CN104812364B - Liquid hidroschesis composition - Google Patents

Liquid hidroschesis composition Download PDF

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Publication number
CN104812364B
CN104812364B CN201380048233.2A CN201380048233A CN104812364B CN 104812364 B CN104812364 B CN 104812364B CN 201380048233 A CN201380048233 A CN 201380048233A CN 104812364 B CN104812364 B CN 104812364B
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mass
ingredient
compounding amount
composition
menthol
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CN201380048233.2A
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CN104812364A (en
Inventor
中江郁青
吉田晋
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/24—Thermal properties
    • A61K2800/244—Endothermic; Cooling; Cooling sensation

Abstract

The present invention provides the liquid hidroschesis composition of a kind of refrigerant sense and excellent in stability.Liquid hidroschesis composition of the present invention is characterized in that, it includes (a) below ~ (e) ingredients, and (d) compounding amount of ingredient is less than 70 mass %:(a) menthol or derivatives thereof, (b) two long chain type cationic surfactant, (c) P-phenol zinc sulfonate, (d) ethyl alcohol, (e) clay mineral.

Description

Liquid hidroschesis composition
Related application
This application claims Japanese patent application 2012-210843 filed on September 25th, 2012 priority, and by its It quotes so far.
Technical field
The present invention relates to liquid hidroschesis compositions, more particularly, to the liquid hidroschesis group of refrigerant sense and excellent in stability Close object.
Background technique
Hidroschesis composition chance used in temperature high season is more.Therefore, seek not only to assign antiperspirancy performance also The hidroschesis composition of the refrigerant senses such as creeping chill can be assigned.
As the example of such hidroschesis composition, disclosed in patent document 1 compounded with the cool feeling substances such as menthol, The creeping chill deodorant cosmetics of the antiperspirant such as P-phenol zinc sulfonate.
In addition, being described in patent document 2: passing through cool feeling substances and the two long chain type cationic tables such as compounding l-menthol The cationic surface active agents such as face activating agent, creeping chill effect improve.
On the other hand, when two long chain type cationic surfactants and P-phenol zinc sulfonate is applied in combination, even if they Compounding amount be minute quantity, composition can also generate white precipitate, and there are problems for stability.
Existing technical literature
Patent document
Patent document 1: Japanese Patent Laid-Open 2002-080335 bulletin
Patent document 2: Japanese Patent Laid-Open 2002-114649 bulletin.
Summary of the invention
Subject to be solved by the invention
The present invention is carried out in view of the aforementioned prior art, and the project to be solved is, provides refrigerant sense and stabilization The excellent liquid hidroschesis composition of property.
The means used to solve the problem
The inventors of the present invention have made intensive studies to solve aforementioned problems, as a result, it has been found that, by compounded with peppermint Alcohol or derivatives thereof, two long chain type cationic surfactants, P-phenol zinc sulfonate composition in be compounded ethyl alcohol and clay Mineral or a certain amount of above ethyl alcohol of compounding can obtain that refrigerant sense, antiperspirancy performance be excellent and stability also excellent liquid Hidroschesis composition, so as to complete the present invention.
That is, liquid hidroschesis composition of the present invention is characterized in that it includes (a) below ~ (e) ingredients, (d) The compounding amount of ingredient is less than 70 mass %.
(a) menthol or derivatives thereof,
(b) two long chain type cationic surfactants,
(c) P-phenol zinc sulfonate,
(d) ethyl alcohol,
(e) clay mineral.
In addition, liquid hidroschesis composition of the present invention is characterized in that, it includes (a) below ~ (d) ingredient, (d) compounding amount of ingredient is 50 mass % or more.
(a) menthol or derivatives thereof,
(b) two long chain type cationic surfactants,
(c) P-phenol zinc sulfonate,
(d) ethyl alcohol.
In aforementioned composition, it is appropriate that, (b) ingredient is VARISOFT TA100 and/or two cocoyl second Base hydroxyethyl methyl ammonium methyl sulphate (Dicocoylethyl hydroxyethylmonium methosulfate).
In aforementioned composition, it is appropriate that, (e) ingredient be a kind in bentonite, kaolin, talcum, mica or Two or more.
The effect of invention
The present invention is capable of providing the liquid hidroschesis composition of refrigerant sense and excellent in stability.
Detailed description of the invention
Fig. 1 is the photo shot for the test example 1-2 for saving 1 week with -5 DEG C.
Specific embodiment
Liquid hidroschesis composition of the present invention is characterized in that it includes (a) menthols or derivatives thereof, (b) Two long chain type cationic surfactants, (c) P-phenol zinc sulfonate, (d) ethyl alcohol,
(d) compounding amount of ingredient is 50 mass % or more, alternatively,
(d) compounding amount of ingredient is less than 70 mass %, and then includes (e) clay mineral.
Hereinafter, being described in detail for each ingredient.
((a) menthol or derivatives thereof)
(a) menthol or derivatives thereof can be compounded the ingredient that usually can be compounded in external preparation.
As (a) ingredient, the menthol such as l-menthol, dl- menthol can be enumerated；Menthyl lactate, l- peppermint The menthol derivatives such as glycerin ether, l- peppermint glucoside, hydroxybutyric acid l- menthyl ester, oxygroup propylene glycol, oxygroup furans.
(a) compounding amount of ingredient is preferably 0.001 mass % or more, more preferably 0.01 mass % or more.Compounding amount is less than When 0.001 mass %, it is difficult to experience refrigerant sense sometimes.
In addition, the compounding amount of (a) ingredient is preferably 3 mass % or less, more preferably 1.5 mass % or less.Even if compounding amount Even more, but it is sometimes too strong to the stimulation of the people of sensibility skin.
((b) two long chain type cationic surfactant)
As (b) two long chain type cationic surfactant, it is preferable to use following formula (I) compounds represented.
[changing 1]
In formula (I), R1~R4Among any two respectively indicate the straight chain of the carbon atom number 8 ~ 36 that can be optionally substituted by a hydroxyl group Or the alkyl or R of branch5(Z1)q(Y1)p-。R5Indicate the straight chain or branch of the carbon atom number 8 ~ 36 that can be optionally substituted by a hydroxyl group The alkyl of chain, Y1 indicate to be selected from-CH2CH2-、-CH2CH2CH2-、-CH2CH2O- ,-CH(OH) CH2Binding groups in O-, Z1 table Show the binding groups in amido bond (- CONH-), ehter bond (- O-), ester bond (- COO-).P and q respectively indicate 0 or 1 it is whole Number.
In addition, R1~R4In residue two alkyl or benzyls for respectively indicating the carbon atom number 1 ~ 3 that can be optionally substituted by a hydroxyl group, It can be identical or respectively different.
X indicate halogen atom, carbon atom number 1 or 2 alkyl sulfide acidic group or eliminate made of the hydrogen atom of organic acid The anion such as residue.
As two long chain type cationic surfactant shown in above-mentioned formula (I), such as distearyl two can be enumerated Ammonio methacrylate, two cocoyl ethyl-hydroxyethyl methyl ammonium methyl sulphates, dimercaptodimethyl ammonium chloride, two cocoyl diformazans Ammonium chloride, two cocoyl ditallowdimethyl ammonium bromides, dilauryl ammonium chloride, myristyl alkyl dimethyl ammonium chloride, two Cetyl dimethyl ammonium chloride, two palmityl alkyl dimethyl ammonium chlorides, distearyl ditallowdimethyl ammonium bromide, two oleyl dimethyl chlorinations Ammonium, two palmityl ethyl-hydroxyethyl methyl ammonium methyl sulphates, two cocoyl hydroxyethyl methyl ammonium methyl sulphates, distearyl Ethyl-hydroxyethyl methyl ammonium chloride etc..
As two long chain type cationic surfactants, it is preferable to use VARISOFT TA100, two cocoyls Ethyl-hydroxyethyl methyl ammonium methyl sulphate.
(b) compounding amount of ingredient is preferably 0.001 mass % or more, more preferably 0.005 mass % or more.Even if being compounded In the case that amount is less than 0.001 mass %, white precipitate also will form when mixing with (c) ingredient, but be unable to satisfy sometimes refrigerant Sense.
In addition, (b) compounding amount of ingredient is preferably 1 mass % or less, more preferably 0.5 mass % or less.Even if compounding amount Even more, but the rising of effect is not observed sometimes.
((c) P-phenol zinc sulfonate)
In the present invention, (c) compounding amount of ingredient is preferably 0.01 mass % or more, more preferably 0.1 mass % or more.Even if In the case where compounding amount is less than 0.01 mass %, it also will form white precipitate when mixing with (b) ingredient, be unable to satisfy sometimes Antiperspirancy performance.
In addition, (c) compounding amount of ingredient is preferably 3 mass % or less, more preferably 1 mass % or less.Even if compounding amount is more Even, but the rising of effect is not observed sometimes.
((d) ethyl alcohol)
When not being compounded (e) clay mineral, (d) compounding amount of ingredient needs for 50 mass % or more.In addition, compounding amount is preferred For 65 mass % or more, more preferably 70 mass % or more.When compounding amount is less than 50 mass %, white precipitate can be generated.
