JP2021147373A - Aqueous composition - Google Patents
Aqueous composition Download PDFInfo
- Publication number
- JP2021147373A JP2021147373A JP2020051164A JP2020051164A JP2021147373A JP 2021147373 A JP2021147373 A JP 2021147373A JP 2020051164 A JP2020051164 A JP 2020051164A JP 2020051164 A JP2020051164 A JP 2020051164A JP 2021147373 A JP2021147373 A JP 2021147373A
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- aqueous composition
- content
- amino acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 83
- 239000000843 powder Substances 0.000 claims abstract description 65
- 150000001413 amino acids Chemical class 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002734 clay mineral Substances 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 229910021647 smectite Inorganic materials 0.000 claims abstract description 5
- 150000001484 arginines Chemical class 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000004615 ingredient Substances 0.000 claims description 4
- 229940024606 amino acid Drugs 0.000 description 42
- 235000001014 amino acid Nutrition 0.000 description 42
- -1 fatty acid salt Chemical class 0.000 description 41
- 239000007788 liquid Substances 0.000 description 31
- 235000014113 dietary fatty acids Nutrition 0.000 description 23
- 239000000194 fatty acid Substances 0.000 description 23
- 229930195729 fatty acid Natural products 0.000 description 23
- 239000002537 cosmetic Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- 239000004359 castor oil Substances 0.000 description 11
- 235000019438 castor oil Nutrition 0.000 description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 11
- 239000006210 lotion Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- GYDYJUYZBRGMCC-INIZCTEOSA-N (2s)-2-amino-6-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NCCCC[C@H](N)C(O)=O GYDYJUYZBRGMCC-INIZCTEOSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 150000001348 alkyl chlorides Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001483 arginine derivatives Chemical class 0.000 description 4
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 4
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 description 4
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 229910000275 saponite Inorganic materials 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- 229940031723 1,2-octanediol Drugs 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 2
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 229940081733 cetearyl alcohol Drugs 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- 229940068939 glyceryl monolaurate Drugs 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- RVRFYZGKUZFYAH-UHFFFAOYSA-N n',n'-dimethylpropane-1,3-diamine;octadecanoic acid Chemical compound CN(C)CCCN.CCCCCCCCCCCCCCCCCC(O)=O RVRFYZGKUZFYAH-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 2
- 229960003104 ornithine Drugs 0.000 description 2
- 235000019477 peppermint oil Nutrition 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 description 2
- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- XTJKNGLLPGBHHO-HNNXBMFYSA-N (2s)-5-(diaminomethylideneamino)-2-(dodecanoylamino)pentanoic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCN=C(N)N XTJKNGLLPGBHHO-HNNXBMFYSA-N 0.000 description 1
- OLDGKSQBWGEFNM-FQEVSTJZSA-N (2s)-6-amino-2-(hexadecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCCN OLDGKSQBWGEFNM-FQEVSTJZSA-N 0.000 description 1
- DEAFEFSHUVGNFC-JTQLQIEISA-N (2s)-6-amino-2-(hexanoylamino)hexanoic acid Chemical compound CCCCCC(=O)N[C@H](C(O)=O)CCCCN DEAFEFSHUVGNFC-JTQLQIEISA-N 0.000 description 1
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OKMWKBLSFKFYGZ-UHFFFAOYSA-N 1-behenoylglycerol Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(O)CO OKMWKBLSFKFYGZ-UHFFFAOYSA-N 0.000 description 1
- QHZLMUACJMDIAE-SFHVURJKSA-N 1-hexadecanoyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- VFDZFKXFURHHDU-UHFFFAOYSA-N 2-hydroxyethyl-dimethyl-propylazanium Chemical compound CCC[N+](C)(C)CCO VFDZFKXFURHHDU-UHFFFAOYSA-N 0.000 description 1
- CPSCNTYWVQYNOQ-UHFFFAOYSA-M 2-hydroxyethyl-dimethyl-propylazanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)CCO CPSCNTYWVQYNOQ-UHFFFAOYSA-M 0.000 description 1
- ZVTDEEBSWIQAFJ-KHPPLWFESA-N 2-hydroxypropyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(C)O ZVTDEEBSWIQAFJ-KHPPLWFESA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- IREAODMQYCOAGP-UHFFFAOYSA-N 3-(hexadecanoylamino)propyl-trimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC(=O)NCCC[N+](C)(C)C IREAODMQYCOAGP-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- CAKGLMPBYAPFCR-UWBMNBDUSA-N Bemisiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@@H](CO)O1 CAKGLMPBYAPFCR-UWBMNBDUSA-N 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- ZNVKGUVDRSSWHV-UHFFFAOYSA-L zinc;4-hydroxybenzenesulfonate Chemical compound [Zn+2].OC1=CC=C(S([O-])(=O)=O)C=C1.OC1=CC=C(S([O-])(=O)=O)C=C1 ZNVKGUVDRSSWHV-UHFFFAOYSA-L 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
Description
本発明は、水性組成物に関する。 The present invention relates to aqueous compositions.
従来、皮膚外用剤、メイクアップ化粧料などの感触改良剤としてナイロン等のプラスチックパウダーが主に使用されてきた。しかしながら、プラスチックパウダーは、生分解性が低い。このため、プラスチックパウダーによる環境への影響が問題となり、プラスチックパウダーの使用を控える必要がある。 Conventionally, plastic powders such as nylon have been mainly used as feel improvers for external preparations for skin and makeup cosmetics. However, plastic powder has low biodegradability. For this reason, the impact of plastic powder on the environment becomes a problem, and it is necessary to refrain from using plastic powder.
生分解性の高い粉体の一つとして、アミノ酸と脂肪酸とからなるアミノ酸系有機粉体が挙げられる。アミノ酸系有機粉体は、水にも有機溶媒にもほとんど溶解せず、撥水性に優れているという特性を有することが知られている。 As one of the highly biodegradable powders, there is an amino acid-based organic powder composed of amino acids and fatty acids. Amino acid-based organic powder is known to have a property of being excellent in water repellency because it is hardly soluble in water or an organic solvent.
アミノ酸系有機粉体を配合した組成物は、例えば特許文献1〜3に開示されている。特許文献1には、メイクアップ化粧料にアミノ酸系有機粉体を配合することによって、使用感や撥水性を向上させる技術が開示されている。また、特許文献2には、クリーム状組成物にアミノ酸系粉体を配合することによって、高級感のあるパール状光沢を有するクリーム状の外観とし、形態安定性を向上させる技術が開示されている。また、特許文献3には、高級脂肪酸を含有する洗浄剤組成物にアミノ酸系有機粉体を配合することによって、洗浄力や泡質などを向上させる技術が開示されている。 Compositions containing amino acid-based organic powders are disclosed in, for example, Patent Documents 1 to 3. Patent Document 1 discloses a technique for improving usability and water repellency by blending an amino acid-based organic powder with a make-up cosmetic. Further, Patent Document 2 discloses a technique for blending an amino acid-based powder into a cream-like composition to give a cream-like appearance having a high-grade pearly luster and improving morphological stability. .. Further, Patent Document 3 discloses a technique for improving detergency, foam quality, etc. by blending an amino acid-based organic powder with a detergent composition containing a higher fatty acid.
