CN104862756B - 在金属合金上直接电化学合成掺杂的导电聚合物 - Google Patents
在金属合金上直接电化学合成掺杂的导电聚合物 Download PDFInfo
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- CN104862756B CN104862756B CN201510075092.4A CN201510075092A CN104862756B CN 104862756 B CN104862756 B CN 104862756B CN 201510075092 A CN201510075092 A CN 201510075092A CN 104862756 B CN104862756 B CN 104862756B
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- anodic oxidation
- aniline
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- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZIOFXYGGAJKWHX-UHFFFAOYSA-N n,2,4-trimethylaniline Chemical group CNC1=CC=C(C)C=C1C ZIOFXYGGAJKWHX-UHFFFAOYSA-N 0.000 description 1
- PEMGGJDINLGTON-UHFFFAOYSA-N n-(3-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=CC(N)=C1 PEMGGJDINLGTON-UHFFFAOYSA-N 0.000 description 1
- CHMBIJAOCISYEW-UHFFFAOYSA-N n-(4-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=C(N)C=C1 CHMBIJAOCISYEW-UHFFFAOYSA-N 0.000 description 1
- UYVJDPLKBZVVFV-UHFFFAOYSA-N n-hexyl-3-methylaniline Chemical compound CCCCCCNC1=CC=CC(C)=C1 UYVJDPLKBZVVFV-UHFFFAOYSA-N 0.000 description 1
- GRSQLQMDSOQXEQ-UHFFFAOYSA-N n-methyl-3-propoxyaniline Chemical compound CCCOC1=CC=CC(NC)=C1 GRSQLQMDSOQXEQ-UHFFFAOYSA-N 0.000 description 1
- GCULWAWIZUGXTO-UHFFFAOYSA-N n-octylaniline Chemical compound CCCCCCCCNC1=CC=CC=C1 GCULWAWIZUGXTO-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- CWCVVRYELBMNJQ-UHFFFAOYSA-N n-propylaniline Chemical compound [CH2]CCNC1=CC=CC=C1 CWCVVRYELBMNJQ-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000009659 non-destructive testing Methods 0.000 description 1
- QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 229960003418 phenoxybenzamine Drugs 0.000 description 1
- JLXXLCJERIYMQG-UHFFFAOYSA-N phenylcyanamide Chemical group N#CNC1=CC=CC=C1 JLXXLCJERIYMQG-UHFFFAOYSA-N 0.000 description 1
- 229940117953 phenylisothiocyanate Drugs 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003583 thiosemicarbazides Chemical class 0.000 description 1
- 229950000329 thiouracil Drugs 0.000 description 1
- 229940036565 thiouracil antithyroid preparations Drugs 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
- C25D11/246—Chemical after-treatment for sealing layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/088—Autophoretic paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/08—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/02—Electrolytic coating other than with metals with organic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4476—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications comprising polymerisation in situ
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/188,259 US10557210B2 (en) | 2014-02-24 | 2014-02-24 | Direct electrochemical synthesis of doped conductive polymers on metal alloys |
| US14/188,259 | 2014-02-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104862756A CN104862756A (zh) | 2015-08-26 |
| CN104862756B true CN104862756B (zh) | 2019-05-03 |
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| CN201510075092.4A Active CN104862756B (zh) | 2014-02-24 | 2015-02-12 | 在金属合金上直接电化学合成掺杂的导电聚合物 |
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| Country | Link |
|---|---|
| US (1) | US10557210B2 (enExample) |
| EP (2) | EP3396028B1 (enExample) |
| JP (2) | JP6441089B2 (enExample) |
| CN (1) | CN104862756B (enExample) |
| CA (1) | CA2878540C (enExample) |
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| HK1258691A1 (zh) * | 2016-03-28 | 2019-11-15 | 奥野制药工业株式会社 | 铝合金的阳极氧化覆膜用封孔处理液、浓缩液和封孔处理方法 |
| JP6862316B2 (ja) * | 2016-09-08 | 2021-04-21 | Ｊｆｅスチール株式会社 | 耐遅れ破壊特性に優れた高強度鋼板およびその製造方法 |
| CN109972185A (zh) * | 2019-04-17 | 2019-07-05 | 邓华斌 | 一种铝合金无镍环保封孔剂及其制备方法 |
| CN110144611B (zh) * | 2019-06-10 | 2021-10-22 | 河北工业大学 | 一种镁合金表面耐蚀耐磨复合涂层及其制备方法 |
| US11952679B2 (en) * | 2019-08-30 | 2024-04-09 | The Regents Of The University Of Michigan | Optimized growth of stable hybrid perovskite materials for electromagnetic and particle radiation detection |
| US11987669B2 (en) | 2020-10-08 | 2024-05-21 | The Boeing Company | Polyaniline compositions, articles thereof, and methods thereof |
| US12448526B2 (en) | 2020-10-08 | 2025-10-21 | The Boeing Company | Conjugated polymer compositions, articles thereof, and methods thereof |
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| US3647645A (en) * | 1969-11-14 | 1972-03-07 | Rohr Corp | Method for selective anodizing of perforated panels |
| US5536452A (en) * | 1993-12-07 | 1996-07-16 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
| US5928795A (en) | 1995-02-03 | 1999-07-27 | Polymer Alloys Llc | Corrosion resistant aluminum article coated with emeraldine base polyaniline |
| US5980723A (en) * | 1997-08-27 | 1999-11-09 | Jude Runge-Marchese | Electrochemical deposition of a composite polymer metal oxide |
| US6328874B1 (en) * | 1998-01-05 | 2001-12-11 | Mcdonnell Douglas Corporation | Anodically formed intrinsically conductive polymer-aluminum oxide composite as a coating on aluminum |
| US7578921B2 (en) | 2001-10-02 | 2009-08-25 | Henkel Kgaa | Process for anodically coating aluminum and/or titanium with ceramic oxides |
| US7235142B2 (en) * | 2002-01-04 | 2007-06-26 | University Of Dayton | Non-toxic corrosion-protection rinses and seals based on cobalt |
| CA2491359A1 (en) * | 2002-06-04 | 2003-12-11 | Lumimove, Inc. D/B/A/ Crosslink Polymer Research | Corrosion-responsive coating formulations for protection of metal surfaces |
| US6942899B2 (en) * | 2002-07-08 | 2005-09-13 | The Boeing Company | Coating for inhibiting oxidation of a substrate |
| US7021993B2 (en) | 2002-07-19 | 2006-04-04 | Cabot Microelectronics Corporation | Method of polishing a substrate with a polishing system containing conducting polymer |
| JP4240961B2 (ja) | 2002-09-04 | 2009-03-18 | チッソ株式会社 | 改質された導電性ポリマーフイルム及びその製造方法 |
| US7125610B2 (en) * | 2003-03-17 | 2006-10-24 | Kemet Electronics Corporation | Capacitor containing aluminum anode foil anodized in low water content glycerine-phosphate electrolyte without a pre-anodizing hydration step |
| US7670511B2 (en) * | 2004-10-01 | 2010-03-02 | Polyone Corporation | Use of cathodic protection compounds on treated metal articles |
| US8101014B2 (en) | 2004-11-10 | 2012-01-24 | Chemetall Gmbh | Process for coating metallic surfaces with a multicomponent aqueous composition |
| EP1812621B1 (de) | 2004-11-10 | 2019-03-06 | Chemetall GmbH | Verfahren zur beschichtung von metallischen oberflächen mit einer wässerigen silan/ silanol/ siloxan/ polysiloxan enthaltenden zusammensetzung |
| JP4603934B2 (ja) | 2005-05-31 | 2010-12-22 | 新日本製鐵株式会社 | 大気環境中において変色を生じにくい発色の純チタン |
| US8691028B2 (en) * | 2006-05-10 | 2014-04-08 | The Boeing Company | Article having a hexavalent-chromium-free, corrosion-inhibiting organic conversion coating thereon, and its preparation |
| US20080317962A1 (en) | 2007-03-05 | 2008-12-25 | Scott Hayes | Multi-layer and composite corrosion resistant coatings |
| WO2010073916A1 (ja) | 2008-12-26 | 2010-07-01 | 日本パーカライジング株式会社 | 金属の電解セラミックスコーティング方法、金属の電解セラミックスコーティング用電解液および金属材料 |
| US9771483B2 (en) | 2013-04-19 | 2017-09-26 | The Boeing Company | Systems, compositions, and methods for corrosion inhibition |
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2014
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2015
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- 2015-01-19 JP JP2015007555A patent/JP6441089B2/ja active Active
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- 2015-02-16 EP EP15155273.4A patent/EP2910668B1/en active Active
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2018
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2910668A3 (en) | 2015-12-02 |
| EP2910668B1 (en) | 2018-04-11 |
| CA2878540A1 (en) | 2015-08-24 |
| EP3396028A3 (en) | 2019-02-27 |
| JP6856608B2 (ja) | 2021-04-07 |
| JP2019023357A (ja) | 2019-02-14 |
| US10557210B2 (en) | 2020-02-11 |
| JP6441089B2 (ja) | 2018-12-19 |
| CN104862756A (zh) | 2015-08-26 |
| JP2015158008A (ja) | 2015-09-03 |
| EP2910668A2 (en) | 2015-08-26 |
| US20150240378A1 (en) | 2015-08-27 |
| CA2878540C (en) | 2017-09-05 |
| EP3396028B1 (en) | 2022-04-06 |
| EP3396028A2 (en) | 2018-10-31 |
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