CN104877501A - Multicolor paint for indoor wall and preparation method of multicolor paint - Google Patents

Multicolor paint for indoor wall and preparation method of multicolor paint Download PDF

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Publication number
CN104877501A
CN104877501A CN201510276751.0A CN201510276751A CN104877501A CN 104877501 A CN104877501 A CN 104877501A CN 201510276751 A CN201510276751 A CN 201510276751A CN 104877501 A CN104877501 A CN 104877501A
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China
Prior art keywords
parts
indoor wall
multicolor finish
vinyl
water
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CN201510276751.0A
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Chinese (zh)
Inventor
秦勇
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Suzhou De Xiang Decorative Engineering Co Ltd
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Suzhou De Xiang Decorative Engineering Co Ltd
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Priority to CN201510276751.0A priority Critical patent/CN104877501A/en
Publication of CN104877501A publication Critical patent/CN104877501A/en
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Abstract

The invention relates to a multicolor paint for an indoor wall and a preparation method of the multicolor paint. The multicolor paint comprises the following components in parts by mass: 30-44 parts of a silicone acrylic emulsion, 2-7 parts of a white emulsion, 4-10 parts of polyvinyl acetate, 20-30 parts of mica-titanium, 11-22 parts of calcium oxide, 3-9 parts of metal powder, 1-5 parts of glitter powder, 0.4-1.8 parts of lead phosphate, 3.5-9 parts of starch, 0.1-0.4 part of hydrogen peroxide, 2-8 parts of trimethylolpropane, 0.2-0.7 part of glycerin, 0.2-0.5 part of color paste, 0.5-1.5 parts of antimonous oxide, 0.1-0.3 part of dimethyl phosphate, 2-7 parts of triethylamine and 3-9 parts of water. The multicolor paint provided by the invention is high in decorating property, coating hardness and scrub resistance.

Description

A kind of indoor wall multicolor finish and preparation method thereof
Technical field
The present invention relates to decorative materials technology, particularly relates to a kind of indoor wall multicolor finish and preparation method thereof.
Background technology
Interior wall coating is exactly the emulsion paint generally fitted up.Namely emulsion paint is emulsion coating, according to the difference of base material, is divided into polyvinyl acetate emulsion and the large class of ACRYLIC EMULSION two.Emulsion paint is thinner with water, be a kind of easy construction, safe, water-fastness, good permeability coating, it can mix different color and lusters according to different scheme of colo(u)r.Emulsion paint is divided into water-based inner wall paint, oiliness interior wall paint, dry powder type interior wall paint.
The decorative effect of existing indoor wall coating is poor on the market at present, and color is few; Coating is hard not, easy to crack; Moistureproof poor air permeability, not easily aging, duration of service is short; Wash-resistant property is poor, scrubs rear easy delustering and fades.Such as Chinese invention patent (the patent No. 201410224024.5, the applying date 2014/05/24) disclose a kind of inner wall of building coating and preparation method thereof, this coating comprises the composite glue of 3.5 ~ 4.5 parts, the light calcium carbonate of 18 ~ 21 parts, the talcum of 4.5 ~ 5 parts, the water of 70 ~ 80 parts, the anti-settling agent of 1 ~ 2 part.By adopting the inner wall of building coating of mentioned component proportioning, in conjunction with cost performance and result of use, whitewashing of inner wall of building metope, there are good market outlook.But the decorative effect of this coating, coating hardness, wash-resistant property etc. are not high.
Summary of the invention
the technical problem solved:for the shortcoming such as existing interior wall coating decorative effect, coating hardness, wash-resistant property be not high, the invention provides a kind of indoor wall multicolor finish and preparation method thereof, the decorate properties of this coating, coating hardness, wash-resistant property are all higher.
technical scheme:a kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 30 ~ 44 parts, white glue with vinyl 2 ~ 7 parts, polyvinyl acetate (PVA) 4 ~ 10 parts, mica titanium 20 ~ 30 parts, 11 ~ 22 parts, calcium hydroxide, metal powder 3 ~ 9 parts, glitter powder 1 ~ 5 part, lead phosphate 0.4 ~ 1.8 part, starch 3.5 ~ 9 parts, 0.1 ~ 0.4 part, hydrogen peroxide, TriMethylolPropane(TMP) 2 ~ 8 parts, glycerol 0.2 ~ 0.7 part, mill base 0.2 ~ 0.5 part, antimonous oxide 0.5 ~ 1.5 part, dimethyl methyl phosphoesterase 30 .1 ~ 0.3 part, triethylamine 2 ~ 7 parts, 3 ~ 9 parts, water.
A kind of indoor wall multicolor finish described above, in mass parts containing following composition: organosilicon crylic acid latex 33 ~ 41 parts, white glue with vinyl 3 ~ 6 parts, polyvinyl acetate (PVA) 5 ~ 9 parts, mica titanium 23 ~ 28 parts, 13 ~ 20 parts, calcium hydroxide, metal powder 4 ~ 8 parts, glitter powder 2 ~ 4 parts, lead phosphate 0.7 ~ 1.5 part, starch 5 ~ 8 parts, 0.15 ~ 0.35 part, hydrogen peroxide, TriMethylolPropane(TMP) 3.5 ~ 7 parts, glycerol 0.3 ~ 0.6 part, mill base 0.28 ~ 0.43 part, antimonous oxide 0.7 ~ 1.3 part, dimethyl methyl phosphoesterase 30 .14 ~ 0.24 part, triethylamine 3 ~ 6 parts, 4 ~ 8 parts, water.
A kind of indoor wall multicolor finish described above, in mass parts containing following composition: organosilicon crylic acid latex 36 ~ 39 parts, white glue with vinyl 4 ~ 5.2 parts, polyvinyl acetate (PVA) 6 ~ 8 parts, mica titanium 25 ~ 27 parts, 15 ~ 18 parts, calcium hydroxide, metal powder 5 ~ 7 parts, glitter powder 2.7 ~ 3.4 parts, lead phosphate 0.9 ~ 1.2 part, starch 6 ~ 7 parts, 0.2 ~ 0.3 part, hydrogen peroxide, TriMethylolPropane(TMP) 4.6 ~ 6 parts, glycerol 0.38 ~ 0.52 part, mill base 0.31 ~ 0.4 part, antimonous oxide 0.9 ~ 1.2 part, dimethyl methyl phosphoesterase 30 .17 ~ 0.22 part, triethylamine 3.5 ~ 5 parts, 5 ~ 7 parts, water.
A kind of indoor wall multicolor finish described above, in mass parts containing following composition: organosilicon crylic acid latex 37 parts, white glue with vinyl 4.6 parts, polyvinyl acetate (PVA) 7 parts, mica titanium 26 parts, 16 parts, calcium hydroxide, metal powder 6 parts, glitter powder 3 parts, lead phosphate 1.1 parts, starch 6.5 parts, 0.25 part, hydrogen peroxide, TriMethylolPropane(TMP) 5.2 parts, glycerol 0.45 part, mill base 0.35 part, antimonous oxide 1 part, dimethyl methyl phosphoesterase 30 .19 part, triethylamine 4.3 parts, 6 parts, water.
The preparation method of a kind of indoor wall multicolor finish described above, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 70 ~ 90 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 40 ~ 60min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 50 ~ 70 DEG C, stirs 20 ~ 30min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 600 ~ 800r/min, is uniformly dispersed and obtains multicolor finish.
In the first step described above, water is added in reactor, be warming up to 80 DEG C, add organosilicon crylic acid latex and white glue with vinyl, be uniformly mixed 50min.
Be cooled to 60 DEG C in second step described above, stir 25min.