特許文献1および2には、油性組成物にアミノ酸系有機粉体を配合することは記載されているが、水性組成物にアミノ酸系有機粉体を配合することの記載はない。また、特許文献3には、高級脂肪酸塩およびアミノ酸系有機粉体を含有する洗浄料組成物が記載されている。しかし、特許文献3に記載の技術は、洗浄料組成物の高い粘性によりアミノ酸系有機粉体を分散させているに過ぎず、全ての水性組成物に適用できる技術ではない。アミノ酸系有機粉体は、撥水性に優れるため、水性組成物の液層にアミノ酸系有機粉体を分散させることは困難である。それゆえ、アミノ酸系有機粉体を含有する水性組成物を調製することは困難であった。 Patent Documents 1 and 2 describe that an amino acid-based organic powder is blended in an oil-based composition, but do not describe that an amino acid-based organic powder is blended in an aqueous composition. Further, Patent Document 3 describes a cleaning composition containing a higher fatty acid salt and an amino acid-based organic powder. However, the technique described in Patent Document 3 merely disperses the amino acid-based organic powder due to the high viscosity of the cleaning agent composition, and is not a technique applicable to all aqueous compositions. Since the amino acid-based organic powder is excellent in water repellency, it is difficult to disperse the amino acid-based organic powder in the liquid layer of the aqueous composition. Therefore, it has been difficult to prepare an aqueous composition containing an amino acid-based organic powder.
本発明は、水性組成物の液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることが可能な水性組成物を実現することを目的とする。 An object of the present invention is to realize an aqueous composition capable of dispersing or redispersing an amino acid-based organic powder in the liquid layer of the aqueous composition.
本発明者らは、上記課題を解決するために鋭意検討した結果、(i)アミノ酸系有機粉体、特定の界面活性剤、および粘土鉱物を配合し、(ii)当該界面活性剤および当該粘土鉱物の含有量に対するアミノ酸系有機粉体の含有量の比率を特定範囲にした水性組成物であれば、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができるという新規知見を見出し、本発明を完成するに至った。すなわち、本発明は以下の構成を含む。 As a result of diligent studies to solve the above problems, the present inventors have added (i) an amino acid-based organic powder, a specific surfactant, and a clay mineral, and (ii) the surfactant and the clay. A new finding that an aqueous composition in which the ratio of the content of amino acid-based organic powder to the content of mineral is within a specific range can be dispersed or re-dispersed in the liquid layer. The present invention has been completed. That is, the present invention includes the following configurations.
〔1〕下記成分A〜Dを含有し、
成分Bの含有量に対する成分Aの含有量(A/B)が、300以下であり、
成分Cの含有量に対する成分Aの含有量(A/C)が、35以下である、水性組成物;
成分A:アミノ酸系有機粉体
成分B:アルキルオキシヒドロキシプロピルアルギニン塩、HLBが12.0〜17.0のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも1種の界面活性剤
成分C:スメクタイト型粘土鉱物
成分D:水。
[1] Containing the following components A to D,
The content (A / B) of the component A with respect to the content of the component B is 300 or less.
An aqueous composition in which the content of component A (A / C) relative to the content of component C is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one selected from the group consisting of alkyloxyhydroxypropyl arginine salts, nonionic surfactants having an HLB of 12.0 to 17.0, and cationic surfactants. Surfactant Component C: Smectite type clay mineral Component D: Water.
〔2〕上記成分Aの含有量が、0.01〜20.0質量%であり、上記成分Bの含有量が、0.005〜2.0質量%であり、上記成分Cの含有量が、0.01〜2.0質量%である、〔1〕の水性組成物。 [2] The content of the component A is 0.01 to 20.0% by mass, the content of the component B is 0.005 to 2.0% by mass, and the content of the component C is 0.005 to 2.0% by mass. , 0.01-2.0% by mass, the aqueous composition of [1].
〔3〕下記成分Eをさらに含む、〔1〕または〔2〕の水性組成物;
成分E:エタノール。
[3] The aqueous composition of [1] or [2] further comprising the following component E;
Ingredient E: Ethanol.
本発明の水性組成物によれば、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができる。 According to the aqueous composition of the present invention, the amino acid-based organic powder can be dispersed or redispersed in the liquid layer.
以下、本発明の実施の形態の一例について詳細に説明するが、本発明は、これらに限定されない。本発明は、以下に説明する各構成に限定されるものではなく、請求の範囲に示した範囲で種々の変更が可能である。また、異なる実施形態または実施例にそれぞれ開示された技術的手段を適宜組み合わせて得られる実施形態または実施例についても、本発明の技術的範囲に含まれる。さらに、各実施形態にそれぞれ開示された技術的手段を組み合わせることにより、新しい技術的特徴を形成することができる。なお、本明細書中に記載された学術文献および特許文献の全てが、本明細書中において参考文献として援用される。 Hereinafter, examples of embodiments of the present invention will be described in detail, but the present invention is not limited thereto. The present invention is not limited to the configurations described below, and various modifications can be made within the scope of the claims. The technical scope of the present invention also includes embodiments or examples obtained by appropriately combining the technical means disclosed in the different embodiments or examples. Furthermore, new technical features can be formed by combining the technical means disclosed in each embodiment. In addition, all the academic documents and patent documents described in the present specification are incorporated as references in the present specification.
本明細書において特記しない限り、数値範囲を表す「X〜Y」は、「X以上Y以下」を意図する。また、本明細書において特記しない限り、成分の含有量を表す質量%は、水性組成物全体の質量を100質量%とした値である。 Unless otherwise specified in the present specification, "X to Y" representing a numerical range is intended to be "X or more and Y or less". Further, unless otherwise specified in the present specification, the mass% representing the content of the component is a value in which the mass of the entire aqueous composition is 100% by mass.
〔1.水性組成物〕
本発明に係る水性組成物は、下記成分A〜Dを含有し、
成分Bの含有量に対する成分Aの含有量(A/B)が、300以下であり、
成分Cの含有量に対する成分Aの含有量(A/C)が、35以下である、水性組成物である;
成分A:アミノ酸系有機粉体
成分B:アルキルオキシヒドロキシプロピルアルギニン塩、HLBが12.0〜17.0のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも1種の界面活性剤
成分C:スメクタイト型粘土鉱物
成分D:水。
[1. Aqueous composition]
The aqueous composition according to the present invention contains the following components A to D and contains the following components A to D.
The content (A / B) of the component A with respect to the content of the component B is 300 or less.
An aqueous composition in which the content of component A (A / C) relative to the content of component C is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one selected from the group consisting of alkyloxyhydroxypropyl arginine salts, nonionic surfactants having an HLB of 12.0 to 17.0, and cationic surfactants. Surfactant Component C: Smectite type clay mineral Component D: Water.
本発明では、上記組成を有することによって、液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させることができる水性組成物を実現することができる。ここで、「液層中にアミノ酸系有機粉体を分散させる、あるいは再分散させる」とは、換言すると、液層に対して有機粉体が濡れ性を有するともいえる。当該濡れ性を有する状態とは、液層とともに有機粉体を撹拌したとき、有機粉体が、液層の液面よりも下に存在する状態をいう。一方、濡れ性を有さない状態とは、水性組成物とともにアミノ酸系有機粉体を撹拌したとき、アミノ酸系有機粉体が液層の液面上(気液界面)に留まったままの状態をいう。 In the present invention, by having the above composition, it is possible to realize an aqueous composition capable of dispersing or redispersing the amino acid-based organic powder in the liquid layer. Here, "dispersing or redispersing the amino acid-based organic powder in the liquid layer" can be said to mean that the organic powder has wettability with respect to the liquid layer. The wettability state means a state in which the organic powder is present below the liquid surface of the liquid layer when the organic powder is stirred together with the liquid layer. On the other hand, the non-wetting state is a state in which the amino acid-based organic powder remains on the liquid surface (gas-liquid interface) of the liquid layer when the amino acid-based organic powder is stirred together with the aqueous composition. say.
