CN110055122A - Anti-corrosion grease and preparation method thereof - Google Patents
Anti-corrosion grease and preparation method thereof Download PDFInfo
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- CN110055122A CN110055122A CN201810045715.7A CN201810045715A CN110055122A CN 110055122 A CN110055122 A CN 110055122A CN 201810045715 A CN201810045715 A CN 201810045715A CN 110055122 A CN110055122 A CN 110055122A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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Abstract
The present invention relates to a kind of anti-corrosion greases and preparation method thereof.A kind of anti-corrosion grease, in terms of mass fraction, including 70 parts~95 parts of base oils, 0.1 part~15 parts of thermoplastic elastomer (TPE), 0.01 part~2 parts of antioxidant, 0.1 part~20 parts of thickening agent and 0.1 part~5 parts of structural stabilizing agent.Above-mentioned anti-corrosion grease, each component cooperate, are verified by experiments, and have high dropping point, high cone penetration, good heat-resistant stable and resistance to ag(e)ing.
Description
Technical field
The present invention relates to a kind of anti-corrosion greases and preparation method thereof.
Background technique
With the development of national economy and the continuous growth of electricity needs, the safety problem of power generation is also increasingly heavier
It wants.Since power supply area is covered by trees, the influence of the factors such as route burn into natural calamity makes the reliability of power distribution network
Face many challenges.
Aerial condutor is the main building block of overhead power line, and effect is transmission electric current, conveys electrical power.It is aerial
Conducting wire includes suspended insulated guide wire and overhead bare conductor, and suspended insulated guide wire is usually to be made of the good copper of electric conductivity, aluminium,
And in one layer of rubber of the outer bread of conducting wire or plastics to insulate.Overhead bare conductor does not include insulating layer, and by air insulation, it can
The weight for mitigating conducting wire, reduces the burden of steel tower, reduces the cost of conducting wire, and bare conductor is conducive to heat dissipation, reduces power consumption.
But due to the harsh weather such as intense UV rays illumination and rain, snow, hail, dust storm and high temperature resistant, low temperature resistant, effective protection smog,
The invasion such as chemical gas, overhead bare conductor are easy aging, and service life is shorter.
Summary of the invention
Based on this, it is necessary to for the weatherable problem of overhead bare conductor, provide a kind of anti-corrosion grease and its preparation
Method.
A kind of anti-corrosion grease, in terms of mass fraction, comprising:
Above-mentioned anti-corrosion grease, each component cooperate, are verified by experiments, and have high dropping point, high cone penetration, cone before and after aging
The variation of in-degree has good heat-resistant stable, resistance to ag(e)ing less than 10%.
The base oil is selected from alkane, cycloalkane, aromatic hydrocarbons, natural gas liquefaction, silicone oil, mine in one of the embodiments,
At least one of object oil and synthetic oil.
The base oil is selected from least one of mineral oil and synthetic oil in one of the embodiments,.
The thermoplastic elastomer (TPE) includes styrene analog thermoplastic elastomer in one of the embodiments,.
The thermoplastic elastomer (TPE) is selected from SB, SEP, SEB, SBS, SEBS, SEPS and ternary in one of the embodiments,
At least one of EP rubbers.
The thickening agent is selected from silica, organobentonite, diatomite, kaolin in one of the embodiments,
And at least one of calcium carbonate.
In one of the embodiments, the structural stabilizing agent in silane coupling agent and metatitanic acid lipid coupling agent extremely
Few one kind.
In one of the embodiments, further include:
0.01 part~5 parts of pour-point depressant；And/or
0.1 part~15 parts of antirust agent.
The antioxidant is selected from aromatic amine antioxidant, Hinered phenols antioxidant, phosphorous in one of the embodiments,
At least one of acid esters kind antioxidant and heterocycle kind antioxidant.
The preparation method of above-mentioned anti-corrosion grease, comprising the following steps: obtain each component Hybrid Heating of the anti-corrosion grease
Anti-corrosion grease.
The preparation method process flow of above-mentioned anti-corrosion grease is simple, low for equipment requirements, is suitble to large-scale industrialization
Production.
Specific embodiment
To facilitate the understanding of the present invention, it is described more fully below mainly in combination with anti-corrosion grease and preparation method thereof.
