CN104936924A - 一种低辐射涂层中具有吸收层的低膜侧反射率和低可见光透射率的涂层制品 - Google Patents
一种低辐射涂层中具有吸收层的低膜侧反射率和低可见光透射率的涂层制品 Download PDFInfo
- Publication number
- CN104936924A CN104936924A CN201380058130.4A CN201380058130A CN104936924A CN 104936924 A CN104936924 A CN 104936924A CN 201380058130 A CN201380058130 A CN 201380058130A CN 104936924 A CN104936924 A CN 104936924A
- Authority
- CN
- China
- Prior art keywords
- layer
- coated products
- absorption layer
- infrared reflecting
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3435—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a nitride, oxynitride, boronitride or carbonitride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3642—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating containing a metal layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
设计一种低辐射(low-E)涂层的吸收层,使所述涂层的膜侧反射率被降低,有利于审美目的。在一些实施例中,吸收层为金属或基本金属的(例如,NiCr或NiCrNx),分别被配置在第一和第二氮化层(例如,基于氮化硅的层)之间,来减少或防止选择性热处理(例如,热钢化、热弯曲、和/或热强化)期间的吸收层的氧化。根据本发明的示例性实施例的涂层制品可用于绝缘玻璃(IG)窗单元以及其他类型的窗中。
Description
本发明涉及一种含有低辐射涂层的涂层制品。在示例性实施例中,低辐射涂层中的吸收层被配置/设计用来使该涂层具有以下特征(i)较低的可见光透射率(例如,小于等于50%,更优选是小于等于40%,且最优选是小于等于35%),以及(ii)较低的可见光膜侧反射率。一个吸收层可被配置在低辐射涂层的上堆栈中,且另一个吸收层被配置在低辐射涂层的下堆栈中。在一些示例性实施例中,吸收层为金属或基本金属的,且分别被配置在第一和第二氮化物层(例如,基于氮化硅的层)之间,来减少或防止选择性热处理(例如,热钢化、热弯曲、和/或热强化)和/或制造期间的吸收层的氧化,由此可实现预期的着色和光学特征。根据本发明的示例性实施例的涂层制品可用于绝缘玻璃(IG)窗单元、车窗、其他类型的窗、或任何其他合适的应用中。
发明背景
本领域中已知的窗应用中所使用的涂层制品有类似绝缘玻璃(IG)窗单元、车窗、和/或其他等。众所周知,在一些情况下,为了钢化、弯曲或其他等,需要对该涂层制品进行热处理(例如,热钢化、热弯曲、和/或热强化)。涂层制品的热处理通常需要使用至少580摄氏度的温度,更优选是至少约600摄氏度,且更优选是至少620摄氏度的高温(例如,5-10分钟或更多),经常使涂层损坏和/或劣化,或是在无法预知的方式中改变。因此,需要一种可承受热处理(例如,热钢化)的涂层,必要时在预知的方式中,其不会明显地损坏涂层。
在一些情况下,涂层制品的设计试图将所需的可见光透射率、所需的颜色、较低的辐射率(或辐射)、和较低的片电阻(Rs)结合。低辐射率(low-E)和较低的片电阻特征使涂层制品可阻挡相当数量的红外辐射,从而减少车辆或建筑物内部不需要的热量。通常,较低的可见光透射率可阻挡(包括反射)更多的红外辐射。
美国专利No.7,597,965公开了一种低辐射涂层,在下介质堆栈中配有NiCr吸收层。但是,该‘965专利中的示例性涂层被设计具有较高的可见光透射率,且事实上可见光透射率(Tvis或TY)为59%。因此,需要较低的可见光透射率。例如,出于审美目的和/或光学特征,所提供的涂层制品(包括低辐射涂层)的可见光透射率须小于等于50%,更优选是小于等于40%,且有时小于等于35%。但是,当涂层制品的可见光透射率经低辐射涂层设计被减少时,涂层的膜侧反射率通常会增加。
美国专利No.7,648,769公开了一种低辐射涂层,在中间的介质堆栈中配有NiCr吸收层,但不是在该涂层的上介质堆栈和下介质堆栈中(例如,参见该‘769专利中的图1)。该‘769专利中的示例1实现,单片测量的,54.5%的可见光透射率和19.5%的膜侧反射率,且在绝缘玻璃(IG)窗单元中测量时可见光透射率的值变为50%,且膜侧反射率为23%。以相似的方式,该‘769专利中的示例2实现,单片测量的,67.5%的可见光透射率和11.5%的膜侧反射率,且在绝缘玻璃(IG)窗单元中测量时,可见光透射率的值变为62%,且膜侧反射率为17%。应该意,该‘769专利中的示例不同时实现以下特征的结合:(i)较低的可见光透射率,和(ii)较低的膜侧反射率。相反,该‘769专利中的示例显示出可见光透射率下降时,膜侧反射率上升。
在此,在详细说明部分,仅在可见光透射率约为40%的低辐射涂层的中间介质堆栈中提供吸收层,导致不理想的30%以上较高的可见光膜侧反射率(RfY)。
因此,含有低辐射涂层的涂层制品,要实现(i)所需的较低的可见光透射率,以及(ii)较低的膜侧反射率两者的结合是十分困难的。本领域的技术人员应理解,现有技术中需要一种具低辐射(或低片电阻)的涂层制品,且较低的可见光透射率(例如,小于等于50%,更优选是小于等于40%,最优选是小于等于35%)和较低的膜侧反射率两者相结合。
发明的示例性实施例概述
一种含有低辐射涂层的涂层制品。在示例性实施例中,低辐射涂层中的吸收层被配置/设计用来使低辐射涂层具有以下特征(i)较低的可见光透射率(例如,小于等于50%,更优选是小于等于40%,且最优选是小于等于35%),以及(ii)较低的可见光膜侧反射率,其有利于审美目的。一个吸收层被配置在低辐射涂层的上堆栈中,且另一个吸收层被配置在低辐射涂层的下堆栈中,且在双银层的实施例中,低辐射涂层的中间堆栈中不配置类似的吸收层。吸收层为金属或基本金属的(例如,NiCr或NiCrNx),且在示例性实施例中分别被配置在第一和第二氮化物层(例如,基于氮化硅的层)之间,来减少或防止选择性热处理(例如,热钢化、热弯曲、和/或热强化)和/或制造期间的吸收层的氧化,由此可实现预期的着色和光学特征。在此发现,在涂层的上部和下部使用该吸收层而不是在银层之间的涂层的中间介质堆栈中,令人惊讶的是可同时实现较低的可见光透射率和较低的膜侧反射率的结合。在示例性实施例中,在绝缘玻璃和/或单片应用中,涂层制品的可见光膜侧反射率(RfY)可小于其可见光玻璃侧反射率(RgY)。根据本发明的示例性实施例的涂层制品可用于绝缘玻璃(IG)窗单元、车窗、其他类型的窗、或任何其他合适的应用中。
在本发明的示例性实施例中,提供一种涂层制品,包括由玻璃基片支撑的涂层,所述涂层包括:第一和第二红外反射层,其中,所述红外反射层由位于其之间的至少一个介质层被彼此隔开,且其中,所述第一红外反射层比所述第二红外反射层更接近所述玻璃基片;基本金属或金属的第一吸收层,所述第一吸收层位于所述玻璃基片和所述第一红外反射层之间;基本金属或金属的第二吸收层,所述第一和第二红外反射层都位于所述玻璃基片和所述第二吸收层之间,且其中,所述第一吸收层和所述第二吸收层分别被夹在含有氮化硅的介质层之间并与其接触。
附图简要说明
图1是根据本发明的示例性实施例的涂层制品的横截面图。
图2是根据本发明的示例性实施例的配置在绝缘玻璃窗单元中的图1的涂层制品的横截面图。
示例性实施例的具体说明
在此,涂层制品可用在包含有单个或多个玻璃基片的绝缘玻璃窗单元、车窗、单片建筑窗、住宅窗、和/或其他合适的应用中。
在本发明的示例性实施例中,涂层包括双银堆栈(如图1所示),但本发明并不局限于该实施例。
例如,在本发明的示例性实施例中,热处理或非热处理的涂层制品具有多个红外反射层(例如两个具间隔的基于银的层)可实现小于等于3.0(更优选是小于等于2.5,甚至更优选是小于等于2.1,且最优选是小于等于2.0)的片电阻(Rs)。在此使用的“热处理(heat treatment)”和“热处理(heattreating)”表示将制品加热至一定的温度来实现玻璃制品的热钢化、热弯曲、和/或热强化。该定义包括,例如,在烤炉或熔炉中以至少580℃的温度来加热涂层制品,更优选是至少600℃,以足够的时间来执行钢化、弯曲、和/或热强化。在一些情况下,热处理至少进行4到5分钟。在本发明的不同实施例中,涂层制品可热处理也可不热处理。
