CN1048750C - Solid buffing compound - Google Patents
Solid buffing compound Download PDFInfo
- Publication number
- CN1048750C CN1048750C CN93118984A CN93118984A CN1048750C CN 1048750 C CN1048750 C CN 1048750C CN 93118984 A CN93118984 A CN 93118984A CN 93118984 A CN93118984 A CN 93118984A CN 1048750 C CN1048750 C CN 1048750C
- Authority
- CN
- China
- Prior art keywords
- polishing
- water
- agent
- solid
- soluble surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- Polishing Bodies And Polishing Tools (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention relates to a solid polishing agent made from polishing powder and adhesives, wherein the adhesives use enough water-soluble surfactants and/or poly(alkylene)diol as a midbody, and the adhesives having a smelting point higher than 30 DEG C can be dissolved in water. Polishing residues attached to products can be easily washed with water after being utilized.
Description
The present invention is the relevant solid polishing agent that uses in the metal manufacture field (being commonly referred to green frotton, white frotton, red frotton).
The solid polishing agent that uses during polished metal surface was that polishing powder and the tackiness agent be made up of lipid such as paraffin class, lipid acid are mixed together in the past, made it attached on the selected polishing wheel metallic surface being polished.
And after the polishing, because have on polishing powder and lipid etc. (calling polishing slag (バ Off カ ス) in the following text) metallic surface attached to goods, so will wash, remove above-mentioned polishing slag to goods.But, as mentioned above, owing to contain lipid in the polishing slag, only wash with water and be difficult to remove, thereby, normally wash for a long time, or use organic solvent flushing such as trieline with the high-temperature water solution that is dissolved with tensio-active agent, also sometimes as required, use ultrasonic wave to wash.
Therefore, the flushing operation of polishing slag is pretty troublesome, time-consuming, also can bring variety of problems to aspects such as operator's safety and sanitation, public hazards when using as organic solvents such as trielines.
The present invention is in view of this former thereby carry out, and the purpose of this invention is to provide the simple flushing of water just can be the clean solid polishing agent of polishing slag removing.
First invention based on the relevant solid polishing agent of above-mentioned purpose is the solid polishing agent that is mixed by polishing powder and tackiness agent, and wherein, tackiness agent is that the water soluble surfactant active and/or its intermediate polyalkylene glycol that adopt fusing point to be higher than 30 ℃ constitute.
In addition, second invention based on above-mentioned purpose is to mix in the solid polishing agent that forms at polishing powder and tackiness agent, tackiness agent is by the mixture of forming with water soluble surfactant active and/or its intermediate polyalkylene glycol more than a kind or 2 kinds in all compositions of lipid, higher alcohols, oil soluble surfactant, metallic soap and paraffin, and the fusing point of this mixture is higher than 30 ℃, is again to adopt to have water miscible material and constitute.Here said oil soluble surfactant is an oil-soluble but water insoluble or be insoluble in the material of water, for example, and various fatty acid ester compounds etc.
In above-mentioned the first and second two inventions, why tackiness agent wherein uses fusing point to be higher than 30 ℃ material, is because if fusing point is lower than 30 ℃, can liquefy at normal temperatures or softening, so just can not use as solid polishing agent.Have again, as consider actual materials used and environment for use, preferably use fusing point to be 40-80 ℃ above-mentioned substance.
In the solid polishing agent of relevant first invention, because what tackiness agent wherein used is water soluble surfactant active and/or its intermediate polyalkylene glycol, if so the flushing of the polishing slag water after the polishing, tackiness agent will be water-soluble, thereby just the polishing slag can be rinsed out.
And, when selecting water soluble surfactant active and/or its intermediate polyalkylene glycol, because of what choose is that fusing point is higher than 30 ℃, so at normal temperatures for solid-state, have same use feeling therefore can use when mixing with the solid polishing agent of selling on the market that is known as green frotton, white frotton with an amount of polishing powder.
