CN104789915B - Waterborne low-foam metal surface cleaning agent for thermal spraying and preparation method thereof - Google Patents
Waterborne low-foam metal surface cleaning agent for thermal spraying and preparation method thereof Download PDFInfo
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- CN104789915B CN104789915B CN201510194455.6A CN201510194455A CN104789915B CN 104789915 B CN104789915 B CN 104789915B CN 201510194455 A CN201510194455 A CN 201510194455A CN 104789915 B CN104789915 B CN 104789915B
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 51
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 45
- 239000002184 metal Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000006260 foam Substances 0.000 title abstract description 10
- 238000007751 thermal spraying Methods 0.000 title abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 56
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 48
- -1 polyoxyethylene Polymers 0.000 claims abstract description 40
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 34
- 239000013530 defoamer Substances 0.000 claims abstract description 25
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 17
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 17
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011575 calcium Substances 0.000 claims abstract description 17
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 17
- 229920000570 polyether Polymers 0.000 claims abstract description 17
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 17
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 17
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 17
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 17
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 16
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 16
- FGFWTUNWGQWDDJ-UHFFFAOYSA-N n,n-diethylethanamine;urea Chemical compound NC(N)=O.CCN(CC)CC FGFWTUNWGQWDDJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 8
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract 4
- 238000002156 mixing Methods 0.000 claims description 44
- 238000005507 spraying Methods 0.000 claims description 25
- OXEDXHIBHVMDST-UHFFFAOYSA-N 12Z-octadecenoic acid Natural products CCCCCC=CCCCCCCCCCCC(O)=O OXEDXHIBHVMDST-UHFFFAOYSA-N 0.000 claims description 16
- 229960001484 edetic acid Drugs 0.000 claims description 16
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 150000001298 alcohols Chemical class 0.000 claims description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 5
- 239000002516 radical scavenger Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 4
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 4
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 claims description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 3
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 3
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 claims 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 12
- 238000004140 cleaning Methods 0.000 abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- 239000012964 benzotriazole Substances 0.000 abstract description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 230000007935 neutral effect Effects 0.000 abstract description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 abstract 1
- 230000009965 odorless effect Effects 0.000 abstract 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 abstract 1
- LKOVPWSSZFDYPG-WUKNDPDISA-N trans-octadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCC\C=C\C(O)=O LKOVPWSSZFDYPG-WUKNDPDISA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- BQODPTQLXVVEJG-UHFFFAOYSA-N [O].C=C Chemical compound [O].C=C BQODPTQLXVVEJG-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000003751 zinc Chemical class 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 108010011935 Poly 18 antigen Chemical group 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a waterborne low-foam metal surface cleaning agent for thermal spraying. The waterborne low-foam metal surface cleaning agent comprises the following raw materials: a component A and a component B, wherein the component A and the component B are mixed at a volume ratio of 4:1 during preparation; in parts by weight, the component A comprises 4-8 parts of ethylenediaminetetraacetic acid, 11-18 parts of polyether, 10-15 parts of trihydroxyethyl amine, 1-4 parts of octadecenoic acid, 5-10 parts of dichloromethane, 10-17 parts of ethylene bis-stearamide, 5-8 parts of calcium alkylbenzene sulfonate, 2-4 parts of zinc dialkyl thiophosphate, 12-15 parts of benzotriazole, 4-6 parts of an antioxidant, 6-8 parts of a defoamer and 75-80 parts of water; in parts by weight, the component B comprises 14-16 parts of sodium carbonate, 3-8 parts of butanediol, 5-7 parts of sodium gluconate, 6-8 parts of triethylamine urea, 17-19 parts of polyoxyethylene aliphatic alcohol ether, 3-6 parts of alkanolamide and 40-55 parts of water. The waterborne low-foam metal surface cleaning agent can be used for radically cleaning dirt such as carbon powder, scrap iron, oil stains and the like formed on the outer surface of a metal workpiece due to machining; the cleaned metal outer surface is not integrally or locally corroded; the raw materials of the waterborne low-foam metal surface cleaning agent are all neutral products, so that the waterborne low-foam metal surface cleaning agent is mild in performance and does not contain chromate and nitrite; the waterborne low-foam metal surface cleaning agent is odorless, free of environmental pollution and harmless to a human body; at the same time, the waterborne low-foam metal surface cleaning agent is low in foam quantity, easy for rinsing and suitable for cleaning operation of an automatic cleaning machine.
Description
Technical field
The present invention relates to a kind of surface cleaning agent and preparation method thereof, specifically a kind of metal surface water used for hot spraying
Low bubble cleaning agent of base and preparation method thereof, belongs to field of metal surface treatment technology.
Background technology
By being early used for many applications known to the coating that thermal spraying applies.For example, in vehicular engine, oil lubrication
The surface of cylinder running surface has been coated the quite a long time especially by plasma spraying, and the coating is outstanding
It is to significantly reduce the coefficient of friction between piston ring and cylinder wall, so as to substantially reduce the abrasion of piston ring and cylinder, is made
Obtain service life of aeroengine to increase, maintenance period (for example changing oil) extends, and also significantly improves engine performance.
Many metal devices plus man-hour often use lubricating oil or coolant, when obtain metal surface and there is greasy dirt,
When thermal spraying is carried out often because the surface impurity such as greasy dirt affects the effect of thermal spraying, serious meeting to cause hot-spraying coating
Stripping, make troubles to processing, therefore often all device surface can be cleaned before spraying, traditional surface is clear
Clean dose has peculiar smell greatly, there is the problem of corrosion to metal surface.
The content of the invention
The technical problem to be solved is, propose a kind of water base low bubble cleaning agent in metal surface used for hot spraying and its
Preparation method, free from extraneous odour, and with very strong dirt-removing power, the spot on metal surface can be quickly removed, to metal watch
Face is corrosion-free.
The present invention solves the technical scheme of above technical problem：There is provided a kind of metal surface used for hot spraying water base low bubble cleaning
Agent, it is characterised in that：Its raw material composition includes A, B amount component, by volume 4 during preparation：1 mixing, wherein component A are by weight
Including：Ethylenediamine tetra-acetic acid 4-8 parts, polyethers 11-18 parts, trihydroxy ethylamine 10-15 parts, octadecenic acid 1-4 parts, dichloromethane
5-10 parts, vinyl bis-stearamides 10-17 part, alkyl benzene calcium sulfonate 5-8 parts, the double pungent primary alkyl zinc salt 2-4 parts of sulphur phosphorus, benzo
Triazole 12-15 part, antioxidant 4-6 parts, defoamer 6-8 parts, water 75-80 parts；
B component includes by weight：Sodium carbonate 14-16 parts, butanediol 3-8 parts, sodium gluconate 5-7 parts, triethylamine urine
Plain 6-8 parts, polyoxyethylene aliphatic alcohol ether 17-19 parts, alkanolamide 3-6 parts, water 40-55 parts.
The further restriction technical scheme of the present invention, the water base low bubble cleaning agent in aforesaid metal surface used for hot spraying is described
Antioxidant is:One or more in sodium hydrogensulfite, sodium pyrosulfite, sodium sulfite or exsiccated sodium sulfite；The defoamer
The mixture of the fatty acid ester compounded thing of dimethyl silicone polymer, higher alcohols, wherein dimethyl silicone polymer and high-carbon polyol fatty acid
The ratio that ester complexes mix by weight is 1:4.
The water base low bubble cleaning agent in aforesaid metal surface used for hot spraying, its raw material composition includes A, B amount component, presses during preparation
Volume ratio 4：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, 11 parts of polyethers, trihydroxy ethylamine 10
Part, 1 part of octadecenic acid, 5 parts of dichloromethane, 10 parts of vinyl bis-stearamides, 5 parts of alkyl benzene calcium sulfonate, the double pungent primary alkane of sulphur phosphorus
2 parts of base zinc salt, 12 parts of BTA, 4 parts of antioxidant, 6 parts of defoamer, 75 parts of water；
B component includes by weight：It is 14 parts of sodium carbonate, 3 parts of butanediol, 5 parts of sodium gluconate, 6 parts of triethylamine urea, poly-
17 parts of oxygen ethene fatty alcohol ether, 3 parts of alkanolamide, 40 parts of water.
The water base low bubble cleaning agent in aforesaid metal surface used for hot spraying, its raw material composition includes A, B amount component, presses during preparation
Volume ratio 4：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, 16 parts of polyethers, trihydroxy ethylamine 13
Part, 2 parts of octadecenic acid, 8 parts of dichloromethane, 15 parts of vinyl bis-stearamides, 6 parts of alkyl benzene calcium sulfonate, the double pungent primary alkane of sulphur phosphorus
3 parts of base zinc salt, 13 parts of BTA, 5 parts of antioxidant, 7 parts of defoamer, 78 parts of water；
B component includes by weight：It is 15 parts of sodium carbonate, 6 parts of butanediol, 6 parts of sodium gluconate, 7 parts of triethylamine urea, poly-
18 parts of oxygen ethene fatty alcohol ether, 5 parts of alkanolamide, 50 parts of water.
The water base low bubble cleaning agent in aforesaid metal surface used for hot spraying, its raw material composition includes A, B amount component, presses during preparation
Volume ratio 4：1 mixing, wherein component A includes by weight：8 parts of ethylenediamine tetra-acetic acid, 18 parts of polyethers, trihydroxy ethylamine 15
Part, 4 parts of octadecenic acid, 10 parts of dichloromethane, 17 parts of vinyl bis-stearamides, 8 parts of alkyl benzene calcium sulfonate, the double pungent primary alkane of sulphur phosphorus
4 parts of base zinc salt, 15 parts of BTA, 6 parts of antioxidant, 8 parts of defoamer, 80 parts of water；
B component includes by weight：It is 16 parts of sodium carbonate, 8 parts of butanediol, 7 parts of sodium gluconate, 8 parts of triethylamine urea, poly-
19 parts of oxygen ethene fatty alcohol ether, 6 parts of alkanolamide, 55 parts of water.
A kind of preparation method of the water base low bubble cleaning agent in metal surface used for hot spraying, comprises the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio for mixing by weight is
1:4, carry out being sufficiently mixed the defoamer made in component A；
Step（2）：By step（1）Ethylenediamine tetra-acetic acid, polyethers, trihydroxy ethyl in the defoamer for obtaining and component A
The double pungent primary alkyl zinc salt of amine, dichloromethane, sulphur phosphorus, octadecenic acid, BTA, put into respectively in the dispersion cylinder equipped with water,
Turn on agitator is slowly stirred, and mixing speed is that 350-400 turns/min, after stirring 25-30min, after estimating its homogeneous transparent, then
Vinyl bis-stearamides in component A, alkyl benzene calcium sulfonate are slowly added under stirring, regulation rotating speed is 250-
350 turns/min, mixing time is 30-35min, control dispersion cylinder temperature≤35 DEG C, the antioxidant being eventually adding in component A, together
Sample is stirred while adding, and it is that 200-300 turns/min, mixing time 30-45min to adjust rotating speed, and Jing filters that surface is obtained is clear
The component A of lotion；
Step（3）：With the water in B component and sodium carbonate, butanediol, triethylamine urea, sodium gluconate, polyoxyethylene fat
Fat alcohol ether, alkanolamide are mixed, and it is that 280-360 turns/min to adjust rotating speed, and mixing time 55-60min, control temperature is less than
30 DEG C, the B component of surface cleaning agent is obtained after filtering；
Step（4）：By step（2）The component A and step of the surface cleaning agent for preparing（3）The surface cleaning agent for obtaining
B component weigh be well mixed in mass ratio, you can obtain thermal spray metal surface scavenger specially.
Further, the preparation method of the water base low bubble cleaning agent in aforesaid metal surface used for hot spraying, in step（2）And step
Suddenly（3）When the component for obtaining is mixed, mixing dispersion barrel temperature is 28-35 DEG C, and incorporation time is 6-8h, and rotating speed is 320-
350 turns/min.
Beneficial effects of the present invention：The present invention on metal works outer surface because of the carbon dust that processing is formed, iron filings, greasy dirt etc.
Dirt carries out thoroughly cleaning, and the outer metallic surface after cleaning integrally or locally corrosion phenomenon will not occur, due to product raw material
It is neutral products, moderate performance, without chromate, nitrite；Odorlessness, environmentally safe, to human body fanout free region；Together
When the present invention with Low-foam and easily rinsing, it is adaptable to automatic rinser washing and cleaning operation.
Specific embodiment
Embodiment 1
The present embodiment is a kind of water base low bubble cleaning agent in metal surface used for hot spraying, and its raw material composition includes that A, B measure component,
By volume 4 during preparation：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, 11 parts of polyethers, trihydroxy second
10 parts of base amine, 1 part of octadecenic acid, 5 parts of dichloromethane, 10 parts of vinyl bis-stearamides, 5 parts of alkyl benzene calcium sulfonate, sulphur phosphorus is double
2 parts of pungent primary alkyl zinc salt, 12 parts of BTA, 4 parts of sodium hydrogensulfite, 6 parts of defoamer, 75 parts of water；The defoamer of the present embodiment
Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols ratio by weight are adopted for 1:4 mixing；
B component includes by weight：It is 14 parts of sodium carbonate, 3 parts of butanediol, 5 parts of sodium gluconate, 6 parts of triethylamine urea, poly-
17 parts of oxygen ethene fatty alcohol ether, 3 parts of alkanolamide, 40 parts of water.
The preparation method of the water base low bubble cleaning agent in metal surface a kind of used for hot spraying that the present embodiment is provided, including following step
Suddenly：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio for mixing by weight is
1:4, carry out being sufficiently mixed the defoamer made in component A；
Step（2）：By step（1）Ethylenediamine tetra-acetic acid, polyethers, trihydroxy ethyl in the defoamer for obtaining and component A
The double pungent primary alkyl zinc salt of amine, dichloromethane, sulphur phosphorus, octadecenic acid, BTA, put into respectively in the dispersion cylinder equipped with water,
Turn on agitator is slowly stirred, and mixing speed is 350 turns/min, after stirring 30min, after estimating its homogeneous transparent, then by component A
In vinyl bis-stearamides, alkyl benzene calcium sulfonate be slowly added under stirring, regulation rotating speed be 250 turns/min, stir
The time is mixed for 35min, control dispersion cylinder temperature≤35 DEG C, the antioxidant being eventually adding in component A is equally stirred while adding,
Regulation rotating speed is 200 turns/min, and mixing time 45min, Jing filters the component A that surface cleaning agent is obtained；
Step（3）：With the water in B component and sodium carbonate, butanediol, triethylamine urea, sodium gluconate, polyoxyethylene fat
Fat alcohol ether, alkanolamide are mixed, and regulation rotating speed is 280 turns/min, and mixing time 60min, control temperature is less than 30 DEG C, Jing
The B component of surface cleaning agent is obtained after filtration；
Step（4）：By step（2）The component A and step of the surface cleaning agent for preparing（3）The surface cleaning agent for obtaining
B component weigh be well mixed in mass ratio, during mixing, mixing dispersion barrel temperature is 28 DEG C, and incorporation time is 6h, and rotating speed is
350 turns/min, you can obtain thermal spray metal surface scavenger specially.
Embodiment 2
The present embodiment provides a kind of metal surface used for hot spraying water base low bubble cleaning agent, and its raw material composition includes A, B amount group
Point, by volume 4 during preparation：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, 16 parts of polyethers, three hydroxyls
13 parts of base ethylamine, 2 parts of octadecenic acid, 8 parts of dichloromethane, 15 parts of vinyl bis-stearamides, 6 parts of alkyl benzene calcium sulfonate, sulphur
Double 3 parts of the pungent primary alkyl zinc salts of phosphorus, 13 parts of BTA, 5 parts of sodium pyrosulfite, 7 parts of defoamer, 78 parts of water；The present embodiment disappears
Infusion adopts dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols ratio by weight for 1:4 mixing；
B component includes by weight：It is 15 parts of sodium carbonate, 6 parts of butanediol, 6 parts of sodium gluconate, 7 parts of triethylamine urea, poly-
18 parts of oxygen ethene fatty alcohol ether, 5 parts of alkanolamide, 50 parts of water.
The preparation method of the water base low bubble cleaning agent in metal surface a kind of used for hot spraying that the present embodiment is provided, including following step
Suddenly：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio for mixing by weight is
1:4, carry out being sufficiently mixed the defoamer made in component A；
Step（2）：By step（1）Ethylenediamine tetra-acetic acid, polyethers, trihydroxy ethyl in the defoamer for obtaining and component A
The double pungent primary alkyl zinc salt of amine, dichloromethane, sulphur phosphorus, octadecenic acid, BTA, put into respectively in the dispersion cylinder equipped with water,
Turn on agitator is slowly stirred, and mixing speed is 380 turns/min, after stirring 27min, after estimating its homogeneous transparent, then by component A
In vinyl bis-stearamides, alkyl benzene calcium sulfonate be slowly added under stirring, regulation rotating speed be 290 turns/min, stir
The time is mixed for 33min, control dispersion cylinder temperature≤35 DEG C, the antioxidant being eventually adding in component A is equally stirred while adding,
Regulation rotating speed is 250 turns/min, and mixing time 35min, Jing filters the component A that surface cleaning agent is obtained；
Step（3）：With the water in B component and sodium carbonate, butanediol, triethylamine urea, sodium gluconate, polyoxyethylene fat
Fat alcohol ether, alkanolamide are mixed, and regulation rotating speed is 330 turns/min, and mixing time 58min, control temperature is less than 30 DEG C, Jing
The B component of surface cleaning agent is obtained after filtration；
Step（4）：By step（2）The component A and step of the surface cleaning agent for preparing（3）The surface cleaning agent for obtaining
B component weigh be well mixed in mass ratio, during mixing, mixing dispersion barrel temperature is 30 DEG C, and incorporation time is 7h, and rotating speed is
340 turns/min, you can obtain thermal spray metal surface scavenger specially.
Embodiment 3
The present embodiment provides a kind of metal surface used for hot spraying water base low bubble cleaning agent, and its raw material composition includes A, B amount group
Point, by volume 4 during preparation：1 mixing, wherein component A includes by weight：8 parts of ethylenediamine tetra-acetic acid, 18 parts of polyethers, three hydroxyls
15 parts of base ethylamine, 4 parts of octadecenic acid, 10 parts of dichloromethane, 17 parts of vinyl bis-stearamides, 8 parts of alkyl benzene calcium sulfonate, sulphur
Double 4 parts of the pungent primary alkyl zinc salts of phosphorus, 15 parts of BTA, 6 parts of sodium pyrosulfite, 8 parts of defoamer, 80 parts of water；The present embodiment disappears
Infusion adopts dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols ratio by weight for 1:4 mixing；
B component includes by weight：It is 16 parts of sodium carbonate, 8 parts of butanediol, 7 parts of sodium gluconate, 8 parts of triethylamine urea, poly-
19 parts of oxygen ethene fatty alcohol ether, 6 parts of alkanolamide, 55 parts of water.
The preparation method of the water base low bubble cleaning agent in metal surface a kind of used for hot spraying that the present embodiment is provided, including following step
Suddenly：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio for mixing by weight is
1:4, carry out being sufficiently mixed the defoamer made in component A；
Step（2）：By step（1）Ethylenediamine tetra-acetic acid, polyethers, trihydroxy ethyl in the defoamer for obtaining and component A
The double pungent primary alkyl zinc salt of amine, dichloromethane, sulphur phosphorus, octadecenic acid, BTA, put into respectively in the dispersion cylinder equipped with water,
Turn on agitator is slowly stirred, and mixing speed is 400 turns/min, after stirring 25min, after estimating its homogeneous transparent, then by component A
In vinyl bis-stearamides, alkyl benzene calcium sulfonate be slowly added under stirring, regulation rotating speed be 350 turns/min, stir
The time is mixed for 30min, control dispersion cylinder temperature≤35 DEG C, the antioxidant being eventually adding in component A is equally stirred while adding,
Regulation rotating speed is 300 turns/min, and mixing time 30min, Jing filters the component A that surface cleaning agent is obtained；
Step（3）：With the water in B component and sodium carbonate, butanediol, triethylamine urea, sodium gluconate, polyoxyethylene fat
Fat alcohol ether, alkanolamide are mixed, and regulation rotating speed is 360 turns/min, and mixing time 55min, control temperature is less than 30 DEG C, Jing
The B component of surface cleaning agent is obtained after filtration；
Step（4）：By step（2）The component A and step of the surface cleaning agent for preparing（3）The surface cleaning agent for obtaining
B component weigh be well mixed in mass ratio, during mixing, mixing dispersion barrel temperature is 35 DEG C, and incorporation time is 6h, and rotating speed is
350 turns/min, you can obtain thermal spray metal surface scavenger specially.
In addition to the implementation, the present invention can also have other embodiment.All employing equivalents or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (7)
1. the water base low bubble cleaning agent in metal surface used for hot spraying, it is characterised in that：Its raw material composition includes that A, B measure component, prepares
When by volume 4：1 mixing, wherein component A includes by weight：Ethylenediamine tetra-acetic acid 4-8 parts, polyethers 11-18 parts, trihydroxy
Ethylamine 10-15 parts, octadecenic acid 1-4 parts, dichloromethane 5-10 parts, vinyl bis-stearamides 10-17 part, alkyl benzene sulphonate
Calcium 5-8 parts, the double pungent primary alkyl zinc salt 2-4 parts of sulphur phosphorus, BTA 12-15 parts, antioxidant 4-6 parts, defoamer 6-8 parts, water 75-
80 parts；
B component includes by weight：Sodium carbonate 14-16 parts, butanediol 3-8 parts, sodium gluconate 5-7 parts, triethylamine urea 6-8
Part, polyoxyethylene aliphatic alcohol ether 17-19 parts, alkanolamide 3-6 parts, water 40-55 parts.
2. the water base low bubble cleaning agent in metal surface used for hot spraying as claimed in claim 1, it is characterised in that：The antioxidant
For:One or more in sodium hydrogensulfite, sodium pyrosulfite, sodium sulfite or exsiccated sodium sulfite；The poly- diformazan of the defoamer
The mixture of the fatty acid ester compounded thing of radical siloxane, higher alcohols, wherein dimethyl silicone polymer are fatty acid ester compounded with higher alcohols
The ratio that thing mixes by weight is 1:4.
3. the water base low bubble cleaning agent in metal surface used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition bag
A, B amount component is included, by volume 4 during preparation：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, polyethers
11 parts, 10 parts of trihydroxy ethylamine, 1 part of octadecenic acid, 5 parts of dichloromethane, 10 parts of vinyl bis-stearamides, alkyl benzene sulphonate
5 parts of calcium, double 2 parts of the pungent primary alkyl zinc salts of sulphur phosphorus, 12 parts of BTA, 4 parts of antioxidant, 6 parts of defoamer, 75 parts of water；
B component includes by weight：14 parts of sodium carbonate, 3 parts of butanediol, 5 parts of sodium gluconate, 6 parts of triethylamine urea, polyoxy second
17 parts of alkene fatty alcohol ether, 3 parts of alkanolamide, 40 parts of water.
4. the water base low bubble cleaning agent in metal surface used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition bag
A, B amount component is included, by volume 4 during preparation：1 mixing, wherein component A includes by weight：4 parts of ethylenediamine tetra-acetic acid, polyethers
16 parts, 13 parts of trihydroxy ethylamine, 2 parts of octadecenic acid, 8 parts of dichloromethane, 15 parts of vinyl bis-stearamides, alkyl benzene sulphonate
6 parts of calcium, double 3 parts of the pungent primary alkyl zinc salts of sulphur phosphorus, 13 parts of BTA, 5 parts of antioxidant, 7 parts of defoamer, 78 parts of water；
B component includes by weight：15 parts of sodium carbonate, 6 parts of butanediol, 6 parts of sodium gluconate, 7 parts of triethylamine urea, polyoxy second
18 parts of alkene fatty alcohol ether, 5 parts of alkanolamide, 50 parts of water.
5. the water base low bubble cleaning agent in metal surface used for hot spraying as claimed in claim 1, it is characterised in that：Its raw material composition bag
A, B amount component is included, by volume 4 during preparation：1 mixing, wherein component A includes by weight：8 parts of ethylenediamine tetra-acetic acid, polyethers
18 parts, 15 parts of trihydroxy ethylamine, 4 parts of octadecenic acid, 10 parts of dichloromethane, 17 parts of vinyl bis-stearamides, benzene sulfonamide
8 parts of sour calcium, double 4 parts of the pungent primary alkyl zinc salts of sulphur phosphorus, 15 parts of BTA, 6 parts of antioxidant, 8 parts of defoamer, 80 parts of water；
B component includes by weight：16 parts of sodium carbonate, 8 parts of butanediol, 7 parts of sodium gluconate, 8 parts of triethylamine urea, polyoxy second
19 parts of alkene fatty alcohol ether, 6 parts of alkanolamide, 55 parts of water.
6. a kind of metal surface used for hot spraying it is water base it is low bubble cleaning agent preparation method, it is characterised in that comprise the following steps：
Step（1）：Dimethyl silicone polymer and the fatty acid ester compounded thing of higher alcohols are weighed, the ratio for mixing by weight is 1:4,
Carry out being sufficiently mixed the defoamer made in component A；
Step（2）：By step（1）Ethylenediamine tetra-acetic acid, polyethers, trihydroxy ethylamine in the defoamer for obtaining and component A, two
The double pungent primary alkyl zinc salt of chloromethanes, sulphur phosphorus, octadecenic acid, BTA, put into respectively in the dispersion cylinder equipped with water, unlatching is stirred
Mix device to be slowly stirred, mixing speed is that 350-400 turns/min, after stirring 25-30min, after estimating its homogeneous transparent, then by A groups
Point in vinyl bis-stearamides, alkyl benzene calcium sulfonate be slowly added under stirring, adjust rotating speed be 250-350 turn/
Min, mixing time is 30-35min, control dispersion cylinder temperature≤35 DEG C, and the antioxidant being eventually adding in component A, same side adds
Enter side stirring, it is that 200-300 turns/min to adjust rotating speed, and mixing time 30-45min, Jing filters the A that surface cleaning agent is obtained
Component；
Step（3）：With the water in B component and sodium carbonate, butanediol, triethylamine urea, sodium gluconate, polyoxyethylene fatty alcohol
Ether, alkanolamide are mixed, and it is that 280-360 turns/min to adjust rotating speed, and mixing time 55-60min, control temperature is less than 30
DEG C, the B component of surface cleaning agent is obtained after filtering；
Step（4）：By step（2）The component A and step of the surface cleaning agent for preparing（3）The B of the surface cleaning agent for obtaining
Component weighs be well mixed in mass ratio, you can obtain thermal spray metal surface scavenger specially.
7. metal surface used for hot spraying according to claim 6 it is water base it is low bubble cleaning agent preparation method, it is characterised in that：
In step（2）And step（3）When the component for obtaining is mixed, mixing dispersion barrel temperature is 28-35 DEG C, and incorporation time is 6-
8h, rotating speed is that 320-350 turns/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510194455.6A CN104789915B (en) | 2015-04-23 | 2015-04-23 | Waterborne low-foam metal surface cleaning agent for thermal spraying and preparation method thereof |
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| CN201510194455.6A CN104789915B (en) | 2015-04-23 | 2015-04-23 | Waterborne low-foam metal surface cleaning agent for thermal spraying and preparation method thereof |
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| US4970014A (en) * | 1989-12-22 | 1990-11-13 | Chem Shield, Inc. | Aluminum cleaning and brightening composition and method of manufacture thereof |
| CN103484884A (en) * | 2013-09-13 | 2014-01-01 | 武汉玻尔科技股份有限公司 | Low-foam middle-cloud-point environment-friendly water base metal cleaner composition and preparing method thereof |
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