CN104804809A - Lubricating grease for protecting aluminum-conductor steel-reinforced cables and preparation method of lubricating grease - Google Patents
Lubricating grease for protecting aluminum-conductor steel-reinforced cables and preparation method of lubricating grease Download PDFInfo
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- CN104804809A CN104804809A CN201510207030.4A CN201510207030A CN104804809A CN 104804809 A CN104804809 A CN 104804809A CN 201510207030 A CN201510207030 A CN 201510207030A CN 104804809 A CN104804809 A CN 104804809A
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- lubricating grease
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- aluminium cable
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Abstract
The invention discloses lubricating grease for protecting aluminum-conductor steel-reinforced cables and a preparation method of the lubricating grease, and relates to the technical field of chemical engineering. The lubricating grease comprises the following components in percentage by weight: 50-90% of base oil, 1-5% of isocyanate, 1-5% of fatty amine, 1-6% of aromatic amine, 1-6% of a tackifier, 1-5% of a rust inhibitor, 0.25-0.8% of an anti-oxidant and 0.04-0.08% of a metal corrosion inhibitor, wherein the base oil is mineral oil or synthetic base oil of which the temperature is 40 DEG C and the kinematic viscosity is 120-500 mm<2>/s. The lubricating grease has the advantages that the normal operation of the aluminum-conductor steel-reinforced cables in a seriously corroded offshore industry area can be guaranteed, the service lives of the aluminum-conductor steel-reinforced cables in the seriously corroded offshore industry area can be effectively prolonged, the water-resistant, rustproof and anti-corrosive functions can be realized, and the protecting requirements for the aluminum-conductor steel-reinforced cables can be ensured.
Description
Technical field:
The present invention relates to chemical technology field, be specifically related to a kind of lubricating grease for Aluminium Cable Steel Reinforced protection and preparation method thereof.
Background technology:
Aluminium Cable Steel Reinforced is by aluminum steel and steel wire is stranded forms, and is widely used in overhead transmission line.As the Aluminium Cable Steel Reinforced of electric power overhead wire leading product, be 30 years in power department life, the work-ing life of Aluminium Cable Steel Reinforced was determined by the steel core life-span, and the key addressed this problem improves the Corrosion Protection of steel core.Steel core can corrode by material effects such as moisture, chemical gas and tears in an atmosphere, and this corrosion is especially more serious in littoral industrial area.The protection on the degree of corrosion and the composition of material and surface has substantial connection.The corrosion of steel core is divided into chemical corrosion and galvanic corrosion.When atmospheric moisture is larger, steel core surface moisture can be condensed into moisture film, and the etchant gas in air such as sulfurous gas, nitrogen peroxide, hydrogen sulfide and salts substances are dissolved in moisture film, forms Thin Electrolyte Layer, reacts thus produce corrode with metal.Inner at Aluminium Cable Steel Reinforced, steel core and aluminium stock contact layer, due to electrode potential difference, also can produce crevice corrosion.After Aluminium Cable Steel Reinforced is corroded, wire obviously becomes fragile, and tensile strength obviously reduces, and can cause disconnected stock, broken string time serious, substantially reduces the work-ing life of Aluminium Cable Steel Reinforced.Therefore, in order to extend the work-ing life of Aluminium Cable Steel Reinforced, the corrosionproof protection of Aluminium Cable Steel Reinforced must be strengthened.
In order to improve the erosion resistance of Aluminium Cable Steel Reinforced, domestic and international production firm coats the anti-corrosion grease that organic materials is made usually between steel core and aluminium twist, such as Vaseline, alkyl fat, be used for stopping that moisture and corrosive gases are to the corrosion of steel core, owing to scribbling the anticorrosion grease of one deck between steel core and aluminum stranded conductor, therebetween because potential difference cause corrosion can obviously weaken.But Vaseline and alkyl fat obtain primarily of the waxed of various low melting point, so dropping point is between 50 ~ 70 DEG C, during the broiling summer, because Aluminium Cable Steel Reinforced inherently can produce certain heat, cosmoline is easy to drip from Aluminium Cable Steel Reinforced, do not have rot-resistant effect, but also add the cost of production firm, also have environment and pollute.
Summary of the invention:
The object of this invention is to provide a kind of lubricating grease for Aluminium Cable Steel Reinforced protection and preparation method thereof, it can be applicable to high-temperature, can provide long-time, excellent protective effect to Aluminium Cable Steel Reinforced.
In order to solve the problem existing for background technology, the present invention is by the following technical solutions: it is made up of following parts by weight: base oil 50 ~ 90%, isocyanic ester 1 ~ 5%, aliphatic amide 1 ~ 5%, aromatic amine 1 ~ 6%, tackifier 1 ~ 6%, rust-preventive agent 1 ~ 5%, oxidation inhibitor 0.25 ~ 0.8%, metal corrosion inhibitor 0.04 ~ 0.08%.