When being compounded (e) clay mineral, (d) compounding amount of ingredient is preferably smaller than 70 mass %.Compounding amount is 70 mass % or more When, the appearance for inhibiting white precipitate effect by being compounded (e) ingredient bring can not be experienced significantly sometimes.
((e) clay mineral)
In liquid hidroschesis composition of the invention, when (d) compounding amount of ethyl alcohol is less than 70 mass %, preferably compounding (e) is viscous Native mineral.
(d) when the compounding amount of ingredient is few, white precipitate is especially easy to produce in low-temperature region, but pass through compounding (e) ingredient is able to suppress white precipitate, obtains the composition of excellent in stability.
As (e) clay mineral, the ingredient being usually compounded in external preparation can be used.
As (e) ingredient, such as bentonite can be enumerated, kaolin, talcum, mica, hectorite, montmorillonite, cover soap Stone, saponite etc..
As (e) ingredient, it is preferable to use bentonite, kaolin, talcum, mica, more preferably use bentonite.
(e) compounding amount of ingredient is preferably 0.001 mass % or more, more preferably 0.02 mass % or more.Compounding amount is less than When 0.001 mass %, white precipitate is generated sometimes.
In addition, (e) compounding amount of ingredient is preferably 1 mass % or less, more preferably 0.1 mass % or less.Even if compounding amount Even more, sticky, use feeling is generated sometimes and is deteriorated.
In addition, (e) compounding amount of ingredient is preferably the 2 times or more of the compounding amount of (b) ingredient.At this point, in low-temperature region It can be realized the superior effect for inhibiting white precipitate.
In liquid hidroschesis composition of the invention, within the scope of the effect of the invention, it can also be compounded usual energy Enough ingredients being compounded in external preparation.As such ingredient, can enumerate for example water, lower alcohol, surfactant, powder, Medicament, buffer, fragrance, fungicide, moisturizer, thickener, pH adjusting agent, preservative, antioxidant, chelating agent, whitening agent, Ultraviolet absorbing agent, color material (color material) etc..
The product form of liquid hidroschesis composition of the invention is not particularly limited, and can enumerate antiperspirant, refreshing body water (body lotion), toner, beautifying liquid etc..
In addition, by making to contain stock solution in liquid hidroschesis composition of the invention, additionally it is possible to provide hidroschesis aerosol Agent composition.
Embodiment
For the present invention, it is exemplified below out embodiment further description, but the present invention is not limited thereto.Compounding amount exists In the case where especially recording, to be indicated relative to the quality % of the system compounded with the ingredient.
Before illustrating embodiment, it is illustrated for method for estimating stability used in the present invention.
Method for estimating stability
Have rated the stability of the sample after saving 1 week with -5 DEG C or 0 DEG C or 5 DEG C or 10 DEG C or 25 DEG C.
◎: not generating white precipitate, whole to have transparent feel.
Zero: being nearly free from white precipitate.
△: a small amount of white precipitate is generated.
×: it is whole to generate white precipitate.
By the way that menthol or derivatives thereof and two long chain type cationic surfactants to be combined, can obtain clear The excellent composition of cool feeling.Thus, for what these compounds were composed with the P-phenol zinc sulfonate with antiperspirancy performance Hidroschesis is studied with composition.
That is, manufacturing the sample of composition shown in following table 1 using conventional method, each examination is evaluated using above-mentioned evaluation method Sample.Show the result in table 1.
In addition, the photo shot for the sample of test example 1-2 when evaluating the stability at -5 DEG C is shown in figure 1。
[table 1]
(* 1): メ ン ト ー Le JP(Takasago spices Industry Co system)
(* 2): FRESCOLAT(シ system ラ イ ズ corporation)
(* 3): カ チ オ Application DSV(Sanyo Chemical Industries, Ltd. system)
(* 4): ス Le Off ォ carbolic acid Ami lead (マ Star モ ト Off ァ イ Application ケ ミ カ Le corporation).
It is compounded with the test example 1-1's of menthol, menthol derivative and two long chain type cationic surfactants Refrigerant sense is excellent, but does not have antiperspirancy performance.
But the test example 1-2 that P-phenol zinc sulfonate is compounded in the composition of test example 1-1 has antiperspirancy performance, But bad stability.
It is specified by table 1 and Fig. 1: when two long chain type cationic surfactants and P-phenol zinc sulfonate is applied in combination, It will form compound, the bad stability for generating white precipitate, composition.