But the invention can be realized in many different forms, however it is not limited to embodiment described herein.On the contrary, providing
The purpose of these embodiments is to keep the disclosure of invention more thorough and comprehensive.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The anti-corrosion grease of one embodiment, in terms of mass fraction, comprising:
Base oil, the oil-based material as anti-corrosion grease.
Base oil is 70 parts~85 parts, further preferably 72 parts~80 parts in one of the embodiments,.
Base oil is selected from alkane, cycloalkane, aromatic hydrocarbons, natural gas liquefaction, mineral oil and synthesis in one of the embodiments,
At least one of oil.
Further, in 4~20 branched paraffin of linear paraffin and carbon atom number of the alkane selected from carbon atom number 4~20 extremely
Few one kind；Cycloalkane is the cycloalkane of ring carbon atom number 5~20；Aromatic hydrocarbons is selected from the aromatic hydrocarbons of ring carbon atom number 6~12；Natural gas system
Oil is selected from the natural gas liquefaction of ring carbon atom number 10~20；Mineral oil be relative molecular weight be 100~500 plus the white mineral of hydrogen
Oil；Synthetic oil is PAO synthetic oil.
In one of the embodiments, the viscosity of base oil be 50cst~5000cst, further preferably 50cst~
500cst。
Further, base oil is selected from least one of mineral oil, synthetic oil and natural gas liquefaction.Further,
Base oil is selected from least one of white mineral oil, PAO synthetic oil and natural gas liquefaction.
Thermoplastic elastomer (TPE) (TPE or TPR), also known as artificial rubber or synthetic rubber, are between rubber and resin
A kind of novel high polymer material.The product of thermoplastic elastomer (TPE) had both had the high resiliency, ageing-resistant, resistance to of traditional cross-linking vulcanized rubber
Oiliness, while feature easy to process but also with common plastics, that processing method is extensive.Thermoplastic elastomer (TPE) be structurally characterized in that by
Chemical bond forms different rubber segments and resin section, and rubber segments are high resiliency segments, and resin section relies on inter-chain action power formation
Manage crosslinking points, the physical crosslinking variation with temperature of resin section and be in reversible change, it is shown that the plastics of thermoplastic elastomer (TPE) add
Work characteristic.
Thermoplastic elastomer (TPE) is selected from styrene analog thermoplastic elastomer, olefin hydrocarbons thermoplasticity in one of the embodiments,
Elastomer, diene analog thermoplastic elastomer, polyvinyl chloride-base thermoplastic elastomer, polyvinyl chloride-base thermoplastic elastomer, urethane class heat
Thermoplastic elastic, esters thermoplastic elastomer (TPE), amide analog thermoplastic elastomer, organic fluoride class thermoplastic elastomer (TPE), organic silicon
At least one of thermoplastic elastomer (TPE) and ethylene analog thermoplastic elastomer.
Further, styrene analog thermoplastic elastomer be selected from Styrene-Butadiene-Styrene Block Copolymer (SBS),
Styrene-isoprene-styrene block copolymer (SIS), hydrogenated styrene-butadiene-styrene block copolymers
(SEBS) and at least one of hydrogenated styrene isoprene block copolymer (SEPS).Olefin hydrocarbons thermoplasticity elastic body choosing
From at least one of TPO and TPV.Diene analog thermoplastic elastomer is selected from least one of TPB and TPI.Polyvinyl chloride-base modeling
Property elastomer be selected from least one of TPVC and TCPE.Urethane analog thermoplastic elastomer is TPU.Esters thermoplastic elastomer (TPE) is
TPEE.Amide analog thermoplastic elastomer is TPAE.Organic fluoride class thermoplastic elastomer (TPE) is TPF.
As the component of anti-corrosion grease, thermoplastic elastomer (TPE) can be with the good intersolubility of base oil, can be with base oil shape
At a kind of stable reticular structure, and also there is good thickening power.
In the present embodiment, thermoplastic elastomer (TPE) is styrene analog thermoplastic elastomer.
Thermoplastic elastomer (TPE) is preferably 2 parts~10 parts in one of the embodiments,.It is still more preferably 4 parts~10
Part.