また、本発明の水性組成物においては、液層中に有機粉体が濡れ粉体層として存在する2層形態であっても、アミノ酸系有機粉体は、液層中に分散しているといえる。当該2層形態としては、例えば、(i)液層の液面下側から液面近くに有機粉体が濡れ粉体層として存在する形態、(ii)液層の底部へ有機粉体が沈降し、当該底部に有機粉体が濡れ粉体層として存在する形態等が挙げられる。 Further, in the aqueous composition of the present invention, even in the two-layer form in which the organic powder exists as a wet powder layer in the liquid layer, the amino acid-based organic powder is dispersed in the liquid layer. I can say. The two-layer form includes, for example, (i) a form in which organic powder exists as a wet powder layer from below the liquid surface of the liquid layer near the liquid surface, and (ii) organic powder settles on the bottom of the liquid layer. However, a form in which the organic powder exists as a wet powder layer on the bottom thereof can be mentioned.
また、本発明において、「水性組成物」とは、実質的に油剤を含有しない組成物をいう。より具体的には、「水性組成物」は、油剤が3.0質量%以下、好ましくは1.0質量%以下、より好ましくは0.5質量%以下の組成物である。さらに、上記油剤としては、油脂、ロウ、シリコーン油、炭化水素、エステル油等が挙げられる。 Further, in the present invention, the "aqueous composition" refers to a composition that does not substantially contain an oil agent. More specifically, the "aqueous composition" is a composition in which the oil agent is 3.0% by mass or less, preferably 1.0% by mass or less, and more preferably 0.5% by mass or less. Further, examples of the above-mentioned oil agent include fats and oils, waxes, silicone oils, hydrocarbons, ester oils and the like.
また、本発明の水性組成物は、25℃における粘度が1000mPa・s以下の液状組成物であることが好ましく、500mPa・s以下の液状組成物であることがより好ましい。上記粘度は、例えば、B型粘度計:VISCTER TV−25(東機産業社製)、若しくは、音叉式振動粘度計:SV−10A(北浜製作所社製)により測定することができる。 Further, the aqueous composition of the present invention is preferably a liquid composition having a viscosity at 25 ° C. of 1000 mPa · s or less, and more preferably 500 mPa · s or less. The viscosity can be measured by, for example, a B-type viscometer: VISCTER TV-25 (manufactured by Toki Sangyo Co., Ltd.) or a tuning fork type vibration viscometer: SV-10A (manufactured by Kitahama Seisakusho Co., Ltd.).
クリーム状組成物およびジェル状組成物の粘度は、1000mPa・sを超える。このような組成物に対しては、濡れ性に関係なく、有機粉体を分散して配合することが可能である。 The viscosities of the cream and gel compositions exceed 1000 mPa · s. For such a composition, the organic powder can be dispersed and blended regardless of the wettability.
一方、液状の水性組成物に対して有機粉体を分散して配合するためには、当該水性組成物の液層に対して有機粉体が濡れ性を有することが必要となる。本発明者らは、驚くべきことに、上記成分A〜Dを配合することによって、有機粉体が水性組成物の液層に対して濡れ性を有するという新規知見を見出した。 On the other hand, in order to disperse and blend the organic powder with respect to the liquid aqueous composition, it is necessary that the organic powder has wettability with respect to the liquid layer of the aqueous composition. Surprisingly, the present inventors have found a novel finding that the organic powder has wettability with respect to the liquid layer of the aqueous composition by blending the above components A to D.
また、本発明の水性組成物は、上記成分A〜Dに加えて、成分E:エタノールをさらに含んでいてもよい。本発明の水性組成物は、上述した成分以外に、他の成分を含んでいてもよい。 Further, the aqueous composition of the present invention may further contain component E: ethanol in addition to the above components A to D. The aqueous composition of the present invention may contain other components in addition to the above-mentioned components.
成分Bの含有量に対する成分Aの含有量(A/B)が、300以下であり、好ましくは2〜250であり、より好ましくは5〜200である。上述の範囲であれば、スメクタイト型粘土鉱物(成分C)の過多によるべたつきの発生を抑制できる。また成分Aの過少による成分Aの効果喪失の恐れを考慮すると、A/Bは、0を超えていればよい。 The content (A / B) of the component A with respect to the content of the component B is 300 or less, preferably 2 to 250, and more preferably 5 to 200. Within the above range, the occurrence of stickiness due to an excess of smectite-type clay mineral (component C) can be suppressed. Further, considering the possibility of loss of the effect of the component A due to the insufficient amount of the component A, the A / B may exceed 0.
成分Cの含有量に対する成分Aの含有量(A/C)が、35以下であり、好ましくは0.1〜30であり、より好ましくは1〜25である。上述の範囲であれば、スメクタイト型粘土鉱物(成分C)の過多によるべたつきの発生を抑制でき、また泡立が過剰となる恐れを抑制し得る。また成分Aの過少による成分Aの効果喪失の恐れを考慮すると、A/Cは、0を超えていればよい。 The content (A / C) of the component A with respect to the content of the component C is 35 or less, preferably 0.1 to 30, and more preferably 1 to 25. Within the above range, the occurrence of stickiness due to an excess of smectite-type clay mineral (component C) can be suppressed, and the possibility of excessive foaming can be suppressed. Further, considering the possibility of loss of the effect of the component A due to the insufficient amount of the component A, the A / C may exceed 0.
以下では、本発明の水性組成物を構成する成分について説明する。 Hereinafter, the components constituting the aqueous composition of the present invention will be described.
〔成分A〕
本発明の水性組成物は、成分Aとして、アミノ酸系有機粉体を含有する。本発明の水性組成物において、上記成分Aを含有させることにより、皮膚に対し塗布後に、サラサラした感触、所謂、サラサラ感を付与するという効果を奏する。上記成分Aは、1種のみを用いてもよいし、2種以上を用いてもよい。
[Component A]
The aqueous composition of the present invention contains an amino acid-based organic powder as component A. In the aqueous composition of the present invention, the inclusion of the above component A has the effect of imparting a smooth feel, a so-called smooth feel, to the skin after application. As the component A, only one kind may be used, or two or more kinds may be used.
上記アミノ酸系有機粉体としては、水性組成物に配合し得るものであれば特に限定されない。具体的には、ラウロイルリジン、パルミトイルリジン、カプロイルリジン等のアシルリジン;ステアロイルオルニチン等のアシルオルニチン;ラウロイルアルギニン等のアシルアルギニン;ココイルヒスチジン等のアシルヒスチジン等のアシル塩基性アミノ酸等が挙げられる。市販品としては、ラウロイルリジンであるアミホープLL(味の素社製)等を用いることができる。 The amino acid-based organic powder is not particularly limited as long as it can be blended in an aqueous composition. Specific examples thereof include acyl lysines such as lauroyl lysine, palmitoyl lysine and caproyl lysine; acyl ornithine such as stearoyl ornithine; acyl arginine such as lauroyl arginine; and acyl basic amino acids such as acyl histidine such as cocoyl histidine. As a commercially available product, Amihope LL (manufactured by Ajinomoto Co., Inc.), which is lauroyl lysine, can be used.
