CN107699139A - A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application - Google Patents
A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application Download PDFInfo
- Publication number
- CN107699139A CN107699139A CN201711070836.9A CN201711070836A CN107699139A CN 107699139 A CN107699139 A CN 107699139A CN 201711070836 A CN201711070836 A CN 201711070836A CN 107699139 A CN107699139 A CN 107699139A
- Authority
- CN
- China
- Prior art keywords
- lapping liquid
- liquid composition
- water
- water base
- super lapping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B1/00—Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
Abstract
The invention discloses a kind of water base super lapping liquid composition of environment-friendly antirust type, its constitutive material is nonionic or amphoteric surfactant, anion surfactant, category complexing agent, boric acid, triethanolamine, silicate or molybdate, organic boronic acid amides, organic long-chain acid, lubricant, abrasive material, defoamer, water, pH adjusting agent.A kind of environmentally-friendly water-based rust-proof type lapping liquid for steel ball grinding provided by the invention, has excellent cleaning concurrently, cooling, lubrication, antirust function are integrated, and is widely used in lappingout and the superfinishing polishing light processing of the steel ball of the materials such as carbon steel, stainless steel.
Description
Technical field
The present invention relates to a kind of super lapping liquid composition, more particularly to a kind of for the environmentally-friendly water-based anti-of steel ball grinding
Rust type lapping liquid composition and preparation and application.
Background technology
The lapping process of steel ball with high precision is steel ball final processing process, it is necessary to be carried out using super lapping liquid to steel ball surface
Small grinding and reparation repeatedly, higher surface smoothness and geometric accuracy requirement, the type of skill of superfinishing grinding fluid are met
The surface quality and efficiency of steel ball are influenceed with application method most important.The usual steel ball lappingout type of skill can be divided into by carrier
Oil base lapping liquid and water base lapping liquid, and water base lapping liquid is divided into emulsification lapping liquid and pure water lapping liquid.It is increasingly tight in environmental protection
Under the trend of lattice, meet the application value and social effect of the pure water lapping liquid of more performances of steel ball high-precision surface quality requirement
It is great.
Chinese patent CN 105440954A disclose a kind of steel ball smooth grinding lapping liquid and its preparation and application,
Including parts by weight meter 10-20 parts bentonite, the coal dust of 5-9 parts, 15-20 parts deionized water, the starch of 1.5-2.5 parts, 0.2-0.6
Sodium metasilicate, the palmitic acid and 4-8 part titanium dioxide of 0.4-0.8 parts of part.The patent adds swelling using water as lapping liquid carrier
The constituents such as soil, coal dust, starch, titanium dioxide play a part of chronic grinding and polishing, but do not have lubrication as abrasive material
Property, rust-preventing characteristic and cleansing power.
Chinese patent CN 101747864A disclose a kind of emulsion type lapping liquid for steel ball grinding, contain 70-75%
46# machinery oil, 25-30% oelic acids, 4-6% petroleum sodium sulfonates, 1-3% sorbitan monooleates, 5-8% polyoxy second
Alkene castor oil, 2-4% triethanolamine oleates, 1.5-3% boric acid diethanol amine and 0.5-1% potassium hydroxide, while can add
Add chromium oxide suspension as abrasive material.The patent uses machinery oil as lapping liquid carrier, although with good lubricity, preventing
Rust property, but cleansing power is general, and steel ball surface can remain more emulsification fluid after grinding, and the cleaning for increasing steel ball surface is born
Certain harmfulness to environment and human body be present in load, simultaneous oxidation chromium.
Chinese patent CN 101974295A disclose a kind of steel ball lapping liquid, contain the second oleate soaps of 8-12% tri-, 10-
14% polyethylene glycol, 8-12% diethylene glycol (DEG)s, 0.5-1.5% glycerine, 6-7% detergents, 1.2-1.8% natrium nitrosums, 0.8-
1.2% industrial sodium carbonate, 0.8-1.2% defoamer, 55-60% water, while chrome green can be added and used as abrasive material
Process is ground in lappingout and superfinishing.The patent using natrium nitrosum be used as antirust agent, using chrome green as abrasive material, to environment with
Certain harmfulness be present in human body.
The content of the invention
For above-mentioned weak point, it is an object of the invention to provide a kind of super lapping liquid of high-accuracy steel ball, collection is ground,
The function such as cooling, cleaning, lubrication, antirust is integrated, and not only meets steel ball in smooth grinding and the high polishability of fine abrasive process
And high efficiency, and with antirust function between excellent sequence, without oiling antirust process, play and reduce process, shorten flow and
Cost-effective purpose, while reduce the harm to environment and human body.