For a preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps: in 1# reactor, add base oil, is warming up to 50 DEG C, is dropped into by isocyanic ester in reactor, stirs 45min; Add base oil to 2# reactor, add aliphatic amide and aromatic amine, be warming up to 80 ~ 100 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 80 ~ 85 DEG C, slowly be warming up to 130 ~ 140 DEG C, constant temperature 10min, then be cooled to 100 ~ 110 DEG C, add tackifier, rust-preventive agent, oxidation inhibitor, metal corrosion inhibitor, make it whole dissolving, and stir 30min at this temperature, be cooled to 80 ~ 90 DEG C, homogenizing process.
As preferably, described base oil is the mixture of one or more different viscosity grade base oils, and the kinematic viscosity of 40 DEG C is 120 ~ 500mm
2/ s.
As preferably, described isocyanic ester is '-diphenylmethane diisocyanate.
As preferably, described aliphatic amide is the one in stearylamine, hexahydroaniline.
As preferably, described aromatic amine is aniline.
As preferably, described tackifier are ethylene-propylene rubber(EPR).
As preferably, described rust-preventive agent is the mixture of a kind of in barium mahogany sulfonate, petroleum sodium sulfonate, dinonyl naphthalene sulfonate barium, dinonylnaphthalene sulfonic acid calcium or any two kinds.More preferred, described rust-preventive agent is the combination of barium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium.
As preferably, described oxidation inhibitor be pentanoic, N-phenyl-a-naphthylamine, alkylphenol, to dioctyl diphenylamine.More preferred, described oxidation inhibitor is dioctyl diphenylamine.
As preferably, described metal corrosion inhibitor is the mixture of a kind of in benzotriazole, thiadiazoles derivative, carboxylate salt and sulfonamide derivatives or any two kinds.More preferred, described metal corrosion inhibitor is carboxylate salt and sulfonamide derivatives.
The beneficial effect that the present invention produces: can meet Aluminium Cable Steel Reinforced and use in the case of a high temperature, can play water resistant, antirust, etch-proof effect simultaneously, can guarantee the requirement of shelter of Aluminium Cable Steel Reinforced.
Accompanying drawing illustrates:
Fig. 1 detects data sheet for the lubricating grease physicochemical property of Aluminium Cable Steel Reinforced protection in this embodiment.
Embodiment:
Below in conjunction with accompanying drawing, the present invention is described in detail.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with the drawings and the specific embodiments, the present invention is further elaborated.Should be appreciated that embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1:
Referring to Fig. 1, a kind of described preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps:
In 1# reactor, adding 200g paraffin base mineral oil, (40 DEG C of kinematic viscosity are 180mm
2/ s), be warming up to 50 DEG C, 16.68g '-diphenylmethane diisocyanate dropped in 1# reactor, stir 45min; (40 DEG C of kinematic viscosity are 180mm to add 238.6g paraffin base mineral oil to 2# reactor
2/ s), add 11.02g stearylamine and 11.4g hexahydroaniline, be warming up to 80 ~ 100 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 85 DEG C, is slowly warming up to 140 DEG C, constant temperature 10min, be cooled to 110 DEG C again, add 10g ethylene-propylene rubber(EPR), 2g dioctyl diphenylamine, 10g barium mahogany sulfonate, 0.3g carboxylate salt and sulfonamide derivatives, make it whole dissolving, and stir 30min at this temperature, be cooled to 90 DEG C, homogenizing process.
Embodiment 2:
Referring to Fig. 1, a kind of described preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps:
In 1# reactor, add 200g gather a alkene (40 DEG C of kinematic viscosity are 210mm
2/ s), be warming up to 50 DEG C, 16.68g '-diphenylmethane diisocyanate dropped in 1# reactor, stir 45min; (40 DEG C of kinematic viscosity are 180mm to add 238.6g paraffin base mineral oil to 2# reactor
2/ s), add 11.02g stearylamine and 11.4g hexahydroaniline, be warming up to 100 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 85 DEG C, is slowly warming up to 140 DEG C, constant temperature 10min, be cooled to 110 DEG C again, add 10g ethylene-propylene rubber(EPR), 2g dioctyl diphenylamine, 10g barium mahogany sulfonate, 0.3g carboxylate salt and sulfonamide derivatives, make it whole dissolving, and stir 30min at this temperature, be cooled to 90 DEG C, homogenizing process.