また、成分Aの含有量は、好ましくは0.01〜20.0質量%、より好ましくは0.1〜15.0質量%、さらに好ましくは0.5〜10.0質量%である。アミノ酸系有機粉体による効果を発揮する観点から、上記含有量は、0.01質量%以上であればよい。また、本発明の水性組成物の使用感の観点から、上記含有量は、20.0質量%以下であればよい。 The content of the component A is preferably 0.01 to 20.0% by mass, more preferably 0.1 to 15.0% by mass, and further preferably 0.5 to 10.0% by mass. From the viewpoint of exerting the effect of the amino acid-based organic powder, the above content may be 0.01% by mass or more. Further, from the viewpoint of usability of the aqueous composition of the present invention, the content may be 20.0% by mass or less.
〔成分B〕
本発明の水性組成物は、成分Bとして、アルキルオキシヒドロキシプロピルアルギニン塩、HLBが12.0〜17.0のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも1種の界面活性剤を含有する。本発明の水性組成物において、上記成分Bを含有させることにより、アミノ酸系有機粉体の液層への濡れ性を付与し、アミノ酸系有機粉体同士のケーキングを抑制することができる。好ましくは、前記界面活性剤は、アルキルオキシヒドロキシプロピルアルギニン塩およびカチオン性界面活性剤からなる群から選ばれる少なくとも1種である。上記成分Bは、1種のみを用いてもよいし、2種以上を用いてもよい。
[Component B]
The aqueous composition of the present invention is at least one selected from the group consisting of an alkyloxyhydroxypropyl arginine salt, a nonionic surfactant having an HLB of 12.0 to 17.0, and a cationic surfactant as component B. Contains the surfactant of. By containing the above-mentioned component B in the aqueous composition of the present invention, the wettability of the amino acid-based organic powder to the liquid layer can be imparted, and the caking of the amino acid-based organic powders can be suppressed. Preferably, the surfactant is at least one selected from the group consisting of alkyloxyhydroxypropyl arginine salts and cationic surfactants. As the component B, only one kind may be used, or two or more kinds may be used.
上記アルキルオキシヒドロキシプロピルアルギニン塩は、アミノ酸系両性界面活性剤の一種である。アルキルオキシヒドロキシプロピルアルギニン塩は、アルキル基が12および14であるN−〔3−アルキル(12,14)オキシ−2−ヒドロキシプロピル〕−L−アルギニンの塩であることが好ましく、N−〔3−アルキル(12,14)オキシ−2−ヒドロキシプロピル〕−L−アルギニン塩酸塩であることがより好ましい。 The alkyloxyhydroxypropylarginine salt is a kind of amino acid amphoteric surfactant. The alkyloxyhydroxypropylarginine salt is preferably a salt of N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine having alkyl groups 12 and 14, preferably N- [3. -Alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride is more preferred.
また、前記塩の対イオンとしては、例えば、アルカリ金属イオンが好ましく、ナトリウムイオン、カリウムイオンがより好ましく、ナトリウムイオンが特に好ましい。 Further, as the counter ion of the salt, for example, an alkali metal ion is preferable, a sodium ion and a potassium ion are more preferable, and a sodium ion is particularly preferable.
HLBが12.0〜17.0のノニオン性界面活性剤としては、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステルの酸化エチレン縮合物、ポリエチレングリコール脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ソルビタン脂肪酸エステルの酸化エチレン縮合物、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油、ポリオキシエチレンラノリン等が挙げられる。 Nonionic surfactants having an HLB of 12.0 to 17.0 include, for example, glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyethylene glycol fatty acid ester, propylene glycol fatty acid ester, and sorbitan fatty acid. Examples thereof include esters, ethylene oxide condensates of sorbitan fatty acid esters, polyoxyalkylene alkyl ethers, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin and the like.
より具体的には、例えば、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリル等のグリセリン脂肪酸エステル;モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ(4〜10)グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ(2〜10)グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ(2〜10)グリセリル、ジステアリン酸ポリ(6〜10)グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ(10)グリセリル等のポリグリセリン脂肪酸エステル; モノステアリン酸ポリオキシエチレングリセリル、モノオレイン酸ポリオキシエチレングリセリル等のグリセリン脂肪酸エステルの酸化エチレン縮合物;モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール等のポリエチレングリコール脂肪酸エステル;モノステアリン酸プロピレングリコール、モノラウリン酸プロピレングリコール、モノオレイン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル; モノオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、ヤシ油脂肪酸ソルビタン等のソルビタン脂肪酸エステル;モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタン等のソルビタン脂肪酸エステルの酸化エチレン縮合物;ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシプロピレンセチルエーテル、ポリオキシプロピレンイソセチルエーテル、ポリオキシプロピレンステアリルエーテル、ポリオキシプロピレンオレイルエーテル等のポリオキシアルキレンアルキルエーテル等が挙げられる。 More specifically, for example, glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate. , Glyceryl monoerkaate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diaraquinate and other glycerin fatty acid esters; Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, mono Diglyceryl oleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly diisostearate (2-10) glyceryl, poly distearate (6-10) glyceryl, diglyceryl triisostearate, poly tristearate (10) Polyglycerin fatty acid esters such as glyceryl; ethylene oxide condensates of glycerin fatty acid esters such as polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate; polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate Polyethylene glycol fatty acid esters such as; propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate and other propylene glycol fatty acid esters; sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, etc. Solbitan fatty acid esters such as sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, sorbitan coconut oil; polyoxyethylene sorbitan monolaurate, poly monopalmitate Oxyethylene sorbitan, polyoxyethylene sorbitan monostearate, Ethylene oxide condensates of sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, polyoxyethylene sorbitan monococonut oil, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan trioleate; Polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether Examples thereof include polyoxyalkylene alkyl ethers such as ether and polyoxypropylene oleyl ether.
これらの中でも、HLBが12.0〜17.0のノニオン性界面活性剤は、酸化エチレンの平均付加モル数が40〜100のポリオキシエチレン硬化ヒマシ油であることが好ましい。このようなポリオキシエチレン硬化ヒマシ油としては、PEG−40水添ヒマシ油、PEG−60水添ヒマシ油、PEG−100水添ヒマシ油が挙げられる。 Among these, the nonionic surfactant having an HLB of 12.0 to 17.0 is preferably polyoxyethylene hydrogenated castor oil having an average addition molar number of ethylene oxide of 40 to 100. Examples of such polyoxyethylene hydrogenated castor oil include PEG-40 hydrogenated castor oil, PEG-60 hydrogenated castor oil, and PEG-100 hydrogenated castor oil.
また、上記ノニオン性界面活性剤のHLBは、12.0〜17.0であり、好ましくは13.0〜17.0であり、より好ましくは14.0〜17.0である。アミノ酸系有機粉体の液層への濡れ性を付与の観点から、当該HLBは、12.0以上であればよい。また、アミノ酸系有機粉体の液層への濡れ性を付与の観点から、当該HLBは、17.0以下であればよい。 The HLB of the nonionic surfactant is 12.0 to 17.0, preferably 13.0 to 17.0, and more preferably 14.0 to 17.0. From the viewpoint of imparting wettability to the liquid layer of the amino acid-based organic powder, the HLB may be 12.0 or more. Further, from the viewpoint of imparting wettability to the liquid layer of the amino acid-based organic powder, the HLB may be 17.0 or less.
