CN104870484B - 加成-断裂低聚物 - Google Patents

加成-断裂低聚物 Download PDF

Info

Publication number
CN104870484B
CN104870484B CN201380065942.1A CN201380065942A CN104870484B CN 104870484 B CN104870484 B CN 104870484B CN 201380065942 A CN201380065942 A CN 201380065942A CN 104870484 B CN104870484 B CN 104870484B
Authority
CN
China
Prior art keywords
meth
acrylate
group
weight
addition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380065942.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN104870484A (zh
Inventor
A·R·弗诺夫
W·H·莫泽
L·R·克雷普斯基
G·D·乔利
A·S·阿比尔雅曼
A·法尔萨菲
B·N·加达姆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN104870484A publication Critical patent/CN104870484A/zh
Application granted granted Critical
Publication of CN104870484B publication Critical patent/CN104870484B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C19/00—Dental auxiliary appliances
    • A61C19/06—Implements for therapeutic treatment
    • A61C19/063—Medicament applicators for teeth or gums, e.g. treatment with fluorides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A61K6/889—Polycarboxylate cements; Glass ionomer cements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/02—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from isocyanates with formation of carbamate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/16—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/604—Polycarboxylic acid esters, the acid moiety containing more than two carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Dental Preparations (AREA)
CN201380065942.1A 2012-12-17 2013-11-27 加成-断裂低聚物 Active CN104870484B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261738067P 2012-12-17 2012-12-17
US61/738,067 2012-12-17
PCT/US2013/072250 WO2014099317A1 (en) 2012-12-17 2013-11-27 Addition-fragmentation oligomers

Publications (2)

Publication Number Publication Date
CN104870484A CN104870484A (zh) 2015-08-26
CN104870484B true CN104870484B (zh) 2016-11-23

Family

ID=49780392

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380065942.1A Active CN104870484B (zh) 2012-12-17 2013-11-27 加成-断裂低聚物

Country Status (6)

Country Link
US (1) US9463146B2 (cg-RX-API-DMAC10.html)
EP (1) EP2931756B1 (cg-RX-API-DMAC10.html)
JP (1) JP6306044B2 (cg-RX-API-DMAC10.html)
KR (1) KR102008353B1 (cg-RX-API-DMAC10.html)
CN (1) CN104870484B (cg-RX-API-DMAC10.html)
WO (1) WO2014099317A1 (cg-RX-API-DMAC10.html)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014151363A1 (en) 2013-03-20 2014-09-25 3M Innovative Properties Company High refractive index addition-fragmentation agents
US9675529B2 (en) 2013-04-15 2017-06-13 3M Innovative Properties Company Dental composition containing high refractive index monomers
EP3046962B1 (en) 2013-09-20 2018-05-23 3M Innovative Properties Company Trithiocarbonate-containing addition-fragmentation agents
JP6138366B2 (ja) 2013-10-16 2017-05-31 スリーエム イノベイティブ プロパティズ カンパニー アリルジスルフィド含有付加開裂オリゴマー
JP6647206B2 (ja) * 2014-02-18 2020-02-14 スリーエム イノベイティブ プロパティズ カンパニー 高屈折率基を有する付加開裂オリゴマー
EP3212153A1 (en) 2014-10-31 2017-09-06 3M Innovative Properties Company Dental materials and methods
US10350297B2 (en) 2014-10-31 2019-07-16 3M Innovative Properties Company Dental materials and methods
EP3259323B1 (en) * 2015-02-20 2020-02-26 3M Innovative Properties Company Addition-fragmentation oligomers
US10492888B2 (en) 2015-07-07 2019-12-03 Align Technology, Inc. Dental materials using thermoset polymers
KR20190031505A (ko) * 2016-07-20 2019-03-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 양자점을 위한 안정화 스티렌계 중합체
CN109890888B (zh) * 2016-10-27 2021-11-12 3M创新有限公司 包含(甲基)丙烯酸类聚合物的可交联组合物以及制备交联组合物的方法
US11952447B2 (en) * 2018-03-30 2024-04-09 Mitsui Chemicals, Inc. Polymerizable composition for dental material, and dental material obtained from said composition
CN116640061A (zh) * 2018-05-04 2023-08-25 阿莱恩技术有限公司 可聚合单体及其聚合方法
KR102935711B1 (ko) 2018-05-04 2026-03-09 얼라인 테크널러지, 인크. 고온 석판인쇄-기반 광중합 공정에서 사용하기 위한 경화형 조성물 및 이로부터 가교 중합체를 제조하는 방법
CN114144386B (zh) 2019-05-24 2023-11-17 科思创(荷兰)有限公司 具有增强的高速可加工性的用于涂覆光纤的辐射可固化组合物
DE102019122174A1 (de) 2019-08-19 2021-02-25 Voco Gmbh Dentale polymerisierbare Zusammensetzung auf der Basis kondensierter Silane
US12215223B2 (en) 2019-10-31 2025-02-04 Align Technology, Inc. Crystallizable resins
WO2022096973A1 (en) * 2020-11-05 2022-05-12 3M Innovative Properties Company Imide addition-fragmentation agents
EP4444809A1 (en) 2021-12-06 2024-10-16 3M Innovative Properties Company Adhesives comprising cyclic imide addition-fragmentation and adhesion agents
US12618138B2 (en) 2021-12-21 2026-05-05 Corning Incorporated Anti-reflective coatings for IR-transmitting substrates