In the solid polishing agent of relevant second invention, wherein tackiness agent is by the mixture of forming with water soluble surfactant active and/or its intermediate polyalkylene glycol more than a kind or 2 kinds in all compositions of lipid, higher alcohols, oil soluble surfactant, metallic soap and paraffin, the fusing point of this mixture is higher than 30 ℃, simultaneously is again to have adopted water-soluble substances, if therefore slag is polished in the water flushing after polishing, this mixture is just water-soluble, and polishing cleaning of slag thus may also just become.
Below, with specific embodiment the present invention is described, for better understanding the present invention.
Embodiment 1
In the beaker of stainless steel, put into 800g polishing chromium oxide powder (Cr
2O
3) and 200g polyoxyethylene glycol (HO (CH
2CH
2O) nCH
2CH
2OH) (specific examples of polyalkylene glycol), heating all becomes paste to it while stirring, and it is flowed in the aluminium vessel, and the cooling back is taken out and has just been obtained solid polishing agent.Polish with its goods that stainless material is done, clean these goods then, the situation of polishing is with identical in the past, and simply washes with normal-temperature water and to get final product.
Embodiment 2
To polish with aluminum oxide (Al
2O
3) powder 700g and water soluble surfactant active, for example, polyoxyethylene polyoxytrimethylene glycol ether 300g packs in the beaker of stainless steel, heat while stirring, all become paste to it, it is flowed in the aluminium vessel, and take out the cooling back, promptly obtains solid polishing agent.Polish test-results with it and show, the polishing situation is with identical in the past, and simply washes with normal-temperature water and to get final product.In addition, the chemical formula of polyoxyethylene polyoxytrimethylene glycol ether can be represented by the formula:
M, n, p are the integer representation polymerization degree in the formula.
Embodiment 3
With 800g polishing chromic oxide (Cr
2O
3) powder and water soluble surfactant active, for example polyoxyethylene fatty acid esters (RCOO (CH
2CH
2O) nCOR) 100g and polyalkylene glycol, for example polyoxyethylene glycol (HO (CH
2CH
2O) nCH
2CH
2OH) 100g puts into the beaker of stainless steel, and heating while stirring is to all becoming paste.It is flowed in aluminium vessel, take out behind the cooling curing, polish, detergency test, the result shows that the polishing situation is compared with the past does not have any difference, just can clean simply with normal-temperature water.
Embodiment 4
To polish with aluminum oxide (Al
2O
3) powder 700g and water soluble surfactant active, for example polyethylene oxide alkyl ethers phosphoric acid ester 300g puts into stainless Steel Beaker, heat while stirring,, make it flow in the aluminium vessel, behind the cooling curing, take out and polish detergency test to all becoming paste.The polishing situation is compared with the past not to have anything to change, and just can clean simply with normal-temperature water.In addition, the chemical formula of polyethylene oxide alkyl ethers phosphoric acid ester can be represented by the formula:
A, B represent H or R-O-(CH in the formula
2CH
2O) n, n are the integer representation polymerization degree.
Embodiment 5
With 800g polishing chromic oxide (Cr
2O
3) powder and water soluble surfactant active, for example polyoxyethylene alkylbenzene phenolic ether 200g puts into stainless Steel Beaker, heating while stirring, to all becoming the paste shape, it is flowed in the aluminium vessel, take out behind the cooling curing polish, detergency test, the result shows that the polishing situation is compared with the past does not have anything to change, and just can clean simply with normal-temperature water.In addition, the chemical formula of polyoxyethylene alkylbenzene phenolic ether can be represented by the formula:
In the formula, R represents alkyl.
Embodiment 6
To polish with aluminum oxide (Al
2O
3) powder 700g and water soluble surfactant active, for example polyoxyethylene polyoxypropylene block copolymers 300g puts into stainless Steel Beaker, and being heated to whole mixtures while stirring becomes the paste shape.It is flowed in aluminium vessel, take out behind the cooling curing polish, detergency test, the result shows that the polishing situation is compared with the past does not have a difference, just can clean simply with normal-temperature water.The chemical formula of polyoxyethylene polyoxypropylene block copolymers in addition can be represented by the formula:
L, m, n are integers in the formula, the expression polymerization degree.
