CN103450974A - Gas-phase rust preventive oil and preparation method thereof - Google Patents

Gas-phase rust preventive oil and preparation method thereof Download PDF

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Publication number
CN103450974A
CN103450974A CN2013103707274A CN201310370727A CN103450974A CN 103450974 A CN103450974 A CN 103450974A CN 2013103707274 A CN2013103707274 A CN 2013103707274A CN 201310370727 A CN201310370727 A CN 201310370727A CN 103450974 A CN103450974 A CN 103450974A
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parts
rust preventive
oil
preventive oil
sodium
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CN103450974B (en
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平利中
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Wujiang Zhenyu Sewing Equipment Co Ltd
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Wujiang Junda Elevator Parts Co Ltd
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Abstract

The invention provides a gas-phase rust preventive oil. The gas-phase rust preventive oil comprises the following ingredients in parts by weight: 50-80 parts of #32 engine oil, 5-10 parts of octadecyl amine, 3-5 parts of petroleum sodium sulfonate, 1-4 parts of petroleum barium sulfonate, 2-5 parts of sodium benzoate, 3-6 parts of polyvinyl alcohol, 1-3 parts of zinc butyloctyl dithiophosphate, 2-6 parts of polyether, 1-5 parts of sorbitan monooleate, 2-4 parts of tripropylamine octanoate, 1-6 parts of dodecyl alcohol and 2-5 parts of amino-modified silicone oil. The rust preventive oil provided by the invention contains a gas-phase rust preventive. In the process of rust prevention, the part free from oil is protected under the action of the gas-phase rust preventive; the rust preventive oil does not contain toxic ingredients, such as sodium nitrite, thereby being safe and environmentally friendly in use.

