CN108728205A - A kind of volatile rust preventive oil - Google Patents

A kind of volatile rust preventive oil Download PDF

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Publication number
CN108728205A
CN108728205A CN201810851385.0A CN201810851385A CN108728205A CN 108728205 A CN108728205 A CN 108728205A CN 201810851385 A CN201810851385 A CN 201810851385A CN 108728205 A CN108728205 A CN 108728205A
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parts
rust preventive
volatile rust
preventive oil
vapor phase
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CN108728205B (en
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李晓栓
赵凯利
郑威
聂晓霖
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Nanjing Ke Run Industrial Media Limited-Liability Co
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Nanjing Ke Run Industrial Media Limited-Liability Co
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M133/10Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms cycloaliphatic
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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/044Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • C10M2215/224Imidazoles
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/48Slushing oils

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a kind of volatile rust preventive oils, are blended by the component of following parts by weight:5~10 parts of antirust agent I, 3~5 parts of antirust agent II, 1~3 part of film forming agent, 3~10 parts of vapor phase inhibitors, 1~2 part of cosolvent, 0.5~1 part of antioxidant and 80~90 parts of base oils;Wherein, it is made by the vapor phase inhibitor is reacted by lauric acid, octylame and dicyclohexyl amine by heating.Volatile rust preventive oil of the present invention has contact antirust function and untouchable antirust function, has good rustless property to a variety of ferrous metal, but also can effectively reduce the smell of volatile rust preventive oil, improves comfort level when operating personnel use.

