CN104805458B - A kind of surface cleaning agent used for hot spraying and preparation method thereof - Google Patents
A kind of surface cleaning agent used for hot spraying and preparation method thereof Download PDFInfo
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- CN104805458B CN104805458B CN201510194594.9A CN201510194594A CN104805458B CN 104805458 B CN104805458 B CN 104805458B CN 201510194594 A CN201510194594 A CN 201510194594A CN 104805458 B CN104805458 B CN 104805458B
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 45
- 238000005507 spraying Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- -1 paratoluenesulfonic acid sodium salt Chemical class 0.000 claims abstract description 63
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 34
- 238000002156 mixing Methods 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 29
- 239000013530 defoamer Substances 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 21
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 17
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical class [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002253 acid Substances 0.000 claims abstract description 17
- FGFWTUNWGQWDDJ-UHFFFAOYSA-N n,n-diethylethanamine;urea Chemical compound NC(N)=O.CCN(CC)CC FGFWTUNWGQWDDJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 17
- 239000010452 phosphate Substances 0.000 claims abstract description 17
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 17
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 17
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 16
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 16
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 16
- 239000011575 calcium Substances 0.000 claims abstract description 16
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 16
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 13
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 13
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 9
- 229940095102 methyl benzoate Drugs 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 8
- 239000000306 component Substances 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 5
- 239000002516 radical scavenger Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 150000004702 methyl esters Chemical class 0.000 claims description 3
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 3
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 230000003111 delayed effect Effects 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 230000007935 neutral effect Effects 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 8
- 150000002191 fatty alcohols Chemical class 0.000 description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 4
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000007751 thermal spraying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VNHHSBRJHXRDTE-UHFFFAOYSA-N benzenesulfonic acid;calcium Chemical compound [Ca].OS(=O)(=O)C1=CC=CC=C1 VNHHSBRJHXRDTE-UHFFFAOYSA-N 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention is a kind of surface cleaning agent used for hot spraying, and its raw material composition includes A, B amount component, by volume 3 during preparation：1 1.5 mixing, wherein component A includes by weight：58 parts of paratoluenesulfonic acid sodium salt, 6 10 parts of phosphate, 37 parts of ethylenediamine, 5 10 parts of methyl benzoate, 38 parts of vinyl bis-stearamides, 6 11 parts of alkyl benzene calcium sulfonate, double pungent 24 parts of the primary alkyl zinc salts of sulphur phosphorus, 27 parts of aliphatic acid diethylate, 46 parts of antioxidant, 35 parts of defoamer, 55 67 parts of water；B component includes by weight：10 16 parts of sodium carbonate, 38 parts of potassium pyrophosphate, 46 parts of triethylamine urea, 8 13 parts of polyoxyethylene aliphatic alcohol ether, 36 parts of alkylnaphthalene sulfonate, 40 55 parts of water.The present invention is to, because of the carbon dust that processing is formed, iron filings, the dirt such as greasy dirt carries out thoroughly cleaning on metal works outer surface, outer metallic surface after cleaning integrally or locally corrosion phenomenon will not occur, because product raw material are neutral products, moderate performance, without chromate, nitrite；Odorlessness, it is environmentally safe, to human body fanout free region；The present invention has Low-foam and easily rinsing simultaneously, it is adaptable to automatic rinser washing and cleaning operation.
Description
Technical field
The present invention relates to a kind of surface cleaning agent and preparation method thereof, specifically a kind of surface cleaning agent used for hot spraying
And preparation method thereof, belong to field of metal surface treatment technology.
Background technology
Early it is used for many applications known to the coating applied by thermal spraying.For example, in vehicular engine, oil lubrication
The surface of cylinder running surface has been coated for quite a long time especially by plasma spraying, and the coating is outstanding
It is to significantly reduce the coefficient of friction between piston ring and cylinder wall, so as to substantially reduce the abrasion of piston ring and cylinder, is made
Obtain service life of aeroengine to increase, maintenance period (for example changing oil), extension, also significantly improved engine performance.
