CN104830394A - Biomass fuel - Google Patents

Biomass fuel Download PDF

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Publication number
CN104830394A
CN104830394A CN201510208463.1A CN201510208463A CN104830394A CN 104830394 A CN104830394 A CN 104830394A CN 201510208463 A CN201510208463 A CN 201510208463A CN 104830394 A CN104830394 A CN 104830394A
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CN
China
Prior art keywords
biomass
biomass fuel
weight part
charcoal powder
fuel according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510208463.1A
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Chinese (zh)
Inventor
史红华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Sino-South Asia & Pacific Environment Science Technology Co Ltd
Original Assignee
Beijing Sino-South Asia & Pacific Environment Science Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Beijing Sino-South Asia & Pacific Environment Science Technology Co Ltd filed Critical Beijing Sino-South Asia & Pacific Environment Science Technology Co Ltd
Priority to CN201510208463.1A priority Critical patent/CN104830394A/en
Publication of CN104830394A publication Critical patent/CN104830394A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A biomass fuel is composed of the following components in parts by weight: 50 to 60 parts of biomass carbon powder, 10 to 20 parts of coal powder, and 5 to 10 parts of combustion promoter. The biomass fuel is prepared by the following steps: mixing a wood material (60 to 70 wt%) with crop straws (30 to 40 wt%), drying, grinding, mixing, pressing, and moulding. The external surface of the biomass fuel is cover by a layer of polyester originated from a biomass resource, and the main repeat units of the polyester are dicarboxylic acid units and glycol units. The combustion promoter is composed of 30 to 40 wt% of talcum, 30 to 50 wt% of slag of sulfuric acid production, 15 to 20 wt% of magnesium chloride block, and 3 to 5 wt% of sodium nitrate. The biomass energy and mineral fuel are combined organically, and the provided biomass fuel has the advantages of good caking ability, high combustion value, and little pollution, barely generates sulfur dioxide and fly ash, and thus protects the environment.

