CN102719302A - Volatile rust preventive oil - Google Patents
Volatile rust preventive oil Download PDFInfo
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- CN102719302A CN102719302A CN2012102287384A CN201210228738A CN102719302A CN 102719302 A CN102719302 A CN 102719302A CN 2012102287384 A CN2012102287384 A CN 2012102287384A CN 201210228738 A CN201210228738 A CN 201210228738A CN 102719302 A CN102719302 A CN 102719302A
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Abstract
The invention discloses volatile rust preventive oil which comprises, by weight, 71-91% of base oil, 5-25% of an oil soluble volatile corrosion inhibitor, 1-5% of an antirusting agent, 1-6% of a cosolvent, 0.5-1% of a mildew-proof agent, 0.5-1% of an antifoaming agent and 1-6% of antioxidant, wherein the base oil is one of 500SN 46# machine oil, 32# machine oil, 600SN 150# machine oil and 100# machine oil; and the oil soluble volatile corrosion inhibitor is a mixture of four kinds of 2-heptadecenyl-imidalidine, octadecylamine, triazole tributylamine, dicyclohexylamine carbonate, dicyclohexylaminenitrite, benzotriazole, tert-butyl chromate, nephthenic soap, petroleum sodium sulfonate, sorbitan monooleate and stearic acid; and the antioxidant is sulfurphosphorousbutyloctyl zinc salt. The volatile rust preventive oil has good volatile rust preventive and corrosion resistant performances, metal which cannot be coated with rust preventive oil can achieve rust preventive protection, the operation is simple, and the cost is low.
Description
Technical field
The invention belongs to technical field of lubricating oil, relate to a kind of volatile rust preventive oil.
Background technology
Slushing oil plays an important role aspect metallic corrosion.Yet existing slushing oil all is made up of base oil and oil-soluble inhibitor, can only play the antirust function of contact, does not reach the position of slushing oil for those, and the special gear box like mover, compressor etc. can not form effective corrosion protection.
Summary of the invention
The technical problem that the present invention will solve is: a kind of volatile rust preventive oil is provided, with the special gear box that solves some equipment (mover, compressor etc.) owing to do not reach slushing oil, oxidation easily, the problem of getting rusty.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of volatile rust preventive oil is characterized in that, it is made up of following components by weight percent:
In the above-mentioned prescription:
Base oil is a kind of in 500SN, 46# machinery oil, 32# machinery oil, 600SN, 150# machinery oil, the 100# machinery oil;
The oil soluble vapour-phase inhibitor is wantonly four a kinds mixture in 2-ethylamino 17 alkenyl imidazolines, stearylamine, triazole Tributylamine, carbonic acid dicyclohexyl amine, hexylamine nitrous acid two rings, benzotriazole, chromic acid tert-butyl, naphthenic soap, petroleum sodium sulfonate, sorbitol monooleate, the Triple Pressed Stearic Acid;
Rust-preventive agent is a kind of in calcium mahogany sulfonate, barium mahogany sulfonate, the alkaline dinonyl naphthalene sulfonate barium;
Solubility promoter is a Sodium Benzoate, SS, para-amino benzoic acid, urea, ethanamide, one or more in the ethanol;
Mould inhibitor is a copper 8-quinolinolate, phenol, copper sulfate, Woodtreat A, one or more in the Sodium Fluoride;
Skimmer is a silicone antifoam agent, one or more in polyethers and the polyether-modified silicon;
Oxidation inhibitor is sulphur phosphorus fourth octyl group zinc.
The preparation method of above-mentioned volatile rust preventive oil: at first in reaction kettle, base oil is heated to 80 ℃, insulation is being lower than the oil soluble vapour-phase inhibitor under 120 ℃ the condition then; Add solubility promoter, heating is dissolved, after the oil soluble vapour-phase inhibitor melts fully; Be added at leisure in the reaction kettle, the limit edged stirs, and then adds rust-preventive agent, mould inhibitor, skimmer and oxidation inhibitor successively again; Insulated and stirred is 2 hours in 90 ℃ reaction kettle, processes volatile rust preventive oil.