图1是例示出根据本发明的非限制性实施例的涂层制品的横截面图。该涂层制品包括:基片1(例如,纯色、绿色、铜色、或蓝绿色玻璃基片,厚度为1.0-10.0mm,更优选是1.0-3.5mm);低辐射涂层(或层体系)30,直接或间接地位于基片1上。涂层(或层体系)30包括:例如底部介质氮化硅层3,可以是高硅类型的Si3N4,用于去雾处理,或是本发明的另一个实施例中的任何其他合适的化学计量的氮化硅;金属或基本金属的吸收层4(例如,包括NiCr、NiCrNx或其他等);附加的介质氮化硅层5,可以是高硅类型的Si3N4,用于去雾处理,或任何其他合适的化学计量的氮化硅;选择性介质层6,包括氧化钛或其他合适的材料;第一下部接触层7(与下部红外反射层9接触);第一导电和金属或基本金属的红外反射层9;第一上部接触层11(与层9接触);介质层13;另一个基于和/或包含氮化硅的层14;基于和/或包含氧化锡的夹层15;第二下部接触层17(与红外反射层19接触)、第二导电和金属或基本金属的红外反射层19;第二上部接触层21(与层19接触);介质层23;介质氮化硅层24,可以是高硅类型的Si3N4,用于去雾处理,或是本发明的另一个实施例中的任何其他合适的化学计量的氮化硅;金属或基本金属的吸收层25(例如,包括NiCr、NiCrNx或其他等);和护膜介质氮化硅层26,可以是高硅类型的Si3N4,用于去雾处理,或是任何其他合适的化学计量的氮化硅。所述接触层7、11、17、和21分别至少与一个红外反射层(例如基于银的层)接触。上述溅射沉积的层3-26形成低辐射(即,低辐射率)涂层30,被配置在玻璃或塑料基片1上。
在为单片时,如图1所示,涂层制品仅包括一个玻璃基片1。但是,该单片的涂层制品可能用于类似叠层的车辆挡风玻璃、绝缘玻璃窗单元等装置中。在用于绝缘玻璃窗单元时,绝缘玻璃窗单元可包括两个具间隔的玻璃基片。在美国专利文件No.2004/0005467中示出并说明了示例性绝缘玻璃窗单元,其公开的内容被纳入此处作为参考。图2示出含有图1中所示的涂层的玻璃基片1的示例性绝缘玻璃窗单元,玻璃基片1通过垫片、密封剂40等被耦合至玻璃基片2,并在其之间定义间隔50。在一些情况下,绝缘玻璃单元实施例中的基片之间的间隔50中,可填入类似氩(Ar)的气体。在一些情况下,示例性绝缘玻璃单元可包括一对具间隔的透明玻璃基片,厚度分别为3-4mm,其中的一个涂有在此所述的涂层30,其中基片之间的间隔50可为5-30mm,更优选是10-20mm,且最优选是约为16mm。在示例中,涂层30可配置在面对间隔的任何一个基片的内表面(图2中涂层被示出位于面对间隔50的基片1的内部主要表面,但也可位于面对间隔50的基片2的内部主要表面)。基片1或基片2中的任何一个可以是建筑外部的绝缘玻璃窗单元的最外层基片(例如,在图2中基片1是最接近建筑外部的基片)。
在本发明的示例性实施例中,吸收层4位于基于氮的介质层3和5之间并与其接触。在示例性实施例中,围绕吸收层4的层3和5分别是氮化物层,并基本或完全非氧化。同样,在本发明的示例性实施例中,吸收层25位于基于氮的层24和26之间并与其接触。在示例性实施例中,围绕吸收层25的层24和26分别为氮化物层,并基本或完全非氧化。选择性地,层26的最外部分为涂层30的最外层时,其可被氧化,并露于大气中。在吸收层4和25周围使用氮化物层3、5、24、26,优点在于可防止(或减少)热处理期间吸收层4、25被氧化,从而更好地使吸收层4、25执行其预期的功能,特别是吸收至少一些数量的可见光(例如,至少5%,更优选是10%)。应理解,当热处理期间,层被过多氧化时,其不能执行作为吸收层的适当功能。
在本发明的示例性实施例中,吸收层4、25可包括NiCr(例如,具任何Ni:Cr合适比例的镍铬),且可以或也可以不氮化(NiCrNx)。图1中示出吸收层4和25位于基于氮的介质层之间并与其接触。在示例性实施例中,围绕吸收层4、25的基于氮的层3、5、24、26分别为氮化物层,并基本或完全非氧化。在示例性实施例中,吸收层4、25可包括0-10%的氧气,更优选是0-5%的氧气,且最优选是0-2%的氧气(原子百分比)。在示例性实施例中,吸收层4、25包括0-20%的氮气,更优选是1-15%的氮气,且最优选是约1-12%的氮气(原子百分比)。虽然对于吸收层4、25来说NiCr是优选材料,但也可替换使用其他材料。例如,在本发明的其他可热处理的示例性实施例中,吸收层4和/或25可以是或包括Ni、Cr、NiCrNx、CrN、ZrN、或TiN。在非热处理的实施例中,任何一个上述的材料可用于吸附/吸收层4和/或25,类似Ti、Zr、NiOx等其他材料。
低辐射涂层30的吸收层4和25被设计用来使涂层30具有较低的可见光透射率,所需的着色,和较低的膜侧反射率。在示例性实施例中,金属或基本金属的吸收层(例如NiCr或NiCrNx)4和25的厚度可分别约为 更优选是厚度为且最优选是厚度约为在示例性实施例中,下部的吸收层4比上部的吸收层25稍薄。例如,在示例性实施例中,下部的吸收层4比上部的吸收层25薄(更优选是薄),从而提供更理想的涂层制品的光学特性。在示例性实施例中,金属或基本金属的吸收层4、25分别被配置在第一和第二氮化物层(例如,基于氮化硅的层)3、5、24、26之间,来减少或防止热处理(例如,热钢化、热弯曲、和/或热强化)期间的氧化,由此随着热处理,可实现预期的着色、透射率、和反射率值。
因此,吸收层25被配置在上部堆栈(上部的基于银的红外反射层19之上),且第二吸收层4被配置在下部堆栈(玻璃基片1和下部的基于银的红外反射层9之间)。优选是,在双银层实施例中(即,低辐射涂层具有两个基于银的红外反射层),一对氮化物层之间的中间介质堆栈中不配置类似的吸收层。也就是说,当吸收层4和25被配置在涂层的下部和上部时,两个基于银的层9和19之间的中间堆栈中所配置的氮化物之间不配置类似的吸收层。在此发现,在涂层的底部和顶部分别使用吸收层4和25,而不是在银之间的涂层的中间部分,令人惊讶的是可在含有涂层30的涂层制品中同时实现较低的可见光透射率和较低的膜侧反射率的结合。在示例性实施例中,在绝缘玻璃和/或单片应用中,涂层制品的可见光膜侧反射率(RfY)可小于其可见光玻璃侧反射率(RgY)。
在本发明的实施例中,介质层3、5、14、24、和26可以是或包括氮化硅。此外,氮化硅层3、5、14、24、和26可提高涂层制品的热处理性以及在选择性的热处理期间保护吸收层,例如类似热钢化等。在本发明的其他实施例中,层3、5、14、24、和26中一个或多个的氮化硅可以是化学计量的类型(例如,Si3N4),或是富硅型的氮化硅。含有富硅型氮化硅的层3和/或5中所存在的自由硅可使类似钠(Na)的原子在热处理期间从玻璃基片1向外移动,在其到达银层9及损坏其之前可更有效地经含有富硅型氮化硅的层被停止。因此,在本发明的示例性实施例中,热处理期间,富硅型SixNy可减少对于银层的损坏,从而使片电阻减少,或以理想的方式保持相同。此外,在本发明可选择的示例性实施例中,层3,5,24和/或26中的富硅型SixNy在热处理期间可减少对于吸收层4(和/或25)的损坏(例如,氧化)。在示例性实施例中,当富硅型氮化硅被使用时,富硅型氮化硅层由此沉积可能具有SixNy层的特性,其中x/y可以是0.76-1.5,更优选是0.8-1.4,甚至更优选是0.82-1.2。此外,在示例性实施例中,在热处理之前和/或之后,富硅型SixNy层的折射系数"n"可至少为2.05,更优选是至少2.07,且有时至少2.10(例如,632nm)(注意,也可使用化学计量的Si3N4,系数"n"为2.02-2.04)。应注意,n和k由于热处理倾向于下降。在本发明的示例性实施例中,在此所述的任何和/或所有氮化硅层可掺杂其他材料,例如不锈钢或铝。例如,在本发明的示例性实施例中,在此所述的任何和/或所有氮化硅层可选择性地包括约0-15%的铝,更优选是约1-10%的铝。在本发明的实施例中,氮化硅可通过在具有氩和氮气的大气中溅射对象Si或SiAl被沉积。在一些情况下,还可在氮化硅层中提供少量的氧气。
红外反射层9和19优选是基本或完全金属的和/或导电的,并可包括或由银(Ag)、金、或其他合适的红外反射材料构成。红外反射层9和19可使涂层具有低辐射和/或更好的太阳能控制特性。在本发明的实施例中,红外反射层可被轻度氧化。
上部的接触层11和12可以是或包括氧化镍(Ni),铬/氧化铬(Cr),NiCr,或类似氧化镍铬(NiCrOx)的氧化镍合金,或其他合适的材料。在本发明的示例性实施例中,例如,层11和/或21中的NiCrOx使用可提高使用寿命。在本发明的示例性实施例中,层11和/或21的NiCrOx可完全被氧化(即,完全化学计量的),或是也可部分氧化。在一些情况下,NiCrOx层11和/或21可至少50%氧化。在本发明的其他实施例中,接触层11和/或12(例如,包括Ni和/或Cr的氧化物)可以或也可以不被氧化分级。氧化分级表示层中的氧化程度在整个层的厚度中变化,因此接触层可被分级,从而,与离附近红外反射层较远或更远/最远的接触层的一部分相比,附近红外反射层的接触界面中则较少地氧化。美国专利No.6,576,349中说明了多种类型的氧化分级的接触层,其公开的内容被纳入此处作为参考。在本发明的其他实施例中,接触层11和/或21(例如,可以是或包括Ni和/或Cr的氧化物)可以或也可以不是连续穿过整个红外反射层。
在本发明的实施例中,介质层13和23可以是或包括氧化锡。但是,在不同的情况下,其他的层也可使用其他的材料。
在本发明的实施例中,下部的接触层7和/或17可以是或包括氧化锌(例如,ZnO)。氧化锌层7和17可包括其他材料,例如Al(例如形成ZnAlOx)例如,本发明的实施例中,一个或多个氧化锌层7、17可掺杂有约1-10%的Al,更优选是约1-5%的Al,且最优选是1-4%的Al。
夹层15可以是或包括氧化锡,被配置在红外反射层19之,从而位于氮化硅层14和氧化锌层17之间。该含有氧化锡的夹层15的使用,与不提供该层的情况相比,具有较大的改进。例如,在此发现,该含有氧化锡的夹层15的使用,使涂层制品可实现以下性能:(a)由于热处理较少的可见光透射率被转移;(b)随热处理,具有更高的可见光透射率;(c)由于热处理,颜色值较少被转移;(d)随热处理,基本为中性颜色;(e)由于热处理,片电阻更稳定或甚至递减;(f)随热处理,片电阻更低以及更低辐射;(g)随热处理,雾特征被改进;(h)热处理之前和/或之后,类似抗划伤的机械寿命被改善。因此,在本发明的示例性实施例中,涂层制品在热处理期间可承受高温,和/或更长的时间,且透射率不会明显下降和/或片电阻增加。在选择性的实施例中,可在氧化锡的层15中掺杂其他材料,例如Al、Zn等。可选择地,在一些情况下,其他金属氧化物也可用于层15。
在本发明的示例性实施例中,介质层6可以是或包括氧化钛。在不同的实施例中,氧化钛可以是或包括TiO2,或任何其他合适的化学计量。
附图中所示的涂层的下部或上部还可配置其他层。因此,虽然层系统或涂层位于基片1“之上”或是“由基片1(直接或间接地)支撑”,但其之间还可配置其他层。因此,例如,尽管层3和基片1之间配置有其他层,图1的涂层也可被认为是位于基片1“之上”或是“由基片1支撑”。此外,在一些实施例中,附图中所示的涂层中的一些层可被去除,且在不脱离本发明实施例的总的思想范围情况下,在本发明的其他实施例中,可在多种层之间添加其他的,或是多种层可与分裂段之间添加的其他层分开。
在本发明的不同实施例中,可使用各种厚度和材料的层,以下,示出用于图1实施例中玻璃基片1上的各层的示例性厚度和材料,自玻璃基片向外的顺序:
示例性材料/厚度;图1实施例
在此可发现,底部的吸收层4基本上比上部的吸收层25厚。例如,在实施例中,底部的吸收层4比上部的吸收层25至少厚更优选是至少厚且甚至更优选是至少厚此外,还可发现,吸收层4和/或25中的一个或两者中,底部的氮化硅层(3和/或24)比顶部的氮化硅层(5和/或26)薄。进一步,围绕层4和/或25,在实施例中,底部的氮化硅层(3和/或24)比顶部的氮化硅层(5和/或26)至少薄更优选是至少薄或
在本发明的示例性实施例中,当被单片测量时,在此的涂层制品可具有以下表2中所述的光学和太阳能特性,在此的片电阻(Rs)考虑到所有的红外反射层(例如,银层9,19)。
光学/太阳能特性(单片;预加热处理)
在示例性实施例中,在此的涂层制品可具有以下的特性,被单片测量,例如在热处理(HT)之后。
光学/太阳能特性(单片;后加热处理)
进一步,在本发明的示例性层压实施例中,在此的涂层制品被选择性地热处理,在一定程度上足以钢化,并被耦合至另一玻璃基片,来形成绝缘玻璃单元,如图2所示的结构(例如,透明玻璃的两个玻璃片分别为4mm厚和6mm厚,具有16mm的间隔,其之间填有90/10的氩/空气),可具有以下绝缘玻璃单元光学/太阳能特性。在此发现,当配置在绝缘玻璃单元中时,膜侧反射率被增加。
示例性光学特性(绝缘玻璃单元的预或后加热处理)
以下示例仅用于举例说明,除非特别声明,并不局限于此。
示例
以下的示例1通过在6mm厚的透明玻璃基片溅射被制成,从而具有近似以下所示的层推栈。示例1是如图1所示的本发明的示例性实施例,而以下的比较示例(CE)则仅在堆栈的中间具有NiCr吸收层,其被提供来作为比较。示例1具有近似以下的层堆栈,其中,厚度单位为且NiCr吸收层4和25被轻度氮化。
示例1
比较示例(CE)具有与示例1相似的NiCr吸收层,但是,在比较示例中,吸收层仅位于银层之间的中间堆栈中。该比较示例具有以下的层堆栈,自玻璃向外的顺序:
比较示例
以下示出示例1与比较示例(CE)相比较的光学特性,被单片测量。
示例1和比较示例之间的对比
从上述内容可发现,与比较示例(CE)相比,示例1具有令人惊讶的较好的(低)可见光膜侧反射率(RfY),甚至与比较示例相比,示例1还具有较低的可见光透射率(TY),即,与比较示例中的32.3%相比,示例1中则为9%。因此,示例1中的低辐射涂层的下部和上部(不同于比较示例中的仅位于中部)的吸收层4和25,令人惊讶地使低辐射涂层可同时具有(i)较低的可见光透射率,和(ii)较低的膜侧反射率。
在本发明的示例性实施例中,提供一种涂层制品,包括涂层30,由玻璃基片1支撑,所述涂层包括:含有银的第一和第二红外反射层9和19,其中,所述红外反射层9和19由位于其之间的至少一个介质层13、14、15和/或16被彼此隔开,且其中,所述第一红外反射层9比所述第二红外反射层19更接近所述玻璃基片1;含有Ni和/或Cr的基本金属或金属的第一吸收层4,所述第一吸收层4位于所述玻璃基片1和所述第一红外反射层9之间;含有Ni和/或Cr的基本金属或金属的第二吸收层25,所述第一和第二红外反射层9和19都位于所述玻璃基片1和所述第二吸收层25之间,且其中,所述第一吸收层4和所述第二吸收层25分别被夹在含有氮化硅的介质层3、5、24、26之间并与其接触。
如前段落中的涂层制品,所述第一和第二吸收层可分别含有NiCr和/或NiCrNx。
如前两个段落中任何一个的涂层制品,所述第一和/或第二吸收层可分别含有1-15%的氮(原子百分比)。
如前三个段落中任何一个的涂层制品,所述第一和第二红外反射层9、19,自所述玻璃基片按顺序至少由含有氧化锡的层13、含有氮化硅的层14、和含有氧化锌的层17被隔开。
如前四个段落中任何一个的涂层制品,在示例性实施例中,所述第一和第二红外反射层之间不配置金属或基本金属的吸收层。
如前五个段落中任何一个的涂层制品,在示例性实施例中,仅两个含有银的红外反射层被包含在所述涂层中。
如前六个段落中任何一个的涂层制品,所述第一吸收层的厚度可约为
如前七个段落中任何一个的涂层制品,所述第二吸收层的厚度可约为
如前八个段落中任何一个的涂层制品,所述第一吸收层4的厚度可基本大于所述第二吸收层25。
如前九个段落中任何一个的涂层制品,所述涂层制品的可见光透射率可为20-43%(更优选是24-33%),其被单片测量。
如前十个段落中任何一个的涂层制品,所述涂层制品可被热处理(例如热钢化)或没有被热处理。
如前十一个段落中任何一个的涂层制品,在示例性实施例中,所述涂层中含有NiCr或NiCrNx的金属或基本金属的吸收层不超过两个。
如前十二个段落中任何一个的涂层制品,所述涂层,可进一步包括含有氧化钛的层6,位于所述第一红外反射层9和所述第一吸收层4之间。
如前十三个段落中任何一个的涂层制品,所述第一红外反射层9和所述第一吸收层4,自所述玻璃基片按顺序至少由位于所述第一吸收层4之上并与其直接接触的含有氮化硅的层5、含有氧化钛的层6、和含有氧化锌的层7被隔开。
如前十四个段落中任何一个的涂层制品,所述涂层制品的可见光膜侧反射率(RfY),被单片测量,小于等于15%,更优选是小于等于12%。
如前十五个段落中任何一个的涂层制品,所述涂层制品的可见光膜侧反射率(RfY)可小于所述涂层制品的可见光玻璃侧反射率(RgY),其被单片测量。例如。所述涂层制品的可见光膜侧反射率(RfY)比可见光玻璃侧反射率(RgY)至少小5个百分点。
在本发明的一个实施例中,提供一种涂层制品,包括由玻璃基片支撑的涂层,所述涂层包括:第一和第二红外反射层,其中,所述红外反射层由位于其之间的至少一个介质层被彼此隔开,且其中,所述第一红外反射层比所述第二红外反射层更接近所述玻璃基片;基本金属或金属的第一吸收层,所述第一吸收层位于所述玻璃基片和所述第一红外反射层之间;基本金属或金属的第二吸收层,所述第一和第二红外反射层都位于所述玻璃基片和所述第二吸收层之间,且其中,所述第一吸收层和所述第二吸收层分别被夹在含有氮化硅的介质层之间并与其接触。
如前段落中的涂层制品,所述第一和第二吸收层可分别含有NiCr和/或NiCrNx。
如前两个段落中任何一个的涂层制品,所述第一和/或第二吸收层可分别含有1-15%的氮(原子百分比)。
如前三个段落中任何一个的涂层制品,所述第一和第二红外反射层,自所述玻璃基片按顺序至少由含有氧化锡的层、含有氮化硅的层、和含有氧化锌的层被隔开。
如前四个段落中任何一个的涂层制品,在示例性实施例中,所述第一和第二红外反射层之间不配置金属或基本金属的吸收层。
如前五个段落中任何一个的涂层制品,在示例性实施例中,仅两个含有银的红外反射层被包含在所述涂层中。
如前六个段落中任何一个的涂层制品,所述第一吸收层的厚度可约为
如前七个段落中任何一个的涂层制品,所述第二吸收层的厚度可约为
如前八个段落中任何一个的涂层制品,所述第一吸收层4的厚度可基本大于所述第二吸收层25。
如前九个段落中任何一个的涂层制品,所述涂层制品的可见光透射率可为20-43%(更优选是24-33%),其被单片测量。
如前十个段落中任何一个的涂层制品,所述涂层制品可被热处理(例如热钢化)或没有被热处理。
如前十一个段落中任何一个的涂层制品,在示例性实施例中,所述涂层中金属或基本金属的吸收层不超过两个(注意,在此Ag或Au的红外反射层为红外反射层,并不是吸收层)。
如前十二个段落中任何一个的涂层制品,所述涂层,可进一步包括含有氧化钛的层,位于所述第一红外反射层和所述第一吸收层之间。
如前十三个段落中任何一个的涂层制品,所述第一红外反射层和所述第一吸收层,自所述玻璃基片按顺序至少由位于所述第一吸收层之上并与其直接接触的含有氮化硅的层、含有氧化钛的层、和含有氧化锌的层被隔开。
如前十四个段落中任何一个的涂层制品,所述涂层制品的可见光膜侧反射率(RfY),被单片测量,小于等于15%,更优选是小于等于12%。
如前十五个段落中任何一个的涂层制品,所述涂层制品的可见光膜侧反射率(RfY)可小于所述涂层制品的可见光玻璃侧反射率(RgY),其被单片测量。例如,所述涂层制品的可见光膜侧反射率(RfY)比可见光玻璃侧反射率(RgY)至少小5个百分点。
如上所述,虽然参照最实用及优选的示例性实施例对本发明进行了说明,但是应理解,本发明并不局限于所述实施例,相反可进行各种修改和变形,修改将由后附的权利要求范围定义。
Claims (22)
1.一种涂层制品,包括由玻璃基片支撑的涂层,所述涂层包括:
含有银的第一和第二红外反射层,其中,所述红外反射层由位于其之间的至少一个介质层被彼此隔开,且其中,所述第一红外反射层比所述第二红外反射层更接近所述玻璃基片;
含有Ni和/或Cr的基本金属或金属的第一吸收层,所述第一吸收层位于所述玻璃基片和所述第一红外反射层之间;
含有Ni和/或Cr的基本金属或金属的第二吸收层,所述第一和第二红外反射层都位于所述玻璃基片和所述第二吸收层之间,且
其中,所述第一吸收层和所述第二吸收层分别被夹在含有氮化硅的介质层之间并与其接触。
2.如权利要求1所述的涂层制品,其中,所述第一和第二吸收层分别含有NiCr。
3.如权利要求1所述的涂层制品,其中,所述第一和第二吸收层分别含有NiCrNx。
4.如权利要求1或3中任何一项所述的涂层制品,其中,所述第一和第二吸收层分别含有1-15%的氮(原子百分比)。
5.如上述权利要求中任何一项所述的涂层制品,其中,所述第一和第二红外反射层,自所述玻璃基片按顺序至少由含有氧化锡的层、含有氮化硅的层、和含有氧化锌的层被隔开。
6.如上述权利要求中任何一项所述的涂层制品,其中,所述第一和第二红外反射层之间不配置金属或基本金属的吸收层。
7.如上述权利要求中任何一项所述的涂层制品,其中,仅两个含有银的红外反射层被包含在所述涂层中。
8.如上述权利要求中任何一项所述的涂层制品,其中,所述第一吸收层的厚度为
9.如上述权利要求中任何一项所述的涂层制品,其中,所述第二吸收层的厚度为
10.如上述权利要求中任何一项所述的涂层制品,其中,所述第一吸收层的厚度大于所述第二吸收层。
11.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光透射率为20-43%,其被单片测量。
12.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光透射率为24-33%,其被单片测量。
13.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品被热钢化。
14.如权利要求1-12中任何一项所述的涂层制品,其中,所述涂层制品没有被热处理。
15.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层中含有NiCr或NiCrNx的金属或基本金属的吸收层不超过两个。
16.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层,进一步包括含有氧化钛的层,位于所述第一红外反射层和所述第一吸收层之间。
17.如上述权利要求中任何一项所述的涂层制品,其中,所述第一红外反射层和所述第一吸收层,自所述玻璃基片按顺序至少由位于所述第一吸收层之上并与其直接接触的含有氮化硅的层、含有氧化钛的层、和含有氧化锌的层被隔开。
18.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光膜侧反射率RfY小于等于15%,被单片测量。
19.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光膜侧反射率RfY小于等于12%,其被单片测量。
20.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光膜侧反射率RfY小于所述涂层制品的可见光玻璃侧反射率RgY,其被单片测量。
21.如上述权利要求中任何一项所述的涂层制品,其中,所述涂层制品的可见光膜侧反射率RfY比所述涂层制品的可见光玻璃侧反射率RgY至少小5个百分点,其被单片测量。
22.一种涂层制品,包括由玻璃基片支撑的涂层,所述涂层包括:
第一和第二红外反射层,其中,所述红外反射层由位于其之间的至少一个介质层被彼此隔开,且其中,所述第一红外反射层比所述第二红外反射层更接近所述玻璃基片;
基本金属或金属的第一吸收层,所述第一吸收层位于所述玻璃基片和所述第一红外反射层之间;
基本金属或金属的第二吸收层,所述第一和第二红外反射层都位于所述玻璃基片和所述第二吸收层之间,且
其中,所述第一吸收层和所述第二吸收层分别被夹在含有氮化硅的介质层之间并与其接触。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/606,276 US9150003B2 (en) | 2012-09-07 | 2012-09-07 | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
US13/606,276 | 2012-09-07 | ||
PCT/US2013/056990 WO2014039345A2 (en) | 2012-09-07 | 2013-08-28 | Coated article with low-e coating having absorbing layers for low film side reflectance and low visible transmission |
Publications (1)
Publication Number | Publication Date |
---|---|
CN104936924A true CN104936924A (zh) | 2015-09-23 |
Family
ID=49170880
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380058130.4A Pending CN104936924A (zh) | 2012-09-07 | 2013-08-28 | 一种低辐射涂层中具有吸收层的低膜侧反射率和低可见光透射率的涂层制品 |
Country Status (13)
Country | Link |
---|---|
US (5) | US9150003B2 (zh) |
EP (1) | EP2892858B1 (zh) |
JP (1) | JP6324386B2 (zh) |
KR (1) | KR20150054863A (zh) |
CN (1) | CN104936924A (zh) |
BR (1) | BR112015005017A2 (zh) |
ES (1) | ES2744493T3 (zh) |
IN (1) | IN2015DN01872A (zh) |
MX (1) | MX2015002863A (zh) |
PL (1) | PL2892858T3 (zh) |
RU (1) | RU2637003C2 (zh) |
TW (2) | TWI630183B (zh) |
WO (1) | WO2014039345A2 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106116178A (zh) * | 2016-08-13 | 2016-11-16 | 咸宁南玻节能玻璃有限公司 | 一种中反银灰色可弯钢双银低辐射镀膜玻璃及其制备方法 |
US9725358B2 (en) | 2012-11-19 | 2017-08-08 | Guardian Industries Corp. | Coated article with low-E coating including zinc oxide inclusive layer(s) with additional metal(s) |
CN110461792A (zh) * | 2017-01-05 | 2019-11-15 | 佳殿玻璃有限公司 | 具有氮化钛和镍铬基ir反射层的可热处理涂覆制品 |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10654748B2 (en) * | 2010-03-29 | 2020-05-19 | Vitro Flat Glass Llc | Solar control coatings providing increased absorption or tint |
US9150003B2 (en) | 2012-09-07 | 2015-10-06 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
ES2691038T5 (es) * | 2013-02-14 | 2023-04-26 | Agc Glass Europe | Acristalamiento antisolar |
JP6423198B2 (ja) * | 2014-08-05 | 2018-11-14 | 日東電工株式会社 | 赤外線反射フィルム |
US10723102B2 (en) | 2015-04-20 | 2020-07-28 | 3M Innovative Properties Company | Durable low emissivity window film constructions |
US10539726B2 (en) * | 2015-09-01 | 2020-01-21 | Vitro Flat Glass Llc | Solar control coating with enhanced solar control performance |
WO2017044606A1 (en) * | 2015-09-11 | 2017-03-16 | Corning Incorporated | Photochromic multi-pane windows |
KR101934062B1 (ko) * | 2015-09-14 | 2019-01-02 | (주)엘지하우시스 | 창호용 기능성 건축 자재 |
WO2017058887A1 (en) | 2015-09-28 | 2017-04-06 | Tru Vue, Inc. | Near infrared reflective coatings |
