JP7424883B2 - aqueous composition - Google Patents
aqueous composition Download PDFInfo
- Publication number
- JP7424883B2 JP7424883B2 JP2020051164A JP2020051164A JP7424883B2 JP 7424883 B2 JP7424883 B2 JP 7424883B2 JP 2020051164 A JP2020051164 A JP 2020051164A JP 2020051164 A JP2020051164 A JP 2020051164A JP 7424883 B2 JP7424883 B2 JP 7424883B2
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- JP
- Japan
- Prior art keywords
- component
- mass
- aqueous composition
- content
- amino acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 82
- 239000000843 powder Substances 0.000 claims description 65
- 150000001413 amino acids Chemical class 0.000 claims description 44
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000002734 clay mineral Substances 0.000 claims description 12
- 229910021647 smectite Inorganic materials 0.000 claims description 9
- 239000003093 cationic surfactant Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 239000004615 ingredient Substances 0.000 claims description 4
- 150000001484 arginines Chemical class 0.000 claims 1
- 229940024606 amino acid Drugs 0.000 description 43
- -1 fatty acid salt Chemical class 0.000 description 41
- 239000007788 liquid Substances 0.000 description 29
- 235000014113 dietary fatty acids Nutrition 0.000 description 24
- 239000000194 fatty acid Substances 0.000 description 24
- 229930195729 fatty acid Natural products 0.000 description 24
- 239000002537 cosmetic Substances 0.000 description 16
- 239000004359 castor oil Substances 0.000 description 11
- 235000019438 castor oil Nutrition 0.000 description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 11
- 239000006210 lotion Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 150000001483 arginine derivatives Chemical class 0.000 description 7
- GYDYJUYZBRGMCC-INIZCTEOSA-N (2s)-2-amino-6-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NCCCC[C@H](N)C(O)=O GYDYJUYZBRGMCC-INIZCTEOSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 4
- IREAODMQYCOAGP-UHFFFAOYSA-N 3-(hexadecanoylamino)propyl-trimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC(=O)NCCC[N+](C)(C)C IREAODMQYCOAGP-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 description 4
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 229940037624 palmitamidopropyltrimonium chloride Drugs 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- 229940031723 1,2-octanediol Drugs 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 2
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 2
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 229960003121 arginine Drugs 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 229940081733 cetearyl alcohol Drugs 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- 229940074045 glyceryl distearate Drugs 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 229940068939 glyceryl monolaurate Drugs 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 2
- 229960003104 ornithine Drugs 0.000 description 2
- 235000019477 peppermint oil Nutrition 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 229910000275 saponite Inorganic materials 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- XTJKNGLLPGBHHO-HNNXBMFYSA-N (2s)-5-(diaminomethylideneamino)-2-(dodecanoylamino)pentanoic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCN=C(N)N XTJKNGLLPGBHHO-HNNXBMFYSA-N 0.000 description 1
- OLDGKSQBWGEFNM-FQEVSTJZSA-N (2s)-6-amino-2-(hexadecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCCN OLDGKSQBWGEFNM-FQEVSTJZSA-N 0.000 description 1
- DEAFEFSHUVGNFC-JTQLQIEISA-N (2s)-6-amino-2-(hexanoylamino)hexanoic acid Chemical compound CCCCCC(=O)N[C@H](C(O)=O)CCCCN DEAFEFSHUVGNFC-JTQLQIEISA-N 0.000 description 1
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OKMWKBLSFKFYGZ-UHFFFAOYSA-N 1-behenoylglycerol Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(O)CO OKMWKBLSFKFYGZ-UHFFFAOYSA-N 0.000 description 1
- ZXNAIPHYBVMMPY-KTKRTIGZSA-N 1-erucoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(=O)OCC(O)CO ZXNAIPHYBVMMPY-KTKRTIGZSA-N 0.000 description 1
- QHZLMUACJMDIAE-SFHVURJKSA-N 1-hexadecanoyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- ZVTDEEBSWIQAFJ-KHPPLWFESA-N 2-hydroxypropyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(C)O ZVTDEEBSWIQAFJ-KHPPLWFESA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CAKGLMPBYAPFCR-UWBMNBDUSA-N Bemisiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@@H](CO)O1 CAKGLMPBYAPFCR-UWBMNBDUSA-N 0.000 description 1
- LKUNXBRZDFMZOK-GFCCVEGCSA-N Capric acid monoglyceride Natural products CCCCCCCCCC(=O)OC[C@H](O)CO LKUNXBRZDFMZOK-GFCCVEGCSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 235000005956 Cosmos caudatus Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
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- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- ZNVKGUVDRSSWHV-UHFFFAOYSA-L zinc;4-hydroxybenzenesulfonate Chemical compound [Zn+2].OC1=CC=C(S([O-])(=O)=O)C=C1.OC1=CC=C(S([O-])(=O)=O)C=C1 ZNVKGUVDRSSWHV-UHFFFAOYSA-L 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- Cosmetics (AREA)
Description
本発明は、水性組成物に関する。 The present invention relates to aqueous compositions.
従来、皮膚外用剤、メイクアップ化粧料などの感触改良剤としてナイロン等のプラスチックパウダーが主に使用されてきた。しかしながら、プラスチックパウダーは、生分解性が低い。このため、プラスチックパウダーによる環境への影響が問題となり、プラスチックパウダーの使用を控える必要がある。 Conventionally, plastic powders such as nylon have been mainly used as feel improvers in external skin preparations, makeup cosmetics, and the like. However, plastic powder has low biodegradability. Therefore, the environmental impact of plastic powder becomes a problem, and it is necessary to refrain from using plastic powder.
生分解性の高い粉体の一つとして、アミノ酸と脂肪酸とからなるアミノ酸系有機粉体が挙げられる。アミノ酸系有機粉体は、水にも有機溶媒にもほとんど溶解せず、撥水性に優れているという特性を有することが知られている。 An example of highly biodegradable powder is an amino acid-based organic powder consisting of amino acids and fatty acids. It is known that amino acid-based organic powders are hardly soluble in water or organic solvents and have excellent water repellency.
アミノ酸系有機粉体を配合した組成物は、例えば特許文献１～３に開示されている。特許文献１には、メイクアップ化粧料にアミノ酸系有機粉体を配合することによって、使用感や撥水性を向上させる技術が開示されている。また、特許文献２には、クリーム状組成物にアミノ酸系粉体を配合することによって、高級感のあるパール状光沢を有するクリーム状の外観とし、形態安定性を向上させる技術が開示されている。また、特許文献３には、高級脂肪酸を含有する洗浄剤組成物にアミノ酸系有機粉体を配合することによって、洗浄力や泡質などを向上させる技術が開示されている。 Compositions containing amino acid-based organic powders are disclosed, for example, in Patent Documents 1 to 3. Patent Document 1 discloses a technique for improving the feel of use and water repellency by blending amino acid-based organic powder into makeup cosmetics. Further, Patent Document 2 discloses a technique for creating a cream-like appearance with a luxurious pearl-like luster and improving morphological stability by blending an amino acid-based powder into a cream-like composition. . Further, Patent Document 3 discloses a technique for improving detergency, foam quality, etc. by blending an amino acid-based organic powder into a detergent composition containing higher fatty acids.
特許文献１および２には、油性組成物にアミノ酸系有機粉体を配合することは記載されているが、水性組成物にアミノ酸系有機粉体を配合することの記載はない。また、特許文献３には、高級脂肪酸塩およびアミノ酸系有機粉体を含有する洗浄料組成物が記載されている。しかし、特許文献３に記載の技術は、洗浄料組成物の高い粘性によりアミノ酸系有機粉体を分散させているに過ぎず、全ての水性組成物に適用できる技術ではない。アミノ酸系有機粉体は、撥水性に優れるため、水性組成物の液層にアミノ酸系有機粉体を分散させることは困難である。それゆえ、アミノ酸系有機粉体を含有する水性組成物を調製することは困難であった。 Patent Documents 1 and 2 describe blending an amino acid-based organic powder into an oil-based composition, but do not describe blending an amino acid-based organic powder into an aqueous composition. Further, Patent Document 3 describes a cleaning composition containing a higher fatty acid salt and an amino acid-based organic powder. However, the technique described in Patent Document 3 merely disperses amino acid-based organic powder using the high viscosity of the cleaning composition, and is not a technique that can be applied to all aqueous compositions. Since the amino acid-based organic powder has excellent water repellency, it is difficult to disperse the amino acid-based organic powder in the liquid layer of an aqueous composition. Therefore, it has been difficult to prepare an aqueous composition containing amino acid-based organic powder.
本発明は、水性組成物の液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることが可能な水性組成物を実現することを目的とする。 An object of the present invention is to realize an aqueous composition in which an amino acid-based organic powder can be dispersed or redispersed in a liquid layer of the aqueous composition.
本発明者らは、上記課題を解決するために鋭意検討した結果、（ｉ）アミノ酸系有機粉体、特定の界面活性剤、および粘土鉱物を配合し、（ｉｉ）当該界面活性剤および当該粘土鉱物の含有量に対するアミノ酸系有機粉体の含有量の比率を特定範囲にした水性組成物であれば、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができるという新規知見を見出し、本発明を完成するに至った。すなわち、本発明は以下の構成を含む。 As a result of intensive studies to solve the above problems, the present inventors found that (i) an amino acid-based organic powder, a specific surfactant, and a clay mineral were blended, and (ii) the surfactant and the clay New finding that amino acid-based organic powder can be dispersed or redispersed in a liquid layer if the aqueous composition has a ratio of amino acid-based organic powder content to mineral content within a specific range. They discovered this and completed the present invention. That is, the present invention includes the following configuration.
〔１〕下記成分Ａ～Ｄを含有し、
成分Ｂの含有量に対する成分Ａの含有量（Ａ／Ｂ）が、３００以下であり、
成分Ｃの含有量に対する成分Ａの含有量（Ａ／Ｃ）が、３５以下である、水性組成物；
成分Ａ：アミノ酸系有機粉体
成分Ｂ：アルキルオキシヒドロキシプロピルアルギニン塩、ＨＬＢが１２．０～１７．０のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも１種の界面活性剤
成分Ｃ：スメクタイト型粘土鉱物
成分Ｄ：水。
[1] Contains the following components A to D,
The content of component A relative to the content of component B (A/B) is 300 or less,
An aqueous composition in which the content of component A relative to the content of component C (A/C) is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one type selected from the group consisting of an alkyloxyhydroxypropyl arginine salt, a nonionic surfactant with an HLB of 12.0 to 17.0, and a cationic surfactant. Surfactant Component C: Smectite clay mineral Component D: Water.
〔２〕上記成分Ａの含有量が、０．０１～２０．０質量％であり、上記成分Ｂの含有量が、０．００５～２．０質量％であり、上記成分Ｃの含有量が、０．０１～２．０質量％である、〔１〕の水性組成物。 [2] The content of the component A is 0.01 to 20.0% by mass, the content of the component B is 0.005 to 2.0% by mass, and the content of the component C is , 0.01 to 2.0% by mass of the aqueous composition of [1].
〔３〕下記成分Ｅをさらに含む、〔１〕または〔２〕の水性組成物；
成分Ｅ：エタノール。
[3] The aqueous composition of [1] or [2], further comprising the following component E;
Component E: Ethanol.
本発明の水性組成物によれば、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができる。 According to the aqueous composition of the present invention, the amino acid-based organic powder can be dispersed or redispersed in the liquid layer.
以下、本発明の実施の形態の一例について詳細に説明するが、本発明は、これらに限定されない。本発明は、以下に説明する各構成に限定されるものではなく、請求の範囲に示した範囲で種々の変更が可能である。また、異なる実施形態または実施例にそれぞれ開示された技術的手段を適宜組み合わせて得られる実施形態または実施例についても、本発明の技術的範囲に含まれる。さらに、各実施形態にそれぞれ開示された技術的手段を組み合わせることにより、新しい技術的特徴を形成することができる。なお、本明細書中に記載された学術文献および特許文献の全てが、本明細書中において参考文献として援用される。 Hereinafter, an example of an embodiment of the present invention will be described in detail, but the present invention is not limited thereto. The present invention is not limited to each configuration described below, and various changes can be made within the scope of the claims. Further, embodiments or examples obtained by appropriately combining technical means disclosed in different embodiments or examples are also included in the technical scope of the present invention. Furthermore, new technical features can be formed by combining the technical means disclosed in each embodiment. Note that all academic literature and patent literature described in this specification are incorporated as references in this specification.
本明細書において特記しない限り、数値範囲を表す「Ｘ～Ｙ」は、「Ｘ以上Ｙ以下」を意図する。また、本明細書において特記しない限り、成分の含有量を表す質量％は、水性組成物全体の質量を１００質量％とした値である。 In this specification, unless otherwise specified, the numerical range "X to Y" is intended to be "more than or equal to X and less than or equal to Y." In addition, unless otherwise specified in this specification, mass % representing the content of a component is a value based on the mass of the entire aqueous composition as 100 mass %.
〔１．水性組成物〕
本発明に係る水性組成物は、下記成分Ａ～Ｄを含有し、
成分Ｂの含有量に対する成分Ａの含有量（Ａ／Ｂ）が、３００以下であり、
成分Ｃの含有量に対する成分Ａの含有量（Ａ／Ｃ）が、３５以下である、水性組成物である；
成分Ａ：アミノ酸系有機粉体
成分Ｂ：アルキルオキシヒドロキシプロピルアルギニン塩、ＨＬＢが１２．０～１７．０のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも１種の界面活性剤
成分Ｃ：スメクタイト型粘土鉱物
成分Ｄ：水。
[1. Aqueous composition]
The aqueous composition according to the present invention contains the following components A to D,
The content of component A relative to the content of component B (A/B) is 300 or less,
An aqueous composition in which the content of component A relative to the content of component C (A/C) is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one type selected from the group consisting of an alkyloxyhydroxypropyl arginine salt, a nonionic surfactant with an HLB of 12.0 to 17.0, and a cationic surfactant. Surfactant Component C: Smectite clay mineral Component D: Water.
本発明では、上記組成を有することによって、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができる水性組成物を実現することができる。ここで、「液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させる」とは、換言すると、液層に対して有機粉体が濡れ性を有するともいえる。当該濡れ性を有する状態とは、液層とともに有機粉体を撹拌したとき、有機粉体が、液層の液面よりも下に存在する状態をいう。一方、濡れ性を有さない状態とは、水性組成物とともにアミノ酸系有機粉体を撹拌したとき、アミノ酸系有機粉体が液層の液面上（気液界面）に留まったままの状態をいう。 In the present invention, by having the above composition, an aqueous composition capable of dispersing or redispersing amino acid-based organic powder in a liquid layer can be realized. Here, "dispersing or redispersing the amino acid-based organic powder in the liquid layer" can be said to mean that the organic powder has wettability with respect to the liquid layer. The wettability state refers to a state in which the organic powder exists below the liquid level of the liquid layer when the organic powder is stirred together with the liquid layer. On the other hand, a state without wettability refers to a state in which the amino acid-based organic powder remains on the liquid surface of the liquid layer (air-liquid interface) when the amino acid-based organic powder is stirred with an aqueous composition. say.