Many metal devices often use lubricating oil or coolant in processing, when obtain metal surface and there is greasy dirt,
When carrying out thermal spraying often because the surface impurity such as greasy dirt influences the effect of thermal spraying, serious meeting causes hot-spraying coating
Stripping, made troubles to processing, therefore often device surface can all be cleaned before spraying, traditional surface is clear
Clean dose has peculiar smell greatly, the problem of having corrosion to metal surface.
The content of the invention
The technical problems to be solved by the invention are to propose a kind of surface cleaning agent used for hot spraying and preparation method thereof, nothing
Peculiar smell, and with very strong dirt-removing power, the spot on metal surface can be quickly removed, it is corrosion-free to metal surface.
The present invention solves the technical scheme of above technical problem：A kind of surface cleaning agent used for hot spraying is provided, its raw material group
Into including A, B amount component, by volume 3 during preparation：1-1.5 is mixed, and wherein component A includes by weight：Paratoluenesulfonic acid sodium salt
5-8 parts, 6-10 parts of phosphate, 3-7 parts of ethylenediamine, 5-10 parts of methyl benzoate, 3-8 parts of vinyl bis-stearamides, alkyl
6-11 parts of benzene sulfonic acid calcium, double pungent 2-4 parts of the primary alkyl zinc salts of sulphur phosphorus, 2-7 parts of aliphatic acid diethylate, 4-6 parts of antioxidant,
3-5 parts of defoamer, 55-67 parts of water；
B component includes by weight：10-16 parts of sodium carbonate, 3-8 parts of potassium pyrophosphate, 4-6 parts of triethylamine urea, polyoxy second
8-13 parts of alkene fatty alcohol ether, 3-6 parts of alkylnaphthalene sulfonate, 40-55 parts of water.
The further restriction technical scheme of the present invention, foregoing surface cleaning agent used for hot spraying, the antioxidant is:Sulfurous
It is one or more in sour hydrogen sodium, sodium pyrosulfite, sodium sulfite or exsiccated sodium sulfite；The defoamer polydimethylsiloxanes
The mixture of the fatty acid ester compounded thing of alkane, higher alcohols, wherein dimethyl silicone polymer are with the fatty acid ester compounded thing of higher alcohols by weight
The ratio for measuring part mixing is 1:2.
Foregoing surface cleaning agent used for hot spraying, its raw material composition includes A, B amount component, by volume 3 during preparation：1 mixes
Close, wherein component A includes by weight：5 parts of paratoluenesulfonic acid sodium salt, 6 parts of phosphate, 3 parts of ethylenediamine, 5 parts of methyl benzoate, second
3 parts of alkenyl bis-stearamides, 6 parts of alkyl benzene calcium sulfonate, double pungent 2 parts of the primary alkyl zinc salts of sulphur phosphorus, aliphatic acid diethylate 2
Part, 4 parts of antioxidant, 3 parts of defoamer, 55 parts of water；
B component includes by weight：10 parts of sodium carbonate, 3 parts of potassium pyrophosphate, 4 parts of triethylamine urea, polyoxyethylene fatty alcohol
8-13 parts of ether, 3 parts of alkylnaphthalene sulfonate, 40 parts of water.
Foregoing surface cleaning agent used for hot spraying, its raw material composition includes A, B amount component, by volume 3 during preparation：1.5
Mixing, wherein component A includes by weight：6 parts of paratoluenesulfonic acid sodium salt, 8 parts of phosphate, 5 parts of ethylenediamine, 6 parts of methyl benzoate,
6 parts of vinyl bis-stearamides, 8 parts of alkyl benzene calcium sulfonate, double pungent 3 parts of the primary alkyl zinc salts of sulphur phosphorus, aliphatic acid diethylate 5
Part, 5 parts of antioxidant, 4 parts of defoamer, 60 parts of water；
B component includes by weight：14 parts of sodium carbonate, 6 parts of potassium pyrophosphate, 5 parts of triethylamine urea, polyoxyethylene fatty alcohol
10 parts of ether, 5 parts of alkylnaphthalene sulfonate, 50 parts of water.