US9684533B2 (en) * | 2015-11-18 | 2017-06-20 | International Business Machines Corporation | Management of a virtual machine in a virtualized computing environment based on a concurrency limit |
KR20190020289A (ko) * | 2016-03-15 | 2019-02-28 | 가디언 글라스, 엘엘씨 | 낮은 태양 인자 값을 갖는 브론즈 착색된 열 처리 가능한 코팅된 물품 |
EA201892764A1 (ru) * | 2016-06-02 | 2019-04-30 | Агк Гласс Юроп | Солнцезащитный элемент остекления |
EP3464208A1 (en) * | 2016-06-02 | 2019-04-10 | AGC Inc. | Solar-control glazing |
KR101914449B1 (ko) * | 2016-08-23 | 2018-11-05 | (주)엘지하우시스 | 창호용 기능성 건축 자재 |
KR101873103B1 (ko) | 2016-09-06 | 2018-06-29 | (주)엘지하우시스 | 창호용 기능성 건축 자재 |
BR112019007955B1 (pt) * | 2016-10-18 | 2022-10-25 | Guardian Glass, LLC | Artigo revestido de cor prata com revestimento de baixa-e que tem camada absorvente e baixa transmissão no espectro visível |
WO2018075005A1 (en) * | 2016-10-18 | 2018-04-26 | Guardian Glass, LLC | Grey colored coated article with low-e coating having absorber layer and low visible transmission |
WO2018109534A1 (en) * | 2016-12-16 | 2018-06-21 | Guardian Glass Holding S.P.C. | Heat treatable coated article for use in backsplash applications |
US10845512B2 (en) | 2016-12-23 | 2020-11-24 | Guardian Glass, LLC | Coated article for use in surveillance window or the like and method of making same |
US10138159B2 (en) * | 2017-03-09 | 2018-11-27 | Guardian Glass, LLC | Coated article having low-E coating with IR reflecting layer(s) and high index nitrided dielectric film having multiple layers |
US10138158B2 (en) * | 2017-03-10 | 2018-11-27 | Guardian Glass, LLC | Coated article having low-E coating with IR reflecting layer(s) and high index nitrided dielectric layers |
SG11201908621YA (en) * | 2017-05-04 | 2019-10-30 | Apogee Enterprises Inc | Low emissivity coatings, glass surfaces including the same, and methods for making the same |
KR102082424B1 (ko) * | 2017-07-25 | 2020-02-27 | 주식회사 케이씨씨 | 저방사 유리 |
EP3680437B1 (en) * | 2017-09-08 | 2023-10-04 | LG Hausys, Ltd. | Functional building material for door and window |
KR102133217B1 (ko) | 2018-01-05 | 2020-07-14 | 주식회사 플렉스이비전 | 금속과 산화물질 증착막을 포함하여 이루어지는 로이 반사필름 및 이의 제조방법 |
WO2019209202A2 (en) * | 2018-01-11 | 2019-10-31 | Turkiye Sise Ve Cam Fabrikalari Anonim Sirketi | Low-e coated glass with efficient thermal and solar control |
CN108178523B (zh) * | 2018-02-11 | 2024-02-09 | 信义玻璃工程(东莞)有限公司 | 高隐私低光污染高性能镀膜玻璃 |
FR3082198B1 (fr) * | 2018-06-12 | 2020-06-26 | Saint-Gobain Glass France | Materiau comprenant un empilement a proprietes thermiques et esthetique |
FR3082199B1 (fr) * | 2018-06-12 | 2020-06-26 | Saint-Gobain Glass France | Materiau comprenant un empilement a proprietes thermiques et esthetiques |
US10336651B1 (en) * | 2018-07-16 | 2019-07-02 | Guardian Glass, LLC | Coated article with IR reflecting layer(s) and silicon zirconium oxynitride layer(s) and method of making same |
US11709297B2 (en) * | 2018-09-24 | 2023-07-25 | Vitro Flat Glass Llc | Articles coated with coatings containing light absorption materials |
FR3088633B1 (fr) * | 2018-11-16 | 2021-04-30 | Saint Gobain | Materiau traite thermiquement a proprietes mecaniques ameliorees |
TR201819739A2 (tr) * | 2018-12-18 | 2020-07-21 | Tuerkiye Sise Ve Cam Fabrikalari Anonim Sirketi | Lami̇nasyonlu otomoti̇v camlarina uygulanabi̇li̇r bi̇r low-e kaplama |
FR3092107B1 (fr) * | 2019-01-30 | 2022-08-12 | Saint Gobain | Substrat muni d’un empilement a proprietes thermiques et a couche absorbante |
WO2020164735A1 (en) * | 2019-02-15 | 2020-08-20 | Glas Trösch Ag | Functional coated article |
WO2020198480A1 (en) * | 2019-03-28 | 2020-10-01 | Vitro Flat Glass Llc | Article having a high visible light reflectance and a neutral color |
KR102481460B1 (ko) * | 2020-09-29 | 2022-12-26 | 한국유리공업 주식회사 | 다층 박막 코팅이 구비된 투명 기재 |
US20220204399A1 (en) * | 2020-12-28 | 2022-06-30 | Vitro Flat Glass Llc | Article Coated with a Solar Control Coating Having Solar Protection and Thermal Insulation |
EP4234508A1 (en) * | 2022-02-24 | 2023-08-30 | AGP Worldwide Operations GmbH | Vehicle glazing roof with metallic appearance and solar-control properties |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5214530A (en) * | 1990-08-16 | 1993-05-25 | Flex Products, Inc. | Optically variable interference device with peak suppression and method |
CN1823023A (zh) * | 2003-07-16 | 2006-08-23 | 格拉沃贝尔公司 | 具有极低日光系数的涂覆基底 |
WO2006124503A2 (en) * | 2005-05-12 | 2006-11-23 | Agc Flat Glass North America, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
US20080070044A1 (en) * | 2006-09-18 | 2008-03-20 | Richard Blacker | Coated article with low-E coating having absorbing layer designed to neutralize color at off-axis viewing angles |
EP2030954A1 (en) * | 2007-08-14 | 2009-03-04 | Cardinal CG Company | Solar control low-emissivity coatings |
US7648769B2 (en) * | 2007-09-07 | 2010-01-19 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layer designed for desirable bluish color at off-axis viewing angles |
US20110261442A1 (en) * | 2010-04-22 | 2011-10-27 | Hartmut Knoll | Coated article having low-E coating with absorber layer(s) |
US20110300319A1 (en) * | 2008-12-22 | 2011-12-08 | Saint-Gobain Glass France | Substrate provided with a multilayer coating having thermal properties and an absorbent layer |
US20110305853A1 (en) * | 2008-12-22 | 2011-12-15 | Saint-Gobain Glass France | Substrate provided with a multilayer coating having thermal properties and absorbent layers |
US20120225317A1 (en) * | 2011-03-03 | 2012-09-06 | Guardian Industries Corp. | Barrier layers comprising Ni-inclusive ternary alloys, coated articles including barrier layers, and methods of making the same |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3039821A1 (de) * | 1980-10-22 | 1982-06-03 | Robert Bosch Gmbh, 7000 Stuttgart | Mehrschichtsystem fuer waermeschutzanwendung |
US5344718A (en) * | 1992-04-30 | 1994-09-06 | Guardian Industries Corp. | High performance, durable, low-E glass |
FR2728559B1 (fr) * | 1994-12-23 | 1997-01-31 | Saint Gobain Vitrage | Substrats en verre revetus d'un empilement de couches minces a proprietes de reflexion dans l'infrarouge et/ou dans le domaine du rayonnement solaire |
US5557462A (en) | 1995-01-17 | 1996-09-17 | Guardian Industries Corp. | Dual silver layer Low-E glass coating system and insulating glass units made therefrom |
US7879448B2 (en) | 2000-07-11 | 2011-02-01 | Guardian Industires Corp. | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US6887575B2 (en) | 2001-10-17 | 2005-05-03 | Guardian Industries Corp. | Heat treatable coated article with zinc oxide inclusive contact layer(s) |
US6576349B2 (en) | 2000-07-10 | 2003-06-10 | Guardian Industries Corp. | Heat treatable low-E coated articles and methods of making same |
FR2818272B1 (fr) * | 2000-12-15 | 2003-08-29 | Saint Gobain | Vitrage muni d'un empilement de couches minces pour la protection solaire et/ou l'isolation thermique |
US20030049464A1 (en) | 2001-09-04 | 2003-03-13 | Afg Industries, Inc. | Double silver low-emissivity and solar control coatings |
US6936347B2 (en) * | 2001-10-17 | 2005-08-30 | Guardian Industries Corp. | Coated article with high visible transmission and low emissivity |
US20040121165A1 (en) * | 2002-12-20 | 2004-06-24 | Laird Ronald E. | Coated article with reduced color shift at high viewing angles |
DE10322446A1 (de) | 2003-05-19 | 2004-12-09 | Henkel Kgaa | Vorbehandlung von Metalloberflächen vor einer Lackierung |
CN100567255C (zh) | 2003-07-10 | 2009-12-09 | 日产化学工业株式会社 | 光学活性β-羟基-α-氨基羧酸衍生物的制造方法 |
US7081302B2 (en) | 2004-02-27 | 2006-07-25 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including tin oxide interlayer |
US7217460B2 (en) | 2004-03-11 | 2007-05-15 | Guardian Industries Corp. | Coated article with low-E coating including tin oxide interlayer |
US7294402B2 (en) * | 2004-03-05 | 2007-11-13 | Guardian Industries Corp. | Coated article with absorbing layer |
US7150916B2 (en) | 2004-03-11 | 2006-12-19 | Centre Luxembourg De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including tin oxide interlayer for high bend applications |
US7585396B2 (en) * | 2004-06-25 | 2009-09-08 | Guardian Industries Corp. | Coated article with ion treated overcoat layer and corresponding method |
US7217461B2 (en) | 2004-09-01 | 2007-05-15 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US7198851B2 (en) | 2004-09-01 | 2007-04-03 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US7153578B2 (en) * | 2004-12-06 | 2006-12-26 | Guardian Industries Corp | Coated article with low-E coating including zirconium silicon oxynitride and methods of making same |
US7166359B2 (en) * | 2005-06-27 | 2007-01-23 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Blue colored coated article with low-E coating |
US7597964B2 (en) | 2005-08-02 | 2009-10-06 | Guardian Industries Corp. | Thermally tempered coated article with transparent conductive oxide (TCO) coating |
US7488538B2 (en) * | 2005-08-08 | 2009-02-10 | Guardian Industries Corp. | Coated article including soda-lime-silica glass substrate with lithium and/or potassium to reduce sodium migration and/or improve surface stability and method of making same |
FR2893023B1 (fr) * | 2005-11-08 | 2007-12-21 | Saint Gobain | Substrat muni d'un empilement a proprietes thermiques |
CL2007003233A1 (es) | 2006-11-09 | 2008-05-30 | Agc Flat Glass North America | Recubrimiento optico sobre un sustrato que comprende, en direccion hacia afuera desde el sustrato, una capa aumentadora de la durabilidad, una capa de nucleacion y una capa reflectante de infrarrojos; unidad de ventana; y metodo para hacer una pelicu |
US7901781B2 (en) * | 2007-11-23 | 2011-03-08 | Agc Flat Glass North America, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
JP2009155169A (ja) * | 2007-12-27 | 2009-07-16 | Asahi Glass Co Ltd | 熱線反射ガラス、および熱線反射ガラスの製造方法 |
US8263227B2 (en) * | 2008-06-25 | 2012-09-11 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including zirconium oxide and/or zirconium silicon oxynitride and methods of making same |
DE102008038653A1 (de) | 2008-08-12 | 2010-03-25 | Henkel Ag & Co. Kgaa | Sukzessive korrosionsschützende Vorbehandlung von Metalloberflächen in einem Mehrstufenprozess |
AU2009311325B2 (en) * | 2008-11-04 | 2014-05-08 | Apogee Enterprises, Inc. | Coated glass surfaces and method for coating a glass substrate |
FR2946639B1 (fr) * | 2009-06-12 | 2011-07-15 | Saint Gobain | Procede de depot de couche mince et produit obtenu. |
US9028956B2 (en) * | 2010-04-22 | 2015-05-12 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article having low-E coating with absorber layer(s) |
US8557391B2 (en) * | 2011-02-24 | 2013-10-15 | Guardian Industries Corp. | Coated article including low-emissivity coating, insulating glass unit including coated article, and/or methods of making the same |
US8679633B2 (en) * | 2011-03-03 | 2014-03-25 | Guardian Industries Corp. | Barrier layers comprising NI-inclusive alloys and/or other metallic alloys, double barrier layers, coated articles including double barrier layers, and methods of making the same |
US9017821B2 (en) | 2012-02-22 | 2015-04-28 | Guardian Industries Corp. | Coated article with low-E coating having multilayer overcoat and method of making same |
US9869016B2 (en) * | 2012-02-22 | 2018-01-16 | Guardian Glass, LLC | Coated article with low-E coating having multilayer overcoat and method of making same |
US9150003B2 (en) | 2012-09-07 | 2015-10-06 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
ES2732875T3 (es) * | 2013-03-12 | 2019-11-26 | Vitro Sab De Cv | Revestimientos de control solar que proporcionan mayor absorción o tinte |
-
2012
- 2012-09-07 US US13/606,276 patent/US9150003B2/en active Active
-
2013
- 2013-08-28 ES ES13762642T patent/ES2744493T3/es active Active
- 2013-08-28 MX MX2015002863A patent/MX2015002863A/es unknown
- 2013-08-28 RU RU2015112577A patent/RU2637003C2/ru active IP Right Revival
- 2013-08-28 WO PCT/US2013/056990 patent/WO2014039345A2/en active Application Filing
- 2013-08-28 KR KR1020157007760A patent/KR20150054863A/ko not_active Application Discontinuation
- 2013-08-28 EP EP13762642.0A patent/EP2892858B1/en not_active Not-in-force
- 2013-08-28 CN CN201380058130.4A patent/CN104936924A/zh active Pending
- 2013-08-28 IN IN1872DEN2015 patent/IN2015DN01872A/en unknown
- 2013-08-28 PL PL13762642T patent/PL2892858T3/pl unknown
- 2013-08-28 BR BR112015005017A patent/BR112015005017A2/pt not_active Application Discontinuation
- 2013-08-28 JP JP2015531126A patent/JP6324386B2/ja active Active
- 2013-09-03 TW TW106132823A patent/TWI630183B/zh not_active IP Right Cessation