また、本発明の水性組成物においては、液層中に有機粉体が濡れ粉体層として存在する２層形態であっても、アミノ酸系有機粉体は、液層中に分散しているといえる。当該２層形態としては、例えば、（ｉ）液層の液面下側から液面近くに有機粉体が濡れ粉体層として存在する形態、（ｉｉ）液層の底部へ有機粉体が沈降し、当該底部に有機粉体が濡れ粉体層として存在する形態等が挙げられる。 In addition, in the aqueous composition of the present invention, even if the organic powder is in a two-layer form in which the organic powder exists as a wet powder layer in the liquid layer, the amino acid-based organic powder is dispersed in the liquid layer. I can say that. The two-layer configuration includes, for example, (i) a configuration in which the organic powder exists as a wet powder layer from below the liquid surface to near the liquid surface, and (ii) an organic powder settles to the bottom of the liquid layer. However, examples include a form in which the organic powder is present as a wet powder layer at the bottom.
また、本発明において、「水性組成物」とは、実質的に油剤を含有しない組成物をいう。より具体的には、「水性組成物」は、油剤が３．０質量％以下、好ましくは１．０質量％以下、より好ましくは０．５質量％以下の組成物である。さらに、上記油剤としては、油脂、ロウ、シリコーン油、炭化水素、エステル油等が挙げられる。 Furthermore, in the present invention, the term "aqueous composition" refers to a composition that does not substantially contain an oil agent. More specifically, the "aqueous composition" is a composition in which the oil agent is 3.0% by mass or less, preferably 1.0% by mass or less, and more preferably 0.5% by mass or less. Furthermore, examples of the above-mentioned oil agents include oils and fats, waxes, silicone oils, hydrocarbons, ester oils, and the like.
また、本発明の水性組成物は、２５℃における粘度が１０００ｍＰａ・ｓ以下の液状組成物であることが好ましく、５００ｍＰａ・ｓ以下の液状組成物であることがより好ましい。上記粘度は、例えば、Ｂ型粘度計：ＶＩＳＣＴＥＲ ＴＶ－２５（東機産業社製）、若しくは、音叉式振動粘度計：ＳＶ－１０Ａ（北浜製作所社製）により測定することができる。 Further, the aqueous composition of the present invention preferably has a viscosity at 25° C. of 1000 mPa·s or less, more preferably 500 mPa·s or less. The above-mentioned viscosity can be measured, for example, with a B-type viscometer: VISCTER TV-25 (manufactured by Toki Sangyo Co., Ltd.) or a tuning fork vibration viscometer: SV-10A (manufactured by Kitahama Seisakusho Co., Ltd.).
クリーム状組成物およびジェル状組成物の粘度は、１０００ｍＰａ・ｓを超える。このような組成物に対しては、濡れ性に関係なく、有機粉体を分散して配合することが可能である。 The viscosity of the cream composition and gel composition exceeds 1000 mPa·s. It is possible to disperse and blend organic powder into such a composition, regardless of its wettability.
一方、液状の水性組成物に対して有機粉体を分散して配合するためには、当該水性組成物の液層に対して有機粉体が濡れ性を有することが必要となる。本発明者らは、驚くべきことに、上記成分Ａ～Ｄを配合することによって、有機粉体が水性組成物の液層に対して濡れ性を有するという新規知見を見出した。 On the other hand, in order to disperse and blend organic powder into a liquid aqueous composition, it is necessary that the organic powder has wettability with respect to the liquid layer of the aqueous composition. Surprisingly, the present inventors have discovered a new finding that by blending the above-mentioned components A to D, the organic powder has wettability with respect to the liquid layer of the aqueous composition.
また、本発明の水性組成物は、上記成分Ａ～Ｄに加えて、成分Ｅ：エタノールをさらに含んでいてもよい。本発明の水性組成物は、上述した成分以外に、他の成分を含んでいてもよい。 Further, the aqueous composition of the present invention may further contain component E: ethanol in addition to the above components A to D. The aqueous composition of the present invention may contain other components in addition to the components described above.
成分Ｂの含有量に対する成分Ａの含有量（Ａ／Ｂ）が、３００以下であり、好ましくは２～２５０であり、より好ましくは５～２００である。上述の範囲であれば、スメクタイト型粘土鉱物（成分Ｃ）の過多によるべたつきの発生を抑制できる。また成分Ａの過少による成分Ａの効果喪失の恐れを考慮すると、Ａ／Ｂは、０を超えていればよい。 The content of component A relative to the content of component B (A/B) is 300 or less, preferably 2 to 250, more preferably 5 to 200. Within the above range, it is possible to suppress the occurrence of stickiness due to an excessive amount of smectite clay mineral (component C). Furthermore, considering the possibility that the effect of component A may be lost due to an insufficient amount of component A, A/B may be greater than 0.
成分Ｃの含有量に対する成分Ａの含有量（Ａ／Ｃ）が、３５以下であり、好ましくは０．１～３０であり、より好ましくは１～２５である。上述の範囲であれば、スメクタイト型粘土鉱物（成分Ｃ）の過多によるべたつきの発生を抑制でき、また泡立が過剰となる恐れを抑制し得る。また成分Ａの過少による成分Ａの効果喪失の恐れを考慮すると、Ａ／Ｃは、０を超えていればよい。 The content of component A relative to the content of component C (A/C) is 35 or less, preferably 0.1 to 30, more preferably 1 to 25. Within the above range, it is possible to suppress the occurrence of stickiness due to an excessive amount of the smectite clay mineral (component C), and also to suppress the possibility of excessive foaming. Furthermore, considering the possibility that the effect of component A may be lost due to an insufficient amount of component A, A/C may be greater than 0.
以下では、本発明の水性組成物を構成する成分について説明する。 Below, the components constituting the aqueous composition of the present invention will be explained.
〔成分Ａ〕
本発明の水性組成物は、成分Ａとして、アミノ酸系有機粉体を含有する。本発明の水性組成物において、上記成分Ａを含有させることにより、皮膚に対し塗布後に、サラサラした感触、所謂、サラサラ感を付与するという効果を奏する。上記成分Ａは、１種のみを用いてもよいし、２種以上を用いてもよい。
[Component A]
The aqueous composition of the present invention contains amino acid-based organic powder as component A. In the aqueous composition of the present invention, by containing the above-mentioned component A, it has the effect of imparting a smooth feel, a so-called dry feeling, after being applied to the skin. The above component A may be used alone or in combination of two or more.
上記アミノ酸系有機粉体としては、水性組成物に配合し得るものであれば特に限定されない。具体的には、ラウロイルリジン、パルミトイルリジン、カプロイルリジン等のアシルリジン；ステアロイルオルニチン等のアシルオルニチン；ラウロイルアルギニン等のアシルアルギニン；ココイルヒスチジン等のアシルヒスチジン等のアシル塩基性アミノ酸等が挙げられる。市販品としては、ラウロイルリジンであるアミホープＬＬ（味の素社製）等を用いることができる。 The amino acid-based organic powder is not particularly limited as long as it can be blended into an aqueous composition. Specific examples thereof include acyl lysine such as lauroyl lysine, palmitoyl lysine, and caproyl lysine; acyl ornithine such as stearoyl ornithine; acyl arginine such as lauroyl arginine; and acyl basic amino acids such as acyl histidine such as cocoyl histidine. As a commercially available product, Amihope LL (manufactured by Ajinomoto Co., Ltd.), which is lauroyl lysine, can be used.
また、成分Ａの含有量は、好ましくは０．０１～２０．０質量％、より好ましくは０．１～１５．０質量％、さらに好ましくは０．５～１０．０質量％である。アミノ酸系有機粉体による効果を発揮する観点から、上記含有量は、０．０１質量％以上であればよい。また、本発明の水性組成物の使用感の観点から、上記含有量は、２０．０質量％以下であればよい。 Further, the content of component A is preferably 0.01 to 20.0% by mass, more preferably 0.1 to 15.0% by mass, and even more preferably 0.5 to 10.0% by mass. From the viewpoint of exhibiting the effects of the amino acid-based organic powder, the content may be 0.01% by mass or more. Moreover, from the viewpoint of the feeling of use of the aqueous composition of the present invention, the above content may be 20.0% by mass or less.
〔成分Ｂ〕
本発明の水性組成物は、成分Ｂとして、アルキルオキシヒドロキシプロピルアルギニン塩、ＨＬＢが１２．０～１７．０のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも１種の界面活性剤を含有する。本発明の水性組成物において、上記成分Ｂを含有させることにより、アミノ酸系有機粉体の液層への濡れ性を付与し、アミノ酸系有機粉体同士のケーキングを抑制することができる。好ましくは、前記界面活性剤は、アルキルオキシヒドロキシプロピルアルギニン塩およびカチオン性界面活性剤からなる群から選ばれる少なくとも１種である。上記成分Ｂは、１種のみを用いてもよいし、２種以上を用いてもよい。
[Component B]
In the aqueous composition of the present invention, component B is at least one selected from the group consisting of an alkyloxyhydroxypropyl arginine salt, a nonionic surfactant having an HLB of 12.0 to 17.0, and a cationic surfactant. Contains surfactants. In the aqueous composition of the present invention, by containing the component B, it is possible to impart wettability to the liquid layer of the amino acid-based organic powder and to suppress caking between the amino acid-based organic powders. Preferably, the surfactant is at least one selected from the group consisting of alkyloxyhydroxypropyl arginine salts and cationic surfactants. The above component B may be used alone or in combination of two or more.
上記アルキルオキシヒドロキシプロピルアルギニン塩は、アミノ酸系両性界面活性剤の一種である。アルキルオキシヒドロキシプロピルアルギニン塩は、アルキル基が１２および１４であるＮ－〔３－アルキル（１２，１４）オキシ－２－ヒドロキシプロピル〕－Ｌ－アルギニンの塩であることが好ましく、Ｎ－〔３－アルキル（１２，１４）オキシ－２－ヒドロキシプロピル〕－Ｌ－アルギニン塩酸塩であることがより好ましい。 The alkyloxyhydroxypropylarginine salt is a type of amino acid-based amphoteric surfactant. The alkyloxyhydroxypropyl arginine salt is preferably a salt of N-[3-alkyl(12,14)oxy-2-hydroxypropyl]-L-arginine in which the alkyl groups are 12 and 14; -alkyl(12,14)oxy-2-hydroxypropyl]-L-arginine hydrochloride is more preferred.
また、前記塩の対イオンとしては、例えば、アルカリ金属イオンが好ましく、ナトリウムイオン、カリウムイオンがより好ましく、ナトリウムイオンが特に好ましい。 Further, as the counter ion of the salt, for example, an alkali metal ion is preferable, a sodium ion and a potassium ion are more preferable, and a sodium ion is particularly preferable.
ＨＬＢが１２．０～１７．０のノニオン性界面活性剤としては、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステルの酸化エチレン縮合物、ポリエチレングリコール脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ソルビタン脂肪酸エステルの酸化エチレン縮合物、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油、ポリオキシエチレンラノリン等が挙げられる。 Examples of nonionic surfactants with an HLB of 12.0 to 17.0 include glycerin fatty acid esters, polyglycerin fatty acid esters, ethylene oxide condensates of glycerin fatty acid esters, polyethylene glycol fatty acid esters, propylene glycol fatty acid esters, and sorbitan fatty acids. Examples include ester, ethylene oxide condensate of sorbitan fatty acid ester, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin, and the like.
より具体的には、例えば、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリル等のグリセリン脂肪酸エステル；モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ（４～１０）グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ（２～１０）グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ（２～１０）グリセリル、ジステアリン酸ポリ（６～１０）グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ（１０）グリセリル等のポリグリセリン脂肪酸エステル； モノステアリン酸ポリオキシエチレングリセリル、モノオレイン酸ポリオキシエチレングリセリル等のグリセリン脂肪酸エステルの酸化エチレン縮合物；モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール等のポリエチレングリコール脂肪酸エステル；モノステアリン酸プロピレングリコール、モノラウリン酸プロピレングリコール、モノオレイン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル； モノオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、ヤシ油脂肪酸ソルビタン等のソルビタン脂肪酸エステル；モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタン等のソルビタン脂肪酸エステルの酸化エチレン縮合物；ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシプロピレンセチルエーテル、ポリオキシプロピレンイソセチルエーテル、ポリオキシプロピレンステアリルエーテル、ポリオキシプロピレンオレイルエーテル等のポリオキシアルキレンアルキルエーテル等が挙げられる。 More specifically, for example, glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate. , glyceryl fatty acid esters such as glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl dialachate; diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly(4-10) glyceryl monolaurate, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly(2-10) glyceryl monostearate, mono diglyceryl oleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly(2-10) glyceryl diisostearate, poly(6-10) glyceryl distearate, diglyceryl triisostearate, poly(10) tristearate Polyglycerin fatty acid esters such as glyceryl; ethylene oxide condensates of glycerin fatty acid esters such as polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate; polyethylene glycol monooleate, polyethylene glycol monostearate, and polyethylene glycol monolaurate. Polyethylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate, etc.; sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, and coconut oil fatty acid sorbitan; polyoxyethylene sorbitan monolaurate, polymonopalmitate Oxyethylene sorbitan, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, monococonut fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene trioleate Ethylene oxide condensates of sorbitan fatty acid esters such as sorbitan; polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether , polyoxyalkylene alkyl ethers such as polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, and polyoxypropylene oleyl ether.
これらの中でも、ＨＬＢが１２．０～１７．０のノニオン性界面活性剤は、酸化エチレンの平均付加モル数が４０～１００のポリオキシエチレン硬化ヒマシ油であることが好ましい。このようなポリオキシエチレン硬化ヒマシ油としては、ＰＥＧ－４０水添ヒマシ油、ＰＥＧ－６０水添ヒマシ油、ＰＥＧ－１００水添ヒマシ油が挙げられる。 Among these, the nonionic surfactant having an HLB of 12.0 to 17.0 is preferably polyoxyethylene hydrogenated castor oil having an average added mole number of ethylene oxide of 40 to 100. Examples of such polyoxyethylene hydrogenated castor oil include PEG-40 hydrogenated castor oil, PEG-60 hydrogenated castor oil, and PEG-100 hydrogenated castor oil.
また、上記ノニオン性界面活性剤のＨＬＢは、１２．０～１７．０であり、好ましくは１３．０～１７．０であり、より好ましくは１４．０～１７．０である。アミノ酸系有機粉体の液層への濡れ性を付与の観点から、当該ＨＬＢは、１２．０以上であればよい。また、アミノ酸系有機粉体の液層への濡れ性を付与の観点から、当該ＨＬＢは、１７．０以下であればよい。 Further, the HLB of the nonionic surfactant is 12.0 to 17.0, preferably 13.0 to 17.0, and more preferably 14.0 to 17.0. From the viewpoint of imparting wettability to the liquid layer of the amino acid-based organic powder, the HLB may be 12.0 or more. Further, from the viewpoint of imparting wettability to the liquid layer of the amino acid-based organic powder, the HLB may be 17.0 or less.
上記カチオン性界面活性剤としては、例えば、モノアルキル型４級アンモニウム塩、ジアルキル型４級アンモニウム塩、トリアルキル型４級アンモニウム塩、モノアルキルエーテル型４級アンモニウム塩、アルキルアミン、脂肪酸アミドアミン等が挙げられる。 Examples of the cationic surfactants include monoalkyl-type quaternary ammonium salts, dialkyl-type quaternary ammonium salts, trialkyl-type quaternary ammonium salts, monoalkyl ether-type quaternary ammonium salts, alkylamines, fatty acid amidoamines, and the like. Can be mentioned.
上記モノアルキル型４級アンモニウム塩としては、例えば、塩化ラウリルトリメチルアンモニウム、塩化ミリスチルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム（ステアルトリモニウムクロリド）、塩化ベへニルトリメチルアンモニウム、塩化アルキル（１６，１８）トリメチルアンモニウム、塩化アルキル（２０～２２）トリメチルアンモニウム、塩化ステアリルジメチルベンジルアンモニウム、塩化ミリスチルジメチルベンジルアンモニウム、塩化トリ（ポリオキシエチレン）ステアリルアンモニウム、塩化ジ（ポリオキシエチレン）オレイルメチルアンモニウム、ジステアロイルエチルジモニウムクロリドセテアリルアルコール（パルミタミドプロピルトリモニウムクロリド）等が挙げられる。 Examples of the monoalkyl quaternary ammonium salt include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride (steartrimonium chloride), behenyltrimethylammonium chloride, alkyl chloride (16 , 18) Trimethylammonium, alkyl(20-22)trimethylammonium chloride, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri(polyoxyethylene)stearylammonium chloride, di(polyoxyethylene)oleylmethylammonium chloride, Examples include stearoyl ethyldimonium chloride, cetearyl alcohol (palmitamidopropyltrimonium chloride), and the like.
上記脂肪酸アミドアミンとしては、例えば、ミリスチン酸ジメチルアミノエチルアミド、ミリスチン酸ジメチルアミノプロピルアミド、ミリスチン酸ジエチルアミノエチルアミド、ミリスチン酸ジエチルアミノプロピルアミド、パルミチン酸ジメチルアミノエチルアミド、パルミチン酸ジメチルアミノプロピルアミド、パルミチン酸ジエチルアミノエチルアミド、パルミチン酸ジエチルアミノプロピルアミド、ステアリン酸ジメチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミド、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジエチルアミノプロピルアミド、ステアリン酸ジプロピルアミノエチルアミド、ステアリン酸ジプロピルアミノプロピルアミド、ベヘニン酸ジメチルアミノエチルアミド、ベヘニン酸ジメチルアミノプロピルアミド、ベヘニン酸ジエチルアミノエチルアミド、ベヘニン酸ジエチルアミノプロピルアミド等が挙げられる。 Examples of the fatty acid amidoamine include myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, myristic acid diethylaminoethylamide, myristic acid diethylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, and palmitic acid. Diethylaminoethylamide, palmitic acid diethylaminopropylamide, stearic acid dimethylaminoethylamide, stearic acid dimethylaminopropylamide, stearic acid diethylaminoethylamide, stearic acid diethylaminopropylamide, stearic acid dipropylaminoethylamide, stearic acid dipropylaminopropylamide amide, behenic acid dimethylaminoethylamide, behenic acid dimethylaminopropylamide, behenic acid diethylaminoethylamide, behenic acid diethylaminopropylamide, and the like.
上記脂肪酸アミドアミンは、有機酸および／または無機酸により塩として用いられることが好ましい。上記有機酸としては、乳酸、リンゴ酸、クエン酸、酒石酸、酢酸等が挙げられる。また、上記無機酸としては、リン酸、塩酸、硫酸等が挙げられる。中でも、乳酸が好ましい。上記有機酸及び無機酸の含有量は、配合される脂肪酸アミドアミンを中和できる量であれば特に限定されない。 Preferably, the fatty acid amidoamine is used as a salt with an organic acid and/or an inorganic acid. Examples of the organic acids include lactic acid, malic acid, citric acid, tartaric acid, and acetic acid. Further, examples of the inorganic acids include phosphoric acid, hydrochloric acid, sulfuric acid, and the like. Among them, lactic acid is preferred. The contents of the organic acid and inorganic acid are not particularly limited as long as they can neutralize the fatty acid amidoamine blended.
上記カチオン性界面活性剤としては、上記の中でも、モノアルキル型４級アンモニウム塩、脂肪酸アミドアミンが好ましく、より好ましくは、塩化ステアリルトリメチルアンモニウム、塩化ベへニルトリメチルアンモニウム、塩化アルキル（１６，１８）トリメチルアンモニウム、塩化アルキル（２０～２２）トリメチルアンモニウム、ステアリン酸ジメチルアミノプロピルアミド、ジステアロイルエチルジモニウムクロリドセテアリルアルコール（パルミタミドプロピルトリモニウムクロリド）、塩化γ－グルコンアミドプロピルジメチルヒドロキシエチルアンモニウムである。 Among the above-mentioned cationic surfactants, monoalkyl-type quaternary ammonium salts and fatty acid amide amines are preferable, and stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, and alkyl(16,18)trimethyl chloride are more preferable. Ammonium, alkyl (20-22) trimethylammonium chloride, stearic acid dimethylaminopropylamide, distearoylethyldimonium chloride cetearyl alcohol (palmitamidopropyltrimonium chloride), γ-gluconamidopropyldimethylhydroxyethylammonium chloride. .
上記成分Ｂの含有量は、好ましくは０．００５～２．０質量％、より好ましくは０．０１０～１．５質量％、さらに好ましくは０．０２０～１．０質量％である。本発明の効果を発揮する観点から、上記含有量は０．００５質量％以上であればよい。また、水性組成物の使用感、すなわち、界面活性剤由来のべたつきに起因して成分Ａによる効果を損なうことを防止するとの観点から、上記含有量は２．０質量％以下であればよい。 The content of component B is preferably 0.005 to 2.0% by mass, more preferably 0.010 to 1.5% by mass, and still more preferably 0.020 to 1.0% by mass. From the viewpoint of exhibiting the effects of the present invention, the content may be 0.005% by mass or more. Further, from the viewpoint of preventing the effect of component A from being impaired due to the feeling of use of the aqueous composition, that is, stickiness derived from the surfactant, the above content may be 2.0% by mass or less.
〔成分Ｃ〕
本発明の水性組成物は、成分Ｃとして、スメクタイト型粘土鉱物を含有する。本発明の水性組成物において、上記成分Ｃを含有させることにより、アミノ酸系有機粉体を沈降させるだけでなく、分散性をも良好にすることができる。上記成分Ｃは、１種のみを用いてもよいし、２種以上を用いてもよい。
[Component C]
The aqueous composition of the present invention contains a smectite clay mineral as component C. In the aqueous composition of the present invention, by containing the component C, not only can the amino acid-based organic powder be precipitated, but also its dispersibility can be improved. The above component C may be used alone or in combination of two or more.
上記成分Ｃは、天然物であっても、合成物であってもよい。天然物のスメクタイト型粘土鉱物としては、モンモリロナイト、サポナイト、ヘクトライト、ベントナイト、ベイデライト、ノントロナイト、サウコナイト、およびステベンサイド等が挙げられる。また、合成物のスメクタイト型粘土鉱物としては、合成サポナイト、および合成ヘクトライト等が挙げられる。これらの中でも、上記成分Ｃは、ベントナイト、合成ヘクトライト（合成ケイ酸ナトリウム・マグネシウム）であることが好ましい。 The component C may be a natural product or a synthetic product. Examples of natural smectite clay minerals include montmorillonite, saponite, hectorite, bentonite, beidellite, nontronite, sauconite, and stevenside. In addition, examples of synthetic smectite clay minerals include synthetic saponite and synthetic hectorite. Among these, the component C is preferably bentonite or synthetic hectorite (synthetic sodium/magnesium silicate).
上記成分Ｃの含有量は、好ましくは０．０１～２．０質量％、より好ましくは０．０５～１．５質量％、さらに好ましくは０．１～１．０質量％である。本発明の効果を発揮する観点から、上記含有量は０．０１質量％以上であればよい。また、水性組成物の使用感、粘土鉱物由来のべたつきおよびきしみ感に起因して成分Ａによる効果を損なうことを防止するとの観点から、上記含有量は２．０質量％以下であればよい。 The content of the component C is preferably 0.01 to 2.0% by mass, more preferably 0.05 to 1.5% by mass, and even more preferably 0.1 to 1.0% by mass. From the viewpoint of exhibiting the effects of the present invention, the content may be 0.01% by mass or more. Further, from the viewpoint of preventing the effect of component A from being impaired due to the feeling of use of the aqueous composition, stickiness and squeaky feeling derived from clay minerals, the content may be 2.0% by mass or less.
〔成分Ｄ〕
本発明の水性組成物は、成分Ｄとして、水を含む。成分Ｄは、特に限定されないが、精製水が好ましい。成分Ｄの水の含有量は、成分Ｄ以外の成分の含有量に応じて適宜設定得るが、好ましくは３０．０～９９．０質量％である。
[Component D]
The aqueous composition of the present invention contains water as component D. Component D is not particularly limited, but purified water is preferred. The content of water in component D can be appropriately set depending on the content of components other than component D, but is preferably 30.0 to 99.0% by mass.
〔成分Ｅ〕
本発明の水性組成物は、成分Ｅとして、エタノールを含む。本発明の水性組成物において、上記成分Ｅを含有させることにより、さっぱり感の向上や、速乾性の向上という効果を奏する。成分Ｅの含有量は、所望する使用感に応じて適宜設定することができ、好ましくは０．１～６５．０質量％、より好ましくは１．０～５０．０質量％である。
[Component E]
The aqueous composition of the present invention contains ethanol as component E. In the aqueous composition of the present invention, by containing the above-mentioned component E, it is possible to improve the refreshing feeling and quick drying properties. The content of component E can be appropriately set depending on the desired feeling in use, and is preferably 0.1 to 65.0% by mass, more preferably 1.0 to 50.0% by mass.
〔その他の成分〕
本発明の水性組成物には、本発明の効果を損なわない範囲であれば、上記に記した成分の他、グリセリン、濃グリセリン、ジグリセリン、ポリグリセリン、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、１，３－ブチレングリコール、グルコース、マルトース、マルチトース、スクロース、マンニトール、ソルビトール、１，２－ペンタンジオール、１，２－ヘキサンジオール、１，２－オクタンジオール、グルコシルトレハロースなどの多価アルコール；ｌ－メントール、メンチルラクテート、カンファー、ｌ－メンチルグリセリルエーテル、ハッカ油、ペパーミント油などの清涼剤；アニオン性界面活性剤、上記アルキルオキシヒドロキシプロピルアルギニン塩以外の両性界面活性剤、抗酸化剤、金属封鎖剤、シリコーン類、脂肪酸エステル油、ビタミン類、ミネラル類、動植物エキス、着色剤、各種香料、防腐剤、殺菌剤、抗炎症剤、紫外線吸収剤、美白剤などを目的に応じて適宜配合してもよい。
[Other ingredients]
In addition to the above-mentioned ingredients, the aqueous composition of the present invention may include glycerin, concentrated glycerin, diglycerin, polyglycerin, ethylene glycol, polyethylene glycol, propylene glycol, di- Polyhydric alcohols such as propylene glycol, 1,3-butylene glycol, glucose, maltose, maltitose, sucrose, mannitol, sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, glucosyltrehalose, etc. ; Refreshing agents such as l-menthol, menthyl lactate, camphor, l-menthyl glyceryl ether, peppermint oil, peppermint oil; anionic surfactants, amphoteric surfactants other than the above alkyloxyhydroxypropyl arginine salts, antioxidants, Sequestering agents, silicones, fatty acid ester oils, vitamins, minerals, animal and plant extracts, coloring agents, various fragrances, preservatives, bactericidal agents, anti-inflammatory agents, ultraviolet absorbers, skin whitening agents, etc. are mixed as appropriate depending on the purpose. You may.
〔２．水性組成物の製造方法〕
本発明の水性組成物の製造方法は、公知の方法で調製することができる。例えば、液体成分が投入された容器に粉体成分を添加し、ディスパー等で攪拌・均一化することによって本発明の水性組成物を製造することができる。
[2. Method for producing aqueous composition]
The aqueous composition of the present invention can be prepared by a known method. For example, the aqueous composition of the present invention can be produced by adding a powder component to a container containing a liquid component and stirring and homogenizing it with a disper or the like.
〔３．本発明の水性組成物の用途〕
例えば、本発明の水性組成物は、２層型皮膚用ローションなどの皮膚用ローションとして使用することができる。この場合、上記皮膚用ローションは、体用のボディーローション、デオドラントローション；顔用の収れんローション、オイルコントロールローションなどの皮膚の何れの部位にも使用することができる。中でも、使用時のさっぱり感に優れ、かつ皮脂の抑制効果に優れる観点から、顔用のローション（化粧水）として使用されるのがより好ましい。
[3. Uses of the aqueous composition of the present invention]
For example, the aqueous composition of the invention can be used as a skin lotion, such as a two-layer skin lotion. In this case, the skin lotion can be used on any part of the skin, such as a body lotion or deodorant lotion for the body; an astringent lotion or an oil control lotion for the face. Among these, it is more preferable to use it as a facial lotion (lotion) from the viewpoint of providing an excellent refreshing feeling when used and having an excellent sebum suppressing effect.
また、本発明の水性組成物は、シート化粧料に使用することができる。シート化粧料は、織布、不織布等のシート基材に化粧料組成物を含浸させて形成されたシート形状の化粧料である。上記シート基材に含侵させる化粧料組成物として、本発明の水性組成物を使用することができる。 Furthermore, the aqueous composition of the present invention can be used in sheet cosmetics. A sheet cosmetic is a sheet-shaped cosmetic formed by impregnating a cosmetic composition into a sheet base material such as a woven fabric or a nonwoven fabric. The aqueous composition of the present invention can be used as the cosmetic composition impregnated into the sheet base material.
この場合、上記シート化粧料は、主に、皮膚（肌）を拭き取るために用いられる。上記シート化粧料により拭き取る部位としては、特に限定されず、例えば、腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中、顔面（例えば、額、目元、目じり、頬、口元等）、頭皮が挙げられる。上記シート化粧料としては、例えば、ボディ用拭き取りシート（頭皮用拭き取りシートを含む）、フェイス用拭き取りシート、ウェットティッシュ、使い捨ておしぼり、シート洗顔料（洗顔シート）、お尻拭きシート、メイク落としシート等が挙げられる。中でも、上記シート化粧料は、優れた冷感付与効果を発揮できるため、ボディ拭き取り用に特に好ましく用いられる。 In this case, the sheet cosmetic is mainly used to wipe off the skin. The areas to be wiped off with the sheet cosmetic are not particularly limited, and include, for example, arms, elbows, backs of hands, fingertips, feet, knees, heels, neck, armpits, back, face (for example, forehead, around the eyes, corners of the eyes, cheeks, mouth). etc.) and the scalp. Examples of the above-mentioned sheet cosmetics include body wiping sheets (including scalp wiping sheets), face wiping sheets, wet tissues, disposable towels, sheet facial cleansers (facial cleansing sheets), butt wiping sheets, makeup remover sheets, etc. can be mentioned. Among these, the above-mentioned sheet cosmetics are particularly preferably used for body wiping because they can exhibit an excellent effect of imparting a cooling sensation.
なお、上述した用途において、本発明の水性組成物は、化粧品、医薬部外品、医薬品、雑貨の何れの形態であってもよい。 In addition, in the above-mentioned uses, the aqueous composition of the present invention may be in the form of cosmetics, quasi-drugs, pharmaceuticals, or miscellaneous goods.
本発明の一実施例について、以下に説明する。 An embodiment of the present invention will be described below.
〔１．実施例１～１４、比較例１～１３〕
表１および表２に示した組成に従い、実施例１～１４および比較例１～１３の水性組成物（組成物１～２７）を調製した。得られた水性組成物の２５℃における粘度は、１００ｍＰａ・ｓ未満であった。
[1. Examples 1 to 14, Comparative Examples 1 to 13]
Aqueous compositions (compositions 1 to 27) of Examples 1 to 14 and Comparative Examples 1 to 13 were prepared according to the compositions shown in Tables 1 and 2. The resulting aqueous composition had a viscosity of less than 100 mPa·s at 25°C.
〔２．各成分の詳細〕
表１および表２中、各成分の詳細は以下の通りである。
[2. Details of each ingredient]
In Tables 1 and 2, details of each component are as follows.
＜成分Ａ：アミノ酸系有機粉体＞
ラウロイルリジン：味の素社製、製品名「アミホープ ＬＬ」。
<Component A: Amino acid-based organic powder>
Lauroyl lysine: Manufactured by Ajinomoto Co., product name "Amihope LL".
＜成分Ｂ：アルキルオキシヒドロキシプロピルアルギニン塩＞
アルキル（Ｃ１２，１４）オキシヒドロキシプロピルアルギニンＨＣｌ：味の素社製、製品名「アミセーフ ＬＭＡ－６０」。
<Component B: Alkyloxyhydroxypropyl arginine salt>
Alkyl (C12,14)oxyhydroxypropylarginine HCl: Manufactured by Ajinomoto Co., product name "Amisafe LMA-60".
＜両性界面活性剤＞
ラウラミドプロピルベタイン：新日本理化社製、製品名「リカビオン Ｂ－３００」。
<Ampholytic surfactant>
Lauramidopropyl betaine: Manufactured by Shin Nippon Rika Co., Ltd., product name "Rikavion B-300".
ココアンホ酢酸Na：川研ファインケミカル社製、製品名「ソフタゾリン ＣＨ」。 Sodium cocoamphoacetate: Manufactured by Kawaken Fine Chemicals, product name "Softazoline CH".
ラウロアンホ酢酸Na：川研ファインケミカル社製、製品名「ソフタゾリン ＬＨＬ」。 Sodium lauroamphoacetate: Manufactured by Kawaken Fine Chemicals, product name: "Softazoline LHL".
＜成分Ｂ：ノニオン性界面活性剤(HLB12.0～17.0)＞
ＰＥＧ－６０水添ヒマシ油(HLB14.8) ：青木油脂社製、製品名「ブラウノン ＲＣＷ－６０」。
<Component B: Nonionic surfactant (HLB12.0-17.0)>
PEG-60 hydrogenated castor oil (HLB14.8): Manufactured by Aoki Yushi Co., Ltd., product name "Brownon RCW-60".
ＰＥＧ－１００水添ヒマシ油(HLB16.5) ：日本エマルジョン社製、製品名「ＥＭＡＬＥＸ ＨＣ－１００」。 PEG-100 hydrogenated castor oil (HLB16.5): Manufactured by Nippon Emulsion Co., Ltd., product name "EMALEX HC-100".
＜ノニオン性界面活性剤＞
ＰＥＧ－３０水添ヒマシ油(HLB11.0) ：日本エマルジョン社製、製品名「ＥＭＡＬＥＸＨＣ－３０」。
<Nonionic surfactant>
PEG-30 hydrogenated castor oil (HLB11.0): Manufactured by Nippon Emulsion Co., Ltd., product name "EMALEXHC-30".
セテス－４０(HLB 17.4)：青木油脂社製、製品名「ブラウノン ＣＨ－３４０」。 Seteth-40 (HLB 17.4): Manufactured by Aoki Yushi Co., Ltd., product name "Brownon CH-340".
カプリル酸ポリグリセリル－３(HLB 11.1)：ＥＶＯＮＩＣ社製、製品名「ＴＥＧＯ Ｃｏｓｍｏ Ｐ８１３」。 Polyglyceryl-3 caprylate (HLB 11.1): manufactured by EVONIC, product name "TEGO Cosmo P813".
＜アニオン性界面活性剤＞
ラウレス硫酸Ｎａ：花王社製、製品名「エマール ２７０Ｊ」。
<Anionic surfactant>
Sodium laureth sulfate: Manufactured by Kao Corporation, product name "Emar 270J".
スルホコハク酸ラウレス２Ｎａ：新日本理化社製、製品名「リカマイルドＥＳ－１００」。 Laureth 2Na sulfosuccinate: Manufactured by Shin Nihon Rika Co., Ltd., product name "Rica Mild ES-100".
＜成分Ｂ：カチオン性界面活性剤＞
ステアルトリモニウムクロリド：花王社製、製品名「コータミン ８６Ｗ」。
<Component B: Cationic surfactant>
Steartrimonium chloride: Manufactured by Kao Corporation, product name "Cortamine 86W".
パルミタミドプロピルトリモニウムクロリド：ＥＶＯＮＩＣ社製、製品名「ＶＡＲＩＳＯＦＴ ＰＡＴＣ」。 Palmitamidopropyltrimonium chloride: manufactured by EVONIC, product name "VARISOFT PATC".
＜成分Ｃ：スメクタイト型粘土鉱物＞
ベントナイト：日本有機粘度社製、製品名「ベンゲル」。
<Component C: Smectite clay mineral>
Bentonite: Manufactured by Japan Organic Viscosity Co., Ltd., product name "Benger".
合成ヘクトライト（合成ケイ酸ナトリウム・マグネシウム）：ＢＹＫ社製、製品名「Ｌａｐｏｎｉｔｅ ＸＬＧ」。 Synthetic hectorite (synthetic sodium/magnesium silicate): manufactured by BYK, product name "Laponite XLG".
＜粘土鉱物＞
カオリン：竹原化学工業社製、製品名「カオリン ＪＰ－１００」。
<Clay minerals>
Kaolin: Manufactured by Takehara Chemical Industry Co., Ltd., product name "Kaolin JP-100".
〔３．評価：粉体濡れ性〕
粉体濡れ性は、調製した各組成物におけるアミノ酸系有機粉体の状態を目視で観察することで評価した。評価結果は、下記の基準に従って示す。
[3. Evaluation: Powder wettability]
Powder wettability was evaluated by visually observing the state of the amino acid-based organic powder in each prepared composition. Evaluation results are shown according to the following criteria.
（評価基準）
◎：全てのアミノ酸系有機粉体が、液層中に分散している、または再分散可能である。
○：一部のアミノ酸系有機粉体が気液界面に存在するが、９割以上のアミノ酸系有機粉体が、液層中に分散している、または再分散可能である。
×：９割以上のアミノ酸系有機粉体が気液界面に存在する。
(Evaluation criteria)
◎: All the amino acid-based organic powders are dispersed in the liquid layer or can be redispersed.
Good: Some amino acid-based organic powder exists at the gas-liquid interface, but 90% or more of the amino acid-based organic powder is dispersed in the liquid layer or can be redispersed.
×: 90% or more of the amino acid-based organic powder exists at the gas-liquid interface.
〔４．試験結果〕
表１および表２から、粉体濡れ性について、実施例１、参考例２～３、および実施例４～１４の水性組成物は、比較例１～１３の水性組成物よりも優れていることが明らかになった。したがって、実施例１、参考例２～３、および実施例４～１４の水性組成物は、アミノ酸系有機粉体を分散させる、あるいは再分散させることができる組成物である。
[4. Test results〕
From Tables 1 and 2, the aqueous compositions of Example 1 , Reference Examples 2 to 3, and Examples 4 to 14 are superior to the aqueous compositions of Comparative Examples 1 to 13 in terms of powder wettability. It became clear. Therefore, the aqueous compositions of Example 1 , Reference Examples 2 to 3, and Examples 4 to 14 are compositions in which the amino acid-based organic powder can be dispersed or redispersed.