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2801185A (en) 1952-05-16 1957-07-30 Du Pont Silica hydrosol powder
US3496250A (en) 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
US4522958A (en) 1983-09-06 1985-06-11 Ppg Industries, Inc. High-solids coating composition for improved rheology control containing chemically modified inorganic microparticles
US4547323A (en) 1984-03-21 1985-10-15 Scm Corporation Synthesis of 2,2-dimethyl-4-methyleneglutaric acid and derivatives
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
US4886861A (en) 1985-04-23 1989-12-12 E. I. Dupont De Nemours And Company Molecular weight control in free radical polymerizations
US5324879A (en) 1985-12-03 1994-06-28 Commonwealth Scientific And Industrial Research Organisation Oligomerization process
US4621131A (en) 1986-02-06 1986-11-04 Scm Corporation Polyesters derived from 2,2-dimethyl-4-methyleneglutaric acid and coatings prepared therefrom
CA1323949C (en) 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
AU618772B2 (en) 1987-12-30 1992-01-09 Minnesota Mining And Manufacturing Company Photocurable ionomer cement systems
JPH0374311A (ja) * 1989-08-14 1991-03-28 Mitsubishi Rayon Co Ltd 歯科用材料
US5154762A (en) 1991-05-31 1992-10-13 Minnesota Mining And Manufacturing Company Universal water-based medical and dental cement
US5506279A (en) 1993-10-13 1996-04-09 Minnesota Mining And Manufacturing Company Acrylamido functional disubstituted acetyl aryl ketone photoinitiators
US5501727A (en) 1994-02-28 1996-03-26 Minnesota Mining And Manufacturing Company Color stability of dental compositions containing metal complexed ascorbic acid
US6126922A (en) 1995-11-17 2000-10-03 3M Innovative Properties Company Fluorid-releasing compositions and compositions with improved rheology
JP4083257B2 (ja) 1997-03-19 2008-04-30 株式会社ジーシー 歯科充填用レジン組成物
DE19943712C1 (de) 1999-09-08 2001-05-17 Ivoclar Ag Schaan Hydrolysierbare und polymerisierbare Silane auf der Basis von Methylendithiepan
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6572693B1 (en) 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
DE60022667T2 (de) 1999-10-28 2006-06-14 3M Innovative Properties Co Dentalmaterialien mit siliciumdioxid-nanoteilchen
EP1244754A1 (en) 1999-11-22 2002-10-02 3M Innovative Properties Company Water-based coating composition
US6794317B2 (en) 2000-04-26 2004-09-21 Creare Inc. Protective cover system including a corrosion inhibitor
US6586483B2 (en) 2001-01-08 2003-07-01 3M Innovative Properties Company Foam including surface-modified nanoparticles
DE10106372A1 (de) 2001-02-12 2002-08-29 Ivoclar Vivadent Ag Thermochromer Dentalwerkstoff
CN100415198C (zh) 2001-08-15 2008-09-03 3M创新有限公司 可硬化的自支撑结构和方法
DE50203474D1 (de) 2001-12-21 2005-07-28 Siemens Ag Vorrichtung zum erfassen und darstellen von bewegungen
CN1319507C (zh) 2002-01-31 2007-06-06 3M创新有限公司 牙科糊剂、牙科制品和方法
US6860084B2 (en) 2002-03-18 2005-03-01 Frito-Lay North America, Inc. Vertical stand-up pouch with zipper seal quick change module
US6762257B1 (en) * 2003-05-05 2004-07-13 3M Innovative Properties Company Azlactone chain transfer agents for radical polymerization
US7452924B2 (en) 2003-08-12 2008-11-18 3M Espe Ag Self-etching emulsion dental compositions and methods
US7649029B2 (en) 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