Technical scheme is summarized as follows：The water base super lapping liquid composition of environment-friendly antirust type, its constitutive material each group
Point mass percent be：
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the nonionic or amophoteric surface active
Agent can natural degradation, it is selected from AEO, low bubble isomery alcohol, alkyl polyglycoside, saccharide fatty acid esters, beet
One kind in alkali, imidazoline, sulfamic acid.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the anion surfactant is can
Natural degradation, it is phosphoric acid polyether ester sylvite.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the metal chelating agent are selected from ethylenediamine
One kind in the sodium of tetraacethyl four or disodium ethylene diamine tetraacetate.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the silicate are sodium metasilicate, described
Molybdate is sodium molybdate.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, organic long-chain acid selected from decanedioic acid,
One or two kinds of mixtures of different n-nonanoic acid.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the lubricant are selected from diethylene glycol (DEG), organic
One or two kinds of mixtures of metaboric acid ester.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the abrasive material are selected from water-dispersion type nanometer
One kind in inorganic matter, organosilane-modified abrasive material.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the water-dispersion type nano-inorganic substance choosing
From nano silicon and its colloidal sol, nano aluminium oxide and its colloidal sol, nano zirconium dioxide and its colloidal sol, nano titanium oxide and
One kind in its colloidal sol.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the defoamer are selected from organic-silicon-modified
Polyether antifoam agent.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the pH adjusting agent are MEA.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the organic boronic acid amides be boric acid with
The reaction product of hydramine.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the oxo solvent are dissident's glycol.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, the antirust agent be BTA or
Its derivative, the antirust agent are a kind of antirust agent of non-ferrous metal.
Preferably, the described super lapping liquid composition of water base environment-friendly antirust type, for achieving the above object, the present invention
Also provide a kind of preparation method of the super lapping liquid composition of water base environment-friendly antirust type, it is characterised in that comprise the following steps：
S1：The water for accounting for total Water 25~60% is heated to 80~140 DEG C, boric acid and three second are sequentially added by the proportioning
Hydramine reacts 0.5~2 hour；If when being reacted at temperature is more than 95 DEG C, need to be reacted in the equipment for possess cooling for reflux；
S2：Add the water of surplus, and cool to less than 60 DEG C, by it is described match add metal chelating agent, silicate or
One kind of molybdate, organic long-chain acid, antirust agent are completely dissolved it；
S3：One sequentially added by the proportioning in anion surfactant, nonionic or amphoteric surfactant
Kind, oxo solvent, organic boronic acid amides, lubricant, abrasive material, defoamer；
S4：Finally the water base environment-friendly antirust type superfinishing is obtained with pH adjusting agent regulation pH scope for 8.3 ± 0.2 to grind
Liquid composition.
Preferably, the preparation method of the described super lapping liquid composition of water base environment-friendly antirust type, water is added in the S1
Heat is reacted 0.5~1 hour to 130~140 DEG C, can prepare the high organic boronic acid amides of purity at this temperature, can be significantly
Increase rustless property, while the dosage of organic boronic acid amides in component can be reduced.
For achieving the above object, the present invention separately provides a kind of super lapping liquid composition user of water base environment-friendly antirust type
Method, the described super lapping liquid composition of water base environment-friendly antirust type is used with water by 3~10% direct dilution.
Preferably, in the described super lapping liquid composition application method of water base environment-friendly antirust type, by the water base environmental protection
The super lapping liquid composition of rust-proof type directly affects antirust between the sequence of steel ball with water by 5~10% directly dilution uses, concentration
Time, if grinding antirust function between the sequence for requiring steel ball simultaneously, 5~10% dilutions use, to improve during turnover or storage
Antirust ability.
Preferably, in the described super lapping liquid composition application method of water base environment-friendly antirust type, the water is deionization
Water or desalted water, the μ s/cm of its electrical conductivity≤20.
The water base super lapping liquid composition of environment-friendly antirust type can be widely used for the lappingout of the steel ball of the materials such as carbon steel, stainless steel
With superfinishing polishing light processing, after steel ball lappingout is up to standard, is further cleaned without using cleaning agent or increase oiling antirust process, can
Directly to carry out turnover, storage or transport between sequence, the anti-rust action of " water generation oil " is played.The super lapping liquid carries by cooling of water
Body, chemical stability is good, to environment and human body non-hazardous, it is safe and convenient to use the features such as, there is nontoxic, tasteless, low foam, can
Degraded, excellent cleaning penetrating power and antirust ability, proper lubrication extreme pressure abrasiveness, collection grinding, cooling, cleaning, lubrication and
Antirust multiple functions are integrated, and are improved surface quality of the steel ball during smooth grinding and fine abrasive, are reduced Micro scratching, reach
The excellent combination of the high polishability of steel ball and high grinding efficiency；Antirust function between excellent sequence, reach oil-less rust-proofing mesh between steel ball sequence
, cleaning and antirust cost have been saved, the harm to environment is further reduced in terms of few process short route.