Foregoing surface cleaning agent used for hot spraying, its raw material composition includes A, B amount component, by volume 3 during preparation：1.2
Mixing, wherein component A includes by weight：8 parts of paratoluenesulfonic acid sodium salt, 10 parts of phosphate, 7 parts of ethylenediamine, methyl benzoate 10
Part, 8 parts of vinyl bis-stearamides, 11 parts of alkyl benzene calcium sulfonate, double pungent 4 parts of the primary alkyl zinc salts of sulphur phosphorus, aliphatic acid diethanol
7 parts of salt, 6 parts of antioxidant, 5 parts of defoamer, 67 parts of water；
B component includes by weight：16 parts of sodium carbonate, 8 parts of potassium pyrophosphate, 6 parts of triethylamine urea, polyoxyethylene fatty alcohol
13 parts of ether, 6 parts of alkylnaphthalene sulfonate, 55 parts of water.
A kind of preparation method of surface cleaning agent used for hot spraying, comprises the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio mixed by weight is
1:2, be sufficiently mixed the defoamer being made in component A；
Step（2）：By step（1）Paratoluenesulfonic acid sodium salt, phosphate, ethylenediamine, benzene in obtained defoamer and component A
Methyl formate, sulphur phosphorus double pungent primary alkyl zinc salt, aliphatic acid diethylates, put into respectively in the dispersion cylinder equipped with water, unlatching is stirred
Mix device to be slowly stirred, mixing speed is that 220-260 turns after/min, stirring 20-25min, is estimated after its homogeneous transparent, then by A groups
Point in vinyl bis-stearamides, alkyl benzene calcium sulfonate be slowly added under stirring, regulation rotating speed be 300-320 turn/
Min, mixing time is 30-35min, control dispersion cylinder temperature≤45 DEG C, is eventually adding the antioxidant in component A, same side adds
Enter side stirring, regulation rotating speed is that 450-520 turns/min, mixing time 30-45min, and the A of surface cleaning agent can be obtained through filtering
Component；
Step（3）：With the water in B component and sodium carbonate, potassium pyrophosphate, triethylamine urea, polyoxyethylene aliphatic alcohol ether, alkane
Base naphthalene sulfonate is mixed, and regulation rotating speed is that 280-320 turns/min, mixing time 30-45min, and control temperature is less than 30 DEG C,
The B component of surface cleaning agent is obtained after filtering；
Step（4）：By step（2）The component A and step of the surface cleaning agent prepared（3）Obtained surface cleaning agent
B component weigh in mass ratio it is well mixed, you can obtain thermal spray metal surface scavenger specially.
Further, the preparation method of foregoing surface cleaning agent used for hot spraying, in step（2）And step（3）Obtain
When component is mixed, the scattered barrel temperature of mixing is 15-25 DEG C, and incorporation time is 8-20h, and rotating speed is that 180-250 turns/min.
Beneficial effects of the present invention：The present invention on metal works outer surface because of the carbon dust that processing is formed, iron filings, greasy dirt etc.
Dirt carries out thoroughly cleaning, and the outer metallic surface after cleaning integrally or locally corrosion phenomenon will not occur, due to product raw material
It is neutral products, moderate performance, without chromate, nitrite；Odorlessness, it is environmentally safe, to human body fanout free region；Together
When the present invention have Low-foam and easily rinsing, it is adaptable to automatic rinser washing and cleaning operation.
Embodiment
Embodiment 1
The present embodiment is a kind of surface cleaning agent used for hot spraying, and its raw material composition includes A, B amount component, volume is pressed during preparation
Than 3：1 mixing, wherein component A includes by weight：5 parts of paratoluenesulfonic acid sodium salt, 6 parts of phosphate, 3 parts of ethylenediamine, benzoic acid first
5 parts of ester, 3 parts of vinyl bis-stearamides, 6 parts of alkyl benzene calcium sulfonate, double pungent 2 parts of the primary alkyl zinc salts of sulphur phosphorus, aliphatic acid two
2 parts of ethylate, 4 parts of sodium pyrosulfite, 3 parts of defoamer, 55 parts of water；Wherein defoamer is dimethyl silicone polymer and high-carbon alcohol ester
Fat acid esters compound ratio 1 by weight:2 mixture；
B component includes by weight：10 parts of sodium carbonate, 3 parts of potassium pyrophosphate, 4 parts of triethylamine urea, polyoxyethylene fatty alcohol
8-13 parts of ether, 3 parts of alkylnaphthalene sulfonate, 40 parts of water.
A kind of preparation method for surface cleaning agent used for hot spraying that the present embodiment is provided, comprises the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio mixed by weight is
1:2, be sufficiently mixed the defoamer being made in component A；
Step（2）：By step（1）Paratoluenesulfonic acid sodium salt, phosphate, ethylenediamine, benzene in obtained defoamer and component A
Methyl formate, sulphur phosphorus double pungent primary alkyl zinc salt, aliphatic acid diethylates, put into respectively in the dispersion cylinder equipped with water, unlatching is stirred
Mix device to be slowly stirred, after mixing speed is 240 turns/min, stirring 23min, estimate after its homogeneous transparent, then by the second in component A
Alkenyl bis-stearamides, alkyl benzene calcium sulfonate are slowly added under stirring, and regulation rotating speed is 310 turns/min, mixing time
For 33min, control dispersion cylinder temperature≤45 DEG C are eventually adding the antioxidant in component A, equally stirred while adding, regulation turns
Speed is 480 turns/min, mixing time 35min, and the component A of surface cleaning agent can be obtained through filtering；
Step（3）：With the water in B component and sodium carbonate, potassium pyrophosphate, triethylamine urea, polyoxyethylene aliphatic alcohol ether, alkane
Base naphthalene sulfonate is mixed, and regulation rotating speed is 300 turns/min, mixing time 35min, and control temperature is less than 30 DEG C, through filtering
The B component of surface cleaning agent is obtained afterwards；
Step（4）：By step（2）The component A and step of the surface cleaning agent prepared（3）Obtained surface cleaning agent
B component weigh in mass ratio well mixed, it is 20 DEG C that scattered barrel temperature is mixed during mixing, and incorporation time is 10h, and rotating speed is
200 turns/min, you can obtain thermal spray metal surface scavenger specially.
Embodiment 2
The present embodiment provides a kind of surface cleaning agent used for hot spraying, and its raw material composition includes A, B amount component, body is pressed during preparation
Product compares 3：1.5 mixing, wherein component A includes by weight：6 parts of paratoluenesulfonic acid sodium salt, 8 parts of phosphate, 5 parts of ethylenediamine, benzene first
Sour 6 parts of methyl esters, 6 parts of vinyl bis-stearamides, 8 parts of alkyl benzene calcium sulfonate, double pungent 3 parts of the primary alkyl zinc salts of sulphur phosphorus, aliphatic acid
5 parts of diethylate, 5 parts of sodium hydrogensulfite, 4 parts of defoamer, 60 parts of water；Wherein defoamer is dimethyl silicone polymer and higher alcohols
Fatty acid ester compounded thing ratio 1 by weight:2 mixture；
B component includes by weight：14 parts of sodium carbonate, 6 parts of potassium pyrophosphate, 5 parts of triethylamine urea, polyoxyethylene fatty alcohol
10 parts of ether, 5 parts of alkylnaphthalene sulfonate, 50 parts of water.
A kind of preparation method for surface cleaning agent used for hot spraying that the present embodiment is provided, comprises the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio mixed by weight is
1:2, be sufficiently mixed the defoamer being made in component A；
Step（2）：By step（1）Paratoluenesulfonic acid sodium salt, phosphate, ethylenediamine, benzene in obtained defoamer and component A
Methyl formate, sulphur phosphorus double pungent primary alkyl zinc salt, aliphatic acid diethylates, put into respectively in the dispersion cylinder equipped with water, unlatching is stirred
Mix device to be slowly stirred, after mixing speed is 220 turns/min, stirring 25min, estimate after its homogeneous transparent, then by the second in component A
Alkenyl bis-stearamides, alkyl benzene calcium sulfonate are slowly added under stirring, and regulation rotating speed is 300 turns/min, mixing time
For 35min, control dispersion cylinder temperature≤45 DEG C are eventually adding the antioxidant in component A, equally stirred while adding, regulation turns
Speed is 450 turns/min, mixing time 45min, and the component A of surface cleaning agent can be obtained through filtering；
Step（3）：With the water in B component and sodium carbonate, potassium pyrophosphate, triethylamine urea, polyoxyethylene aliphatic alcohol ether, alkane
Base naphthalene sulfonate is mixed, and regulation rotating speed is 280 turns/min, mixing time 45min, and control temperature is less than 30 DEG C, through filtering
The B component of surface cleaning agent is obtained afterwards；
Step（4）：By step（2）The component A and step of the surface cleaning agent prepared（3）Obtained surface cleaning agent
B component weigh in mass ratio well mixed, it is 15 DEG C that scattered barrel temperature is mixed during mixing, and incorporation time is 20h, and rotating speed is
180 turns/min, you can obtain thermal spray metal surface scavenger specially.
Embodiment 3
The present embodiment provides a kind of surface cleaning agent used for hot spraying, and its raw material composition includes A, B amount component, body is pressed during preparation
Product compares 3：1.2 mixing, wherein component A includes by weight：8 parts of paratoluenesulfonic acid sodium salt, 10 parts of phosphate, 7 parts of ethylenediamine, benzene first
Sour 10 parts of methyl esters, 8 parts of vinyl bis-stearamides, 11 parts of alkyl benzene calcium sulfonate, double pungent 4 parts of the primary alkyl zinc salts of sulphur phosphorus, fat
Sour 7 parts of diethylate, 6 parts of sodium sulfite, 5 parts of defoamer, 67 parts of water；Wherein defoamer is dimethyl silicone polymer and high-carbon
Polyol fatty acid ester complexes example 1 by weight:2 mixture；
B component includes by weight：16 parts of sodium carbonate, 8 parts of potassium pyrophosphate, 6 parts of triethylamine urea, polyoxyethylene fatty alcohol
13 parts of ether, 6 parts of alkylnaphthalene sulfonate, 55 parts of water.
A kind of preparation method for surface cleaning agent used for hot spraying that the present embodiment is provided, comprises the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio mixed by weight is
1:2, be sufficiently mixed the defoamer being made in component A；
Step（2）：By step（1）Paratoluenesulfonic acid sodium salt, phosphate, ethylenediamine, benzene in obtained defoamer and component A
Methyl formate, sulphur phosphorus double pungent primary alkyl zinc salt, aliphatic acid diethylates, put into respectively in the dispersion cylinder equipped with water, unlatching is stirred
Mix device to be slowly stirred, after mixing speed is 260 turns/min, stirring 20min, estimate after its homogeneous transparent, then by the second in component A
Alkenyl bis-stearamides, alkyl benzene calcium sulfonate are slowly added under stirring, and regulation rotating speed is 320 turns/min, mixing time
For 30min, control dispersion cylinder temperature≤45 DEG C are eventually adding the antioxidant in component A, equally stirred while adding, regulation turns
Speed is 520 turns/min, mixing time 30min, and the component A of surface cleaning agent can be obtained through filtering；
Step（3）：With the water in B component and sodium carbonate, potassium pyrophosphate, triethylamine urea, polyoxyethylene aliphatic alcohol ether, alkane
Base naphthalene sulfonate is mixed, and regulation rotating speed is 320 turns/min, mixing time 30min, and control temperature is less than 30 DEG C, through filtering
The B component of surface cleaning agent is obtained afterwards；
Step（4）：By step（2）The component A and step of the surface cleaning agent prepared（3）Obtained surface cleaning agent
B component weigh in mass ratio well mixed, it is 25 DEG C that scattered barrel temperature is mixed during mixing, and incorporation time is 15h, and rotating speed is
250 turns/min, you can obtain thermal spray metal surface scavenger specially.
In addition to the implementation, the present invention can also have other embodiment.All use equivalent substitution or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (6)
1. a kind of surface cleaning agent used for hot spraying, it is characterised in that：Its raw material composition includes A, B amount component, and volume is pressed during preparation
Than 3：1-1.5 is mixed, and wherein component A includes by weight：5-8 parts of paratoluenesulfonic acid sodium salt, 6-10 parts of phosphate, ethylenediamine 3-7
Part, 5-10 parts of methyl benzoate, 3-8 parts of vinyl bis-stearamides, 6-11 parts of alkyl benzene calcium sulfonate, the double pungent primary alkyl zinc of sulphur phosphorus
2-4 parts of salt, 2-7 parts of aliphatic acid diethylate, 4-6 parts of antioxidant, 3-5 parts of defoamer, 55-67 parts of water；
B component includes by weight：10-16 parts of sodium carbonate, 3-8 parts of potassium pyrophosphate, 4-6 parts of triethylamine urea, polyoxyethylene fat
8-13 parts of fat alcohol ether, 3-6 parts of alkylnaphthalene sulfonate, 40-55 parts of water；
The antioxidant is:It is one or more in sodium hydrogensulfite, sodium pyrosulfite, sodium sulfite or exsiccated sodium sulfite；Institute
State the mixture of the fatty acid ester compounded thing of defoamer dimethyl silicone polymer, higher alcohols, wherein dimethyl silicone polymer and high-carbon
The ratio that polyol fatty acid ester complexes are mixed by weight is 1:2.
2. surface cleaning agent used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition includes A, B amount component,
By volume 3 during preparation：1 mixing, wherein component A includes by weight：5 parts of paratoluenesulfonic acid sodium salt, 6 parts of phosphate, ethylenediamine 3
Part, 5 parts of methyl benzoate, 3 parts of vinyl bis-stearamides, 6 parts of alkyl benzene calcium sulfonate, double pungent 2 parts of the primary alkyl zinc salts of sulphur phosphorus, fat
Fat 2 parts of diethylate of acid, 4 parts of antioxidant, 3 parts of defoamer, 55 parts of water；
B component includes by weight：10 parts of sodium carbonate, 3 parts of potassium pyrophosphate, 4 parts of triethylamine urea, polyoxyethylene aliphatic alcohol ether 8-
13 parts, 3 parts of alkylnaphthalene sulfonate, 40 parts of water.
3. surface cleaning agent used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition includes A, B amount component,
By volume 3 during preparation：1.5 mixing, wherein component A includes by weight：6 parts of paratoluenesulfonic acid sodium salt, 8 parts of phosphate, second two
5 parts of amine, 6 parts of methyl benzoate, 6 parts of vinyl bis-stearamides, 8 parts of alkyl benzene calcium sulfonate, the double pungent primary alkyl zinc salts 3 of sulphur phosphorus
Part, 5 parts of aliphatic acid diethylate, 5 parts of antioxidant, 4 parts of defoamer, 60 parts of water；
B component includes by weight：14 parts of sodium carbonate, 6 parts of potassium pyrophosphate, 5 parts of triethylamine urea, polyoxyethylene aliphatic alcohol ether 10
Part, 5 parts of alkylnaphthalene sulfonate, 50 parts of water.
4. surface cleaning agent used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition includes A, B amount component,
By volume 3 during preparation：1.2 mixing, wherein component A includes by weight：8 parts of paratoluenesulfonic acid sodium salt, 10 parts of phosphate, second two
7 parts of amine, 10 parts of methyl benzoate, 8 parts of vinyl bis-stearamides, 11 parts of alkyl benzene calcium sulfonate, the double pungent primary alkyl zinc salts of sulphur phosphorus
4 parts, 7 parts of aliphatic acid diethylate, 6 parts of antioxidant, 5 parts of defoamer, 67 parts of water；
B component includes by weight：16 parts of sodium carbonate, 8 parts of potassium pyrophosphate, 6 parts of triethylamine urea, polyoxyethylene aliphatic alcohol ether 13
Part, 6 parts of alkylnaphthalene sulfonate, 55 parts of water.
5. a kind of preparation method of surface cleaning agent used for hot spraying, it is characterised in that comprise the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio mixed by weight is 1:2,
Be sufficiently mixed the defoamer being made in component A；
Step（2）：By step（1）Paratoluenesulfonic acid sodium salt, phosphate, ethylenediamine, benzoic acid in obtained defoamer and component A
The double pungent primary alkyl zinc salts of methyl esters, sulphur phosphorus, aliphatic acid diethylate are put into the dispersion cylinder equipped with water respectively, and turn on agitator is delayed
Slow stirring, mixing speed is that 220-260 turns after/min, stirring 20-25min, is estimated after its homogeneous transparent, then by component A
Vinyl bis-stearamides, alkyl benzene calcium sulfonate are slowly added under stirring, and regulation rotating speed is that 300-320 turns/min, is stirred
The time is mixed for 30-35min, control dispersion cylinder temperature≤45 DEG C are eventually adding the antioxidant in component A, same to be stirred when adding
Mix, regulation rotating speed is that 450-520 turns/min, mixing time 30-45min, and the component A of surface cleaning agent can be obtained through filtering；
Step（3）：With the water in B component and sodium carbonate, potassium pyrophosphate, triethylamine urea, polyoxyethylene aliphatic alcohol ether, alkylnaphthalene
Sulfonate is mixed, and regulation rotating speed is that 280-320 turns/min, mixing time 30-45min, and control temperature is less than 30 DEG C, passed through
The B component of surface cleaning agent is obtained after filter；
Step（4）：By step（2）The component A and step of the surface cleaning agent prepared（3）The B of obtained surface cleaning agent
Component weighs well mixed in mass ratio, you can obtain thermal spray metal surface scavenger specially.
6. the preparation method of surface cleaning agent used for hot spraying according to claim 5, it is characterised in that：In step（2）With
Step（3）When obtained component is mixed, the scattered barrel temperature of mixing is 15-25 DEG C, and incorporation time is 8-20h, and rotating speed is
180-250 turns/min.
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| CN201510194594.9A CN104805458B (en) | 2015-04-23 | 2015-04-23 | A kind of surface cleaning agent used for hot spraying and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1231350A (en) * | 1998-04-06 | 1999-10-13 | 高福麒 | Electro-acoustic quick oil, scale and rust removing clean agent for metal and clean method thereof |
| CN103789778A (en) * | 2014-01-23 | 2014-05-14 | 江苏兴达钢帘线股份有限公司 | Surface active agent in steel wire pickling solution |
| CN103898535A (en) * | 2013-11-13 | 2014-07-02 | 东南大学 | Preparation raw material and method of black metal descaling agent |
| CN104073815A (en) * | 2014-06-26 | 2014-10-01 | 青岛启源振东电气有限公司 | Metal surface decontamination cleaning agent |
-
2015
- 2015-04-23 CN CN201510194594.9A patent/CN104805458B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1231350A (en) * | 1998-04-06 | 1999-10-13 | 高福麒 | Electro-acoustic quick oil, scale and rust removing clean agent for metal and clean method thereof |
| CN103898535A (en) * | 2013-11-13 | 2014-07-02 | 东南大学 | Preparation raw material and method of black metal descaling agent |
| CN103789778A (en) * | 2014-01-23 | 2014-05-14 | 江苏兴达钢帘线股份有限公司 | Surface active agent in steel wire pickling solution |
| CN104073815A (en) * | 2014-06-26 | 2014-10-01 | 青岛启源振东电气有限公司 | Metal surface decontamination cleaning agent |
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