Description

Volatile rust preventive oil and preparation method thereof
Technical field
The invention belongs to the metal rust preventing technical field, be specifically related to a kind of volatile rust preventive oil and preparation method thereof.
Background technology
Corrosion is one of principal mode that metal products is destroyed, and for fear of corrosion, reduce the loss, people have adopted various methods, and protecting metal products with rust-preventive agent is one of current modal means of defence.Rust-preventive agent is in the petroleum-type basal component, to add one or more rust-inhibiting additives and supplementary additive thereof to form, and it is easy to use, with low cost, effective, simple to operate, and metal current goods industry is all in a large amount of uses.But effective droplet that existing vapor phase inhibitor ejects is larger, can not be completely covered in the technical face of using back part, nor can arrive some complex structures, the finedraw place of part or the subassembly of tiny hole is arranged, make result of use not good; Because the diameter of droplet is larger, the inwall metallic walls that rides over more antirust airtight small spaces is, droplet can not effectively suspend, even if suspension time is also shorter, so corrosion mitigating effect is not good, current aerosol rust-preventive agent affects the work-ing life of parts, so mostly can not meet the demand of manufacturers fully.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art and a kind of volatile rust preventive oil is provided, can effectively improve the metal parts corrosion mitigating effect.
A kind of volatile rust preventive oil comprises in components by weight percent: 50~80 parts, No. 32 machine oil, 5~10 parts of stearylamines, 3~5 parts of petroleum sodium sulfonates, 1~4 part of barium mahogany sulfonate, 2~5 parts of Sodium Benzoates, 3~6 parts of polyvinyl alcohol, 1~3 part, sulphur phosphorus fourth octyl group zinc, 2~6 parts of polyethers, 1~5 part of sorbitol monooleate, 2~4 parts of sad Tributylamines, 1~6 part of lauryl alcohol, 2~5 parts of amido silicon oils.
Above-mentioned volatile rust preventive oil comprises in components by weight percent: 65 parts, No. 32 machine oil, 8 parts of stearylamines, 4 parts of petroleum sodium sulfonates, 3 parts of barium mahogany sulfonates, 3 parts of Sodium Benzoates, 5 parts of polyvinyl alcohol, 2 parts, sulphur phosphorus fourth octyl group zinc, 4 parts of polyethers, 3 parts of sorbitol monooleates, 3 parts of sad Tributylamines, 4 parts of lauryl alcohols, 3 parts of amido silicon oils.
The preparation method of above-mentioned volatile rust preventive oil is, No. 32 machine oil are added in reactor, be heated to 80~90 ℃ of insulations, then by stearylamine, petroleum sodium sulfonate, barium mahogany sulfonate, Sodium Benzoate, polyvinyl alcohol, sulphur phosphorus fourth octyl group zinc, polyethers, sorbitol monooleate, sad Tributylamine, lauryl alcohol, amido silicon oil, slowly add in reactor, the limit edged stirs, after adding in reactor 80~90 ℃ of insulated and stirred, make volatile rust preventive oil.
The present invention compared with prior art its remarkable advantage is: contain vapor phase inhibitor in slushing oil of the present invention, in antirust process, oil sticky less than position due to the effect of vapor phase inhibitor, be protected; Do not contain the toxic ingredients such as Sodium Nitrite, safety and environmental protection during use.
Embodiment
Embodiment 1
A kind of volatile rust preventive oil comprises in components by weight percent: 50 parts, No. 32 machine oil, 5 parts of stearylamines, 3 parts of petroleum sodium sulfonates, 1 part of barium mahogany sulfonate, 2 parts of Sodium Benzoates, 3 parts of polyvinyl alcohol, 1 part, sulphur phosphorus fourth octyl group zinc, 2 parts of polyethers, 1 part of sorbitol monooleate, 2 parts of sad Tributylamines, 1 part of lauryl alcohol, 2 parts of amido silicon oils.
No. 32 machine oil are added in reactor, be heated to 80~90 ℃ of insulations, then by stearylamine, petroleum sodium sulfonate, barium mahogany sulfonate, Sodium Benzoate, polyvinyl alcohol, sulphur phosphorus fourth octyl group zinc, polyethers, sorbitol monooleate, sad Tributylamine, lauryl alcohol, amido silicon oil, slowly add in reactor, the limit edged stirs, after adding in reactor 90 ℃ of insulated and stirred 2h, make volatile rust preventive oil.
Embodiment 2
A kind of volatile rust preventive oil comprises in components by weight percent: 65 parts, No. 32 machine oil, 8 parts of stearylamines, 4 parts of petroleum sodium sulfonates, 3 parts of barium mahogany sulfonates, 3 parts of Sodium Benzoates, 5 parts of polyvinyl alcohol, 2 parts, sulphur phosphorus fourth octyl group zinc, 4 parts of polyethers, 3 parts of sorbitol monooleates, 3 parts of sad Tributylamines, 4 parts of lauryl alcohols, 3 parts of amido silicon oils.
No. 32 machine oil are added in reactor, be heated to 80~90 ℃ of insulations, then by stearylamine, petroleum sodium sulfonate, barium mahogany sulfonate, Sodium Benzoate, polyvinyl alcohol, sulphur phosphorus fourth octyl group zinc, polyethers, sorbitol monooleate, sad Tributylamine, lauryl alcohol, amido silicon oil, slowly add in reactor, the limit edged stirs, after adding in reactor 80 ℃ of insulated and stirred 2h, make volatile rust preventive oil.
Embodiment 3
A kind of volatile rust preventive oil comprises in components by weight percent: 80 parts, No. 32 machine oil, 10 parts of stearylamines, 5 parts of petroleum sodium sulfonates, 4 parts of barium mahogany sulfonates, 5 parts of Sodium Benzoates, 6 parts of polyvinyl alcohol, 3 parts, sulphur phosphorus fourth octyl group zinc, 6 parts of polyethers, 5 parts of sorbitol monooleates, 4 parts of sad Tributylamines, 6 parts of lauryl alcohols, 5 parts of amido silicon oils.
No. 32 machine oil are added in reactor, be heated to 80~90 ℃ of insulations, then by stearylamine, petroleum sodium sulfonate, barium mahogany sulfonate, Sodium Benzoate, polyvinyl alcohol, sulphur phosphorus fourth octyl group zinc, polyethers, sorbitol monooleate, sad Tributylamine, lauryl alcohol, amido silicon oil, slowly add in reactor, the limit edged stirs, after adding in reactor 85 ℃ of insulated and stirred 2h, make volatile rust preventive oil.
Embodiment 1 to 3 gained volatile rust preventive oil the performance test results is as follows:
Figure BDA0000370907230000031

Claims (3)