The present invention using water as coolant carrier, using can natural degradation nonionic surfactant, anion surface active
Agent, the low bubble infiltration emulsification of oxo solvent, improve the cleansing power of lapping liquid；Utilize long chain organic acid, boric acid and hydramine
Chemical reactant enhancing sodium molybdate and BTA, meet the antirust requirement being had enough to meet the need between steel ball grinding process and sequence；Utilize
The lubrication property of short chain alcohol and organic boric acid ester, there is provided suitable boundary lubrication and contact lubricate；Utilize nanometer abrasive, control mill
The amount of cutting and grinding efficiency is improved, realize the super lapping process of steel ball to being ground, cooling down, cleaning, lubricating, the performance requirement of antirust.
The beneficial effects of the invention are as follows：
(1) the super lapping liquid of the present invention is mainly using water as coolant carrier, without chromium oxide or chromium trioxide abrasive material, and meanwhile it is contained
Surfactant or antirust agent all can effectively from degrade, to environment and human body non-hazardous；
(2) the super lapping liquid of the present invention integrates grinding, cooling, cleaning, lubrication and antirust multiple functions, reaches steel ball height
The excellent combination of polishability and high grinding efficiency；
(3) the super lapping liquid of the present invention further cleans or oiling antirust without using cleaning agent, meets to have enough to meet the need between steel ball sequence
Or storage antirust requirement.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
Embodiment 1
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：AEO
0.5wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Dissident glycol 2.0wt%, tetrasodium ethylenediamine tetraacetate 1.0wt%；Boric acid
4.0wt%；Triethanolamine 18.0wt%；Sodium metasilicate 2.0wt%；Organic boronic acid amides and diethylene glycol (DEG) amount to 6.0wt%；The last of the ten Heavenly stems two
Sour 2.8wt%；BTA 0.2wt%；Organic metaboric acid ester 9.0wt%；Nano silicon dioxide sol 15.0wt%；It is organic
Silicon-modified polyether defoamer 0.005wt%；Water 38.5%；MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 32.47%), is heated to 95 DEG C, then adds 40 grams of boric acid, 180 grams of triethanolamine stirring reactions 1
Hour；Remaining 260 grams of deionized waters are added, less than 60 DEG C is cooled to, sequentially adds 10 grams of tetrasodium ethylenediamine tetraacetates, 20
Gram sodium metasilicate, 28 grams of decanedioic acid, 2 grams of BTAs are stirred to being completely dissolved；Sequentially add 10 grams of phosphoric acid polyether ester potassium
Salt, 5 grams of AEOs, 20 grams of dissident's glycol, 60 grams of organic boronic acid amides, 30 grams of diethylene glycol (DEG)s, 60 grams of organic inclined boron
Acid esters, 150 grams of nano silicon dioxide sols, 0.05 gram of organosilicon modified polyether defoamer；Finally pH=is adjusted with MEA
8.5。
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 3% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 2
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：AEO
0.5wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Dissident's glycol 2.0wt%；Disodium ethylene diamine tetraacetate 1.0wt%；Boric acid
4.0wt%；Triethanolamine 18.0wt%；Sodium metasilicate 2.0wt%；Organic boronic acid amides 2.0wt%；Decanedioic acid 1.5wt%；Benzene
And triazole 0.1wt%；Organic metaboric acid ester 3.0wt%；Nano silicon dioxide sol 15.0wt%；Organosilicon modified polyether disappears
Infusion 0.005wt%；Water 49.9wt%；MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 25.05%), is heated to 140 DEG C, then 40 grams of boric acid of addition in cooling and reflux device, 180 grams
Triethanolamine stirring reaction 0.5 hour；Remaining 374 grams of deionized waters are added, less than 60 DEG C is cooled to, sequentially adds 10 grams
Disodium ethylene diamine tetraacetate, 20 grams of sodium metasilicates, 15 grams of decanedioic acid, 1 gram of BTA are stirred to being completely dissolved；Add successively again
Enter 10 grams of phosphoric acid polyether ester sylvite, 5 grams of AEOs, 20 grams of dissident's glycol, 20 grams of organic boronic acid amides, 30 grams have
Machine metaboric acid ester, 150 grams of nano silicon dioxide sols, 0.05 gram of organosilicon modified polyether defoamer；Finally adjusted with MEA