It should be noted that the excellent in stability of the composition of test example 1-3, but due to not being compounded two long chain types cation Property surfactant, therefore the composition than test example 1-2 is more not felt by refrigerant sense.
It has studied compounded with inhibiting white in the composition of two long chain type cationic surfactants and P-phenol zinc sulfonate Color precipitate, the ingredient for improving stability.
The inventors of the present invention utilize above-mentioned evaluation method pair using the sample formed shown in conventional method manufacture following table 2 Each sample is evaluated.Show the result in table 2.
[table 2]
Specified based on table 2: with the increase of ethyl alcohol compounding amount, stability can be improved.
Therefore, liquid hidroschesis of the present invention composition is needed comprising (a) menthol or derivatives thereof, with distearyl Base alkyl dimethyl ammonium chloride is that (b) two long chain type cationic surfactant, (c) P-phenol zinc sulfonate, (d) of representative are being combined The ethyl alcohol of 50 mass % or more is accounted in object.Not only refrigerant sense, antiperspirancy performance are excellent with composition for such hidroschesis of the invention, surely It is qualitative also excellent.
Then, it has studied compounded with being mentioned in the composition of two long chain type cationic surfactants and P-phenol zinc sulfonate The ingredient of height temperature stability.
The inventors of the present invention utilize above-mentioned evaluation method pair using the sample formed shown in conventional method manufacture following Table 3 Each sample is evaluated.Show the result in table 3.
[table 3]
(* 5): ベ Application ゲ Le FW(ホ ー ジ ュ Application corporation).
It is specified by table 3: even if being compounded with bentonitic test example 3-1 in test example 2-3 at low temperature, stability Also excellent.
Therefore, when especially the compounding amount of ethyl alcohol is less than 70 mass %, liquid hidroschesis composition of the present invention is preferred Include (a) menthol or derivatives thereof, (b) two long chain type cationic surfactant, (c) P-phenol zinc sulfonate, (d) second Alcohol, using bentonite as (e) of representative clay mineral.The low-temperature stability of the liquid hidroschesis composition is excellent, therefore can also It is saved in freezer.
Then, the compounding amount of (e) clay mineral is had studied.
The inventors of the present invention utilize above-mentioned evaluation method pair using the sample formed shown in conventional method manufacture following table 4 Each sample is evaluated.Show the result in table 4.
[table 4]
As shown in Table 4, though bentonitic compounding amount be it is a small amount of, stability can also improve.
By them it is found that (e) compounding amount of clay mineral is preferably 0.001 ~ 1 mass %.
Then, it is studied for the type of (b) two long chain type cationic surfactant.
The inventors of the present invention utilize above-mentioned evaluation method pair using the sample formed shown in conventional method manufacture following table 5 Each sample is evaluated.Show the result in table 5.
[table 5]
(* 6): Dehyquart L80(BASF corporation).
According to the result of table 5, as (b) of the invention two long chain type cationic surfactant, two also be can be used Cocoyl ethyl-hydroxyethyl methyl ammonium methyl sulphate.
In addition, being based on table 4 and table 5, in order to obtain the composition with superior low-temperature stability, (e) ingredient is matched Mixed amount is preferably the 2 times or more of the compounding amount of (b) ingredient.
Then, it is studied for the type of (e) clay mineral.
The inventors of the present invention utilize above-mentioned evaluation method pair using the sample formed shown in conventional method manufacture following table 6 Each sample is evaluated.Show the result in table 6.
[table 6]
(* 7): ASP-900(BASF Catalysts corporation)
(* 8): タ ルク JA-68R(Asada Flours K. K. system)
(* 9): セ リ サ イ ト MAS (T) (キ Application セ イ マ テ ッ Network corporation).
Based on table 6, as (e) clay mineral of the invention, other than bentonite, can also use kaolin, talcum, Mica.Even if can generally also be taken care of with freezer using these (e) ingredient.
But when carrying out keeping at 0 DEG C or less, as (e) ingredient, it is preferable to use bentonite.
Hereinafter, the prescription example of liquid hidroschesis composition of the invention can be enumerated.
The refreshing body water of 1 liquid hidroschesis of prescription example
0.3 mass % of l-menthol
Menthyl lactate 0.2
VARISOFT TA100 0.005
P-phenol zinc sulfonate 0.5
Ethyl alcohol 45
Bentonite 0.01
Benza (48%) 0.1
Lactic acid 0.04
Fragrance qs
Water surplus