1. a volatile rust preventive oil, is characterized in that, in components by weight percent, comprises: 50~80 parts, No. 32 machine oil, 5~10 parts of stearylamines, 3~5 parts of petroleum sodium sulfonates, 1~4 part of barium mahogany sulfonate, 2~5 parts of Sodium Benzoates, 3~6 parts of polyvinyl alcohol, 1~3 part, sulphur phosphorus fourth octyl group zinc, 2~6 parts of polyethers, 1~5 part of sorbitol monooleate, 2~4 parts of sad Tributylamines, 1~6 part of lauryl alcohol, 2~5 parts of amido silicon oils.
2. volatile rust preventive oil according to claim 1, is characterized in that, in components by weight percent, comprises: 65 parts, No. 32 machine oil, 8 parts of stearylamines, 4 parts of petroleum sodium sulfonates, 3 parts of barium mahogany sulfonates, 3 parts of Sodium Benzoates, 5 parts of polyvinyl alcohol, 2 parts, sulphur phosphorus fourth octyl group zinc, 4 parts of polyethers, 3 parts of sorbitol monooleates, 3 parts of sad Tributylamines, 4 parts of lauryl alcohols, 3 parts of amido silicon oils.
3. the preparation method of claim 1 or 2 described volatile rust preventive oil, it is characterized in that: No. 32 machine oil are added in reactor, be heated to 80~90 ℃ of insulations, then by stearylamine, petroleum sodium sulfonate, barium mahogany sulfonate, Sodium Benzoate, polyvinyl alcohol, sulphur phosphorus fourth octyl group zinc, polyethers, sorbitol monooleate, sad Tributylamine, lauryl alcohol, amido silicon oil, slowly add in reactor, the limit edged stirs, after adding in reactor 80~90 ℃ of insulated and stirred, make volatile rust preventive oil.
CN201310370727.4A 2013-08-23 2013-08-23 Gas-phase rust preventive oil and preparation method thereof Expired - Fee Related CN103450974B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103992852A (en) * 2014-04-17 2014-08-20 天长市润达金属防锈助剂有限公司 Volatile rust preventive oil
CN104312671A (en) * 2014-10-29 2015-01-28 合肥市华阳工程机械有限公司 Thin-layer high-permeability rust-preventive oil
CN104312668A (en) * 2014-10-29 2015-01-28 合肥市华阳工程机械有限公司 Long-acting rust-preventing oil
CN105647258A (en) * 2016-04-06 2016-06-08 温州任和教育科技有限责任公司 Wear-resisting and antirust paint with good adhesion and preparation method of paint
WO2018000433A1 (en) * 2016-07-01 2018-01-04 深圳市恒兆智科技有限公司 Anti-rust agent, metal workpiece and anti-rust treatment method
CN111892975A (en) * 2020-07-21 2020-11-06 南京正明观新材料有限公司 Novel anti-rust oil and preparation method thereof
CN112760652A (en) * 2020-12-25 2021-05-07 武汉百洁科技有限公司 Fluorine-free antirust agent for parts of refrigerator compressor and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030069146A1 (en) * 2001-07-13 2003-04-10 Renewable Lubricants, Inc. Biodegradable penetrating lubricant
CN102719302A (en) * 2012-07-03 2012-10-10 上海福岛化工科技发展有限公司 Volatile rust preventive oil
CN103232883A (en) * 2013-04-24 2013-08-07 浙江绿岛科技有限公司 Gas-phase rust-preventing aerosol and preparation process thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030069146A1 (en) * 2001-07-13 2003-04-10 Renewable Lubricants, Inc. Biodegradable penetrating lubricant
CN102719302A (en) * 2012-07-03 2012-10-10 上海福岛化工科技发展有限公司 Volatile rust preventive oil
CN103232883A (en) * 2013-04-24 2013-08-07 浙江绿岛科技有限公司 Gas-phase rust-preventing aerosol and preparation process thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103992852A (en) * 2014-04-17 2014-08-20 天长市润达金属防锈助剂有限公司 Volatile rust preventive oil
CN104312671A (en) * 2014-10-29 2015-01-28 合肥市华阳工程机械有限公司 Thin-layer high-permeability rust-preventive oil
CN104312668A (en) * 2014-10-29 2015-01-28 合肥市华阳工程机械有限公司 Long-acting rust-preventing oil
CN105647258A (en) * 2016-04-06 2016-06-08 温州任和教育科技有限责任公司 Wear-resisting and antirust paint with good adhesion and preparation method of paint
WO2018000433A1 (en) * 2016-07-01 2018-01-04 深圳市恒兆智科技有限公司 Anti-rust agent, metal workpiece and anti-rust treatment method
CN111892975A (en) * 2020-07-21 2020-11-06 南京正明观新材料有限公司 Novel anti-rust oil and preparation method thereof
CN112760652A (en) * 2020-12-25 2021-05-07 武汉百洁科技有限公司 Fluorine-free antirust agent for parts of refrigerator compressor and preparation process thereof

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