PH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 4% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 3
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：AEO
0.4wt%；Phosphoric acid polyether ester sylvite 1.5wt%；Disodium ethylene diamine tetraacetate 1.0wt%；Boric acid 4.0wt%；Triethanolamine
20.0wt%；Sodium metasilicate 2.0wt%；Organic boronic acid amides 8.0wt%；Decanedioic acid 2.8wt%；Diethylene glycol (DEG) 6.0%；Nano oxygen
Change Alumina gel 20.0wt%；Organosilicon modified polyether defoamer 0.005wt%；Water 34.3wt%；MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 120 grams of deionized waters
(ratio for accounting for total Water is 34.99%), is heated to 80 DEG C, then adds 40 grams of boric acid, 200 grams of triethanolamine stirring reactions 1
Hour；Add remaining 223 grams of deionized waters, sequentially add 10 grams of disodium ethylene diamine tetraacetates, 20 grams of sodium metasilicates, 28 grams
Decanedioic acid, stirring is to being completely dissolved；Sequentially add 15 grams of phosphoric acid polyether ester sylvite, 4 grams of AEOs, 80 grams have
Machine boric acid acid amides, 60 grams of diethylene glycol (DEG)s, 200 grams of nano alumina sols, 0.05 gram of organosilicon modified polyether defoamer；Finally with single
Monoethanolamine adjusts pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 5% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 4
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：Alkyl polyglycoside 1.0wt%；Phosphorus
Polyether acid ester sylvite 2.0wt%；Disodium ethylene diamine tetraacetate 0.8wt%；Boric acid 3.5wt%；Triethanolamine 19.0wt%；Inclined silicon
Sour sodium 2.0wt%；Organic boronic acid amides 3.0wt%；Decanedioic acid 3.0wt%；BTA 0.2wt%, organic metaboric acid ester
3.0wt%；Nano alumina sol 18.0wt%；Organosilicon modified polyether defoamer 0.005wt%；Water 44.5wt%；Dan Yi
Hydramine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 160 grams of deionized waters
(ratio for accounting for total Water is 45.71%), is heated to 130 DEG C, then adds 35 grams of boric acid, 190 grams of triethanolamine stirring reactions 1
Hour；Remaining 285 grams of deionized waters are added, less than 60 DEG C is cooled to, sequentially adds 8 grams of disodium ethylene diamine tetraacetates, 20
Gram sodium metasilicate, 30 grams of decanedioic acid, 2 grams of BTAs are stirred to being completely dissolved；Sequentially add 20 grams of phosphoric acid polyether ester potassium
Salt, 10 grams of alkyl polyglycosides, 30 grams of organic boronic acid amides, 30 grams of organic metaboric acid esters, 180 grams of nano alumina sols, 0.05 gram
Organosilicon modified polyether defoamer；Finally pH=8.5 is adjusted with MEA.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 6% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 5
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：Live on saccharide fatty acid esters surface
Property agent 0.2wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Tetrasodium ethylenediamine tetraacetate 1.5wt%；Boric acid 3wt%；Triethanolamine
15wt%；Sodium molybdate 1wt%；Organic boronic acid amides 10wt%；Decanedioic acid and different n-nonanoic acid 5wt%；Organic metaboric acid ester 8wt%；
Nano zircite colloidal sol 10wt%；Organosilicon modified polyether defoamer 0.0025wt%；Water 45.3wt%；MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 200 grams of deionized waters
(ratio for accounting for total Water is 44.15%), is heated to 85 DEG C, then adds 30 grams of boric acid, 150 grams of triethanolamine stirring reactions 2
Hour；Remaining 253 grams of deionized waters are added, sequentially add 15 grams of tetrasodium ethylenediamine tetraacetates, 10 grams of sodium molybdates, 20 grams of last of the ten Heavenly stems two
Acid, 30 grams of different n-nonanoic acids, stirring is to being completely dissolved；Sequentially add 10 grams of phosphoric acid polyether ester sylvite, 2 grams of saccharide fatty acid esters surfaces are lived
Property agent, 100 grams of organic boronic acid amides, 80 grams of organic metaboric acid esters, 100 grams of nano zircite colloidal sols, 0.05 gram it is organic-silicon-modified
Polyether antifoam agent；Finally pH=8.5 is adjusted with MEA.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 8% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 6
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：Beet alkali surface activator
0.8wt%；Phosphoric acid polyether ester sylvite 1.5wt%；Tetrasodium ethylenediamine tetraacetate 2.0wt%；Boric acid 3.5wt%；Triethanolamine
18.0wt%；Sodium molybdate 2.0wt%；Organic boronic acid amides 8.0wt%；Decanedioic acid 3.0wt%；Diethylene glycol (DEG) and organic metaboric acid ester
9.0wt% altogether；Nano-titanium oxide colloidal sol 15.0wt%；Organosilicon modified polyether defoamer 0.002wt%；Water 37.2wt%；
MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 33.60%), is heated to 85 DEG C, then adds 35 grams of boric acid, 180 grams of triethanolamine stirring reactions 1
Hour；Remaining 247 grams of deionized waters are added, sequentially add 20 grams of tetrasodium ethylenediamine tetraacetates, 20 grams of sodium molybdates, 10 grams of last of the ten Heavenly stems two
Acid, 20 grams of different n-nonanoic acids, stirring is to being completely dissolved；Sequentially add 15 grams of phosphoric acid polyether ester sylvite, 8 grams of beet alkali surface activators,
80 grams of organic boronic acid amides, 60 grams of diethylene glycol (DEG)s, 30 grams of organic metaboric acid esters, 150 grams of nano-titanium oxide colloidal sols, 0.05 gram of organosilicon
Modified polyether defoamer；Finally pH=8.5 is adjusted with MEA.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 10% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 7
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：Imidazoline surfactant
0.5wt%；Phosphoric acid polyether ester sylvite 1.2wt%；Tetrasodium ethylenediamine tetraacetate 1.8wt%；Boric acid 4.0wt%；Triethanolamine
17.0wt%；Sodium metasilicate 2.8wt%；Organic boronic acid amides 10.0wt%；Decanedioic acid and different n-nonanoic acid amount to 3.0wt%；Two is sweet
Alcohol 3.0wt%；Nano-titanium oxide colloidal sol 18.0wt%；Organosilicon modified polyether defoamer 0.002wt%；Water 38.7wt%；It is single
Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 200 grams of deionized waters
(ratio for accounting for total Water is 51.68%), is heated to 100 DEG C, then 40 grams of boric acid of addition in cooling and reflux device, 170 grams
Triethanolamine stirring reaction 1.5 hours；Remaining 187 grams of deionized waters are added, less than 60 DEG C is cooled to, sequentially adds 18 grams of second
The sodium of ethylenediamine tetraacetic acid (EDTA) four, 28 grams of sodium metasilicates, 12 grams of decanedioic acid, 18 grams of different n-nonanoic acids, stirring is to being completely dissolved；Add 12 grams of phosphoric acid
Polyether ester sylvite, 5 grams of imidazoline surfactants, 100 grams of organic boronic acid amides, 30 grams of diethylene glycol (DEG)s, 180 grams of nano-titanium oxides are molten
Glue, 0.02 gram of organosilicon modified polyether defoamer；Finally pH=8.5 is adjusted with MEA.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 7% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Embodiment 8
The water base super lapping liquid composition of environment-friendly antirust type, it is included by mass percentage：Sulfamic acid surfactant
1.0wt%；Phosphoric acid polyether ester sylvite 1.8wt%；Disodium ethylene diamine tetraacetate 1.6wt%；Boric acid 3.5wt%；Triethanolamine
19w.0t%；Sodium molybdate 2.0wt%；Organic boronic acid amides 6.0wt%；Different n-nonanoic acid 2.0wt%；Diethylene glycol (DEG) 6.0wt%；Nano oxygen
Change zirconium colloidal sol 19.0wt%；Organosilicon modified polyether defoamer 0.002wt%；Water 38.1wt%；MEA, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, comprises the following steps：Weigh 160 grams of deionized waters
(ratio for accounting for total Water is 41.99%), is heated to 95 DEG C, then adds 35 grams of boric acid, 190 grams of triethanolamine stirring reactions
1.5 hour；Remaining 221 grams of deionized waters are added, less than 60 DEG C is cooled to, sequentially adds 20 grams of sodium molybdates, 16 grams of ethylenediamines
Tetraacethyl disodium, 20 grams of different n-nonanoic acids, stirring is to being completely dissolved；Add 18 grams of phosphoric acid polyether ester sylvite, 10 grams of sulfamic acid surfaces
Activating agent, 60 grams of organic boronic acid amides, 60 grams of diethylene glycol (DEG)s, 190 grams of nano zircite colloidal sols, 0.02 gram of organosilicon modified polyether disappear
Infusion；Finally pH=8.5 is adjusted with MEA.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：Diluted with water by 10% for steel ball lapping process
In use.Transfer or storage or the dirts such as the grinding impurity of steel ball surface are washed with water after steel ball grinding is up to standard, between direct sequence
Contaminate thing and carry out finished product packing.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited
In specific details.