Description

A kind of volatile rust preventive oil
Technical field
The present invention relates to a kind of volatile rust preventive oils, belong to metal rust preventing technical field.
Background technology
Metal is easy to happen oxidation reaction in wet condition, causes metal surface that corrosion occurs, to influence made of metal The use of product and beauty.Therefore, antirust can all be carried out when the metal products such as mechanical equipment, weaponry and auto parts and components dispatch from the factory Processing.Prevent the method got rusty very much, industrial common method is to cover one layer of antirust agent, the road under entrance in metal surface Process or using preceding being cleaned.But for the equipment of large scale structure complexity, whole immersion in liquid preventives oil or antirust oil can not be made All surface is covered, or large-scale closed storage tank is only capable of the equipment for carrying out oil spout operation with aperture, traditional antirust oil can not solve The certainly above problem.Therefore birth volatile rust preventive oil has both contact antirust oil and non-contact antirust function.
Volatile rust preventive oil basic principle is that vapor phase inhibitor is added in antirust oil.Common vapor phase inhibitor is nitrous acid Dicyclohexyl amine, dicyclohexyl amine, cyclohexylamine, benzotriazole, fatty amines or morpholine class etc..Two rings are added in volatile rust preventive oil Other aminated compounds such as hexylamine can give out strong smell, although to can metal generate rust-proof effect, two hexamethylenes The aminated compounds such as amine are all irritant to the eyes and skin and respiratory tract of operating personnel, to generate harm to human body. Therefore a kind of exploitation of volatile rust preventive oil safe to use is necessary.
Invention content
Goal of the invention:To solve the problems of the prior art, the present invention provides a kind of volatile rust preventive oil, the volatile rust preventive oil Salt is reacted into dicyclohexyl amine, octylame using lauric acid, so as to reduce the smell of volatile rust preventive oil, and then it is anti-to reduce gas phase Irritation of the rust oil to human body.
The technical solution adopted in the present invention is:
A kind of volatile rust preventive oil is blended by the component of following parts by weight:5~10 parts of antirust agent I, 3~5 parts of antirusts Agent II, 1~3 part of film forming agent, 3~10 parts of vapor phase inhibitors, 1~2 part of cosolvent, 0.5~1 part of antioxidant and 80~90 parts of bases Plinth oil;Wherein, it is made by the vapor phase inhibitor is reacted by lauric acid, octylame and dicyclohexyl amine by heating.
Vapor phase inhibitor in volatile rust preventive oil of the present invention is made of lauric acid, dicyclohexyl amine and octylame, passes through lauric acid Salt is reacted into dicyclohexyl amine, octylame effectively reduces the smell of dicyclohexyl amine and octylame in volatile rust preventive oil.
Wherein, the antirust agent I is in dinonyl naphthalene sulfonate barium, petroleum sodium sulfonate, barium mahogany sulfonate or calcium mahogany sulfonate One or two.
Wherein, the antirust agent II is dodecenylsuccinic acid half ester, KORANTIN SH-octadecylamine salt or 2- amino second One or both of 17 alkenyl imidazoline of base.
Wherein, the film forming agent is one or both of oxidized paraffin wax, vaseline, refined paraffin wax or Petropols.
Wherein, the cosolvent is octyl phthalate or Span-80.
Wherein, the antioxidant is 2,6- di-tert-butyl-4-methy phenols.
Wherein, viscosity of the base oil at 40 DEG C is 8~11cSt.Low viscosity can realize smaller consumption.
Wherein, the vapor phase inhibitor is prepared with the following method:By the desired amount of lauric acid, octylame and two hexamethylenes Amine, which is placed in reaction kettle, is sufficiently stirred 30~50min;Uniformly mixed reaction mass is heated to 90 ± 10 DEG C of heat preservations, continues to stir Mix 30~50min;Heating is closed, a certain amount of base oil is added into reaction kettle, it is after mixing that obtained vapor phase inhibitor is cold But to room temperature.
Compared with prior art, beneficial effects of the present invention are:
Volatile rust preventive oil of the present invention has contact antirust function and untouchable antirust function, has to a variety of ferrous metal There is good rustless property, but also can effectively reduce the smell of volatile rust preventive oil, improves comfortable when operating personnel use Degree.
Cosolvent in inventive formulation can effectively improve the stability of integral formula, due to octylame and dicyclohexyl amine with Lauric acid reaction is easy to be precipitated from base oil at salt, at the substance after salt, therefore has added octyl phthalate in formula Or dissolubility of each substance in base oil can be effectively improved after Span-80, it effectively prevent substance to be precipitated from base oil, into And improve the stability of formula;Antirust agent 1, antirust agent II and vapor phase inhibitor collective effect realize that the lasting contact of product is anti- Rust and non-contact antirust.
Specific implementation mode
Technical solution of the present invention is further elaborated with reference to specific embodiment.
Embodiment 1
Volatile rust preventive oil of the present invention is prepared by the raw material components of following parts by weight:
80 parts of 10# white oils, 5 parts of dinonyl naphthalene sulfonate barium, 5 parts of barium mahogany sulfonate, 17 alkenyl imidazoline 3 of 2- amino-ethyls Part, 1 part of oxidized paraffin wax, 1 part of vaseline, 5 parts of vapor phase inhibitor, 1 part of Span-80 and 2,6- di-tert-butyl-4-methy phenols 1 part.
Wherein, vapor phase inhibitor is reacted by heating with octylame and dicyclohexyl amine for lauric acid and is made:
It takes 10 parts of lauric acid, 6 parts of octylames and 9 parts of dicyclohexyl amines to be placed in glass reaction kettle, stirs 40min, mixing speed For 150rpm;Then the temperature of glass reaction kettle is increased to 90 DEG C, continues to stir 40min;Heating is closed, 10# white oils are added 10 parts, it is cooled to room temperature stopping stirring, obtains vapor phase inhibitor.
The preparation of volatile rust preventive oil of the present invention:
80 parts of 10# white oils are added in a kettle, are heated to 80 DEG C, open stirring, are added 1 part 2 into reaction kettle successively, 6- di-tert-butyl-4-methy phenols, 5 parts of dinonyl naphthalene sulfonate bariums, 5 parts of barium mahogany sulfonates, 3 parts of 17 alkenyl miaows of 2- amino-ethyls Oxazoline, 1 part of oxidized paraffin wax, 1 part of vaseline, 1 part of Span-80 and 5 parts of vapor phase inhibitors close heating after stirring 60min, cooling To room temperature to get to volatile rust preventive oil.
Embodiment 2
Volatile rust preventive oil of the present invention is prepared by the raw material components of following parts by weight:
90 parts of 10# white oils, 5 parts of petroleum sodium sulfonate, 5 parts of calcium mahogany sulfonate, KORANTIN SH -5 parts of octadecylamine salt, oxidation 1 part of paraffin, 1 part of Petropols, 5 parts of vapor phase inhibitor, 2 parts of dioctyl phthalate and 2,6- di-t-butyl -4- methyl 0.5 part of phenol.
Wherein, vapor phase inhibitor is reacted by heating with octylame and dicyclohexyl amine for lauric acid and is made:
It takes 12 parts of lauric acid, 6 parts of octylames and 10 parts of dicyclohexyl amines to be placed in glass reaction kettle, stirs 50min, mixing speed For 150rpm;Then the temperature of glass reaction kettle is increased to 90 DEG C, continues to stir 40min;Heating is closed, 10# white oils 5 are added Part, it is cooled to room temperature stopping stirring, obtains vapor phase inhibitor.
The preparation of volatile rust preventive oil of the present invention:
90 parts of 10# white oils are added in a kettle, are heated to 80 DEG C, open stirring, are added 0.5 part into reaction kettle successively 2,6- di-tert-butyl-4-methy phenols, 5 parts of petroleum sodium sulfonates, 5 parts of calcium mahogany sulfonates, 5 parts of octadecylamine base-N- oleoyls musculamines acid, 1 part of oxidized paraffin wax, 1 part of Petropols, 2 parts of dioctyl phthalates and 5 parts of vapor phase inhibitors, stir 60min after close plus Heat is cooled to room temperature to get to volatile rust preventive oil.
Product testing
Volatile rust preventive oil of the present invention does not have penetrating odor, while still there is good lasting contact antirust to prevent with non-contact The effect of rust.
Product testing the result shows that, volatile rust preventive oil of the present invention has reached JB/T-4050.1 index requests.And pass through work Factory uses, it was demonstrated that and this product has good rustless property, can solve the place that equipment blind hole etc. does not reach antirust oil, and And there is no penetrating odor.
The present invention reacts into salt using octylame and dicyclohexyl amine with lauric acid, improves conventional gas phase antirust agent octylame and two The existing penetrating odor of cyclohexylamine, enhances the human comfort of volatile rust preventive oil;And after amine is at salt, pass through formula The coordinated of middle other components, ensure that the gaseous phase antirust function of vapor phase inhibitor, and have lasting volatile rust prevention work( Energy.The method can be widely used in the antirust of ferrous metal, including mechanical equipment and part be sealed or the length of weaponry Phase antirust.