Embodiment 7
With polishing powder aluminum oxide (Al
2O
3) 750g and lipid acid, for example stearic acid (CH
3(CH
2)
15COOH) 150g and water soluble surfactant active, for example polyoxyethylene dehydration sorb (sugar) alcohol fatty acid ester 100g puts into beaker, and heating to becoming viscosity mud shape thing, is injected in the mold case of stainless steel while stirring, and cooling is solidified at normal temperatures.Polish test with its component,, on usability, do not have what variation with the solid polishing agent comparison of same system in the past to stainless steel.Wash available water at low temperature and carry out, dipping time shortens to 1/3 under the uniform temp condition.In addition, the chemical formula of polyoxyethylene dehydration sorb (sugar) alcohol fatty acid ester can be represented by the formula:
R represents alkyl in the formula; N is the integer representation polymerization degree.
Embodiment 8
With polishing powder chromic oxide (Cr
2O
3) 750g and lipid acid, for example palmitinic acid (CH
3(CH
2)
14COOH) 100g, solidified oil 50g and water soluble surfactant active, for example fatty acid polyglycol ester (RCOO (CH
2CH
2O) nCOR) 100g puts into beaker, and the promptly difficult one-tenth viscosity of heating while stirring mud shape thing is injected in the mold case of stainless steel, cools off, solidifies at normal temperatures.
Polish test with its component to stainless steel, compare with the solid polishing agent of same system in the past, usability does not almost change.Simultaneously, available water at low temperature is cleaned operation, and dipping time shortens 1/2 under uniform temp.
Embodiment 9
With polishing powder silicon-dioxide (Sio
2) 750g and lipid acid, for example 22 (carbon) alkanoic acid (CH
3(CH
2)
20COOH) 100g, higher alcohols 50g and water soluble surfactant active, for example polyoxyethylene nonyl phenylate
(CH
2CH
2O) nH) 100g puts into beaker, heats while stirring promptly to form viscosity mud shape thing, is injected in the mold case of stainless steel cooling, curing at normal temperatures.Polish test with its component to stainless steel.Comparing with the solid polishing agent of same system does not in the past almost change on usability, just can clean operation with water at low temperature, and dipping time shortens 1/2 under uniform temp.
Embodiment 10
With polishing powder aluminum oxide (Al
2O
3) 750g and lipid acid, for example stearic acid (CH
3(CH
2)
16COOH) 150g and polyalkylene glycol, for example, polyoxyethylene glycol (HO (CH
2CH
2O) nCH
2CH
2OH) 100g puts into beaker, and heating while stirring promptly forms viscosity mud shape thing, is injected in the mold case of stainless steel cooling, curing at normal temperatures.
Polish test with its component to stainless steel.Compare with the solid polishing agent of same system in the past, on usability, almost do not change.Just can clean operation with water at low temperature, dipping time shortens 1/2 under uniform temp.
Embodiment 11
With polishing powder aluminum oxide (Al
2O
3) 750g and oil soluble surfactant, for example sorbitan stearate 150g and water soluble surfactant active, for example polyoxyethylene nonylplenyl ether (
) 100g puts into beaker, heating while stirring promptly forms the mud shape thing of viscosity, is injected in the mold case of stainless steel, cooling, solidifies at normal temperatures.
Polish test with its component to stainless steel.Compare with the solid polishing agent of in the past same system, almost do not change on usability, the goods after the use clean also and are very easy to.In addition, the chemical formula of sorbitan stearate.For example, can represent with following formula:
Can obviously learn from above explanation, in solid polishing agent about the 1st and the 2nd invention, because of the tackiness agent water soluble, thus can wash easily attached to the polishing slag on the goods, and insoluble in all the other washing composition, solvent, can make simplified equipment.
And no matter warm water still is cold water can both be cleaned, and along with the simplification of flushing operation, washing time also can shorten.