Claims (19)
1. a kind of super lapping liquid composition of water base environment-friendly antirust type, the mass percent of its constitutive material each component are：
2. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the nonionic or two
Property surfactant can natural degradation, it is selected from AEO, low bubble isomery alcohol, alkyl polyglycoside, glycosyl fat
One kind in fat acid esters, glycine betaine, imidazoline, sulfamic acid.
3. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the anionic surface
Activating agent can natural degradation, it is phosphoric acid polyether ester sylvite.
4. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the metal chelating agent
One kind in tetrasodium ethylenediamine tetraacetate or disodium ethylene diamine tetraacetate.
5. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the silicate is inclined
Sodium metasilicate, the molybdate are sodium molybdate.
6. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the organic long-chain acid
One or two kinds of mixtures selected from decanedioic acid, different n-nonanoic acid.
7. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the lubricant is selected from
One or two kinds of mixtures of diethylene glycol (DEG), organic metaboric acid ester.
8. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the abrasive material is selected from water
One kind of decentralized nano-inorganic substance, organosilane-modified abrasive material.
9. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 8, it is characterised in that the water-dispersion type is received
Rice inorganic matter is selected from nano silicon and its colloidal sol, nano aluminium oxide and its colloidal sol, nano zirconium dioxide and its colloidal sol, nanometer
One kind in titanium dioxide and its colloidal sol.
10. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the defoamer is
Organosilicon modified polyether defoamer.
11. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the pH adjusting agent
For MEA.
12. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the organic boronic
Acid amides is the reaction product of boric acid and hydramine.
13. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the oxo solvent
For dissident's glycol.
14. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, it is characterised in that the antirust agent is
BTA or derivatives thereof.
15. one kind prepares the system of the super lapping liquid composition of water base environment-friendly antirust type described in any one in claim 1-14
Preparation Method, it is characterised in that comprise the following steps：
S1：The water for accounting for total Water 25~60% is heated to 80~140 DEG C, boric acid and triethanolamine are sequentially added by the proportioning
Reaction 0.5~2 hour；
S2：The water of surplus is added, and cools to less than 60 DEG C, metal chelating agent, silicate or molybdic acid are added by the proportioning
One kind of salt, organic long-chain acid, antirust agent are completely dissolved it；
S3：By it is described match sequentially add in anion surfactant, nonionic or amphoteric surfactant one kind, contain
Oxygen solvent, organic boronic acid amides, lubricant, abrasive material, defoamer；
S4：The scope that pH is finally adjusted with pH adjusting agent obtains the super lapping liquid combination of water base environment-friendly antirust type for 8.3 ± 0.2
Thing.
16. the preparation method of the water base super lapping liquid composition of environment-friendly antirust type as claimed in claim 15, it is characterised in that institute
State and 130~140 DEG C are heated the water in S1.
17. one kind prepares making for the water base super lapping liquid composition of environment-friendly antirust type described in any one in claim 1-14
With method, it is characterised in that：The water base super lapping liquid composition water of environment-friendly antirust type is made by 3~10% directly dilutions
With.
18. the application method of the super lapping liquid composition of water base environment-friendly antirust type as described in right 17, it is characterised in that by described in
The water base super lapping liquid composition of environment-friendly antirust type is used with water by 5~10% directly dilutions.