上記カチオン性界面活性剤としては、例えば、モノアルキル型4級アンモニウム塩、ジアルキル型4級アンモニウム塩、トリアルキル型4級アンモニウム塩、モノアルキルエーテル型4級アンモニウム塩、アルキルアミン、脂肪酸アミドアミン等が挙げられる。 Examples of the cationic surfactant include monoalkyl type quaternary ammonium salt, dialkyl type quaternary ammonium salt, trialkyl type quaternary ammonium salt, monoalkyl ether type quaternary ammonium salt, alkylamine, fatty acid amidamine and the like. Can be mentioned.
上記モノアルキル型4級アンモニウム塩としては、例えば、塩化ラウリルトリメチルアンモニウム、塩化ミリスチルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム(ステアルトリモニウムクロリド)、塩化ベへニルトリメチルアンモニウム、塩化アルキル(16,18)トリメチルアンモニウム、塩化アルキル(20〜22)トリメチルアンモニウム、塩化ステアリルジメチルベンジルアンモニウム、塩化ミリスチルジメチルベンジルアンモニウム、塩化トリ(ポリオキシエチレン)ステアリルアンモニウム、塩化ジ(ポリオキシエチレン)オレイルメチルアンモニウム、ジステアロイルエチルジモニウムクロリドセテアリルアルコール(パルミタミドプロピルトリモニウムクロリド)等が挙げられる。 Examples of the monoalkyl type quaternary ammonium salt include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride (stealtrimonium chloride), behenyltrimethylammonium chloride, and alkyl chloride (16). , 18) trimethylammonium, alkyl (20-22) trimethylammonium, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri (polyoxyethylene) stearylammonium chloride, di (polyoxyethylene) oleylmethylammonium, di Examples thereof include stearoyl ethyldimonium chloride cetearyl alcohol (palmitamide propyltrimonium chloride).
上記脂肪酸アミドアミンとしては、例えば、ミリスチン酸ジメチルアミノエチルアミド、ミリスチン酸ジメチルアミノプロピルアミド、ミリスチン酸ジエチルアミノエチルアミド、ミリスチン酸ジエチルアミノプロピルアミド、パルミチン酸ジメチルアミノエチルアミド、パルミチン酸ジメチルアミノプロピルアミド、パルミチン酸ジエチルアミノエチルアミド、パルミチン酸ジエチルアミノプロピルアミド、ステアリン酸ジメチルアミノエチルアミド、ステアリン酸ジメチルアミノプロピルアミド、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジエチルアミノプロピルアミド、ステアリン酸ジプロピルアミノエチルアミド、ステアリン酸ジプロピルアミノプロピルアミド、ベヘニン酸ジメチルアミノエチルアミド、ベヘニン酸ジメチルアミノプロピルアミド、ベヘニン酸ジエチルアミノエチルアミド、ベヘニン酸ジエチルアミノプロピルアミド等が挙げられる。 Examples of the fatty acid amide amine include myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, myristic acid diethylaminoethylamide, myristic acid diethylaminopropylamide, palmitate dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, and palmitic acid. Diethylaminoethylamide, diethylaminopropylamide palmitate, dimethylaminoethylamide stearate, dimethylaminopropylamide stearate, diethylaminoethylamide stearate, diethylaminopropylamide stearate, dipropylaminoethyl stearate, dipropylaminopropyl stearate Examples thereof include amides, behenic acid dimethylaminoethylamides, behenic acid dimethylaminopropylamides, behenic acid diethylaminoethylamides, and behenic acid diethylaminopropylamides.
上記脂肪酸アミドアミンは、有機酸および/または無機酸により塩として用いられることが好ましい。上記有機酸としては、乳酸、リンゴ酸、クエン酸、酒石酸、酢酸等が挙げられる。また、上記無機酸としては、リン酸、塩酸、硫酸等が挙げられる。中でも、乳酸が好ましい。上記有機酸及び無機酸の含有量は、配合される脂肪酸アミドアミンを中和できる量であれば特に限定されない。 The fatty acid amidoamine is preferably used as a salt by an organic acid and / or an inorganic acid. Examples of the organic acid include lactic acid, malic acid, citric acid, tartaric acid, acetic acid and the like. Examples of the inorganic acid include phosphoric acid, hydrochloric acid, sulfuric acid and the like. Of these, lactic acid is preferable. The contents of the organic acid and the inorganic acid are not particularly limited as long as they can neutralize the fatty acid amidoamine to be blended.
上記カチオン性界面活性剤としては、上記の中でも、モノアルキル型4級アンモニウム塩、脂肪酸アミドアミンが好ましく、より好ましくは、塩化ステアリルトリメチルアンモニウム、塩化ベへニルトリメチルアンモニウム、塩化アルキル(16,18)トリメチルアンモニウム、塩化アルキル(20〜22)トリメチルアンモニウム、ステアリン酸ジメチルアミノプロピルアミド、ジステアロイルエチルジモニウムクロリドセテアリルアルコール(パルミタミドプロピルトリモニウムクロリド)、塩化γ−グルコンアミドプロピルジメチルヒドロキシエチルアンモニウムである。 Among the above, the cationic surfactant is preferably a monoalkyl quaternary ammonium salt or a fatty acid amidoamine, and more preferably stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, or alkyl (16,18) trimethyl chloride. Ammonium, alkyl chloride (20-22) trimethylammonium, dimethylaminopropylamide stearate, distearoyl ethyldimonium chloride cetearyl alcohol (palmitamide propyltrimonium chloride), γ-gluconamide propyldimethylhydroxyethylammonium chloride. ..
上記成分Bの含有量は、好ましくは0.005〜2.0質量%、より好ましくは0.010〜1.5質量%、さらに好ましくは0.020〜1.0質量%である。本発明の効果を発揮する観点から、上記含有量は0.005質量%以上であればよい。また、水性組成物の使用感、すなわち、界面活性剤由来のべたつきに起因して成分Aによる効果を損なうことを防止するとの観点から、上記含有量は2.0質量%以下であればよい。 The content of the component B is preferably 0.005 to 2.0% by mass, more preferably 0.010 to 1.5% by mass, and further preferably 0.020 to 1.0% by mass. From the viewpoint of exerting the effect of the present invention, the content may be 0.005% by mass or more. Further, the content may be 2.0% by mass or less from the viewpoint of preventing the effect of the component A from being impaired due to the feeling of use of the aqueous composition, that is, the stickiness derived from the surfactant.
〔成分C〕
本発明の水性組成物は、成分Cとして、スメクタイト型粘土鉱物を含有する。本発明の水性組成物において、上記成分Cを含有させることにより、アミノ酸系有機粉体を沈降させるだけでなく、分散性をも良好にすることができる。上記成分Cは、1種のみを用いてもよいし、2種以上を用いてもよい。
[Component C]
The aqueous composition of the present invention contains a smectite-type clay mineral as component C. By containing the above component C in the aqueous composition of the present invention, not only the amino acid-based organic powder can be precipitated, but also the dispersibility can be improved. As the component C, only one kind may be used, or two or more kinds may be used.