Control stirring velocity described above is 700r/min.
beneficial effect:a kind of indoor wall multicolor finish provided by the invention and preparation method thereof; good decorating effect, the color of this coating are varied; and its coating hardness, wash-resistant property, resistance to cleavage, moistureproof permeability are all very high; coating is not easy to crack, scrub after can not delustering be faded, the ageing-resistant life-span is long, there is the effect of well decoration and protection indoor wall.
Embodiment
embodiment 1
A kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 30 parts, white glue with vinyl 2 parts, polyvinyl acetate (PVA) 4 parts, mica titanium 20 parts, 11 parts, calcium hydroxide, metal powder 3 parts, glitter powder 1 part, lead phosphate 0.4 part, starch 3.5 parts, 0.1 part, hydrogen peroxide, TriMethylolPropane(TMP) 2 parts, glycerol 0.2 part, mill base 0.2 part, antimonous oxide 0.5 part, dimethyl methyl phosphoesterase 30 .1 part, triethylamine 2 parts, 3 parts, water.
A preparation method for indoor wall multicolor finish, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 70 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 40min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 50 DEG C, stirs 20min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 600r/min, is uniformly dispersed and obtains multicolor finish.
embodiment 2
A kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 44 parts, white glue with vinyl 7 parts, polyvinyl acetate (PVA) 10 parts, mica titanium 30 parts, 22 parts, calcium hydroxide, metal powder 9 parts, glitter powder 5 parts, lead phosphate 1.8 parts, starch 9 parts, 0.4 part, hydrogen peroxide, TriMethylolPropane(TMP) 8 parts, glycerol 0.7 part, mill base 0.5 part, antimonous oxide 1.5 parts, dimethyl methyl phosphoesterase 30 .3 part, triethylamine 7 parts, 9 parts, water.
A preparation method for indoor wall multicolor finish, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 90 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 60min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 70 DEG C, stirs 30min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 800r/min, is uniformly dispersed and obtains multicolor finish.
embodiment 3
A kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 33 parts, white glue with vinyl 3 parts, polyvinyl acetate (PVA) 5 parts, mica titanium 23 parts, 13 parts, calcium hydroxide, metal powder 4 parts, glitter powder 2 parts, lead phosphate 0.7 part, starch 5 parts, 0.15 part, hydrogen peroxide, TriMethylolPropane(TMP) 3.5 parts, glycerol 0.3 part, mill base 0.28 part, antimonous oxide 0.7 part, dimethyl methyl phosphoesterase 30 .14 part, triethylamine 3 parts, 4 parts, water.
A preparation method for indoor wall multicolor finish, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 80 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 50min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 60 DEG C, stirs 25min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 700r/min, is uniformly dispersed and obtains multicolor finish.
embodiment 4
A kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 36 parts, white glue with vinyl 4 parts, polyvinyl acetate (PVA) 6 parts, mica titanium 25 parts, 15 parts, calcium hydroxide, metal powder 5 parts, glitter powder 2.7 parts, lead phosphate 0.9 part, starch 6 parts, 0.2 part, hydrogen peroxide, TriMethylolPropane(TMP) 4.6 parts, glycerol 0.38 part, mill base 0.31 part, antimonous oxide 0.9 part, dimethyl methyl phosphoesterase 30 .17 part, triethylamine 3.5 parts, 5 parts, water.
A preparation method for indoor wall multicolor finish, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 80 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 50min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 60 DEG C, stirs 25min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 700r/min, is uniformly dispersed and obtains multicolor finish.
embodiment 5
A kind of indoor wall multicolor finish, in mass parts containing following composition: organosilicon crylic acid latex 37 parts, white glue with vinyl 4.6 parts, polyvinyl acetate (PVA) 7 parts, mica titanium 26 parts, 16 parts, calcium hydroxide, metal powder 6 parts, glitter powder 3 parts, lead phosphate 1.1 parts, starch 6.5 parts, 0.25 part, hydrogen peroxide, TriMethylolPropane(TMP) 5.2 parts, glycerol 0.45 part, mill base 0.35 part, antimonous oxide 1 part, dimethyl methyl phosphoesterase 30 .19 part, triethylamine 4.3 parts, 6 parts, water.