Description

A kind of biomass fuel
Technical field
The invention belongs to technical field of new energies, be specifically related to a kind of biomass fuel.
Background technology
Economic fast development be unable to do without the energy, and the problem in short supply of traditional fossil energy oil, Sweet natural gas and coal is day by day serious.Biomass energy is as the fourth-largest energy, and the feature such as, zero carbon emission renewable with it, becomes a kind of energy that development potentiality in new forms of energy is larger.
Biomass solid fuel is a kind of Land use systems of biomass energy, and its raw materials for production are forestry " three surplus things " (wood machining residues, forest harvesting residuum, producing material residuum), various wooden tankage, wood wastes, agricultural crop straw and shrub etc.Production process be quality is loosened, can the little biomass material of force density, through the operation such as pulverizing, dry, be then processed into biomass solid particle fuel through ring mold pressing roll extrusion molding mode.The epigranular of biomass granule fuel, unit intensity can reach 1 ~ 1.4g/cm3, and intensity increases, conveniently, combustionproperty is obviously improved for transport and storage, and after burning, energy utilization rate can improve more than 80%, almost there is no sulfur dioxide emissions, the ashes after burning or the organic fertilizer of high-quality.
Plant material mainly contains Mierocrystalline cellulose, hemicellulose, lignin composition.Because lignin belongs to noncrystal, being a kind of thermal plastic high polymer material, without determining fusing point, but there is higher glass transition temperature.When temperature is 70-110 DEG C, lignin is softening and have stickiness, can by the hemicellulose in plant material, Mierocrystalline cellulose under stress compression bonded become granular fuel, lignin can play a kind of effect of binding agent.Different types of plant material, its lignin, Mierocrystalline cellulose, hemicellulose level are different.Usually, in timber, the content of lignin is 27-32% (over dry raw material), and in grass kind plant, lignin content is 14-25%.Usually the Pericarppium arachidis hypogaeae be dropped in the course of processing, rice husk, wood chip etc. all can be used as the raw material of biomass granule fuel, further across compacting, become efficient carbon source.But current biomass granule fuel exists the defect that calorific value is low, burning slagging scorification is high, be unfavorable for promoting and utilizing.
Summary of the invention
Technical problem to be solved by this invention is that providing a kind of improves the composite biomass fuel that calorific value also can reduce burning slagging scorification.
For solving the problems of the technologies described above, technical solution of the present invention is:
A kind of biomass fuel, comprises biomass charcoal powder 50-60 weight part, coal dust 10-20 weight part, accelerating agent 5-10 weight part; Described biomass charcoal powder is obtained by following methods: by agricultural crop straw drying, the pulverizing of wood materials and the 30-40wt% containing 60-70wt%, mix, compression moulding; The outside surface of described biomass fuel wraps up the polyester of one deck from biomass resource, and the predominant repeat unit of described polyester is dicarboxylic acid units and diol units; Described accelerating agent contains talcum 30-40wt%, Sulphuric acid waste residue 30-50wt%, magnesium chloride enriched bittern cake 15-20wt%, SODIUMNITRATE 3-5wt%.
Further, the moisture control of described biomass charcoal powder is at 12wt%-15wt%.
Further, the particle diameter of described biomass charcoal powder is less than 1mm.
Further, the wood chip that described wood materials is selected from wooden tankage, wooden waste products, wood working produce or its combination.
Further, described agricultural crop straw is selected from wheat stalk, maize straw, broomcorn straw, cotton stem or its combination.
Further, described coal dust is pulverized obtained by raw coal, its moisture control is at 5wt%-8wt%.
Further, the particle diameter of described coal dust is less than 1mm.
Further, the polyester thickness of described biomass resource is 20-50 micron.
Further, described biomass fuel comprises biomass charcoal powder 55 weight part, coal dust 20 weight part, accelerating agent 8 weight part.
Further, described accelerating agent contains talcum 35-40wt%, Sulphuric acid waste residue 40-45wt%.
The invention has the beneficial effects as follows: biomass energy and mineral fuel are organically combined, the biomass fuel caking ability produced is good, and fuel value is high, and Air–pollution From Combustion is little, produces sulfurous gas and flying dust hardly, is beneficial to the construction of ecotope; The biomass polyester of its outside surface parcel makes this fuel storage convenient transportation, and particle is not easily broken.In addition, owing to employing accelerating agent, can improve thermo-efficiency about 10%, reduce slag remaining carbon about 10%, make the concentration of sulfur dioxide in flue gas reduce 50-60%, in flue gas, carbon monoxide concentration reduces about 40%.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in more detail.
Embodiment 1
A kind of biomass fuel, comprises biomass charcoal powder 50 weight part, coal dust 20 weight part, accelerating agent 10 weight part; Described biomass charcoal powder is obtained by following methods: by agricultural crop straw drying, the pulverizing of wood materials and the 40wt% containing 60wt%, mix, compression moulding; The outside surface Jacket thickness of described biomass fuel is the polyester of 20 microns of biomass resources, and the predominant repeat unit of described polyester is dicarboxylic acid units and diol units; Described accelerating agent contains talcum 30wt%, Sulphuric acid waste residue 50wt%, magnesium chloride enriched bittern cake 15wt%, SODIUMNITRATE 3wt%.
Embodiment 2
With reference to embodiment 1, difference is that biomass fuel comprises biomass charcoal powder 60 weight part, coal dust 10 weight part, accelerating agent 8 weight part; Described biomass charcoal powder is containing the wood materials of 65wt% and the agricultural crop straw of 35wt%; The outside surface Jacket thickness of described biomass fuel is the polyester of 50 microns of biomass resources; Described accelerating agent contains talcum 40wt%, Sulphuric acid waste residue 30wt%, magnesium chloride enriched bittern cake 20wt%, SODIUMNITRATE 5wt%.
Embodiment 3
With reference to embodiment 1, difference is that biomass fuel comprises biomass charcoal powder 55 weight part, coal dust 15 weight part, accelerating agent 5 weight part; Described biomass charcoal powder is containing the wood materials of 70wt% and the agricultural crop straw of 30wt%; The outside surface Jacket thickness of described biomass fuel is the polyester of 35 microns of biomass resources; Described accelerating agent contains talcum 35wt%, Sulphuric acid waste residue 40wt%, magnesium chloride enriched bittern cake 18wt%, SODIUMNITRATE 4wt%.
Embodiment 4
With reference to embodiment 1, difference is that biomass fuel comprises biomass charcoal powder 55 weight part, coal dust 20 weight part, accelerating agent 8 weight part.Further, the moisture control of described biomass charcoal powder is at 12wt%.The particle diameter of described biomass charcoal powder is 0.8mm.The mixture of the wood chip that described wood materials is wooden tankage, wooden waste products and wood working produce.Described agricultural crop straw is the mixture of wheat stalk, maize straw, broomcorn straw, cotton stem.Described coal dust is pulverized obtained by raw coal, its moisture control is at 5wt%.The particle diameter of described coal dust is less than 1mm.
Embodiment 5
With reference to embodiment 4, difference is, the moisture control of described biomass charcoal powder is at 15wt%.The particle diameter of described biomass charcoal powder is 0.5mm.The wood chip that described wood materials produces for wood working.Described agricultural crop straw is maize straw.Described coal dust moisture control is at 8wt%.The particle diameter 0.2mm of described coal dust.
Embodiment 6
With reference to embodiment 4, difference is, the moisture control of described biomass charcoal powder is at 13wt%.The particle diameter of described biomass charcoal powder is 0.5mm.Described wood materials is wooden waste products.Described agricultural crop straw is broomcorn straw.Described coal dust moisture control is at 7wt%.The particle diameter 0.5mm of described coal dust.
Embodiment 7
With reference to embodiment 2, further, the moisture control of described biomass charcoal powder is at 14wt%.The particle diameter of described biomass charcoal powder is 0.1mm.Described wood materials is wooden tankage.Described agricultural crop straw is Cotton Stalk.Described coal dust moisture control is at 6wt%.The particle diameter 0.2mm of described coal dust.
Embodiment 8
With reference to embodiment 3, further, the moisture control of described biomass charcoal powder is at 13wt%.The particle diameter of described biomass charcoal powder is 0.08mm.Described wood materials is wooden waste products.Described agricultural crop straw is broomcorn straw.Described coal dust moisture control is at 7wt%.The particle diameter 0.05mm of described coal dust.
Embodiment 9
With reference to embodiment 4, further, the moisture control of described biomass charcoal powder is at 15wt%.The particle diameter of described biomass charcoal powder is 0.05mm.The wood chip that described wood materials produces for wood working.Described agricultural crop straw is wheat stalk.Described coal dust moisture control is at 7wt%.The particle diameter 0.05mm of described coal dust.
Embodiment 10
With reference to embodiment 5, further, the moisture control of described biomass charcoal powder is at 14wt%.The particle diameter of described biomass charcoal powder is 0.1mm.Described wood materials is wooden tankage.Described agricultural crop straw is Cotton Stalk.Described coal dust moisture control is at 6wt%.The particle diameter 0.05mm of described coal dust.The outside surface Jacket thickness of described biomass fuel is the polyester of 50 microns of biomass resources.
Above-mentioned exemplary embodiment to be described, to should not be construed as and limit the invention.Although disclosed multiple exemplary embodiment, those skilled in the art have been readily appreciated that various deformation possible in exemplary embodiment, and inherently do not depart from novel teachings of the present invention and advantage.Therefore, being included in as defined by the following claims in scope of the present invention of all these Amoebidas.Be understandable that, aforementioned is explanation to various exemplary embodiment, and be not the specific embodiments of limit publicity, the distortion of disclosed embodiment and other exemplary embodiment, object is contained in the scope of claims.