Further, thermoplastic elastomer (TPE) is selected from the diblock copolymer and rubber chain of rubber segment and styrene segment
At least one of section, polystyrene chain segment and triblock copolymer of alkene.
Thermoplastic elastomer (TPE) is selected from styrene-butadiene block copolymer (SB), benzene second in one of the embodiments,
Alkene-isoprene-styrene block copolymer (SEP), styrene-butadiene-vinyl block polymer (SEB), styrene-fourth
Styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymers (SEBS), hydrogenation of benzene second
At least one of alkene-isoprene block copolymer (SEPS) and ethylene propylene diene rubber.
Thickening agent has dispersibility, surface lipophilicity, stability, anti-corrosive properties, can disperse and be formed knot in base oil
Structure skeleton makes base oil adsorb and be fixed in structural framework.As the component of anti-corrosion grease, thickening agent can be improved antiseptic oil
The consistency of rouge increases high temperature resistance, and anti-corrosion grease is made to be not easy drip under high temperature environment for a long time.
Thickening agent is 5 parts~15 parts, further preferably 6 parts~13 parts in one of the embodiments,.
Thickening agent is in metal soap base thickening agent, organic thickening agent, inorganic thickening agent in one of the embodiments,
It is at least one.
Thickening agent is inorganic thickening agent in one of the embodiments,.Further, thickening agent is selected from silica, has
At least one of machine bentonite, diatomite, kaolin and calcium carbonate.Further, thickening agent be fumed silica or
Organobentonite.
Structural stabilizing agent can make anti-corrosion oil/fat composition form more stable reticular structure.
Structural stabilizing agent is 0.1 part~1.5 parts in one of the embodiments,.
In one of the embodiments, structural stabilizing agent in silane coupling agent and metatitanic acid lipid coupling agent at least one
Kind.
Structural stabilizing agent is selected from silane resin acceptor kh-550, silane coupling agent KH560, silicon in one of the embodiments,
At least one of alkane coupling agent KH570.
Structural stabilizing agent is selected from triisopropyl phosphorous acid metatitanic acid rouge and triisopropyl stearic acid in one of the embodiments,
At least one of metatitanic acid rouge.
Anti-corrosion grease further includes antioxidant in one of the embodiments,.As the component of anti-corrosion grease, antioxidant can
The oxidation process for effectively product being inhibited to occur in other circumstances, delays its aging and improves his service life.Wherein one
In a embodiment, antioxidant is 0.1 part~1.5 parts, further preferably 0.1 part~1 part.
Further, antioxidant is selected from aromatic amine antioxidant and Hinered phenols antioxidant, phosphite antioxidant and miscellaneous
At least one of ring kind antioxidant.
Further, antioxidant is selected from least one of Hinered phenols antioxidant and phosphite ester antioxidant.
Further, antioxidant is Hinered phenols antioxidant.
Anti-corrosion grease further includes 0.01 part~5 parts of pour-point depressant in one of the embodiments,.Pour-point depressant, which has to reduce, to coagulate
Solid point, the function of increasing mobility.As the component of anti-corrosion grease, pour-point depressant, which can make anti-corrosion grease at low temperature, to be had well
Mobility and dispersibility, can be good at promoted anti-corrosion grease cryogenic property.
Pour-point depressant is 0.01 part~2 parts, further preferably 0.1 part~1 part in one of the embodiments,.
In one of the embodiments, pour-point depressant be selected from polymethacrylate pour-point depressant, polyalphaolefin class pour-point depressant,
At least one of vinylacetate pour-point depressant, vinyl acetate modified dose of class pour-point depressant, copolymer-maleic anhydride class pour-point depressant.
Further, pour-point depressant is selected from polyalphaolefin class pour-point depressant, polymethacrylate pour-point depressant, vinylacetate
At least one of pour-point depressant and vinyl acetate modified dose of class pour-point depressant.
Further, pour-point depressant is polymethacrylate pour-point depressant.
Anti-corrosion grease further includes 0.1 part~15 parts of antirust agent in one of the embodiments,.Group as anti-corrosion grease
Point, antirust agent can prevent plain conductor to be corroded.
Antirust agent is 4 parts~12 parts, further preferably 6 parts~10 parts in one of the embodiments,.