〔処方例〕
［２層型皮膚用ローション］
ラウロイルリジン １．０質量％
アルキルオキシヒドロキシプロピルアルギニン塩 ０．０４質量％
ベントナイト ０．２質量％
エタノール １０．０質量％
１，２－オクタンジオール ０．２質量％
グリセリン ７．０質量％
サリチル酸 ０．１質量％
ｌ－メントール ０．３質量％
塩化ナトリウム ０．１質量％
リン酸Ｎａ ０．１質量％
リン酸２Ｎａ ０．３質量％
メチルパラベン ０．３質量％
香料 ０．０３質量％
精製水 残 余
合計 １００．０質量％。
[Prescription example]
[Two-layer skin lotion]
Lauroyl lysine 1.0% by mass
Alkyloxyhydroxypropyl arginine salt 0.04% by mass
Bentonite 0.2% by mass
Ethanol 10.0% by mass
1,2-octanediol 0.2% by mass
Glycerin 7.0% by mass
Salicylic acid 0.1% by mass
l-menthol 0.3% by mass
Sodium chloride 0.1% by mass
Sodium phosphate 0.1% by mass
DiNa phosphate 0.3% by mass
Methylparaben 0.3% by mass
Fragrance 0.03% by mass
Purified water remainder
Total 100.0% by mass.
［２層型腋臭防止剤］
ラウロイルリジン ４．０質量％
無水ケイ酸 ０．５質量％
塩化γ‐グルコンアミドプロピルジメチルヒドロキシエチルアンモニウム ０．１質量％
合成ヘクトライト（合成ケイ酸ナトリウム・マグネシウム） ０．４質量％
エタノール ３０．０質量％
ジプロピレングリコール ５．０質量％
ｌ－メントール ０．１質量％
パラフェノールスルホン酸亜鉛 ０．３質量％
イソプロピルメチルフェノール ０．１質量％
ヒドロキシエチルセルロース ０．０５質量％
香料 ０．０５質量％
精製水 残 余
合計 １００．０質量％。
[Two-layered armpit odor prevention agent]
Lauroyl lysine 4.0% by mass
Silicic anhydride 0.5% by mass
γ-gluconamidopropyldimethylhydroxyethylammonium chloride 0.1% by mass
Synthetic hectorite (synthetic sodium/magnesium silicate) 0.4% by mass
Ethanol 30.0% by mass
Dipropylene glycol 5.0% by mass
l-menthol 0.1% by mass
Zinc paraphenolsulfonate 0.3% by mass
Isopropylmethylphenol 0.1% by mass
Hydroxyethylcellulose 0.05% by mass
Fragrance 0.05% by mass
Purified water remainder
Total 100.0% by mass.
［シート化粧料］
不織布１００質量部に対し、下記組成からなる化粧料組成物４００質量部を含浸させて、シート化粧料とした。
ラウロイルリジン ３．０質量％
ＰＥＧ－６０水添ヒマシ油 ０．０５質量％
ベントナイト ０．２質量％
ＢＧ １０．０質量％
グリチルリチン酸ジカリウム ０．０５質量％
メチルパラベン ０．２質量％
フェノキシエタノール ０．６質量％
エタノール ４．０質量％
キサンタンガム ０．０３質量％
精製水 残 余
合計 １００．０質量％。
[Sheet cosmetics]
A sheet cosmetic was prepared by impregnating 100 parts by mass of the nonwoven fabric with 400 parts by mass of a cosmetic composition having the composition shown below.
Lauroyl lysine 3.0% by mass
PEG-60 hydrogenated castor oil 0.05% by mass
Bentonite 0.2% by mass
BG 10.0% by mass
Dipotassium glycyrrhizinate 0.05% by mass
Methylparaben 0.2% by mass
Phenoxyethanol 0.6% by mass
Ethanol 4.0% by mass
Xanthan gum 0.03% by mass
Purified water remainder
Total 100.0% by mass.
本発明の水性組成物は、皮膚用ローション、シート化粧料等に使用することができる。 The aqueous composition of the present invention can be used in skin lotions, sheet cosmetics, and the like.
Claims (3)
成分Ｂの含有量に対する成分Ａの含有量（Ａ／Ｂ）が、３００以下であり、
成分Ｃの含有量に対する成分Ａの含有量（Ａ／Ｃ）が、３５以下である、水性組成物；
成分Ａ：アミノ酸系有機粉体
成分Ｂ：アルキルオキシヒドロキシプロピルアルギニン塩、およびカチオン性界面活性剤からなる群から選ばれる少なくとも１種の界面活性剤
成分Ｃ：スメクタイト型粘土鉱物
成分Ｄ：水。 Contains the following ingredients A to D,
The content of component A relative to the content of component B (A/B) is 300 or less,
An aqueous composition in which the content of component A relative to the content of component C (A/C) is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one surfactant selected from the group consisting of alkyloxyhydroxypropyl arginine salts and cationic surfactants.
Component C: Smectite clay mineral Component D: Water.
前記成分Ｂの含有量が、０．００５～２．０質量％であり、
前記成分Ｃの含有量が、０．０１～２．０質量％である、請求項１に記載の水性組成物。 The content of the component A is 0.01 to 20.0% by mass,
The content of the component B is 0.005 to 2.0% by mass,
The aqueous composition according to claim 1, wherein the content of component C is 0.01 to 2.0% by mass.
成分Ｅ：エタノール。
The aqueous composition according to claim 1 or 2, further comprising the following component E;
Component E: Ethanol.
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| KR1020210018326A KR102565406B1 (en) | 2020-03-23 | 2021-02-09 | Aqueous composition |
| CN202110210547.4A CN113425613B (en) | 2020-03-23 | 2021-02-25 | Aqueous composition |
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|---|---|---|---|---|
| JP2008056609A (en) | 2006-08-31 | 2008-03-13 | Mandom Corp | Cleansing cosmetic material |
| JP2011051923A (en) | 2009-09-01 | 2011-03-17 | Mandom Corp | Two-layer cosmetic |
| JP2013517289A (en) | 2010-01-15 | 2013-05-16 | 味の素株式会社 | N-acyl basic amino acid dispersion |
| WO2017188279A1 (en) | 2016-04-26 | 2017-11-02 | 味の素株式会社 | Composition for cosmetics and cosmetic comprising same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08259434A (en) * | 1995-03-23 | 1996-10-08 | Shiseido Co Ltd | Liquid cosmetic |
| JP6139836B2 (en) * | 2012-09-25 | 2017-05-31 | 株式会社 資生堂 | Liquid antiperspirant composition |
| CN108348448B (en) * | 2015-10-05 | 2021-08-20 | 陶氏东丽株式会社 | Oil-in-water organopolysiloxane emulsion, method for producing same, cosmetic raw material, and cosmetic |
| WO2018008762A1 (en) | 2016-07-08 | 2018-01-11 | 味の素株式会社 | Cream-like composition |
| JP2017197559A (en) | 2017-06-09 | 2017-11-02 | 味の素株式会社 | Composite powders and makeup cosmetics |
| JP7327902B2 (en) | 2018-03-08 | 2023-08-16 | 株式会社ノエビア | detergent composition |
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Patent Citations (4)
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| JP2008056609A (en) | 2006-08-31 | 2008-03-13 | Mandom Corp | Cleansing cosmetic material |
| JP2011051923A (en) | 2009-09-01 | 2011-03-17 | Mandom Corp | Two-layer cosmetic |
| JP2013517289A (en) | 2010-01-15 | 2013-05-16 | 味の素株式会社 | N-acyl basic amino acid dispersion |
| WO2017188279A1 (en) | 2016-04-26 | 2017-11-02 | 味の素株式会社 | Composition for cosmetics and cosmetic comprising same |
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| CN113425613A (en) | 2021-09-24 |
| KR102565406B1 (en) | 2023-08-09 |
| JP2021147373A (en) | 2021-09-27 |
| KR20210118737A (en) | 2021-10-01 |
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