Embodiment 3:
Referring to Fig. 1, a kind of described preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps:
In 1# reactor, adding 160g paraffin base mineral oil, (40 DEG C of kinematic viscosity are 260mm
2/ s), be warming up to 50 DEG C, 14.68g '-diphenylmethane diisocyanate dropped in 1# reactor, stir 45min; (40 DEG C of kinematic viscosity are 260mm to add 168.2g paraffin base mineral oil to 2# reactor
2/ s), add 8.02g stearylamine and 8.8g aniline, be warming up to 90 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 80 DEG C, is slowly warming up to 135 DEG C, constant temperature 10min, be cooled to 105 DEG C again, add 8g ethylene-propylene rubber(EPR), 2g dioctyl diphenylamine, 8g barium mahogany sulfonate, 0.2g carboxylate salt and sulfonamide derivatives, make it whole dissolving, and stir 30min at this temperature, be cooled to 85 DEG C, homogenizing process.
Embodiment 4:
Referring to Fig. 1, a kind of described preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps:
In 1# reactor, add 160g gather a alkene (40 DEG C of kinematic viscosity are 300mm
2/ s), be warming up to 50 DEG C, 14.68g '-diphenylmethane diisocyanate dropped in 1# reactor, stir 45min; (40 DEG C of kinematic viscosity are 300mm to add 168.2g paraffin base mineral oil to 2# reactor
2/ s), add 8.02g stearylamine and 8.8g aniline, be warming up to 90 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 80 DEG C, is slowly warming up to 135 DEG C, constant temperature 10min, be cooled to 105 DEG C again, add 8g ethylene-propylene rubber(EPR), 2g dioctyl diphenylamine, 8g barium mahogany sulfonate, 0.2g carboxylate salt and sulfonamide derivatives, make it whole dissolving, and stir 30min at this temperature, be cooled to 85 DEG C, homogenizing process, this lubricating grease obtained.
Embodiment 5:
Referring to Fig. 1, a kind of described preparation of greases method for Aluminium Cable Steel Reinforced protection, it comprises following steps:
In 1# reactor, adding 120g paraffin base mineral oil, (40 DEG C of kinematic viscosity are 220mm
2/ s), be warming up to 50 DEG C, 12.68g '-diphenylmethane diisocyanate dropped in 1# reactor, stir 45min; (40 DEG C of kinematic viscosity are 220mm to add 128.6g paraffin base mineral oil to 2# reactor
2/ s), add 6.02g stearylamine and 6.4g hexahydroaniline, be warming up to 80 DEG C, stir 40min.2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 80 DEG C, is slowly warming up to 130 DEG C, constant temperature 10min, be cooled to 100 DEG C again, add 6g ethylene-propylene rubber(EPR), 1g dioctyl diphenylamine, 6g barium mahogany sulfonate, 6g dinonylnaphthalene sulfonic acid calcium, 0.2g carboxylate salt and sulfonamide derivatives, make it whole dissolving, and stir 30min at this temperature, be cooled to 80 DEG C, homogenizing process.
The beneficial effect that this embodiment produces: can meet Aluminium Cable Steel Reinforced and use in the case of a high temperature, can play water resistant, antirust, etch-proof effect simultaneously, can guarantee the requirement of shelter of Aluminium Cable Steel Reinforced.
The above is only in order to illustrate technical scheme of the present invention and unrestricted, other amendment that those of ordinary skill in the art make technical scheme of the present invention or equivalently to replace, only otherwise depart from the spirit and scope of technical solution of the present invention, all should be encompassed in the middle of right of the present invention.
Claims (10)
1., for a lubricating grease for Aluminium Cable Steel Reinforced protection, it is characterized in that: it is made up of following parts by weight: base oil 50 ~ 90%, isocyanic ester 1 ~ 5%, aliphatic amide 1 ~ 5%, aromatic amine 1 ~ 6%, tackifier 1 ~ 6%, rust-preventive agent 1 ~ 5%, oxidation inhibitor 0.25 ~ 0.8%, metal corrosion inhibitor 0.04 ~ 0.08%.
2., for a preparation of greases method for Aluminium Cable Steel Reinforced protection, it is characterized in that it comprises following steps:
In 1# reactor, add base oil, be warming up to 50 DEG C, isocyanic ester is dropped in reactor, stir 45min; Add base oil to 2# reactor, add aliphatic amide and aromatic amine, be warming up to 80 ~ 100 DEG C, stir 40min, 2# reactor material is slowly added 1# reactor, reaction 1h, temperature remains on 80 ~ 85 DEG C, slowly be warming up to 130 ~ 140 DEG C, constant temperature 10min, then be cooled to 100 ~ 110 DEG C, add tackifier, rust-preventive agent, oxidation inhibitor, metal corrosion inhibitor, makes it whole dissolving, and stirs 30min at this temperature, be cooled to 80 ~ 90 DEG C, homogenizing process.
3. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, it is characterized in that: described base oil is the mixture of one or more different viscosity grade base oils, the kinematic viscosity of 40 DEG C is 120 ~ 500mm
2/ s.
4. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, is characterized in that: described isocyanic ester is '-diphenylmethane diisocyanate.
5. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, is characterized in that: described aliphatic amide is the one in stearylamine, hexahydroaniline.
6. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, is characterized in that: described aromatic amine is aniline.
7. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, is characterized in that: described tackifier are ethylene-propylene rubber(EPR).
8. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, it is characterized in that: described rust-preventive agent is the mixture of a kind of in barium mahogany sulfonate, petroleum sodium sulfonate, dinonyl naphthalene sulfonate barium, dinonylnaphthalene sulfonic acid calcium or any two kinds, the combination of preferred barium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium.
9. according to claim 1 a kind of for Aluminium Cable Steel Reinforced protection lubricating grease, it is characterized in that: described oxidation inhibitor be pentanoic, N-phenyl-a-naphthylamine, alkylphenol, to dioctyl diphenylamine, preferred dioctyl diphenylamine.
10. a kind of lubricating grease for Aluminium Cable Steel Reinforced protection according to claim 1, it is characterized in that: described metal corrosion inhibitor is the mixture of a kind of in benzotriazole, thiadiazoles derivative, carboxylate salt and sulfonamide derivatives or any two kinds, optimization acid's salt and sulfonamide derivatives.
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105861125A (en) * | 2016-04-19 | 2016-08-17 | 天津海航石油能源科技有限公司 | Anti-corrosion lubricating grease for unbonded prestressed ribs and preparation method of anti-corrosion lubricating grease |
CN107057812A (en) * | 2017-04-22 | 2017-08-18 | 郑州市欧普士科技有限公司 | A kind of steel strand wires special anti-corrosion fat and preparation method thereof |
CN107760427A (en) * | 2017-11-16 | 2018-03-06 | 郑州市欧普士科技有限公司 | A kind of extremely low point of oil cut rate aerial condutor anti-corrosion grease and preparation method thereof |
CN107794108A (en) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | A kind of round wires concentric gallows empty conductor conduction anti-corrosion grease and preparation method thereof |
CN109868179A (en) * | 2019-02-26 | 2019-06-11 | 天津市金海利油脂有限公司 | A kind of manufacturing method of extreme pressure grease |
CN110055122A (en) * | 2018-01-17 | 2019-07-26 | 上杭鑫昌龙实业有限公司 | Anti-corrosion grease and preparation method thereof |
CN111117730A (en) * | 2019-12-27 | 2020-05-08 | 柳州欧维姆结构检测技术有限公司 | Protective grease for bridge inhaul cable and preparation method thereof |
CN112852525A (en) * | 2020-04-03 | 2021-05-28 | 郑州市欧普士科技有限公司 | Heat-resistant lubricating grease and preparation method and application thereof |
CN113077943A (en) * | 2021-04-19 | 2021-07-06 | 江苏南瑞银龙电缆有限公司 | Preparation method of low-strength extremely-poor steel-cored aluminum strand |
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2015
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105861125A (en) * | 2016-04-19 | 2016-08-17 | 天津海航石油能源科技有限公司 | Anti-corrosion lubricating grease for unbonded prestressed ribs and preparation method of anti-corrosion lubricating grease |
CN107057812A (en) * | 2017-04-22 | 2017-08-18 | 郑州市欧普士科技有限公司 | A kind of steel strand wires special anti-corrosion fat and preparation method thereof |
CN107760427A (en) * | 2017-11-16 | 2018-03-06 | 郑州市欧普士科技有限公司 | A kind of extremely low point of oil cut rate aerial condutor anti-corrosion grease and preparation method thereof |
CN107794108A (en) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | A kind of round wires concentric gallows empty conductor conduction anti-corrosion grease and preparation method thereof |
CN110055122A (en) * | 2018-01-17 | 2019-07-26 | 上杭鑫昌龙实业有限公司 | Anti-corrosion grease and preparation method thereof |
CN109868179A (en) * | 2019-02-26 | 2019-06-11 | 天津市金海利油脂有限公司 | A kind of manufacturing method of extreme pressure grease |
CN111117730A (en) * | 2019-12-27 | 2020-05-08 | 柳州欧维姆结构检测技术有限公司 | Protective grease for bridge inhaul cable and preparation method thereof |
CN111117730B (en) * | 2019-12-27 | 2022-04-15 | 柳州欧维姆结构检测技术有限公司 | Protective grease for bridge inhaul cable and preparation method thereof |
CN112852525A (en) * | 2020-04-03 | 2021-05-28 | 郑州市欧普士科技有限公司 | Heat-resistant lubricating grease and preparation method and application thereof |
CN113077943A (en) * | 2021-04-19 | 2021-07-06 | 江苏南瑞银龙电缆有限公司 | Preparation method of low-strength extremely-poor steel-cored aluminum strand |
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Application publication date: 20150729 |