19. the application method of the super lapping liquid composition of water base environment-friendly antirust type as described in any one of right 17-18, its feature
It is, the water is deionized water or desalted water, the μ s/cm of its electrical conductivity≤20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711070836.9A CN107699139B (en) | 2017-11-03 | 2017-11-03 | A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711070836.9A CN107699139B (en) | 2017-11-03 | 2017-11-03 | A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107699139A true CN107699139A (en) | 2018-02-16 |
| CN107699139B CN107699139B (en) | 2018-10-19 |
Family
ID=61177820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711070836.9A Active CN107699139B (en) | 2017-11-03 | 2017-11-03 | A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107699139B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109810749A (en) * | 2019-03-04 | 2019-05-28 | 富莱德科技(浙江)有限公司 | A kind of fully synthetic cutting fluid |
| CN110257150A (en) * | 2019-07-15 | 2019-09-20 | 海门市明珠钢球有限公司 | Steel ball grinding liquid and preparation method thereof |
| CN111849601A (en) * | 2020-08-11 | 2020-10-30 | 广州洛德化工科贸有限公司 | Low-temperature antirust agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN111893490A (en) * | 2020-08-14 | 2020-11-06 | 北美防锈技术（上海）有限公司 | Environment-friendly water-based antirust agent |
| CN114106702A (en) * | 2021-12-13 | 2022-03-01 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN114921788A (en) * | 2022-07-21 | 2022-08-19 | 山东祺裕新材料有限公司 | Antirust composition material for hot-rolled pickled plate and application method thereof |
| WO2022205911A1 (en) * | 2021-03-31 | 2022-10-06 | 煤炭科学技术研究院有限公司 | Protective liquid for hydraulic system, preparation method therefor and use of thereof |
| CN115948193A (en) * | 2022-12-12 | 2023-04-11 | 上海纳米技术及应用国家工程研究中心有限公司 | Super-lubricating water-based cutting fluid and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090071950A (en) * | 2007-12-28 | 2009-07-02 | 셰플러코리아(유) | Water-based grinding fluid for manufacturing bearing and the method thereof |
| CN101747864A (en) * | 2009-12-21 | 2010-06-23 | 洛阳轴研科技股份有限公司 | Method for preparing and using emulsion type lapping liquid for steel ball grinding |
| CN101974295A (en) * | 2010-09-07 | 2011-02-16 | 安徽舒城云飞工贸有限公司 | Steel ball lapping liquid |
| CN102102008A (en) * | 2009-12-18 | 2011-06-22 | 安集微电子（上海）有限公司 | Water-based glass grinding fluid and using method thereof |
| CN102311718A (en) * | 2011-04-26 | 2012-01-11 | 东莞市安美润滑科技有限公司 | Aqueous grinding fluid applied to super precision grinding of hard and brittle materials and application method thereof |
| CN102796596A (en) * | 2011-05-27 | 2012-11-28 | 大连力鹏润滑油有限公司 | Energy-saving environmentally-friendly complete synthetic anticorrosive grinding and turning liquid |
| CN104017636A (en) * | 2014-06-06 | 2014-09-03 | 清华大学 | Water soluble full-alloy metal grinding fluid |
| CN104087403A (en) * | 2014-07-29 | 2014-10-08 | 马思特（上海）化学有限公司 | Enhanced grinding fluid for protecting aluminum and preparation method thereof |
| CN105440954A (en) * | 2015-11-10 | 2016-03-30 | 铜陵市明诚铸造有限责任公司 | Grinding liquid for fine grinding of steel ball and preparation and use methods for grinding liquid |
-
2017
- 2017-11-03 CN CN201711070836.9A patent/CN107699139B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090071950A (en) * | 2007-12-28 | 2009-07-02 | 셰플러코리아(유) | Water-based grinding fluid for manufacturing bearing and the method thereof |
| CN102102008A (en) * | 2009-12-18 | 2011-06-22 | 安集微电子（上海）有限公司 | Water-based glass grinding fluid and using method thereof |
| CN101747864A (en) * | 2009-12-21 | 2010-06-23 | 洛阳轴研科技股份有限公司 | Method for preparing and using emulsion type lapping liquid for steel ball grinding |
| CN101974295A (en) * | 2010-09-07 | 2011-02-16 | 安徽舒城云飞工贸有限公司 | Steel ball lapping liquid |
| CN102311718A (en) * | 2011-04-26 | 2012-01-11 | 东莞市安美润滑科技有限公司 | Aqueous grinding fluid applied to super precision grinding of hard and brittle materials and application method thereof |
| CN102796596A (en) * | 2011-05-27 | 2012-11-28 | 大连力鹏润滑油有限公司 | Energy-saving environmentally-friendly complete synthetic anticorrosive grinding and turning liquid |
| CN104017636A (en) * | 2014-06-06 | 2014-09-03 | 清华大学 | Water soluble full-alloy metal grinding fluid |
| CN104087403A (en) * | 2014-07-29 | 2014-10-08 | 马思特（上海）化学有限公司 | Enhanced grinding fluid for protecting aluminum and preparation method thereof |
| CN105440954A (en) * | 2015-11-10 | 2016-03-30 | 铜陵市明诚铸造有限责任公司 | Grinding liquid for fine grinding of steel ball and preparation and use methods for grinding liquid |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109810749A (en) * | 2019-03-04 | 2019-05-28 | 富莱德科技(浙江)有限公司 | A kind of fully synthetic cutting fluid |