The invention has the beneficial effects as follows:
The present invention utilizes vapour-phase inhibitor to volatilize gas at normal temperatures automatically and forms protective membrane in the metallic surface, plays the effect that metallic corrosion is got rusty that suppresses.The present invention combines base oil and a kind of oil soluble vapour-phase inhibitor, processes a kind of volatile rust preventive oil because this slushing oil contains vapor phase inhibitor, thereby when rust-proof seal, oil sticking less than the position also owing to the effect of vapor phase inhibitor is protected; Do not contain toxic ingredient and easy formation ash compositions such as organic solvent, suet such as Sodium Nitrite in its component.Safety and environmental protection during use, the Working environment cleaning has been saved degreasing process, has saved labor force and material, has improved efficiency, has reduced cost.
Embodiment
Below in conjunction with embodiment, the present invention is further specified.
Embodiment 1
The 1# volatile rust preventive oil, form by following components by weight percent:
Product preparation method and step are following:
Be equipped with each component of raw material in proportion: 91 parts of 500SN base oils, 5 parts of benzotriazoles, chromic acid tert-butyl, naphthenic soap, the mixture of petroleum sodium sulfonate, 1 part of calcium mahogany sulfonate, 1 part of Sodium Benzoate, 0.5 part of silicone antifoam agent, 1 part of sulphur phosphorus fourth octyl group zinc, 0.5 part of phenol.
The mixture of benzotriazole, chromic acid tert-butyl, naphthenic soap, petroleum sodium sulfonate being lower than under 120 ℃ the condition, is added Sodium Benzoate, and heating is dissolved; After the mixture of benzotriazole, chromic acid tert-butyl, naphthenic soap, petroleum sodium sulfonate melts fully; Be added at leisure in the reaction kettle, the limit edged stirs, and then adds calcium mahogany sulfonate, phenol, silicone antifoam agent and sulphur phosphorus fourth octyl group zinc successively again; Insulated and stirred is 2 hours in 90 ℃ reaction kettle, processes volatile rust preventive oil.
Embodiment 2
The 2# volatile rust preventive oil, form by following components by weight percent:
Be equipped with each component of raw material according to the above ratio, the preparation method of product and step are with embodiment 1.
Embodiment 3
The 3# volatile rust preventive oil, form by following components by weight percent:
Be equipped with each component of raw material according to the above ratio, the preparation method of product and step are with embodiment 1.
Embodiment 4
The 4# volatile rust preventive oil, form by following components by weight percent:
Be equipped with each component of raw material according to the above ratio, the preparation method of product and step are with embodiment 1.
Embodiment 5
The 5# volatile rust preventive oil, form by following components by weight percent:
Be equipped with each component of raw material according to the above ratio, the preparation method of product and step are with embodiment 1.
Embodiment 6
The 6# volatile rust preventive oil, form by following components by weight percent:
Be equipped with each component of raw material according to the above ratio, the preparation method of product and step are with embodiment 1.
The performance test test:
Volatile rust preventive oil product performance test data among the embodiment of the invention 1-6 is following:
Volatile rust preventive oil main performance index and simultaneous test data are following:
Can know by above-mentioned performance test data and simultaneous test data; Volatile rust preventive oil each item performance of the present invention all reaches the requirement of slushing oil JB/T4050-1999 quality index; Compare with U.S. CORTEC VPCI-329 volatile rust preventive oil, through the corrosion experiment result: U.S. CORTEC VPCI-329 volatile rust preventive oil: steel 0.08 brass 0.06 aluminium 0.1; 5# oil among the present invention: steel 0.05 brass 0.03 aluminium 0.08, show that volatile rust preventive oil of the present invention has good volatile rust prevention corrosion resistance, make the metal that can't apply slushing oil also can obtain corrosion protection, and simple to operate, cost is low.
