CN104946372A - Environment-friendly water aqua type wire cutting working solution - Google Patents
Environment-friendly water aqua type wire cutting working solution Download PDFInfo
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- CN104946372A CN104946372A CN201510300985.4A CN201510300985A CN104946372A CN 104946372 A CN104946372 A CN 104946372A CN 201510300985 A CN201510300985 A CN 201510300985A CN 104946372 A CN104946372 A CN 104946372A
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Abstract
The invention discloses an environment-friendly water aqua type wire cutting working solution. The working solution is prepared through mixing up a nonionic surfactant, triethanolamine oleate, an EP-antiwear agent, an antiseptic and an antifoaming agent. The nonionic surfactant accounts for 23-27% of the working solution by weight. The triethanolamine oleate accounts for 11-18% of the working solution by weight. The EP-antiwear agent accounts for 10-15% of the working solution by weight. The antiseptic accounts for 18-25% of the working solution by weight. The antifoaming agent accounts for 17-23% of the working solution by weight. The environment-friendly water aqua type wire cutting working solution is good in extreme pressure antiwear property, excellent in thermal stability and corrosion-free.
Description
Technical field
The present invention relates to a kind of environmental protection water aqua type wire cutting working solution.
Background technology
Stainless steel coolant is a kind of high performance semi-synthetic metal working fluid, and be mainly applicable to all types of processing of all kinds of hard metal and Wimet, it extremely proves effective to the general processing of most of iron metal.Outstanding lubrication and cooling effect can have been given play to when processing stainless steel, hard alloy steel and other special steels simultaneously.Stainless steel coolant can form stable emulsion in soft water and hard water, adds simultaneously and has anticorrosive agent and bactericidal additive.Product is particularly suitable for the general processing and the high strength processing that are used as the material such as stainless steel, hardened steel.Except ferrous metal, this product is also applicable to semiconductor material, opticglass, the precision work of hard mass.
Summary of the invention
The invention provides a kind of environmental protection water aqua type wire cutting working solution with advantages such as excellent cooling, oilness, rust-preventing characteristic and cleaning performances.
Technical scheme of the present invention is: a kind of environmental protection water aqua type wire cutting working solution, described environmental protection water aqua type wire cutting working solution comprises nonionogenic tenside, triethanolamine oleate, extreme pressure anti-wear additives, sanitas and defoamer mix, described defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glyceryl ether or polydimethylsiloxane, described nonionogenic tenside accounts for the 23%-27% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for the 11%-18% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for the 10%-15% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for the 18%-25% of the overall component of environmental protection water aqua type wire cutting working solution, described defoamer accounts for the 17%-23% of the overall component of environmental protection water aqua type wire cutting working solution.
In a preferred embodiment of the present invention, described extreme pressure anti-wear additives comprises borate and boric acid ester.
In a preferred embodiment of the present invention, described nonionogenic tenside accounts for 25% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for 16% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for 13% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution, and described defoamer accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution.
A kind of environmental protection water aqua type wire cutting working solution of the present invention, has the advantages such as excellent cooling, oilness, rust-preventing characteristic and cleaning performance.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Wherein, described environmental protection water aqua type wire cutting working solution comprises nonionogenic tenside, triethanolamine oleate, extreme pressure anti-wear additives, sanitas and defoamer mix, described defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glyceryl ether or polydimethylsiloxane, described nonionogenic tenside accounts for the 23%-27% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for the 11%-18% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for the 10%-15% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for the 18%-25% of the overall component of environmental protection water aqua type wire cutting working solution, described defoamer accounts for the 17%-23% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives comprises borate and boric acid ester.
Further illustrate, described nonionogenic tenside accounts for 25% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for 16% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for 13% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution, and described defoamer accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution.
Further illustrate, defoamer mostly is liquid compound product, is mainly divided three classes: mineral oils, silicone based, polyethers.Mineral oil defoaming agent is made up of carrier, promoting agent etc. usually.Carrier is the material of low surface tension, and its effect is carrying and dilution, and common carrier is water, fatty alcohol etc.; The effect of promoting agent suppresses and eliminates foam, and conventional has wax, aliphatic amide, fat etc.Silicone based defoamer generally comprises polydimethylsiloxane etc.Silicone based defoamer solvability is poor, have at normal temperatures antifoaming speed very fast, press down bubble better, but at high temperature occur layering, antifoaming speed comparatively slow, press down the features such as bubble is poor.Polyethers defoamer comprises polyoxypropylene ethylene oxide glyceryl ether etc.The features such as polyethers defoamer has but the bubble time is long, effective, antifoaming speed is fast, Heat stability is good.Such as defoamer will be used in the production processes such as beverage made of fruits or vegetables, bean product, sucrose.Take polydimethylsiloxane as the defoamer of base material be the defoamer that in antifoaming system, a class is desirable, be exactly because it is water insoluble, more difficult emulsification, polydimethylsiloxane is lower than carbochain hydrocarbon surface property, therefore lower than the usual tensio-active agent surface tension applied in textile industry.Simple polydimethylsiloxane suds suppressing properties is poor and slow, froth breaking effect needs silicon dioxide granule to strengthen, silicon dioxide granule to be taken in the air-water termination of foam by silicone oil and enters air bubble liquid-membrane due to its hydrophobicity, 90 ° are greater than with the foam contact angle of drop of tensio-active agent, thus force foaming liquid to arrange from solid hydrophobic particle surface, draw local foamy rapid drainage and cause breaking, like this, due to synergy, two kinds of components create good defoaming effect.Polysiloxane defoamers is owing to having excellent froth breaking usefulness and other advantages, in a lot of fields widespread use, and particularly in yarn fabric dyeing and finishing processing, development is particularly rapid, and research finds, with polydimethylsiloxane and
polyethylenemultipolymer be the silicone glycols defoamer of base material, due to special solubility property, in jet dyeing and the processing of other yarn fabrics, there is desirable defoaming effect.