US7090721B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7156911B2 (en) 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
US7090722B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Acid-reactive dental fillers, compositions, and methods
US20060058418A1 (en) 2004-09-14 2006-03-16 Brandenburg Charles J Materials leading to improved dental composites and dental composites made therefrom
US7241437B2 (en) 2004-12-30 2007-07-10 3M Innovative Properties Company Zirconia particles
WO2006086646A2 (en) 2005-02-10 2006-08-17 The Regents Of The University Of Colorado, A Body Corporate Stress relaxation in crosslinked polymers
AU2006244182B2 (en) 2005-05-09 2012-02-02 3M Innovative Properties Company Dental compositions containing hybrid monomers
WO2007146210A2 (en) 2006-06-09 2007-12-21 Dentsply International Inc. Low stress flowable dental compositions
WO2008082881A1 (en) 2006-12-28 2008-07-10 3M Innovative Properties Company (meth)acryloyl-containing materials, compositions, and methods
US8402819B2 (en) 2007-05-15 2013-03-26 Anasys Instruments, Inc. High frequency deflection measurement of IR absorption
EP2231714B1 (en) 2008-01-15 2012-08-29 DENTSPLY International Inc. Functional resin composition for regulated polymerization stress
EP2105419A1 (en) 2008-03-28 2009-09-30 Lafarge Additives for cement
US7838110B2 (en) 2008-12-02 2010-11-23 3M Innovative Properties Company Aziridine-functional photoactive crosslinking compounds
US9237990B2 (en) 2010-03-31 2016-01-19 3M Innovative Properties Company Polymerizable isocyanurate monomers and dental compositions
EP2401998A1 (en) 2010-07-02 2012-01-04 3M Innovative Properties Company Dental composition, kit of parts and use thereof
EP2965742B1 (en) * 2011-02-15 2020-09-09 3M Innovative Properties Company Dental compositions comprising ethylenically unsaturated addition-fragmentation agent
US20120208965A1 (en) 2011-02-15 2012-08-16 3M Innovative Properties Company Addition-fragmentation agents
EP2675421A2 (en) 2011-02-15 2013-12-25 3M Innovative Properties Company Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer
WO2013028401A1 (en) 2011-08-23 2013-02-28 3M Innovative Properties Company Addition-fragmentation agents
RU2586743C2 (ru) 2011-08-23 2016-06-10 Зм Инновейтив Пропертиз Компани Стоматологические композиции, содержащие агенты присоединения-фрагментации
WO2014074427A1 (en) 2012-11-12 2014-05-15 3M Innovative Properties Company Addition-fragmentation agents
KR102174015B1 (ko) 2012-11-12 2020-11-04 쓰리엠 이노베이티브 프로퍼티즈 컴파니 부가-단편화제를 포함하는 치과용 조성물

Also Published As

Publication number Publication date
KR20150096479A (ko) 2015-08-24
US9463146B2 (en) 2016-10-11
CN104870484A (zh) 2015-08-26
EP2931756B1 (en) 2018-08-08
WO2014099317A1 (en) 2014-06-26
EP2931756A1 (en) 2015-10-21
US20150328086A1 (en) 2015-11-19
JP2016513071A (ja) 2016-05-12
JP6306044B2 (ja) 2018-04-04
KR102008353B1 (ko) 2019-08-07

Similar Documents

Publication Publication Date Title
US11111320B2 (en) Addition-fragmentation oligomers
JP6306044B2 (ja) 付加開裂オリゴマー
CN106029802B (zh) 具有高折射率基团的加成-断裂低聚物
CN105683257B (zh) 包含烯丙基二硫化物的加成‑断裂低聚物
CN103370041B (zh) 包含烯键式不饱和加成-断裂剂的牙科用组合物
JP6300899B2 (ja) 高屈折率の付加−開裂剤
CN105555855B (zh) 包含三硫代碳酸酯的加成-断裂剂

Legal Events

Date Code Title Description
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant