CN104910700A - 一种纳米抗菌防火涂料 - Google Patents
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Abstract
本发明公开一种纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25~35份、改性纳米沸石粉1~10份、纳米二氧化钛5~15份、无卤阻燃剂15~25份、成膜助剂2~7份、pH值调节剂1~5份、消泡剂3~9份、偶联剂4~12份、防沉剂1~5份、去离子水20~30份。本发明制备的纳米抗菌防火涂料，加入纳米二氧化钛，抗菌防霉性能优异。加入无卤阻燃剂，防火阻燃效果好、环保无毒，涂层附着力强、耐候性和耐水性好，适用于住宅、医院和写字楼的内外墙装饰装修领域。
Description
技术领域
本发明涉及涂料领域，尤其涉及一种纳米抗菌防火涂料。
背景技术
随着经济建设的不断加快，各种大型工业设施、商业建筑、地下建筑逐渐增多，潜在的火灾隐患也随之增加。为杜绝和减少火灾的损害，人们常在相应设施和建筑物的表面涂敷各种防火涂料，以便形成防火涂层来在一定的时间内保持涂覆物内部结构的完好。
防火涂料是用于可燃性基材表面，能降低被涂材料表面的可燃性、阻滞火灾的迅速蔓延，用以提高被涂材料耐火极限的一种特种涂料。然而，目前市场的防火涂料大多只具有阻燃性能，而抗菌功能不是很好，涂层表面容易滋生霉菌，因此具有抗菌防霉性能则略显薄弱。
纳米技术应用在涂料中，主要是使用荷叶双蔬机理，提高涂料的抗菌防霉性能。作为涂料，它是由多种化学成分组成，独特理化反应而成的。
发明内容
本发明的目的在于克服上述现有技术存在的不足，提供一种抗菌性能优异、阻燃效果和耐候性好的纳米抗菌防火涂料。
为达到上述目的，本发明是通过以下技术方案实现的：
一种纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25~35份、改性纳米沸石粉1~10份、纳米二氧化钛5~15份、无卤阻燃剂15~25份、成膜助剂2~7份、pH值调节剂1~5份、消泡剂3~9份、偶联剂4~12份、防沉剂1~5份、去离子水20~30份。
优选的，所述无卤阻燃剂为季戊四醇、氢氧化镁、氢氧化铝、三聚氰胺焦磷酸酯中的至少一种。
优选的，所述成膜助剂为丙二醇苯醚、十二碳醇酯、甲氧基丁醇中的至少一种。
优选的，所述pH值调节剂为氨水、乙醇胺中的至少一种。
优选的，所述消泡剂为二甲基硅油、聚醚改性有机硅、高碳醇中的至少一种。
优选的，所述偶联剂为硅烷偶联剂、铝酸酯偶联剂、钛酸酯偶联剂中的至少一种。
本发明的有益效果：
本发明制备的纳米抗菌防火涂料，加入纳米二氧化钛，抗菌防霉性能优异。加入无卤阻燃剂，防火阻燃效果好、环保无毒，涂层附着力强、耐候性和耐水性好，适用于住宅、医院和写字楼的内外墙装饰装修领域。
具体实施方式
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进。这些都属于本发明的保护范围。
一种纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25~35份、改性纳米沸石粉1~10份、纳米二氧化钛5~15份、无卤阻燃剂15~25份、成膜助剂2~7份、pH值调节剂1~5份、消泡剂3~9份、偶联剂4~12份、防沉剂1~5份、去离子水20~30份。
本发明制备的纳米抗菌防火涂料，具有抗菌性能优异、阻燃效果和耐候性好等优点。
实施例1
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25份、改性纳米沸石粉10份、纳米二氧化钛15份、季戊四醇15份、丙二醇苯醚7份、氨水5份、二甲基硅油3份、硅烷偶联剂12份、防沉剂5份、去离子水30份。
实施例2
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物35份、改性纳米沸石粉1份、纳米二氧化钛5份、季戊四醇25份、丙二醇苯醚2份、氨水、乙醇胺1份、聚醚改性有机硅9份、铝酸酯偶联剂4份、防沉剂1份、去离子水20份。
实施例3
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物30份、改性纳米沸石粉6份、纳米二氧化钛11份、氢氧化镁20份、甲氧基丁醇4份、氨水3份、高碳醇6份、钛酸酯偶联剂8份、防沉剂3份、去离子水25份。
实施例4
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物22份、改性纳米沸石粉3份、纳米二氧化钛7份、三聚氰胺焦磷酸酯17份、十二碳醇酯3份、乙醇胺2份、聚醚改性有机硅4份、铝酸酯偶联剂6份、防沉剂2份、去离子水23份。
实施例5
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物32份、改性纳米沸石粉8份、纳米二氧化钛12份、三聚氰胺焦磷酸酯22份、甲氧基丁醇5份、氨水4份、高碳醇7份、钛酸酯偶联剂10份、防沉剂4份、去离子水28份。
实施例6
本发明的纳米抗菌防火涂料，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25份、改性纳米沸石粉5份、纳米二氧化钛7份、季戊四醇22份、丙二醇苯醚2份、氨水5份、二甲基硅油9份、硅烷偶联剂8份、防沉剂1~5份、去离子水26份。
性能测试
本发明的主要技术性能如表1和表2所示：
表1
表2
从表1和表2可见，本发明制备的纳米抗菌防火涂料，具有抗菌性能优异、阻燃效果和耐候性好等优点。
以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变形或修改，这并不影响本发明的实质内容。
Claims (6)
1.一种纳米抗菌防火涂料，其特征在于，按重量份数计包括下列组分：乙烯-乙酸乙烯酯共聚物25~35份、改性纳米沸石粉1~10份、纳米二氧化钛5~15份、无卤阻燃剂15~25份、成膜助剂2~7份、pH值调节剂1~5份、消泡剂3~9份、偶联剂4~12份、防沉剂1~5份、去离子水20~30份。
2.根据权利要求1所述的纳米抗菌防火涂料，其特征在于：所述无卤阻燃剂为季戊四醇、氢氧化镁、氢氧化铝、三聚氰胺焦磷酸酯中的至少一种。
3. 根据权利要求1所述的纳米抗菌防火涂料，其特征在于：所述成膜助剂为丙二醇苯醚、十二碳醇酯、甲氧基丁醇中的至少一种。
4.根据权利要求1所述的纳米抗菌防火涂料，其特征在于：所述pH值调节剂为氨水、乙醇胺中的至少一种。
5.根据权利要求1所述的纳米抗菌防火涂料，其特征在于：所述消泡剂为二甲基硅油、聚醚改性有机硅、高碳醇中的至少一种。
6.根据权利要求1所述的纳米抗菌防火涂料，其特征在于：所述偶联剂为硅烷偶联剂、铝酸酯偶联剂、钛酸酯偶联剂中的至少一种。
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