Antirust agent is selected from barium mahogany sulfonate, dodecenylsuccinic acid, dinonylnaphthalene sulfonic acid in one of the embodiments,
At least one of barium, petroleum sodium sulfonate.
Further, antirust agent in barium mahogany sulfonate, dodecenylsuccinic acid and dinonyl naphthalene sulfonate barium at least
It is a kind of.
Further, antirust agent is barium mahogany sulfonate or dinonyl naphthalene sulfonate barium.
Above-mentioned anti-corrosion grease, each component cooperate, are verified by experiments, and have high dropping point, high cone penetration, cone before and after aging
The variation of in-degree is smaller, has good heat-resistant stable, resistance to ag(e)ing, coated in can guarantee frame after on overhead bare conductor
Empty bare conductor can be steady in a long-term use.
The preparation method of above-mentioned anti-corrosion grease, comprising the following steps:
S110, by base oil and thermoplastic elastomer (TPE) heating stirring, obtain the first mixture.
Base oil is first heated to 110 DEG C~120 DEG C in one of the embodiments, thermoplastic elastomer (TPE) is then added,
With 2500r/min~3500r/min insulated and stirred 15min~90min.
It heats and stirs in one of the embodiments, and carried out under closed or protective atmosphere, to prevent component to be oxidized.
S120, antioxidant, pour-point depressant, structural stabilizing agent, antirust agent and thickening agent and the first mixture are stirred, are taken off
Gas obtains anti-corrosion grease.
Antioxidant, pour-point depressant, knot are added after the first mixture is cooled to 80 DEG C~90 DEG C in one of the embodiments,
Structure stabilizer, antirust agent and thickening agent.
In one of the embodiments, mixing speed be 500r/min~5000r/min, mixing time be 15min~
90min.30min~60min is further preferably stirred with 2000r/min~3500r/min.
First antioxidant, pour-point depressant, structural stabilizing agent and antirust agent and the first mixture are stirred in one of the embodiments,
It mixes after mixing, adds thickening agent and stir evenly.Further, it is added after thickening agent with 2000n/min~3500n/
Min stirs 15min~60min.
It is understood that antioxidant, pour-point depressant, structural stabilizing agent, antirust agent and thickening agent can be added first several times
In mixture, so as to save stirring power cost while stirring more evenly.Certain antioxidant, structural stabilizing agent, is prevented pour-point depressant
Rust agent and thickening agent can be separately added into the first mixture, be added in the first mixture after can also being pre-mixed.
The preparation method process flow of above-mentioned anti-corrosion grease is simple, low for equipment requirements, is suitble to large-scale industrialization
Production.
The following are specific embodiments.
Number in following embodiment is mass fraction.Following embodiment does not then include removing and can not keeping away if not otherwise specified
The other components outside impurity exempted from.The preparation parameter of Examples 1 to 8 is shown in Table 1, the specific steps are as follows:
1) base oil, thermoplastic elastomer (TPE), antioxidant, thickening agent, structural stabilizing agent, pour-point depressant are weighed according to table 2 and prevented
Rust agent.
2) base oil is heated to T1, thermoplastic elastomer (TPE) is added in temperature after stablizing, constant temperature is kept to stir t1 with S1, obtains the
One mixture meets after base oil dissolves each other after thermoplastic elastomer (TPE) and is cooled to T2.
3) antioxidant, pour-point depressant, structural stabilizing agent and antirust agent are added in the first mixture, after stirring t2 with S2, are added
Enter thickening agent, continues to stir t3 with S3, then vacuum defoamation obtains anti-corrosion grease.
Table 1
Note: by stearic acid, benzoic acid and aluminium isopropoxide, 1:1:2 carries out saponification system to complex lithium thickening agent in molar ratio
?.