Claims (2)

1. liquid hidroschesis composition, which is characterized in that it includes (a) below ~ (e) ingredients, and (d) compounding amount of ingredient is less than 70 mass %, (e) compounding amount of ingredient is the 2 times or more of the compounding amount of (b) ingredient,
(a) l-menthol, dl- menthol, menthyl lactate, l- menthyl glyceryl ether, l- peppermint glucoside, hydroxybutyric acid l- are selected from 0.001 ~ 3 mass % of one kind or two or more compound in menthyl ester, oxygroup propylene glycol and oxygroup furans,
(b) two long chain type cationic surfactants, 0.001 ~ 1 mass %,
(c) 0.01 ~ 3 mass % of P-phenol zinc sulfonate,
(d) ethyl alcohol,
(e) one kind or two or more 0.001 ~ 1 mass % of clay mineral in bentonite, kaolin, talcum, mica.
2. liquid hidroschesis composition according to claim 1, which is characterized in that (b) ingredient is distearyl dimethyl Ammonium chloride and/or two cocoyl ethyl-hydroxyethyl methyl ammonium methyl sulphates.
CN201380048233.2A 2012-09-25 2013-09-05 Liquid hidroschesis composition Active CN104812364B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012210843A JP6139836B2 (en) 2012-09-25 2012-09-25 Liquid antiperspirant composition
JP2012-210843 2012-09-25
PCT/JP2013/073965 WO2014050487A1 (en) 2012-09-25 2013-09-05 Liquid antiperspirant composition

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CN104812364A CN104812364A (en) 2015-07-29
CN104812364B true CN104812364B (en) 2019-03-08

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FR3029777B1 (en) 2014-12-15 2019-11-29 L'oreal USE OF THE ASSOCIATION OF AN ASSOCIATIVE NON-IONIC POLYURETHANE POLYETHER AND A CYCLOHEXANOL DERIVATIVE AS A SKIN-REFRESHING AGENT
JP6606343B2 (en) * 2015-03-25 2019-11-13 住友精化株式会社 Gel-like antiperspirant composition
JP6334646B2 (en) 2016-10-31 2018-05-30 株式会社 資生堂 Liquid skin composition
JP7266975B2 (en) * 2018-07-20 2023-05-01 株式会社 資生堂 Skin gel formulation for external use
AT521769B1 (en) 2018-12-18 2020-06-15 Dipl Ing Alfred Edlinger Process for processing molten material
JP7424883B2 (en) * 2020-03-23 2024-01-30 株式会社マンダム aqueous composition

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JP2002080335A (en) * 2000-09-01 2002-03-19 Shiseido Co Ltd Cool feeling-imparting deodorant cosmetic
JP2002114649A (en) * 2000-10-10 2002-04-16 Takasago Internatl Corp Composition for improving cool feeling effect
JP2003095907A (en) * 2001-09-26 2003-04-03 Lion Corp Skin cosmetic
JP2005068028A (en) * 2003-08-28 2005-03-17 Rohto Pharmaceut Co Ltd Skin care preparation for external use

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JP2014065671A (en) 2014-04-17
JP6139836B2 (en) 2017-05-31
WO2014050487A1 (en) 2014-04-03
TW201417834A (en) 2014-05-16
HK1211214A1 (en) 2016-05-20
KR20150060680A (en) 2015-06-03
TWI634904B (en) 2018-09-11

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