Claims (3)
1. solid polishing agent, it is mixed by polishing powder and tackiness agent, is to be attached on the polishing wheel, the metallic surface is polished the solid polishing agent of usefulness, it is characterized in that, in the described tackiness agent, adopt to have the water soluble surfactant active of water miscible fusing point 40~80 ℃ of scopes.
2. solid polishing agent, it is mixed by polishing powder and tackiness agent, is to be attached on the polishing wheel, the metallic surface is polished the solid polishing agent of usefulness, it is characterized in that adopt in the described tackiness agent to have water misciblely, fusing point is at the polyalkylene glycol of 40~80 ℃ of scopes.
3. solid polishing agent, it is mixed by polishing powder and tackiness agent, be to be attached on the polishing wheel, the solid polishing agent of usefulness is polished in the metallic surface, it is characterized in that, in the described tackiness agent, adopt a kind of mixture of forming by water soluble surfactant active and this water soluble surfactant active's intermediate polyalkylene glycol, and the fusing point of this mixture is 40~80 ℃ scope, and has water-soluble.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP04257116A JP3108547B2 (en) | 1992-08-11 | 1992-08-11 | Easy-to-clean solid buffing abrasive |
CN93118984A CN1048750C (en) | 1992-08-11 | 1993-09-07 | Solid buffing compound |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP04257116A JP3108547B2 (en) | 1992-08-11 | 1992-08-11 | Easy-to-clean solid buffing abrasive |
CN93118984A CN1048750C (en) | 1992-08-11 | 1993-09-07 | Solid buffing compound |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1100125A CN1100125A (en) | 1995-03-15 |
CN1048750C true CN1048750C (en) | 2000-01-26 |
Family
ID=36869984
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN93118984A Expired - Fee Related CN1048750C (en) | 1992-08-11 | 1993-09-07 | Solid buffing compound |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP3108547B2 (en) |
CN (1) | CN1048750C (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2547373B2 (en) * | 1993-07-23 | 1996-10-23 | 茂雄 依田 | Oily buff abrasive containing surfactant or degreasing agent |
JP3640317B2 (en) * | 1995-04-13 | 2005-04-20 | 昭和電工株式会社 | Texturing composition |
JP4866503B2 (en) * | 1998-12-28 | 2012-02-01 | 日立化成工業株式会社 | Metal polishing liquid material and metal polishing liquid |
KR100761649B1 (en) * | 1999-05-19 | 2007-09-27 | 제일모직주식회사 | Composition for polishing |
DE102007032004A1 (en) | 2007-07-09 | 2009-01-15 | Manroland Ag | Method for controlling an inkjet printing device |
CN103666279A (en) * | 2012-09-24 | 2014-03-26 | 天津博克尼科技发展有限公司 | Anti-static vehicle paint surface body polishing emulsion wax |
CN102990536B (en) * | 2012-12-26 | 2015-06-24 | 冉许润 | Knife sharpening strop |
CN115651608B (en) * | 2022-10-31 | 2024-03-26 | 太仓硅源纳米材料有限公司 | Preparation method and application of nano aluminum oxide composite abrasive particles |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4071333A (en) * | 1976-10-18 | 1978-01-31 | American Cyanamid Company | Abrasive scouring block (and support therefor) |
JPS62297062A (en) * | 1986-06-16 | 1987-12-24 | Yushiro Chem Ind Co Ltd | Lapping agent composition and manufacture thereof |
-
1992
- 1992-08-11 JP JP04257116A patent/JP3108547B2/en not_active Expired - Fee Related
-
1993
- 1993-09-07 CN CN93118984A patent/CN1048750C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4071333A (en) * | 1976-10-18 | 1978-01-31 | American Cyanamid Company | Abrasive scouring block (and support therefor) |
JPS62297062A (en) * | 1986-06-16 | 1987-12-24 | Yushiro Chem Ind Co Ltd | Lapping agent composition and manufacture thereof |
Also Published As
Publication number | Publication date |
---|---|
JPH06122868A (en) | 1994-05-06 |
CN1100125A (en) | 1995-03-15 |
JP3108547B2 (en) | 2000-11-13 |
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GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |