CN103820195B - Exempt from oven dry can water-washing type fin machining oil and preparation method thereof - Google Patents
Exempt from oven dry can water-washing type fin machining oil and preparation method thereof Download PDFInfo
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- CN103820195B CN103820195B CN201410093369.1A CN201410093369A CN103820195B CN 103820195 B CN103820195 B CN 103820195B CN 201410093369 A CN201410093369 A CN 201410093369A CN 103820195 B CN103820195 B CN 103820195B
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Abstract
The invention discloses one exempt from oven dry can water-washing type fin machining oil and preparation method thereof, of the present invention exempt from oven dry can water-washing type fin machining oil by base oil, antioxidant addn, lubricant, synthetic ester, tensio-active agent and penetrant form according to specified weight proportions, this exempts to dry can have that exempt to dry can the characteristic of water-washing type by water-washing type fin machining oil, part can be had to volatilize through certain hour at normal temperatures, make fin machining rear surface can not there is oil products many especially, oil product consumption is reduced, and the oil film remaining in fin surface in complete machine uses through the flushing of water of condensation, can be pulled away along with water of condensation, Energy Efficiency Ratio is not affected in like this air-conditioning being used, save and dried the Sweet natural gas used, equipment, electricity, personnel and place, decrease simultaneously combustion of natural gas be discharged into carbonic acid gas in environment, also to take obvious economy to client.
Description
Technical field
The present invention relates to a kind of fin machining oil and preparation method thereof, be specifically related to a kind of have exempt from dry and can wash characteristic fin machining oil and preparation method thereof.
Background technology
Have punching in fin machining process, stretch, the machining deformations such as flange, have fresh surface to be formed after machining, and need outstanding oilness to ensure its normal process in the course of processing.No clean is developed into from capable of washing in the evolution of fin machining oil, developing deeply is to drying-type, what use in the market is all drying-type, after fin machining completes, assembling completes rear surface has volatile product to remain, need to enter debinding furnace to dry its volatile oil is volatilized completely, object be avoid affecting aluminium foil wetting ability thus affect Energy Efficiency Ratio.Need to expend in whole processes process dry use Sweet natural gas, electricity, personnel, place, and when drying gas-firing (or electricity consumption) the carbonic acid gas be discharged in air large impact is also caused on environment.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides one exempt from oven dry can water-washing type fin machining oil and preparation method thereof, originally exempt to dry and can have that exempt to dry can the characteristic of water-washing type by water-washing type fin machining oil, in guarantee fin machining demand simultaneously, the life cycle of extension device, save oil product usage quantity, the Sweet natural gas of drying use, equipment, electricity, personnel and place are saved, decrease simultaneously combustion of natural gas be discharged into carbonic acid gas in environment, also to take obvious economy to client.
The present invention in order to the technical scheme solving its technical problem and adopt is:
One exempt from oven dry can water-washing type fin machining oil, in total weight percent, each component proportion is as follows:
Base oil: 60-100%;
Antioxidant addn: 0-3%;
Lubricant: 0-40%;
Synthetic ester: 0-30%;
Tensio-active agent: 0-15%;
Penetrant: 0-5%;
Described exempt to dry can the specifications parameter of water-washing type fin machining oil as follows:
Outward appearance: colourless or light yellow transparent liquid;
Proportion (15/4 DEG C): 0.75-0.98;
Viscosity (40 DEG C, mm2/s) :≤20;
Flash-point (DEG C): 20.0-300.0.
The present invention in order to the further technical scheme solving its technical problem and adopt is:
Described antioxidant addn is right, right '-diisopropyl benzene pentanoic.
Described base oil is at least one in isoparaffin, Porous deproteinized bone solvent oil and hydrogenation aromatics-removing solvent oil, and the specifications parameter of described base oil is as follows:
Outward appearance: colourless transparent liquid;
Proportion (15/4 DEG C): 0.7-0.98;
Viscosity: 0.7-5.0;
Flash-point: 20-200;
Flow process: 80-300;
Sulphur content :≤5.0%.
Described lubricant be molecular weight the low-molecular-weight polyisobutylene of 100-4000, carbonatoms be the polyalphaolefin of 4-40, the carbonatoms at least one that to be the straight chain alcohol of 8-20 and carbonatoms be in the isomery alcohol of 8-20.
The lipid acid of described synthetic ester to be carbonatoms be 4-20 and carbonatoms are the synthetic ester that the alcohol of 4-20 reacts gained.
Described carbonatoms is that the lipid acid of 4-20 comprises straight chain fatty acid and branched chain fatty acid, and described synthetic ester comprises straight chain and side chain.
Described tensio-active agent is OP(octyl phenol polyoxy ether), TX(alkylphenol polyoxyethylene), NP(polyoxyethylene nonylphenol ether) and isomeric alcohol polyethenoxy ether class nonionogenic tenside at least one, and contained EO number is 2-20.
Described tensio-active agent is anion surfactant.
Described penetrant is ethylene glycol amine.
Above-mentioned exempt to dry can the preparation method of water-washing type fin machining oil, carries out successively in the steps below:
1) described base oil is dropped in reactor, and be warming up to 40 ± 5 DEG C, keep temperature 10 ± 5min;
2) then drop into described antioxidant addn, lubricant and synthetic ester, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min;
3) then input table surface-active agent and penetrant, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min.
The invention has the beneficial effects as follows: of the present invention exempt from oven dry can water-washing type fin machining oil by base oil, antioxidant addn, lubricant, synthetic ester, tensio-active agent and penetrant form according to specified weight proportions, base oil used in the present invention has outstanding volatility, biodegradable and nonirritant, ensure that product can volatilize at normal temperatures and can not cause peculiar smell and pollution to environment, the lubricant added, antioxidant addn and tensio-active agent have outstanding oilness, ensure lubricating requirement during aluminum fin-stock punching press, product of the present invention can have part to volatilize through certain hour at normal temperatures, make fin machining rear surface can not there is oil products many especially, oil product consumption is reduced, because having special composition (tensio-active agent) in product of the present invention, the oil film making to remain in fin surface in complete machine uses through the flushing of water of condensation, can be pulled away along with water of condensation, Energy Efficiency Ratio is not affected in like this air-conditioning being used.It can water-washing type fin machining oil be according to the requirement of air-conditioner fin complete processing that the present invention exempts from oven dry, reduce production and application amount, reduce during air-conditioning is produced the Sweet natural gas burnt, reduce effective discharge of carbonic acid gas in air simultaneously, work in-process usage quantity can reduce to processes the over half of usage quantity at present, simultaneously due to outstanding Rust Preventing Oil Film that product has, pressing equipment can be significantly avoided to get rusty phenomenon, greatly improve the life cycle of equipment, for client reduces equipment, the energy, place, the aspects such as personnel, economic benefit also to be taken very objective income.
Embodiment
Below by way of specific specific examples, the specific embodiment of the present invention is described, those skilled in the art can understand advantage of the present invention and effect easily by content disclosed in the present specification.The present invention also can be implemented in further, different ways, that is, not departing under disclosed category, can give different modifications and change.
Embodiment: of the present inventionly exempt to dry and the formula of embodiment 1 to 9 of water-washing type fin machining oil can see the following form 1:
Table 1(unit: weight percent %)
Wherein, described antioxidant addn is right, right '-diisopropyl benzene pentanoic.
Wherein, described base oil is at least one in isoparaffin, Porous deproteinized bone solvent oil and hydrogenation aromatics-removing solvent oil, and the specifications parameter of described base oil is as follows:
Outward appearance: colourless transparent liquid;
Proportion (15/4 DEG C): 0.7-0.98;
Viscosity: 0.7-5.0;
Flash-point: 20-200;
Flow process: 80-300;
Sulphur content :≤5.0%.
Wherein, described lubricant be molecular weight the low-molecular-weight polyisobutylene of 100-4000, carbonatoms be the polyalphaolefin of 4-40, the carbonatoms at least one that to be the straight chain alcohol of 8-20 and carbonatoms be in the isomery alcohol of 8-20.
Wherein, the lipid acid of described synthetic ester to be carbonatoms be 4-20 and carbonatoms are the synthetic ester that the alcohol of 4-20 reacts gained.Described carbonatoms is that the lipid acid of 4-20 comprises straight chain fatty acid and branched chain fatty acid, and described synthetic ester comprises straight chain and side chain.
Wherein, described tensio-active agent is OP(octyl phenol polyoxy ether), TX(alkylphenol polyoxyethylene), NP(polyoxyethylene nonylphenol ether) and isomeric alcohol polyethenoxy ether class nonionogenic tenside at least one, and contained EO number is 2-20.Except above-mentioned nonionogenic tenside, also anion surfactant can be used.
Wherein, described penetrant is ethylene glycol amine.
Above-mentioned exempt to dry can the preparation method of water-washing type fin machining oil, carries out successively in the steps below:
1) production unit is clean, and equipment well runs;
2) described base oil is dropped in reactor, and be warming up to 40 ± 5 DEG C, keep temperature 10 ± 5min;
3) then drop into described antioxidant addn, lubricant and synthetic ester, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min;
4) then input table surface-active agent and penetrant, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min;
5) sampling detects qualified rear packaging.
Of the present invention exempt to dry can the specifications parameter of water-washing type fin machining oil as follows:
Outward appearance: colourless or light yellow transparent liquid;
Proportion (15/4 DEG C): 0.75-0.98;
Viscosity (40 DEG C, mm2/s) :≤20;
Flash-point (DEG C): 20.0-300.0.
By the continuous debugging of formula for a product, according to the technique that on-site customer uses, product all shows good performance in the actual test of client.The base oil that product of the present invention uses has outstanding volatility, biodegradable and nonirritant, ensures that product can volatilize at normal temperatures and can not cause peculiar smell and pollution to environment.Add lubricant, antioxidant addn and surfactant component through the allotment of specified proportion technique, there is outstanding oilness, ensure lubricating requirement during aluminum fin-stock punching press; In product, composition has the oil product of 0.0-90% in fin machining technological process, volatilize (generally product volatilization 70-75%) under field conditions (factors), at the oil product (generally residual 30%) of fin surface by residual 10-100%, make fin machining rear surface can not there is oil products many especially, oil product consumption is reduced, and product reduces over half than current volatility treated oil in usage quantity.Because having special composition (tensio-active agent) in product, the oil film making to remain in fin surface through the flushing of water of condensation, can be pulled away along with water of condensation, not affect Energy Efficiency Ratio in using like this on air-conditioning in complete machine uses.
Should be understood that above-described embodiment is only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within claims of the present invention limited range equally after the content of having read the present invention's instruction.
Claims (2)
1. one kind exempt from oven dry can water-washing type fin machining oil, it is characterized in that: in total weight percent, each component proportion is as follows:
Base oil: 60-90%;
Antioxidant addn: 0.1-3%;
Lubricant: 0-20%;
Synthetic ester: 0.2-30%;
Tensio-active agent: 0.4-15%;
Penetrant: 0.1-5%;
Described exempt to dry can the specifications parameter of water-washing type fin machining oil as follows:
Outward appearance: colourless or light yellow transparent liquid;
The proportion of the water relative to 4 DEG C 15 DEG C time: 0.75-0.98;
Viscosity≤20mm under 40 DEG C of temperature regulate
2/ s;
Flash-point: 20.0-300.0 DEG C;
Described base oil is hydrogenation aromatics-removing solvent oil;
Described lubricant is the low-molecular-weight polyisobutylene of molecular weight at 100-4000;
Described tensio-active agent is OP, and contained EO number is 2-20;
Described antioxidant addn is right, right '-diisopropyl benzene pentanoic;
The lipid acid of described synthetic ester to be carbonatoms be 4-20 and carbonatoms are the synthetic ester that the alcohol of 4-20 reacts gained, described carbonatoms is that the lipid acid of 4-20 comprises straight chain fatty acid and branched chain fatty acid, and described synthetic ester is the synthetic ester that molecular structure comprises straight chain and side chain;
Described penetrant is ethylene glycol amine.
2. exempting from as claimed in claim 1 to dry can the preparation method of water-washing type fin machining oil, it is characterized in that: carry out successively in the steps below:
1) described base oil is dropped in reactor, and be warming up to 40 ± 5 DEG C, keep temperature 10 ± 5min;
2) then drop into described antioxidant addn, lubricant and synthetic ester, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min;
3) then input table surface-active agent and penetrant, and be stirred to transparent, whipping process temperature controls at 40 ± 5 DEG C, and churning time is 30 ± 5min.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104479823A (en) * | 2014-12-05 | 2015-04-01 | 柳州市顺菱汽车配件有限责任公司 | Environment-friendly violate punching oil |
| CN104611091A (en) * | 2015-01-28 | 2015-05-13 | 浙江海洋学院 | Environment-friendly strong-volatility aluminum fin punching oil and preparation method thereof |
| CN106147947B (en) * | 2015-04-01 | 2019-11-01 | 北京钟云科技有限公司 | A kind of punching oil and its application in aluminium and copper material processing |
| CN108130170A (en) * | 2017-12-14 | 2018-06-08 | 诺而曼环保科技（江苏）有限公司 | A kind of tasteless safe volatile rust preventive oil |
| CN111120313B (en) * | 2019-12-24 | 2021-11-02 | 烟台德高石油有限公司 | Cleaning agent for online cleaning of screw air compressor |
| CN112980550B (en) * | 2021-02-03 | 2022-09-16 | 苏州铱诺化学材料有限公司 | Air conditioner accessory processing oil and preparation method thereof |
| CN113462453A (en) * | 2021-07-23 | 2021-10-01 | 苏州安美润滑科技有限公司 | Aging volatile cleaning-free forming oil and preparation method thereof |
| CN114317083B (en) * | 2021-12-31 | 2022-09-13 | 上海恩坤工业技术有限公司 | Lubricating composition, preparation method and lubricating method |
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| CN102719303A (en) * | 2012-06-04 | 2012-10-10 | 苏州铱诺化学材料有限公司 | Volatile aluminum fin punching oil and preparation method thereof |
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| CN102719303A (en) * | 2012-06-04 | 2012-10-10 | 苏州铱诺化学材料有限公司 | Volatile aluminum fin punching oil and preparation method thereof |
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| "HC-L200挥发性冲压油的研制及工业应用";张华豪等;《石油炼制与化工》;20070831;第38卷(第8期);第44～47页 * |
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