Table 2
| Embodiment | T1/℃ | S1/r·min-1 | t1/min | T2/℃ | S2/r·min-1 | t2/min | S3//r·min-1 | t3/min |
| 1 | 115 | 3000 | 30 | 90 | 3000 | 51 | 3000 | 25 |
| 2 | 120 | 2800 | 35 | 85 | 2800 | 41 | 3000 | 28 |
| 3 | 110 | 3300 | 60 | 90 | 3300 | 42 | 2800 | 15 |
| 4 | 118 | 3000 | 28 | 80 | 3000 | 36 | 3000 | 24 |
| 5 | 120 | 2500 | 60 | 85 | 2500 | 30 | 2500 | 25 |
| 6 | 115 | 3500 | 35 | 90 | 3500 | 35 | 3500 | 18 |
| 7 | 118 | 3000 | 28 | 80 | 0 | 0 | 3000 | 24 |
| 8 | 120 | 2800 | 35 | 85 | 0 | 0 | 3000 | 28 |
The resulting anti-corrosion grease of Examples 1 to 8 is tested for the property, test result is as shown in table 3.
Table 3
From table 3 it can be seen that the anti-corrosion grease each component of Examples 1 to 6 cooperates, embodiment 7 and embodiment are compared
8, the anti-corrosion grease of Examples 1 to 6 has that cone penetration change rate before and after higher dropping point, aging is smaller, high-temperature stability is stronger,
Anticorrosion effect is more preferably, oxidation induction period is longer, low temperature viscometric property is stronger.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of anti-corrosion grease, which is characterized in that in terms of mass fraction, comprising:
2. anti-corrosion grease according to claim 1, which is characterized in that the base oil be selected from alkane, cycloalkane, aromatic hydrocarbons,
At least one of natural gas liquefaction, silicone oil, mineral oil and synthetic oil.
3. anti-corrosion grease according to claim 1, which is characterized in that the base oil is in mineral oil and synthetic oil
It is at least one.
4. anti-corrosion grease according to claim 1, which is characterized in that the thermoplastic elastomer (TPE) is styrene analog thermoplastic
Elastomer.
5. anti-corrosion grease according to claim 1, which is characterized in that the thermoplastic elastomer (TPE) be selected from SB, SEP, SEB,
At least one of SBS, SEBS, SEPS and ethylene propylene diene rubber.
6. anti-corrosion grease according to claim 1, which is characterized in that the thickening agent is selected from silica, organic swelling
At least one of soil, diatomite, kaolin and calcium carbonate.
7. anti-corrosion grease according to claim 1, which is characterized in that the structural stabilizing agent is selected from silane coupling agent and titanium
At least one of sour lipid coupling agent.
8. described in any item anti-corrosion greases according to claim 1~7, which is characterized in that further include:
0.01 part~5 parts of pour-point depressant；And/or
0.1 part~15 parts of antirust agent.
9. anti-corrosion grease according to claim 1, which is characterized in that the antioxidant be selected from aromatic amine antioxidant, by
Hinder at least one of phenolic antioxidant, phosphite ester antioxidant and heterocycle kind antioxidant.
10. the preparation method of anti-corrosion grease described in claim 1, which comprises the following steps:
The each component Hybrid Heating of the anti-corrosion grease is obtained into anti-corrosion grease.
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| CN201810045715.7A CN110055122A (en) | 2018-01-17 | 2018-01-17 | Anti-corrosion grease and preparation method thereof |
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| CN201810045715.7A CN110055122A (en) | 2018-01-17 | 2018-01-17 | Anti-corrosion grease and preparation method thereof |
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| CN110055122A true CN110055122A (en) | 2019-07-26 |
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| CN201810045715.7A Pending CN110055122A (en) | 2018-01-17 | 2018-01-17 | Anti-corrosion grease and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112457902A (en) * | 2020-10-14 | 2021-03-09 | 纳拓润滑技术江苏有限公司 | Lubricating grease composition for overhead conductor and production process thereof |
| CN113293047A (en) * | 2021-04-29 | 2021-08-24 | 北京联飞翔科技股份有限公司 | High-temperature lubricating grease for vehicles |