上記成分Cは、天然物であっても、合成物であってもよい。天然物のスメクタイト型粘土鉱物としては、モンモリロナイト、サポナイト、ヘクトライト、ベントナイト、ベイデライト、ノントロナイト、サウコナイト、およびステベンサイド等が挙げられる。また、合成物のスメクタイト型粘土鉱物としては、合成サポナイト、および合成ヘクトライト等が挙げられる。これらの中でも、上記成分Cは、ベントナイト、合成ヘクトライト(合成ケイ酸ナトリウム・マグネシウム)であることが好ましい。 The component C may be a natural product or a synthetic product. Examples of natural smectite-type clay minerals include montmorillonite, saponite, hectorite, bentonite, beidelite, nontronite, saponite, and stebenside. Examples of the smectite-type clay mineral of the synthetic product include synthetic saponite and synthetic hectorite. Among these, the component C is preferably bentonite or synthetic hectorite (synthetic sodium / magnesium silicate).
上記成分Cの含有量は、好ましくは0.01〜2.0質量%、より好ましくは0.05〜1.5質量%、さらに好ましくは0.1〜1.0質量%である。本発明の効果を発揮する観点から、上記含有量は0.01質量%以上であればよい。また、水性組成物の使用感、粘土鉱物由来のべたつきおよびきしみ感に起因して成分Aによる効果を損なうことを防止するとの観点から、上記含有量は2.0質量%以下であればよい。 The content of the component C is preferably 0.01 to 2.0% by mass, more preferably 0.05 to 1.5% by mass, and further preferably 0.1 to 1.0% by mass. From the viewpoint of exerting the effect of the present invention, the content may be 0.01% by mass or more. Further, the content may be 2.0% by mass or less from the viewpoint of preventing the effect of the component A from being impaired due to the feeling of use of the aqueous composition, the stickiness derived from the clay mineral and the squeaky feeling.
〔成分D〕
本発明の水性組成物は、成分Dとして、水を含む。成分Dは、特に限定されないが、精製水が好ましい。成分Dの水の含有量は、成分D以外の成分の含有量に応じて適宜設定得るが、好ましくは30.0〜99.0質量%である。
[Component D]
The aqueous composition of the present invention contains water as component D. The component D is not particularly limited, but purified water is preferable. The water content of the component D can be appropriately set according to the content of the components other than the component D, but is preferably 30.0 to 99.0% by mass.
〔成分E〕
本発明の水性組成物は、成分Eとして、エタノールを含む。本発明の水性組成物において、上記成分Eを含有させることにより、さっぱり感の向上や、速乾性の向上という効果を奏する。成分Eの含有量は、所望する使用感に応じて適宜設定することができ、好ましくは0.1〜65.0質量%、より好ましくは1.0〜50.0質量%である。
[Component E]
The aqueous composition of the present invention contains ethanol as component E. In the aqueous composition of the present invention, the inclusion of the above component E has the effects of improving the refreshing feeling and improving the quick-drying property. The content of the component E can be appropriately set according to the desired feeling of use, and is preferably 0.1 to 65.0% by mass, more preferably 1.0 to 50.0% by mass.
〔その他の成分〕
本発明の水性組成物には、本発明の効果を損なわない範囲であれば、上記に記した成分の他、グリセリン、濃グリセリン、ジグリセリン、ポリグリセリン、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコール、グルコース、マルトース、マルチトース、スクロース、マンニトール、ソルビトール、1,2−ペンタンジオール、1,2−ヘキサンジオール、1,2−オクタンジオール、グルコシルトレハロースなどの多価アルコール;l−メントール、メンチルラクテート、カンファー、l−メンチルグリセリルエーテル、ハッカ油、ペパーミント油などの清涼剤;アニオン性界面活性剤、上記アルキルオキシヒドロキシプロピルアルギニン塩以外の両性界面活性剤、抗酸化剤、金属封鎖剤、シリコーン類、脂肪酸エステル油、ビタミン類、ミネラル類、動植物エキス、着色剤、各種香料、防腐剤、殺菌剤、抗炎症剤、紫外線吸収剤、美白剤などを目的に応じて適宜配合してもよい。
[Other ingredients]
In addition to the components described above, the aqueous composition of the present invention contains glycerin, concentrated glycerin, diglycerin, polyglycerin, ethylene glycol, polyethylene glycol, propylene glycol, and di, as long as the effects of the present invention are not impaired. Polyhydric alcohols such as propylene glycol, 1,3-butylene glycol, glucose, maltose, multitose, sucrose, mannitol, sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, glucosyltrehalose Cooling agents such as l-menthol, menthyllactate, camphor, l-mentylglyceryl ether, peppermint oil, peppermint oil; anionic surfactants, amphoteric surfactants other than the above alkyloxyhydroxypropylarginine salts, antioxidants, Metal sequestering agents, silicones, fatty acid ester oils, vitamins, minerals, animal and plant extracts, coloring agents, various fragrances, preservatives, bactericides, anti-inflammatory agents, ultraviolet absorbers, whitening agents, etc. are appropriately mixed according to the purpose. You may.
〔2.水性組成物の製造方法〕
本発明の水性組成物の製造方法は、公知の方法で調製することができる。例えば、液体成分が投入された容器に粉体成分を添加し、ディスパー等で攪拌・均一化することによって本発明の水性組成物を製造することができる。
[2. Method for producing aqueous composition]
The method for producing the aqueous composition of the present invention can be prepared by a known method. For example, the aqueous composition of the present invention can be produced by adding a powder component to a container in which a liquid component is charged, stirring and homogenizing with a disper or the like.
〔3.本発明の水性組成物の用途〕
例えば、本発明の水性組成物は、2層型皮膚用ローションなどの皮膚用ローションとして使用することができる。この場合、上記皮膚用ローションは、体用のボディーローション、デオドラントローション;顔用の収れんローション、オイルコントロールローションなどの皮膚の何れの部位にも使用することができる。中でも、使用時のさっぱり感に優れ、かつ皮脂の抑制効果に優れる観点から、顔用のローション(化粧水)として使用されるのがより好ましい。
[3. Applications of the aqueous composition of the present invention]
For example, the aqueous composition of the present invention can be used as a skin lotion such as a two-layer skin lotion. In this case, the skin lotion can be used on any part of the skin such as a body lotion, a deodorant lotion; a facial astringent lotion, and an oil control lotion. Above all, it is more preferable to use it as a lotion (lotion) for the face from the viewpoint of excellent refreshing feeling at the time of use and excellent effect of suppressing sebum.
また、本発明の水性組成物は、シート化粧料に使用することができる。シート化粧料は、織布、不織布等のシート基材に化粧料組成物を含浸させて形成されたシート形状の化粧料である。上記シート基材に含侵させる化粧料組成物として、本発明の水性組成物を使用することができる。 In addition, the aqueous composition of the present invention can be used for sheet cosmetics. The sheet cosmetic is a sheet-shaped cosmetic formed by impregnating a sheet base material such as a woven fabric or a non-woven fabric with a cosmetic composition. The aqueous composition of the present invention can be used as the cosmetic composition impregnated in the sheet substrate.