The application test example
Volatile rust preventive oil of the present invention; In the special gear box of the mover of Shanghai Diesel Engine Co., Ltd, compressor etc., use; From result of use; Oxidation easily that volatile rust preventive oil of the present invention can solve some equipment owing to do not reach slushing oil, the problem of getting rusty do not reach the position of slushing oil for those, can form effective corrosion protection.
Claims (5)
1. a volatile rust preventive oil is characterized in that, its component and each composition weight percentage composition are:
In the above-mentioned prescription:
Base oil is a kind of in 500SN, 46# machinery oil, 32# machinery oil, 600SN, 150# machinery oil, the 100# machinery oil;
The oil soluble vapour-phase inhibitor is wantonly four a kinds mixture in 2-ethylamino 17 alkenyl imidazolines, stearylamine, triazole Tributylamine, carbonic acid dicyclohexyl amine, hexylamine nitrous acid two rings, benzotriazole, chromic acid tert-butyl, naphthenic soap, petroleum sodium sulfonate, sorbitol monooleate, the Triple Pressed Stearic Acid;
Oxidation inhibitor is sulphur phosphorus fourth octyl group zinc.
2. volatile rust preventive oil as claimed in claim 1 is characterized in that, said rust-preventive agent is a kind of in calcium mahogany sulfonate, barium mahogany sulfonate, the alkaline dinonyl naphthalene sulfonate barium.
3. volatile rust preventive oil as claimed in claim 2 is characterized in that, said solubility promoter is one or more in Sodium Benzoate, SS, para-amino benzoic acid, urea, ethanamide, the ethanol.
4. volatile rust preventive oil as claimed in claim 3 is characterized in that, said mould inhibitor is a copper 8-quinolinolate, phenol, copper sulfate, Woodtreat A, one or more in the Sodium Fluoride.
5. volatile rust preventive oil as claimed in claim 4 is characterized in that, said skimmer is a silicone antifoam agent, one or more in polyethers and the polyether-modified silicon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102287384A CN102719302A (en) | 2012-07-03 | 2012-07-03 | Volatile rust preventive oil |
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|---|---|---|---|
| CN2012102287384A CN102719302A (en) | 2012-07-03 | 2012-07-03 | Volatile rust preventive oil |
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| CN102977717A (en) * | 2012-11-02 | 2013-03-20 | 铜陵市明诚铸造有限责任公司 | Metal antirust agent |
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| CN102993879A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Preparation method of metal rust inhibitor containing dimethyl silicon oil |
| CN103031191A (en) * | 2012-12-17 | 2013-04-10 | 铜陵市东方矿冶机械有限责任公司 | Tallow amine gaseous phase sustained-release anti-rust oil and preparation method thereof |
| CN103045329A (en) * | 2012-12-17 | 2013-04-17 | 铜陵市东方矿冶机械有限责任公司 | Urea gas phase slow-release anti-rust oil and preparation method thereof |
| CN103045331A (en) * | 2012-12-17 | 2013-04-17 | 铜陵市东方矿冶机械有限责任公司 | Modified attapulgite rustic phase slow-release rust preventive oil and preparation method thereof |
| CN103254786A (en) * | 2013-04-16 | 2013-08-21 | 马鞍山采石矶涂料有限公司 | Polyester anti-rust oil and preparation method thereof |
| CN103450974A (en) * | 2013-08-23 | 2013-12-18 | 吴江骏达电梯部件有限公司 | Gas-phase rust preventive oil and preparation method thereof |
| CN103468384A (en) * | 2013-08-24 | 2013-12-25 | 天长市康和金属材料有限公司 | Aqueous wire drawing lubricant |
| CN103525514A (en) * | 2013-07-18 | 2014-01-22 | 吴江骏达电梯部件有限公司 | Environment-friendly gas-phase rustproof oil and preparation method thereof |
| CN103980998A (en) * | 2014-04-17 | 2014-08-13 | 天长市润达金属防锈助剂有限公司 | Gas-phase rust preventive oil |
| CN103992852A (en) * | 2014-04-17 | 2014-08-20 | 天长市润达金属防锈助剂有限公司 | Volatile rust preventive oil |