A preparation method for indoor wall multicolor finish, the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 80 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 50min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 60 DEG C, stirs 25min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 700r/min, is uniformly dispersed and obtains multicolor finish.
comparative example 1
Patent of invention publication number is that the patent of CN 103979832A comprises the steps:
Step one: according to aforementioned proportion composite glue, light calcium carbonate, talcum and anti-settling agent poured in stirrer and stir;
Step 2: to be poured in stirrer by water according to aforementioned proportion and stir, churning time is 5 ~ 10 minutes, stirs after terminating and can obtain.
The above-mentioned technical performance index stating the coating of the coating of embodiment 1 ~ embodiment 5 and comparative example 1, its detected result is as follows:
Test item Technical indicator Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 1
Sticking power GB/T9286 1 grade 1 grade 1 grade 1 grade 1 grade 1 grade
Abrasion resistance GB/T9266-1988 8025 times 8032 times 8027 times 8034 times 8037 times 4215 times
Work-ing life 11 years 11 years 12 years 12 years 13 years 5 years
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (8)

1. an indoor wall multicolor finish, to it is characterized in that in mass parts containing following composition: organosilicon crylic acid latex 30 ~ 44 parts, white glue with vinyl 2 ~ 7 parts, polyvinyl acetate (PVA) 4 ~ 10 parts, mica titanium 20 ~ 30 parts, 11 ~ 22 parts, calcium hydroxide, metal powder 3 ~ 9 parts, glitter powder 1 ~ 5 part, lead phosphate 0.4 ~ 1.8 part, starch 3.5 ~ 9 parts, 0.1 ~ 0.4 part, hydrogen peroxide, TriMethylolPropane(TMP) 2 ~ 8 parts, glycerol 0.2 ~ 0.7 part, mill base 0.2 ~ 0.5 part, antimonous oxide 0.5 ~ 1.5 part, dimethyl methyl phosphoesterase 30 .1 ~ 0.3 part, triethylamine 2 ~ 7 parts, 3 ~ 9 parts, water.
2. a kind of indoor wall multicolor finish according to claim 1, to it is characterized in that in mass parts containing following composition: organosilicon crylic acid latex 33 ~ 41 parts, white glue with vinyl 3 ~ 6 parts, polyvinyl acetate (PVA) 5 ~ 9 parts, mica titanium 23 ~ 28 parts, 13 ~ 20 parts, calcium hydroxide, metal powder 4 ~ 8 parts, glitter powder 2 ~ 4 parts, lead phosphate 0.7 ~ 1.5 part, starch 5 ~ 8 parts, 0.15 ~ 0.35 part, hydrogen peroxide, TriMethylolPropane(TMP) 3.5 ~ 7 parts, glycerol 0.3 ~ 0.6 part, mill base 0.28 ~ 0.43 part, antimonous oxide 0.7 ~ 1.3 part, dimethyl methyl phosphoesterase 30 .14 ~ 0.24 part, triethylamine 3 ~ 6 parts, 4 ~ 8 parts, water.
3. a kind of indoor wall multicolor finish according to claim 1, to it is characterized in that in mass parts containing following composition: organosilicon crylic acid latex 36 ~ 39 parts, white glue with vinyl 4 ~ 5.2 parts, polyvinyl acetate (PVA) 6 ~ 8 parts, mica titanium 25 ~ 27 parts, 15 ~ 18 parts, calcium hydroxide, metal powder 5 ~ 7 parts, glitter powder 2.7 ~ 3.4 parts, lead phosphate 0.9 ~ 1.2 part, starch 6 ~ 7 parts, 0.2 ~ 0.3 part, hydrogen peroxide, TriMethylolPropane(TMP) 4.6 ~ 6 parts, glycerol 0.38 ~ 0.52 part, mill base 0.31 ~ 0.4 part, antimonous oxide 0.9 ~ 1.2 part, dimethyl methyl phosphoesterase 30 .17 ~ 0.22 part, triethylamine 3.5 ~ 5 parts, 5 ~ 7 parts, water.