この場合、上記シート化粧料は、主に、皮膚(肌)を拭き取るために用いられる。上記シート化粧料により拭き取る部位としては、特に限定されず、例えば、腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中、顔面(例えば、額、目元、目じり、頬、口元等)、頭皮が挙げられる。上記シート化粧料としては、例えば、ボディ用拭き取りシート(頭皮用拭き取りシートを含む)、フェイス用拭き取りシート、ウェットティッシュ、使い捨ておしぼり、シート洗顔料(洗顔シート)、お尻拭きシート、メイク落としシート等が挙げられる。中でも、上記シート化粧料は、優れた冷感付与効果を発揮できるため、ボディ拭き取り用に特に好ましく用いられる。 In this case, the sheet cosmetic is mainly used for wiping the skin (skin). The part to be wiped off with the sheet cosmetic is not particularly limited, and for example, arms, elbows, back of hands, fingertips, feet, knees, heels, neck, armpits, back, face (forehead, eyes, eyes, cheeks, mouth). Etc.), scalp is mentioned. Examples of the sheet cosmetics include body wipe sheets (including scalp wipe sheets), face wipe sheets, wet wipes, disposable wipes, sheet wash pigments (face wash sheets), butt wipe sheets, makeup remover sheets, and the like. Can be mentioned. Among them, the above-mentioned sheet cosmetics are particularly preferably used for wiping the body because they can exert an excellent cooling sensation imparting effect.
なお、上述した用途において、本発明の水性組成物は、化粧品、医薬部外品、医薬品、雑貨の何れの形態であってもよい。 In the above-mentioned applications, the aqueous composition of the present invention may be in any form of cosmetics, quasi-drugs, pharmaceuticals, and miscellaneous goods.
本発明の一実施例について、以下に説明する。 An embodiment of the present invention will be described below.
〔1.実施例1〜14、比較例1〜13〕
表1および表2に示した組成に従い、実施例1〜14および比較例1〜13の水性組成物(組成物1〜27)を調製した。得られた水性組成物の25℃における粘度は、100mPa・s未満であった。
[1. Examples 1-14, Comparative Examples 1-13]
Aqueous compositions (compositions 1-27) of Examples 1-14 and Comparative Examples 1-13 were prepared according to the compositions shown in Tables 1 and 2. The viscosity of the obtained aqueous composition at 25 ° C. was less than 100 mPa · s.
〔2.各成分の詳細〕
表1および表2中、各成分の詳細は以下の通りである。
[2. Details of each ingredient]
Details of each component in Tables 1 and 2 are as follows.
<成分A:アミノ酸系有機粉体>
ラウロイルリジン:味の素社製、製品名「アミホープ LL」。
<Component A: Amino acid-based organic powder>
Lauroyl lysine: Made by Ajinomoto Co., Inc., product name "Amihope LL".
<成分B:アルキルオキシヒドロキシプロピルアルギニン塩>
アルキル(C12,14)オキシヒドロキシプロピルアルギニンHCl:味の素社製、製品名「アミセーフ LMA−60」。
<Component B: Alkyloxyhydroxypropylarginine salt>
Alkyl (C12,14) Oxyhydroxypropylarginine HCl: Manufactured by Ajinomoto Co., Inc., product name "Amisafe LMA-60".
<両性界面活性剤>
ラウラミドプロピルベタイン:新日本理化社製、製品名「リカビオン B−300」。
<Amphoteric surfactant>
Lauramide Propyl Betaine: Made by Shin Nihon Rika Co., Ltd., product name "Recabion B-300".
ココアンホ酢酸Na:川研ファインケミカル社製、製品名「ソフタゾリン CH」。 Sodium cocoamphoacetate: manufactured by Kawaken Fine Chemicals, product name "Softazoline CH".
ラウロアンホ酢酸Na:川研ファインケミカル社製、製品名「ソフタゾリン LHL」。 Lauroamphoacetate Na: Made by Kawaken Fine Chemicals, product name "Softazoline LHL".
<成分B:ノニオン性界面活性剤(HLB12.0〜17.0)>
PEG−60水添ヒマシ油(HLB14.8) :青木油脂社製、製品名「ブラウノン RCW−60」。
<Component B: Nonionic surfactant (HLB 12.0 to 17.0)>
PEG-60 Hydrogenated Castor Oil (HLB14.8): Made by Aoki Oil & Fat Co., Ltd., product name "Brownon RCW-60".
PEG−100水添ヒマシ油(HLB16.5) :日本エマルジョン社製、製品名「EMALEX HC−100」。 PEG-100 Hydrogenated Castor Oil (HLB16.5): Made by Nippon Emulsion Co., Ltd., product name "EMALEX HC-100".
<ノニオン性界面活性剤>
PEG−30水添ヒマシ油(HLB11.0) :日本エマルジョン社製、製品名「EMALEXHC−30」。
<Nonionic surfactant>
PEG-30 hydrogenated castor oil (HLB11.0): manufactured by Nippon Emulsion Co., Ltd., product name "EMALEXHC-30".
セテス−40(HLB 17.4):青木油脂社製、製品名「ブラウノン CH−340」。 Setes-40 (HLB 17.4): Made by Aoki Oil & Fat Co., Ltd., product name "Brownon CH-340".
カプリル酸ポリグリセリル−3(HLB 11.1):EVONIC社製、製品名「TEGO Cosmo P813」。 Polyglyceryl caprylate-3 (HLB 11.1): manufactured by EVONIC, product name "TEGO Cosmo P813".
<アニオン性界面活性剤>
ラウレス硫酸Na:花王社製、製品名「エマール 270J」。
<Anionic surfactant>
Sodium Laureth Sulfate: Made by Kao Corporation, product name "Emar 270J".
スルホコハク酸ラウレス2Na:新日本理化社製、製品名「リカマイルドES−100」。 Laureth sulfosuccinate 2Na: Made by Shin Nihon Rika Co., Ltd., product name "Rica Mild ES-100".
<成分B:カチオン性界面活性剤>
ステアルトリモニウムクロリド:花王社製、製品名「コータミン 86W」。
<Component B: Cationic surfactant>
Stealtrimonium chloride: Made by Kao Corporation, product name "Cotamin 86W".
パルミタミドプロピルトリモニウムクロリド:EVONIC社製、製品名「VARISOFT PATC」。 Palmitamid Propyl Trimonium Chloride: Made by EVONIC, product name "VARISOFT PATC".
<成分C:スメクタイト型粘土鉱物>
ベントナイト:日本有機粘度社製、製品名「ベンゲル」。
<Component C: smectite type clay mineral>
Bentonite: Made by Nippon Organic Viscosity Co., Ltd., product name "Bengel".
合成ヘクトライト(合成ケイ酸ナトリウム・マグネシウム):BYK社製、製品名「Laponite XLG」。 Synthetic hectorite (synthetic sodium / magnesium silicate): Made by BYK, product name "Laponite XLG".
<粘土鉱物>
カオリン:竹原化学工業社製、製品名「カオリン JP−100」。
<Clay minerals>
Kaolin: Made by Takehara Chemical Industry Co., Ltd., product name "Kaolin JP-100".
〔3.評価:粉体濡れ性〕
粉体濡れ性は、調製した各組成物におけるアミノ酸系有機粉体の状態を目視で観察することで評価した。評価結果は、下記の基準に従って示す。
[3. Evaluation: Powder wettability]
The powder wettability was evaluated by visually observing the state of the amino acid-based organic powder in each of the prepared compositions. The evaluation results are shown according to the following criteria.