Further illustrating, extreme pressure anti-wear additives comprises borate and boric acid ester.The anti-extreme pressure ability of borate, much larger than sulphur phosphorous and chlorine lead-type additive, is a kind of novel Lubricating grease extreme pressure additive.Amorphous microspheric borate is dispersed in the oil-dispersions formed in lubricating oil.Tasteless, nontoxic.There is good extreme pressure anti-wear and thermostability, corrosion-free to copper.Be slightly soluble in water, can be used for the gear oil that do not contact with water and lubricating grease.Use advantage is as follows: abrasion resistant extreme-pressure is effective, in low viscosity oil, particularly have good abrasion resistant extreme-pressure effect.There is the gear oil of energy-save oil, be exactly that low viscosity oil adds boron-containing additive and makes, meet the requirement of abrasion resistant extreme-pressure.Borate Ep Additive long service life, its mechanism of action is the extreme pressure film of the FexBy form formed by boronising, and this one deck surface film has higher hardness, good resistance to abrasion, good oxidation-resistance, erosion resistance.And the extreme pressure property of sulfur-bearing phosphorus chlorine active element, the mechanism of action mainly active element generates a skim with metal react with, and the shear strength of this tunic is lower than underlying metal, therefore in use, this tunic is easy to be worn away, and the ratio borate of such depletion of additive is fast.
The resistance to abrasion of borate additive, insensitive to the selectivity of metallic substance, all adaptation is compared to various metallic substance, and phosphorous sulphur chlorine additive, resistance to abrasion quality is with the relevant system of metal body.As the lubrication to 18Gr2Ni4WA steel matter, the anti-extreme pressure effect of lubricating oil adding sulphur phosphorus additive is general, and in the oil containing chlorine additive, anti-extreme pressure can be good.No. 50 carbon steel materials, the lubricating oil resistance to compression effect of phosphor-included additive is general, chloride good with anti-extreme pressure energy in the oil of sulfur additives.45# steel matter, the lubricating oil resistance to compression effect of phosphorous sulfur additives is general, and in the oil containing chlorine additive, anti-extreme pressure can be good.Cadmium Ni-Mo alloy steel material, the lubricating oil resistance to compression effect of phosphorous chlorine additive is general, and in the oil of sulfur-containing additive, anti-extreme pressure can be good.And borate additive can be all fine to above-mentioned all material anti-extreme pressures.The invention provides a kind of environmental protection water aqua type wire cutting working solution, there is the advantages such as excellent cooling, oilness, rust-preventing characteristic and cleaning performance.
The specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention, and the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (3)
1. an environmental protection water aqua type wire cutting working solution, it is characterized in that: described environmental protection water aqua type wire cutting working solution comprises nonionogenic tenside, triethanolamine oleate, extreme pressure anti-wear additives, sanitas and defoamer mix, described defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glyceryl ether or polydimethylsiloxane, described nonionogenic tenside accounts for the 23%-27% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for the 11%-18% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for the 10%-15% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for the 18%-25% of the overall component of environmental protection water aqua type wire cutting working solution, described defoamer accounts for the 17%-23% of the overall component of environmental protection water aqua type wire cutting working solution.
2. environmental protection water aqua type wire cutting working solution according to claim 1, is characterized in that: described extreme pressure anti-wear additives comprises borate and boric acid ester.
3. environmental protection water aqua type wire cutting working solution according to claim 1, it is characterized in that: described nonionogenic tenside accounts for 25% of the overall component of environmental protection water aqua type wire cutting working solution, described triethanolamine oleate accounts for 16% of the overall component of environmental protection water aqua type wire cutting working solution, described extreme pressure anti-wear additives accounts for 13% of the overall component of environmental protection water aqua type wire cutting working solution, described sanitas accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution, and described defoamer accounts for 23% of the overall component of environmental protection water aqua type wire cutting working solution.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462674A (en) * | 2015-11-26 | 2016-04-06 | 宁波虎兴数控科技有限公司 | Formula of environment-friendly aqueous solution type wire cutting working solution |
| CN111575100A (en) * | 2020-05-25 | 2020-08-25 | 南京工程学院 | Copper-magnesium composite plate strip incremental forming emulsion and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104164283A (en) * | 2014-08-19 | 2014-11-26 | 清华大学 | Microemulsion metal cutting fluid |
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2015
- 2015-06-04 CN CN201510300985.4A patent/CN104946372A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104164283A (en) * | 2014-08-19 | 2014-11-26 | 清华大学 | Microemulsion metal cutting fluid |
Non-Patent Citations (1)
| Title |
|---|
| 王家序等: "水基切削液的研制及应用"", 《润滑与密封》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462674A (en) * | 2015-11-26 | 2016-04-06 | 宁波虎兴数控科技有限公司 | Formula of environment-friendly aqueous solution type wire cutting working solution |
| CN111575100A (en) * | 2020-05-25 | 2020-08-25 | 南京工程学院 | Copper-magnesium composite plate strip incremental forming emulsion and preparation method thereof |
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Application publication date: 20150930 |