| CN114958467A (en) * | 2022-06-22 | 2022-08-30 | 浙江渤威能源科技有限公司 | Environment-friendly cooling preparation for air compressor |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5116522A (en) * | 1988-09-08 | 1992-05-26 | Exxon Research And Engineering Company | Grease composition containing an ethylene copolymer having a melt index of at least about 40 |
| US20020042468A1 (en) * | 2000-08-19 | 2002-04-11 | Choi Chi Hoon | Thermosetting resin composition for outer panel of automobile |
| CN1944518A (en) * | 2006-09-26 | 2007-04-11 | 居学成 | High efficiency energy saving conductive composite ester and its producing process |
| CN101876735A (en) * | 2010-06-04 | 2010-11-03 | 深圳尤尼吉尔通信有限公司 | Half-dry environment-friendly optical fiber filling paste and preparation technology thereof |
| CN102053322A (en) * | 2009-11-10 | 2011-05-11 | 上海鸿辉光通材料有限公司 | Optical fiber filling paste for optical fiber composite overhead ground wire (OPGW) and preparation method thereof |
| CN103484205A (en) * | 2013-08-29 | 2014-01-01 | 中国石油化工股份有限公司 | Thermoplastic-elastomer-containing complex aluminum-based lubricating grease composition and preparation method thereof |
| CN104181655A (en) * | 2014-03-11 | 2014-12-03 | 黄燕生 | Fiber filling paste and preparation method thereof |
| CN104804809A (en) * | 2015-04-28 | 2015-07-29 | 天津市金海利油脂有限公司 | Lubricating grease for protecting aluminum-conductor steel-reinforced cables and preparation method of lubricating grease |
| CN106981331A (en) * | 2017-04-25 | 2017-07-25 | 浙江舟电子科技股份有限公司 | It is a kind of have block water and the shield type of tension function surpasses six class cables |
-
2018
- 2018-01-17 CN CN201810045715.7A patent/CN110055122A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5116522A (en) * | 1988-09-08 | 1992-05-26 | Exxon Research And Engineering Company | Grease composition containing an ethylene copolymer having a melt index of at least about 40 |
| US20020042468A1 (en) * | 2000-08-19 | 2002-04-11 | Choi Chi Hoon | Thermosetting resin composition for outer panel of automobile |
| CN1944518A (en) * | 2006-09-26 | 2007-04-11 | 居学成 | High efficiency energy saving conductive composite ester and its producing process |
| CN102053322A (en) * | 2009-11-10 | 2011-05-11 | 上海鸿辉光通材料有限公司 | Optical fiber filling paste for optical fiber composite overhead ground wire (OPGW) and preparation method thereof |
| CN101876735A (en) * | 2010-06-04 | 2010-11-03 | 深圳尤尼吉尔通信有限公司 | Half-dry environment-friendly optical fiber filling paste and preparation technology thereof |
| CN103484205A (en) * | 2013-08-29 | 2014-01-01 | 中国石油化工股份有限公司 | Thermoplastic-elastomer-containing complex aluminum-based lubricating grease composition and preparation method thereof |
| CN104181655A (en) * | 2014-03-11 | 2014-12-03 | 黄燕生 | Fiber filling paste and preparation method thereof |
| CN104804809A (en) * | 2015-04-28 | 2015-07-29 | 天津市金海利油脂有限公司 | Lubricating grease for protecting aluminum-conductor steel-reinforced cables and preparation method of lubricating grease |
| CN106981331A (en) * | 2017-04-25 | 2017-07-25 | 浙江舟电子科技股份有限公司 | It is a kind of have block water and the shield type of tension function surpasses six class cables |
Non-Patent Citations (4)
| Title |
|---|
| 于守武等: "《高分子材料改性——原理与技术》", 31 May 2015, 知识产权出版社 * |
| 李东: "《最新石蜡、润滑油、润滑剂（脂）提炼技术、工艺流程及质量检验实务全书》", 31 July 2004, 当代中国音像出版社 * |
| 杨柳涛等: "《高分子材料》", 30 June 2016 * |
| 祝志祥等: "架空输电导线的腐蚀分析与防护", 《中国电力》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112457902A (en) * | 2020-10-14 | 2021-03-09 | 纳拓润滑技术江苏有限公司 | Lubricating grease composition for overhead conductor and production process thereof |
| CN113293047A (en) * | 2021-04-29 | 2021-08-24 | 北京联飞翔科技股份有限公司 | High-temperature lubricating grease for vehicles |
| CN114958467A (en) * | 2022-06-22 | 2022-08-30 | 浙江渤威能源科技有限公司 | Environment-friendly cooling preparation for air compressor |
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