Claims (10)

1. a biomass fuel, is characterized in that, comprises biomass charcoal powder 50-60 weight part, coal dust 10-20 weight part, accelerating agent 5-10 weight part; Described biomass charcoal powder is obtained by following methods: by agricultural crop straw drying, the pulverizing of wood materials and the 30-40wt% containing 60-70wt%, mix, compression moulding; The outside surface of described biomass fuel wraps up the polyester of one deck from biomass resource, and the predominant repeat unit of described polyester is dicarboxylic acid units and diol units; Described accelerating agent contains talcum 30-40wt%, Sulphuric acid waste residue 30-50wt%, magnesium chloride enriched bittern cake 15-20wt%, SODIUMNITRATE 3-5wt%.
2. biomass fuel according to claim 1, is characterized in that, the moisture control of described biomass charcoal powder is at 12wt%-15wt%.
3. biomass fuel according to claim 1, is characterized in that, the particle diameter of described biomass charcoal powder is less than 1mm.
4. biomass fuel according to claim 1, is characterized in that, the wood chip that described wood materials is selected from wooden tankage, wooden waste products, wood working produce or its combination.
5. biomass fuel according to claim 1, is characterized in that, described agricultural crop straw is selected from wheat stalk, maize straw, broomcorn straw, cotton stem or its combination.
6. biomass fuel according to claim 1, is characterized in that, described coal dust is pulverized obtained by raw coal, its moisture control is at 5wt%-8wt%.
7. biomass fuel according to claim 1, is characterized in that, the particle diameter of described coal dust is less than 1mm.
8. biomass fuel according to claim 1, is characterized in that, the polyester thickness of described biomass resource is 20-50 micron.
9. biomass fuel according to claim 1, is characterized in that, described biomass fuel comprises biomass charcoal powder 55 weight part, coal dust 20 weight part, accelerating agent 8 weight part.
10. biomass fuel according to claim 1, is characterized in that, described accelerating agent contains talcum 35-40wt%, Sulphuric acid waste residue 40-45wt%.
CN201510208463.1A 2015-04-28 2015-04-28 Biomass fuel Pending CN104830394A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105969465A (en) * 2016-02-18 2016-09-28 安徽东方金河精密机械制造有限公司 Biomass briquette fuel with good bonding ability and fast moulding and production method thereof
CN107735483A (en) * 2015-04-22 2018-02-23 西北大学 Carbonaceous raw material are produced by useless carbon source
CN109880655A (en) * 2019-03-26 2019-06-14 长沙如洋环保科技有限公司 A kind of agricultural-forestry biomass gasification electricity-generating method
CN114657001A (en) * 2022-03-30 2022-06-24 鞍钢股份有限公司 Method for manufacturing composite fuel for sintering

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076717A (en) * 1992-03-21 1993-09-29 青岛海洋大学 Combustion-supporting agent for coal with efficient energy-saving and pollution-reducing functions
CN103937574A (en) * 2014-02-26 2014-07-23 泗洪新创源木业有限公司 Biomass granular fuel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076717A (en) * 1992-03-21 1993-09-29 青岛海洋大学 Combustion-supporting agent for coal with efficient energy-saving and pollution-reducing functions
CN103937574A (en) * 2014-02-26 2014-07-23 泗洪新创源木业有限公司 Biomass granular fuel

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107735483A (en) * 2015-04-22 2018-02-23 西北大学 Carbonaceous raw material are produced by useless carbon source
CN105969465A (en) * 2016-02-18 2016-09-28 安徽东方金河精密机械制造有限公司 Biomass briquette fuel with good bonding ability and fast moulding and production method thereof
CN109880655A (en) * 2019-03-26 2019-06-14 长沙如洋环保科技有限公司 A kind of agricultural-forestry biomass gasification electricity-generating method
CN114657001A (en) * 2022-03-30 2022-06-24 鞍钢股份有限公司 Method for manufacturing composite fuel for sintering
CN114657001B (en) * 2022-03-30 2023-06-20 鞍钢股份有限公司 Method for manufacturing composite fuel for sintering

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Application publication date: 20150812