One or more of sodium salt, APES formaldehyde condensation product sulfuric acid etc..
Thickener can be one or more of xanthan gum, aluminium-magnesium silicate, bentonite, white carbon black etc..
PH adjusting agent can be in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
It is one or more of.
Stabilizer can be epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, dibutyl hydroxy toluene, not eat
One or more of sub- propyl propionate, tert-butylhydroquinone etc..
Defoaming agent can be one or more of silicone compound, methanol, silicone oil etc..
Antifreezing agent can be one or more of in glycerol, ethylene glycol, propylene glycol, sorbierite, polyethylene glycol etc..
Filler can be kaolin, diatomite, bentonite, white carbon black, precipitated calcium carbonate, attapulgite, clay, talcum
One or more of powder, quartz sand, starch, alkyl polyglycoside etc..
(2) bioassay test
Embodiment 6: prevention and treatment powdery mildew of cucumber field trial.
Test site is located at the Huizhou town Ma An, using spray-on process.Using 25% fluxapyroxad suspending agent,
50% Boscalid water dispersible granules set 7 chemicals treatments, 4 repetitions of each processing, in application as comparison medicament, test altogether
The preceding investigation cucumber disease number of sheets, 3 days after application, respectively control efficiency of investigation, the sick number of sheets of record calculate control efficiency, test within 7 days
The results are shown in Table 1.
Table 1, succinate dehydrogenase inhibitors bactericidal composition prevent and treat powdery mildew of cucumber test result
As can be seen from Table 1,20% fluxapyroxad Boscalid suspending agent, 15% fluxapyroxad Boscalid
Aqueous emulsion, 20% fluxapyroxad Boscalid microemulsion, 48% fluxapyroxad Boscalid wettable powder, 54%
Fluxapyroxad Boscalid water dispersible granules prevent and treat the effect of powdery mildew of cucumber better than the processing of each control single dose, illustrate amber
Dehydrogenase inhibitor, which mutually compounds, can improve control efficiency, reduce the dosage of pesticide, reduce pesticide to environment
It influences, reduces drug cost.
Embodiment 7: prevention and treatment grey mould fruit rot of strawberry field trial.
Test site is located at Hunan Yueyang Huarong County, using spray-on process.Using 25% fluxapyroxad suspending agent,
50% Boscalid water dispersible granules set 7 chemicals treatments, 4 repetitions of each processing, in application as comparison medicament, test altogether
The preceding investigation strawberry disease number of sheets, 3 days after application, respectively control efficiency of investigation, the sick number of sheets of record calculate control efficiency, test within 7 days
The results are shown in Table 2.
Table 2, succinate dehydrogenase inhibitors bactericidal composition prevent and treat grey mould fruit rot of strawberry test result
As can be seen from Table 2,20% fluxapyroxad Boscalid suspending agent, 18% fluxapyroxad Boscalid
Aqueous emulsion, 18% fluxapyroxad Boscalid microemulsion, 50% fluxapyroxad Boscalid wettable powder, 50%
Fluxapyroxad Boscalid water dispersible granules prevent and treat the effect of grey mould fruit rot of strawberry better than the processing of each control single dose, illustrate amber
Dehydrogenase inhibitor, which mutually compounds, can improve control efficiency, reduce the dosage of pesticide, reduce pesticide to environment
It influences, reduces drug cost.
Embodiment 8: prevention and treatment rice sheath blight disease field trial
Test site is located at the Huizhou town Ma An, using spray-on process.Using 25% fluxapyroxad suspending agent,
For 24% thifluzamide suspending agent as comparison medicament, test sets 7 chemicals treatments altogether, and 4 repetitions of each processing are adjusted before application
Rice diseased plant number is looked into, 3 days after application, respectively control efficiency of investigation, record diseased plant number calculate control efficiency, test result within 7 days
As shown in table 3.
Table 3, succinate dehydrogenase inhibitors bactericidal composition prevent and treat rice sheath blight disease test result
As can be seen from Table 3,20% fluxapyroxad thifluzamide suspending agent, 24% fluxapyroxad thifluzamide
Aqueous emulsion, 24% fluxapyroxad thifluzamide microemulsion, 40% fluxapyroxad thifluzamide wettable powder, 50%
Fluxapyroxad thifluzamide water dispersible granule prevents and treats the effect of rice sheath blight disease better than the processing of each control single dose, illustrates amber
Dehydrogenase inhibitor, which mutually compounds, can improve control efficiency, reduce the dosage of pesticide, reduce pesticide to environment
It influences, reduces drug cost.
Claims (4)
1. a kind of agricultural bactericidal composition is fluxapyroxad comprising effective constituents A and B and insecticides adjuvant, effective constituents A,
Effective component B is selected from one of Boscalid or thifluzamide;Effective constituents A and the weight ratio of B are 1:3,1:4 or 1:5, are had
Weight percent is 1%~90% to the weight summation of effect ingredient A and B in the composition.
2. a kind of agricultural bactericidal composition according to claim 1, it is characterised in that: its dosage form is aqueous emulsion, micro emulsion
One of agent, suspending agent, wettable powder, water dispersible granules.
3. a kind of application of the agricultural bactericidal composition described in claim 1 in prevention and treatment corps diseases.
4. a kind of application of the agricultural bactericidal composition according to claim 3 in prevention and treatment corps diseases, feature
Be: the corps diseases are powdery mildew of cucumber, powdery mildew of strawberry, gray mold of cucumber, grey mould fruit rot of strawberry or rice banded sclerotial blight
Disease.
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CN112250508A (en) * | 2020-11-03 | 2021-01-22 | 中诚国联(河南)生物科技有限公司 | Preparation method and application of pesticide-fertilizer granules containing thifluzamide and azoxystrobin |
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