- 2013-09-03 TW TW102131650A patent/TWI605027B/zh not_active IP Right Cessation
-
2015
- 2015-09-14 US US14/852,834 patent/US9328017B2/en active Active
-
2016
- 2016-04-14 US US15/098,344 patent/US9919961B2/en active Active
-
2018
- 2018-03-19 US US15/924,401 patent/US10112866B2/en active Active
- 2018-10-18 US US16/163,700 patent/US10487011B2/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5214530A (en) * | 1990-08-16 | 1993-05-25 | Flex Products, Inc. | Optically variable interference device with peak suppression and method |
CN1823023A (zh) * | 2003-07-16 | 2006-08-23 | 格拉沃贝尔公司 | 具有极低日光系数的涂覆基底 |
WO2006124503A2 (en) * | 2005-05-12 | 2006-11-23 | Agc Flat Glass North America, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
WO2006124503A3 (en) * | 2005-05-12 | 2007-11-29 | Afg Ind | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
US20080070044A1 (en) * | 2006-09-18 | 2008-03-20 | Richard Blacker | Coated article with low-E coating having absorbing layer designed to neutralize color at off-axis viewing angles |
EP2030954A1 (en) * | 2007-08-14 | 2009-03-04 | Cardinal CG Company | Solar control low-emissivity coatings |
US7648769B2 (en) * | 2007-09-07 | 2010-01-19 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layer designed for desirable bluish color at off-axis viewing angles |
US20110300319A1 (en) * | 2008-12-22 | 2011-12-08 | Saint-Gobain Glass France | Substrate provided with a multilayer coating having thermal properties and an absorbent layer |
US20110305853A1 (en) * | 2008-12-22 | 2011-12-15 | Saint-Gobain Glass France | Substrate provided with a multilayer coating having thermal properties and absorbent layers |
US20110261442A1 (en) * | 2010-04-22 | 2011-10-27 | Hartmut Knoll | Coated article having low-E coating with absorber layer(s) |
US20120225317A1 (en) * | 2011-03-03 | 2012-09-06 | Guardian Industries Corp. | Barrier layers comprising Ni-inclusive ternary alloys, coated articles including barrier layers, and methods of making the same |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9725358B2 (en) | 2012-11-19 | 2017-08-08 | Guardian Industries Corp. | Coated article with low-E coating including zinc oxide inclusive layer(s) with additional metal(s) |
CN106116178A (zh) * | 2016-08-13 | 2016-11-16 | 咸宁南玻节能玻璃有限公司 | 一种中反银灰色可弯钢双银低辐射镀膜玻璃及其制备方法 |
CN110461792A (zh) * | 2017-01-05 | 2019-11-15 | 佳殿玻璃有限公司 | 具有氮化钛和镍铬基ir反射层的可热处理涂覆制品 |
CN110461792B (zh) * | 2017-01-05 | 2022-08-02 | 佳殿玻璃有限公司 | 具有氮化钛和镍铬基ir反射层的可热处理涂覆制品 |
Also Published As
Publication number | Publication date |
---|---|
TW201827377A (zh) | 2018-08-01 |
EP2892858B1 (en) | 2019-06-19 |
JP6324386B2 (ja) | 2018-05-16 |
ES2744493T3 (es) | 2020-02-25 |
EP2892858A2 (en) | 2015-07-15 |
WO2014039345A2 (en) | 2014-03-13 |
KR20150054863A (ko) | 2015-05-20 |
TW201412674A (zh) | 2014-04-01 |
US9328017B2 (en) | 2016-05-03 |
US20140072784A1 (en) | 2014-03-13 |
JP2015529187A (ja) | 2015-10-05 |
US20160002102A1 (en) | 2016-01-07 |
US10487011B2 (en) | 2019-11-26 |
BR112015005017A2 (pt) | 2017-07-04 |
IN2015DN01872A (zh) | 2015-08-07 |
US9919961B2 (en) | 2018-03-20 |
RU2015112577A (ru) | 2016-11-10 |
WO2014039345A3 (en) | 2014-07-17 |
TWI605027B (zh) | 2017-11-11 |
TWI630183B (zh) | 2018-07-21 |
US20180208502A1 (en) | 2018-07-26 |
MX2015002863A (es) | 2015-10-09 |
RU2637003C2 (ru) | 2017-11-29 |
US20190047908A1 (en) | 2019-02-14 |
PL2892858T3 (pl) | 2020-03-31 |
US10112866B2 (en) | 2018-10-30 |
US9150003B2 (en) | 2015-10-06 |
US20160221866A1 (en) | 2016-08-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104936924A (zh) | 一种低辐射涂层中具有吸收层的低膜侧反射率和低可见光透射率的涂层制品 | |
CN104781203A (zh) | 一种低辐射涂层中具有吸收层的低膜侧反射率和低可见光透射率的涂层制品 | |
CN103958431B (zh) | 用于增加外反射率的功能层上带有吸收层的低辐射涂层制品 | |
CN104936925B (zh) | 具附加金属的含氧化锌层的低辐射涂层的涂层制品 | |
CN104837785A (zh) | 具有低可见光透射率的低辐射涂层的涂层制品 | |
CN105050979A (zh) | 具附加金属的含氧化锡层的低辐射涂层的涂层制品 | |
AU2012200149A1 (en) | Low Emissivity Coating with Low Solar Heat Gain Coefficient, Enhanced Chemical and Mechanical Properties and Method of Making the Same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
AD01 | Patent right deemed abandoned | ||
AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20200811 |