4. a kind of indoor wall multicolor finish according to claim 1, to is characterized in that in mass parts containing following composition: organosilicon crylic acid latex 37 parts, white glue with vinyl 4.6 parts, polyvinyl acetate (PVA) 7 parts, mica titanium 26 parts, 16 parts, calcium hydroxide, metal powder 6 parts, glitter powder 3 parts, lead phosphate 1.1 parts, starch 6.5 parts, 0.25 part, hydrogen peroxide, TriMethylolPropane(TMP) 5.2 parts, glycerol 0.45 part, mill base 0.35 part, antimonous oxide 1 part, dimethyl methyl phosphoesterase 30 .19 part, triethylamine 4.3 parts, 6 parts, water.
5. the preparation method of a kind of indoor wall multicolor finish as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
The first step: added by water in reactor, is warming up to 70 ~ 90 DEG C, adds organosilicon crylic acid latex and white glue with vinyl, is uniformly mixed 40 ~ 60min;
Second step: add polyvinyl acetate (PVA), hydrogen peroxide, TriMethylolPropane(TMP), glycerol, triethylamine in reactor, is cooled to 50 ~ 70 DEG C, stirs 20 ~ 30min to mixing;
3rd step: adding mica titanium, calcium hydroxide, metal powder, glitter powder, lead phosphate, starch, mill base, antimonous oxide, dimethyl methyl phosphorodithioate in reactor, control stirring velocity is 600 ~ 800r/min, is uniformly dispersed and obtains multicolor finish.
6. the preparation method of a kind of indoor wall multicolor finish according to claim 5, is characterized in that: add in reactor by water in the described the first step, is warming up to 80 DEG C, add organosilicon crylic acid latex and white glue with vinyl, be uniformly mixed 50min.
7. the preparation method of a kind of indoor wall multicolor finish according to claim 5, is characterized in that: be cooled to 60 DEG C in described second step, stirs 25min.
8. the preparation method of a kind of indoor wall multicolor finish according to claim 5, is characterized in that: described control stirring velocity is 700r/min.
CN201510276751.0A 2015-05-27 2015-05-27 Multicolor paint for indoor wall and preparation method of multicolor paint Pending CN104877501A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1131173A (en) * 1995-03-11 1996-09-18 韩景耀 Series pearl multi-colour paint and production method
CN1138608A (en) * 1995-12-27 1996-12-25 吴钢 Water-based color pattern spraying coating
CN201380617Y (en) * 2009-03-25 2010-01-13 王炳阳 Adhesive sticker film for flashing decorations
JP2013221033A (en) * 2012-04-12 2013-10-28 Shikoku Chem Corp Water-based coating material composition and wall surface decoration method
CN104403447A (en) * 2014-11-13 2015-03-11 无锡中洁能源技术有限公司 Solar energy-resistant coating used for building outer wall and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1131173A (en) * 1995-03-11 1996-09-18 韩景耀 Series pearl multi-colour paint and production method
CN1138608A (en) * 1995-12-27 1996-12-25 吴钢 Water-based color pattern spraying coating
CN201380617Y (en) * 2009-03-25 2010-01-13 王炳阳 Adhesive sticker film for flashing decorations
JP2013221033A (en) * 2012-04-12 2013-10-28 Shikoku Chem Corp Water-based coating material composition and wall surface decoration method
CN104403447A (en) * 2014-11-13 2015-03-11 无锡中洁能源技术有限公司 Solar energy-resistant coating used for building outer wall and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周建国等: "《精细无机化工》", 31 March 1999 *

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Application publication date: 20150902