(評価基準)
◎:全てのアミノ酸系有機粉体が、液層中に分散している、または再分散可能である。
○:一部のアミノ酸系有機粉体が気液界面に存在するが、9割以上のアミノ酸系有機粉体が、液層中に分散している、または再分散可能である。
×:9割以上のアミノ酸系有機粉体が気液界面に存在する。
(Evaluation criteria)
⊚: All amino acid-based organic powders are dispersed or redispersable in the liquid layer.
◯: Some amino acid-based organic powders are present at the gas-liquid interface, but 90% or more of the amino acid-based organic powders are dispersed or redispersible in the liquid layer.
X: 90% or more of amino acid-based organic powder is present at the gas-liquid interface.
〔4.試験結果〕
表1および表2から、粉体濡れ性について、実施例1〜14の水性組成物は、比較例1〜13の水性組成物よりも優れていることが明らかになった。したがって、実施例1〜14の水性組成物は、アミノ酸系有機粉体を分散させる、あるいは再分散させることができる組成物である。
[4. Test results〕
From Tables 1 and 2, it was revealed that the aqueous compositions of Examples 1 to 14 were superior to the aqueous compositions of Comparative Examples 1 to 13 in terms of powder wettability. Therefore, the aqueous compositions of Examples 1 to 14 are compositions capable of dispersing or redispersing amino acid-based organic powders.
〔処方例〕
[2層型皮膚用ローション]
ラウロイルリジン 1.0質量%
アルキルオキシヒドロキシプロピルアルギニン塩 0.04質量%
ベントナイト 0.2質量%
エタノール 10.0質量%
1,2−オクタンジオール 0.2質量%
グリセリン 7.0質量%
サリチル酸 0.1質量%
l−メントール 0.3質量%
塩化ナトリウム 0.1質量%
リン酸Na 0.1質量%
リン酸2Na 0.3質量%
メチルパラベン 0.3質量%
香料 0.03質量%
精製水 残 余
合計 100.0質量%。
[Prescription example]
[Two-layer skin lotion]
Lauroyl lysine 1.0% by mass
Alkyloxyhydroxypropylarginine salt 0.04% by mass
Bentonite 0.2% by mass
Ethanol 10.0% by mass
1,2-octanediol 0.2% by mass
Glycerin 7.0% by mass
Salicylic acid 0.1% by mass
l-Menthol 0.3% by mass
Sodium chloride 0.1% by mass
Na phosphate 0.1% by mass
Phosphate 2Na 0.3% by mass
Methylparaben 0.3% by mass
Fragrance 0.03% by mass
Purified water residue Total 100.0% by mass.
[2層型腋臭防止剤]
ラウロイルリジン 4.0質量%
無水ケイ酸 0.5質量%
塩化γ‐グルコンアミドプロピルジメチルヒドロキシエチルアンモニウム 0.1質量%
合成ヘクトライト(合成ケイ酸ナトリウム・マグネシウム) 0.4質量%
エタノール 30.0質量%
ジプロピレングリコール 5.0質量%
l−メントール 0.1質量%
パラフェノールスルホン酸亜鉛 0.3質量%
イソプロピルメチルフェノール 0.1質量%
ヒドロキシエチルセルロース 0.05質量%
香料 0.05質量%
精製水 残 余
合計 100.0質量%。
[Two-layer type axillary odor inhibitor]
Lauroyl lysine 4.0% by mass
Silica anhydride 0.5% by mass
Γ-Gluconamide propyldimethylhydroxyethylammonium 0.1% by mass
Synthetic hectorite (synthetic sodium / magnesium silicate) 0.4% by mass
Ethanol 30.0% by mass
Dipropylene glycol 5.0% by mass
l-menthol 0.1% by mass
Zinc paraphenol sulfonate 0.3% by mass
Isopropylmethylphenol 0.1% by mass
Hydroxyethyl cellulose 0.05% by mass
Fragrance 0.05% by mass
Purified water residue Total 100.0% by mass.
[シート化粧料]
不織布100質量部に対し、下記組成からなる化粧料組成物400質量部を含浸させて、シート化粧料とした。
ラウロイルリジン 3.0質量%
PEG−60水添ヒマシ油 0.05質量%
ベントナイト 0.2質量%
BG 10.0質量%
グリチルリチン酸ジカリウム 0.05質量%
メチルパラベン 0.2質量%
フェノキシエタノール 0.6質量%
エタノール 4.0質量%
キサンタンガム 0.03質量%
精製水 残 余
合計 100.0質量%。
[Sheet cosmetics]
A sheet cosmetic was prepared by impregnating 100 parts by mass of the non-woven fabric with 400 parts by mass of a cosmetic composition having the following composition.
Lauroyl lysine 3.0% by mass
PEG-60 hydrogenated castor oil 0.05% by mass
Bentonite 0.2% by mass
BG 10.0% by mass
Dipotassium glycyrrhizinate 0.05% by mass
Methylparaben 0.2% by mass
Phenoxyethanol 0.6% by mass
Ethanol 4.0% by mass
Xanthan gum 0.03% by mass
Purified water residue Total 100.0% by mass.
本発明の水性組成物は、皮膚用ローション、シート化粧料等に使用することができる。 The aqueous composition of the present invention can be used for skin lotions, sheet cosmetics and the like.
Claims (3)
成分Bの含有量に対する成分Aの含有量(A/B)が、300以下であり、
成分Cの含有量に対する成分Aの含有量(A/C)が、35以下である、水性組成物;
成分A:アミノ酸系有機粉体
成分B:アルキルオキシヒドロキシプロピルアルギニン塩、HLBが12.0〜17.0のノニオン性界面活性剤、およびカチオン性界面活性剤からなる群から選ばれる少なくとも1種の界面活性剤
成分C:スメクタイト型粘土鉱物
成分D:水。 Contains the following components A to D,
The content (A / B) of the component A with respect to the content of the component B is 300 or less.
An aqueous composition in which the content of component A (A / C) relative to the content of component C is 35 or less;
Component A: Amino acid-based organic powder Component B: At least one selected from the group consisting of alkyloxyhydroxypropyl arginine salts, nonionic surfactants having an HLB of 12.0 to 17.0, and cationic surfactants. Surfactant Component C: Smectite type clay mineral Component D: Water.
前記成分Bの含有量が、0.005〜2.0質量%であり、
前記成分Cの含有量が、0.01〜2.0質量%である、請求項1に記載の水性組成物。 The content of the component A is 0.01 to 20.0% by mass.
The content of the component B is 0.005 to 2.0% by mass, and the content is 0.005 to 2.0% by mass.
The aqueous composition according to claim 1, wherein the content of the component C is 0.01 to 2.0% by mass.
成分E:エタノール。 The aqueous composition according to claim 1 or 2, further comprising the following component E;
Ingredient E: Ethanol.
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KR102653544B1 (en) * | 2015-10-05 | 2024-04-03 | 듀폰 도레이 스페셜티 머티리얼즈 가부시키가이샤 | Oil-in-water organopolysiloxane emulsion, manufacturing method thereof, cosmetic raw materials and cosmetics |
JP7063265B2 (en) | 2016-07-08 | 2022-05-09 | 味の素株式会社 | Creamy composition |
JP2017197559A (en) | 2017-06-09 | 2017-11-02 | 味の素株式会社 | Composite powders and makeup cosmetics |
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CN113425613B (en) | 2023-08-25 |
CN113425613A (en) | 2021-09-24 |
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