CN104805305B - 一种以热镀锌渣湿法冶炼无害化生产锌锭的方法 - Google Patents
一种以热镀锌渣湿法冶炼无害化生产锌锭的方法 Download PDFInfo
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- CN104805305B CN104805305B CN201510244713.7A CN201510244713A CN104805305B CN 104805305 B CN104805305 B CN 104805305B CN 201510244713 A CN201510244713 A CN 201510244713A CN 104805305 B CN104805305 B CN 104805305B
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- Prior art keywords
- zinc
- slag
- iron
- leaching
- washing
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 118
- 239000011701 zinc Substances 0.000 title claims abstract description 105
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 102
- 238000000034 method Methods 0.000 title claims abstract description 94
- 239000002893 slag Substances 0.000 title claims abstract description 92
- 238000005246 galvanizing Methods 0.000 title claims abstract description 38
- 238000003723 Smelting Methods 0.000 title claims abstract description 15
- 238000002386 leaching Methods 0.000 claims abstract description 64
- 239000000460 chlorine Substances 0.000 claims abstract description 46
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 46
- 238000005406 washing Methods 0.000 claims abstract description 37
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000005266 casting Methods 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000011282 treatment Methods 0.000 claims abstract description 16
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 14
- 230000003647 oxidation Effects 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 182
- 229910052742 iron Inorganic materials 0.000 claims description 68
- 239000007788 liquid Substances 0.000 claims description 43
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 30
- 239000002699 waste material Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 238000001914 filtration Methods 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- 239000000706 filtrate Substances 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 15
- 239000011787 zinc oxide Substances 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 13
- 238000009854 hydrometallurgy Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 239000002244 precipitate Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000006386 neutralization reaction Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 238000011033 desalting Methods 0.000 claims description 7
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 6
- 238000010517 secondary reaction Methods 0.000 claims description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 6
- 229960001763 zinc sulfate Drugs 0.000 claims description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 238000007885 magnetic separation Methods 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- CUPCBVUMRUSXIU-UHFFFAOYSA-N [Fe].OOO Chemical compound [Fe].OOO CUPCBVUMRUSXIU-UHFFFAOYSA-N 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- 229910021519 iron(III) oxide-hydroxide Inorganic materials 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 230000000382 dechlorinating effect Effects 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims description 2
- 239000011344 liquid material Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000010612 desalination reaction Methods 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229910006540 α-FeOOH Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000003912 environmental pollution Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 230000001172 regenerating effect Effects 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 239000000428 dust Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229910052595 hematite Inorganic materials 0.000 description 2
- 239000011019 hematite Substances 0.000 description 2
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 2
- 229910052935 jarosite Inorganic materials 0.000 description 2
- WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013058 crude material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052981 lead sulfide Inorganic materials 0.000 description 1
- 229940056932 lead sulfide Drugs 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009856 non-ferrous metallurgy Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Description
Claims (9)
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CN201510244713.7A CN104805305B (zh) | 2015-05-14 | 2015-05-14 | 一种以热镀锌渣湿法冶炼无害化生产锌锭的方法 |
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CN201510244713.7A CN104805305B (zh) | 2015-05-14 | 2015-05-14 | 一种以热镀锌渣湿法冶炼无害化生产锌锭的方法 |
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CN104805305A CN104805305A (zh) | 2015-07-29 |
CN104805305B true CN104805305B (zh) | 2017-04-05 |
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Families Citing this family (3)
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CN106756063B (zh) * | 2016-12-12 | 2018-09-07 | 株洲冶炼集团股份有限公司 | 一种铝锌硅渣的综合回收方法 |
CN112725835B (zh) * | 2020-12-29 | 2024-03-12 | 吉首市金湘资源科技开发有限公司 | 利用高氯铜烟灰和铜泥锌物料清洁生产高纯电解锌的方法 |
CN113603148A (zh) * | 2021-07-13 | 2021-11-05 | 斯瑞尔环境科技股份有限公司 | 一种高含量锌铁废酸分步沉淀分离的资源化利用方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1023818C (zh) * | 1991-03-19 | 1994-02-16 | 昆明工学院 | 热镀锌渣真空蒸馏提锌方法及其设备 |
CN1041757C (zh) * | 1991-08-02 | 1999-01-20 | 北京矿冶研究总院 | 一种浸出电解法从含锌物料中生产锌粉的方法 |
CN1125883C (zh) * | 1999-07-09 | 2003-10-29 | 水口山有色金属有限责任公司 | 一种高纯锌金属的制备方法 |
CN1341760A (zh) * | 2001-08-06 | 2002-03-27 | 邵家跃 | 一种湿法炼锌工艺 |
CN1181213C (zh) * | 2001-11-23 | 2004-12-22 | 宝山钢铁股份有限公司 | 热镀锌锌渣的再生新工艺 |
CN101580901B (zh) * | 2008-05-15 | 2012-09-12 | 甘肃世恒有色资源再利用有限公司 | 采用含锌渣料提炼锌的方法 |
CN102433449B (zh) * | 2011-12-31 | 2014-07-02 | 北京北矿锌业有限责任公司 | 用热镀锌渣直接制备高纯度锌制品的蒸馏炉 |
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Effective date of registration: 20170324 Address after: 618400, Sichuan, Shifang Pavilion moonlight Lane No. 16, building 1, unit 3, building 2, No. Patentee after: Sun Weicheng Address before: 618000 Deyang Zhujiang Road, Sichuan, No. 99 Patentee before: Star of renewable resources (Deyang) Co. Ltd. |
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CB03 | Change of inventor or designer information |
Inventor after: Liu Hongbo Inventor after: Liu Anrong Inventor after: Wang Zhenjie Inventor before: Sun Weicheng Inventor before: Liu Hongbo |
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Effective date of registration: 20171115 Address after: 550002 Baoshan South Road, Guiyang, Guiyang, Guizhou Patentee after: Guizhou Institute of Metallurgy Chemical Address before: 618400, Sichuan, Shifang Pavilion moonlight Lane No. 16, building 1, unit 3, building 2, No. Patentee before: Sun Weicheng |
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