| CN110257150A (en) * | 2019-07-15 | 2019-09-20 | 海门市明珠钢球有限公司 | Steel ball grinding liquid and preparation method thereof |
| CN111849601A (en) * | 2020-08-11 | 2020-10-30 | 广州洛德化工科贸有限公司 | Low-temperature antirust agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN111893490A (en) * | 2020-08-14 | 2020-11-06 | 北美防锈技术（上海）有限公司 | Environment-friendly water-based antirust agent |
| WO2022205911A1 (en) * | 2021-03-31 | 2022-10-06 | 煤炭科学技术研究院有限公司 | Protective liquid for hydraulic system, preparation method therefor and use of thereof |
| CN114106702A (en) * | 2021-12-13 | 2022-03-01 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN114106702B (en) * | 2021-12-13 | 2022-11-18 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN114921788A (en) * | 2022-07-21 | 2022-08-19 | 山东祺裕新材料有限公司 | Antirust composition material for hot-rolled pickled plate and application method thereof |
| CN114921788B (en) * | 2022-07-21 | 2022-10-25 | 山东祺裕新材料有限公司 | Antirust composition material for hot-rolled pickled plate and application method thereof |
| CN115948193A (en) * | 2022-12-12 | 2023-04-11 | 上海纳米技术及应用国家工程研究中心有限公司 | Super-lubricating water-based cutting fluid and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107699139B (en) | 2018-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107699139B (en) | A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application | |
| CN102311718B (en) | Aqueous grinding fluid applied to super precision grinding of hard and brittle materials and application method thereof | |
| CN103013638B (en) | Water-soluble cooling liquid for fixed abrasive material line cutting, and preparation method thereof | |
| CN100485018C (en) | Rust-proof cutting fluid | |
| CN101531946A (en) | Metal cutting solution of green semi-synthesis double-base oil and preparation method thereof | |
| CN102102008B (en) | Water-based glass grinding fluid and using method thereof | |
| CN102703196B (en) | Environment-friendly water-based metal cutting fluid | |
| CN104498164A (en) | Anticorrosive, anti-fading and environmentally-friendly water-based magnesium alloy cutting fluid | |
| CN104774679A (en) | Environment-friendly water-based sapphire cutting fluid | |
| CN106635369A (en) | Fully synthetic cutting fluid and production method thereof | |
| CN102041137B (en) | Polycrystalline silicon or monocrystalline silicon cutting fluid | |
| CN106800963B (en) | A kind of water soluble oil metalworking fluid raw material and metalworking fluid | |
| CN101631846A (en) | Metalworking fluid and metalworking method | |
| CN103045336A (en) | Micro emulsion semisynthetic copper wire drawing liquid composition | |
| CN107325877A (en) | A kind of water-soluble fully synthetic hard alloy cuts grinding fluid | |
| CN102746932B (en) | A kind of preparation method of environment protection water-based metal working fluid | |
| CN102925271A (en) | Multiple-effect type semi-synthetic micro-emulsion cutting solution | |
| CN105670758A (en) | High-lubricity and ecological safety water-based cutting fluid and preparation method thereof | |
| CN104357201A (en) | Microemulsified cutting fluid applicable to magnesium alloy material machining and preparation method thereof | |
| CN104312710A (en) | Fully synthesized magnesium alloy cutting fluid and preparation method thereof | |
| CN104371818A (en) | High-performance water-based full-synthetic cutting fluid and preparation method thereof | |
| CN107955697A (en) | A kind of fully synthetic cutting fluid with high wear-resistant high rustless property and preparation method thereof | |
| CN104263486A (en) | Water-based metal wire drawing liquid with good lubricating effect and preparation method thereof | |
| CN106811280A (en) | A kind of cutting fluid and preparation method thereof | |
| CN1746282A (en) | Environmental-protective grinding fluid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Water-based environment-friendly antirust superfinishing liquid composition and preparation and application methods thereof Effective date of registration: 20190626 Granted publication date: 20181019 Pledgee: Bank of Fuxin, Limited by Share Ltd. Pledgor: LIAONING BAORUI TECHNOLOGY Co.,Ltd. Registration number: 2019210000022 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220817 Granted publication date: 20181019 Pledgee: Bank of Fuxin, Limited by Share Ltd. Pledgor: LIAONING BAORUI TECHNOLOGY Co.,Ltd. Registration number: 2019210000022 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A kind of water-based environment-friendly rust-proof super-finishing liquid composition and preparation and use method thereof Effective date of registration: 20220817 Granted publication date: 20181019 Pledgee: Bank of Fuxin, Limited by Share Ltd. Pledgor: LIAONING BAORUI TECHNOLOGY Co.,Ltd. Registration number: Y2022210000117 |