| CN104194620A (en) * | 2014-09-10 | 2014-12-10 | 江苏欣安新材料技术有限公司 | Method for preparing VCI double-metal composite coating |
| CN104312668A (en) * | 2014-10-29 | 2015-01-28 | 合肥市华阳工程机械有限公司 | Long-acting rust-preventing oil |
| CN104371808A (en) * | 2014-10-29 | 2015-02-25 | 合肥市华阳工程机械有限公司 | Wear-resisting anti-rust oil |
| CN104388944A (en) * | 2014-12-03 | 2015-03-04 | 泰伦特生物工程股份有限公司 | Microencapsulated vapor phase rust inhibitor and preparation method thereof |
| CN104388148A (en) * | 2014-11-14 | 2015-03-04 | 无锡信大气象传感网科技有限公司 | Long-acting metal rust inhibitor for transformer and preparation method of long-acting metal rust inhibitor |
| CN104513988A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Environmentally-friendly gas phase antirust agent and preparation method thereof |
| CN104513989A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Aluminium alloy gas phase anti-rust agent and preparation method thereof |
| CN104513990A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Steel use gas phase antirusting agent and preparation method thereof |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104531290A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Phosphating anti-rust oil |
| CN104532252A (en) * | 2014-11-28 | 2015-04-22 | 安徽省宿州市龙华机械制造有限公司 | Fire retardant vapor phase rust inhibitor and preparation method thereof |
| CN104532253A (en) * | 2014-11-28 | 2015-04-22 | 安徽省宿州市龙华机械制造有限公司 | Vapor phase rust inhibitor containing tung oil, and preparation method thereof |
| CN104531317A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Phenol formaldehyde resin anti-rust oil |
| CN104531319A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Ship plate rolling machine anti-rust oil |
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| CN104531314A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Lubricating anti-rust oil |
| CN105297059A (en) * | 2015-11-09 | 2016-02-03 | 广东新球清洗科技股份有限公司 | Hydrocarbon cleaner resistant to metal surface oxidation and color change |
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| CN103992852A (en) * | 2014-04-17 | 2014-08-20 | 天长市润达金属防锈助剂有限公司 | Volatile rust preventive oil |
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| CN104371808A (en) * | 2014-10-29 | 2015-02-25 | 合肥市华阳工程机械有限公司 | Wear-resisting anti-rust oil |
| CN104312668A (en) * | 2014-10-29 | 2015-01-28 | 合肥市华阳工程机械有限公司 | Long-acting rust-preventing oil |
| CN104388148A (en) * | 2014-11-14 | 2015-03-04 | 无锡信大气象传感网科技有限公司 | Long-acting metal rust inhibitor for transformer and preparation method of long-acting metal rust inhibitor |
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| CN104513989A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Aluminium alloy gas phase anti-rust agent and preparation method thereof |
| CN104532252A (en) * | 2014-11-28 | 2015-04-22 | 安徽省宿州市龙华机械制造有限公司 | Fire retardant vapor phase rust inhibitor and preparation method thereof |
| CN104513990A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Steel use gas phase antirusting agent and preparation method thereof |
| CN104513988A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Environmentally-friendly gas phase antirust agent and preparation method thereof |
| CN104532251A (en) * | 2014-11-28 | 2015-04-22 | 安徽省宿州市龙华机械制造有限公司 | Antistatic vapor phase rust inhibitor and preparation method thereof |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104388944B (en) * | 2014-12-03 | 2017-06-13 | 泰伦特生物工程股份有限公司 | A kind of microencapsulation vapor phase inhibitor and preparation method thereof |
| CN104388944A (en) * | 2014-12-03 | 2015-03-04 | 泰伦特生物工程股份有限公司 | Microencapsulated vapor phase rust inhibitor and preparation method thereof |
| CN104531314A (en) * | 2014-12-09 | 2015-04-22 | 安徽荣达阀门有限公司 | Lubricating anti-rust oil |
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Application publication date: 20121010 |