Claims (9)

1. a kind of volatile rust preventive oil, it is characterised in that:It is blended by the component of following parts by weight:5~10 parts of antirust agent I, 3 ~5 parts of antirust agent II, 1~3 part of film forming agent, 3~10 parts of vapor phase inhibitors, 1~2 part of cosolvent, 0.5~1 part of antioxidant and 80~90 parts of base oils;Wherein, it is made by the vapor phase inhibitor is reacted by lauric acid, octylame and dicyclohexyl amine by heating.
2. volatile rust preventive oil according to claim 1, it is characterised in that:The antirust agent I is dinonyl naphthalene sulfonate barium, stone One or both of oily sodium sulfonate, barium mahogany sulfonate or calcium mahogany sulfonate.
3. volatile rust preventive oil according to claim 1, it is characterised in that:The antirust agent II is dodecenylsuccinic acid half One or both of 17 alkenyl imidazoline of ester, KORANTIN SH-octadecylamine salt or 2- amino-ethyls.
4. volatile rust preventive oil according to claim 1, it is characterised in that:The film forming agent is oxidized paraffin wax, vaseline, essence One or both of paraffin or Petropols processed.
5. volatile rust preventive oil according to claim 1, it is characterised in that:The cosolvent be octyl phthalate or this Disk -80.
6. volatile rust preventive oil according to claim 1, it is characterised in that:The antioxidant is 2,6- di-t-butyl -4- first Base phenol.
7. volatile rust preventive oil according to claim 1, it is characterised in that:Viscosity of the base oil at 40 DEG C be 8~ 11cSt。
8. volatile rust preventive oil according to claim 1, it is characterised in that:The vapor phase inhibitor by mass fraction be 9~ 12 parts of lauric acid, 5~7 parts of octylames and 8~10 parts of dicyclohexyl amines are made by reaction by heating.
9. volatile rust preventive oil according to claim 8, it is characterised in that:The vapor phase inhibitor is prepared with the following method It forms:The desired amount of lauric acid, octylame and dicyclohexyl amine are placed in reaction kettle and are sufficiently stirred 30~50min;It will be uniformly mixed Reaction mass be heated to 90 ± 10 DEG C heat preservation, continue 30~50min of stirring;Heating is closed, is added into reaction kettle a certain amount of Base oil, obtained vapor phase inhibitor is cooled to room temperature after mixing.
CN201810851385.0A 2018-07-27 2018-07-27 Gas-phase anti-rust oil Active CN108728205B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110184113A (en) * 2019-05-31 2019-08-30 上海正玺新材料科技有限公司 A kind of antirust oil used for magnesium alloy and preparation method thereof
CN110903885A (en) * 2019-09-04 2020-03-24 宿迁盾嘉生物科技有限公司 Track antirust oil and preparation method thereof
CN112266817A (en) * 2020-11-14 2021-01-26 马鞍山中集瑞江润滑油有限公司 Special anti-rust oil for ultra-low sound bearing
CN112457904A (en) * 2019-09-09 2021-03-09 东莞市英飞特润滑科技有限公司 Long-acting volatile anti-rust oil and preparation method thereof
CN114058429A (en) * 2021-10-22 2022-02-18 华润宝润滑科技(宁波)有限公司 Steel pipe antirust oil capable of improving drainage performance
EP4131690A4 (en) * 2020-03-31 2024-03-06 NHK Spring Co., Ltd. Balancer and balancer system

Citations (6)

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Denomination of invention: A kind of vapor phase antirust oil

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