CN107057812A - A kind of steel strand wires special anti-corrosion fat and preparation method thereof - Google Patents
A kind of steel strand wires special anti-corrosion fat and preparation method thereof Download PDFInfo
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- CN107057812A CN107057812A CN201710267862.4A CN201710267862A CN107057812A CN 107057812 A CN107057812 A CN 107057812A CN 201710267862 A CN201710267862 A CN 201710267862A CN 107057812 A CN107057812 A CN 107057812A
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Abstract
The present invention discloses a kind of steel strand wires special anti-corrosion fat, consisting of:12 5%~10%w of hydroxy stearic acid;Industrial 1%~3%w of stearic acid;3%~5%w of lithium hydroxide;0.5%~1%w of white lime;8%~13%w of water;70%~75%w of 650SN mineral oil;0.5%~1%w of viscosity index improver;0.5%~1%w of detersive;0.5%~1%w of antirust agent;0.5%~1%w of antioxidant.The invention also discloses the preparation method of above-mentioned lubricating oil; the preparation method of the anti-corrosion grease; the colloid stability that boric acid improves lubricating grease is mainly added in saponification process; and polymethacrylates is added in harmonic process enables filling oil firmly to wrap in soap fiber; the Stencil oil-dividing rate of anti-corrosion grease can be greatly improved; solve current steel strand wires anti-corrosion grease condensate oil serious, reach effective protection to steel strand wires.
Description
Technical field
The present invention relates to anti-corrosion material technical field, more particularly to a kind of the steel of steel strand wires can be effectively protected for a long time
Twisted wire special anti-corrosion fat and preparation method thereof.
Background technology
The application of steel strand wires in daily life is fairly common, but its corrosion is but always one troubling
Problem.What steel strand wires corroded wants harm to be not only in that the loss of itself, the loss caused by more seriously article construction is damaged
It is big to can not estimate.Metal surface is brushed or be attached to general anti-corrosion of metal material all simply, plays buffer action, is unable to undergo
Corollary failure year in year out, guard time is very short.
At present, what the formula and method that anti-corrosion grease is substantially according to lithium saponify or compositing lithio ester were produced, should
Product prepared by method, Stencil oil-dividing is substantially all within 10% or 5%, and Stencil oil-dividing rate is not reaching to very low water
It is flat.But this high-voltage conducting wires be easy to because electric current is excessive and it is very high to rise to temperature, in this case, according to current skill
Anti-corrosion grease condensate oil problem prepared by art is serious, and its result can cause protective effect of the anti-corrosion grease to wire drastically to decline, Jin Erying
The whole service life of wire is rung.
Stencil oil-dividing rate turns into the bottleneck problem that can steel strand wires effectively be protected.Accordingly, it would be desirable to be directed to this key technology
Problem is optimized comprehensively, it is ensured that high altitude wire can obtain prolonged effectively protection.
The content of the invention
For the weak point of the preparation method that overcomes existing steel strand wires anti-corrosion grease, anti-corrosion is directed to the invention provides one kind
Fat condensate oil is serious, steel strand wires are carried out with steel strand wires special anti-corrosion fat of permanently effective protection and preparation method thereof.
A kind of steel strand wires special anti-corrosion fat, consisting of:5%~10%w of 12- hydroxy stearic acids;Industrial stearic acid 1%~
3%w;3%~5%w of lithium hydroxide;0.5%~1%w of white lime;8%~13%w of water;70%~75%w of 650SN mineral oil;
0.5%~1%w of viscosity index improver;0.5%~1%w of detersive;0.5%~1%w of antirust agent;Antioxidant 0.5%~
1%w.
Further improved to be, described viscosity index improver can be polymethacrylates or ethylene propylene copolymer
Thing or polyisobutene.
Further improved to be, described detersive can be polyisobutene sulphur barium phosphate salt.
Further improved to be, described antirust agent can be barium mahogany sulfonate or petroleum sodium sulfonate or zinc naphthenate.
Further improved to be, described antioxidant can be diphenylamines or butylated hydroxy anisole or gallic acid third
Ester.
A kind of preparation method of steel strand wires special anti-corrosion fat, its step is as follows:
A. 650SN mineral oil is filled with the saponification kettle added with boric acid, and is warming up to 55~75 DEG C;
B. 12- hydroxy stearic acids are then added, industrial stearic acid, lithium hydroxide, white lime, water plays pressure, perseverance after having added
Pressure, release, then temperature is increased between 150~190 DEG C, adds 650SN 100~500L of mineral oil, it is continuously heating to 220~
248 DEG C carry out chilling mixing and are transferred in mediation kettle, carry out circulation shear;
C. polymethacrylates is added, polyisobutene sulphur barium phosphate salt, barium mahogany sulfonate, diphenylamines passes through adjustment
650SN mineral oil measure cone penetration be 220-295 anti-corrosion grease, after meeting the requirements, homogeneous, degassing.
The beneficial effects of the invention are as follows:The preparation method of this steel strand wires special anti-corrosion fat, is mainly added in saponification process
Boric acid improves the colloid stability of lubricating grease, and addition polymethacrylates enables filling oil firmly in harmonic process
Bag can greatly improve the Stencil oil-dividing rate of anti-corrosion grease in soap fiber, solve current steel strand wires anti-corrosion grease condensate oil seriously, reach
Effective protection to steel strand wires.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments, based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made,
Belong to the scope of protection of the invention.
Embodiment 1
A kind of steel strand wires special anti-corrosion fat, consisting of:5%~10%w of 12- hydroxy stearic acids;Industrial stearic acid 1%~
3%w;3%~5%w of lithium hydroxide;0.5%~1%w of white lime;8%~13%w of water;70%~75%w of 650SN mineral oil;
0.5%~1%w of viscosity index improver;0.5%~1%w of detersive;0.5%~1%w of antirust agent;Antioxidant 0.5%~
1%w.
Further improved to be, viscosity index improver can be polymethacrylates or ethylene propylene copolymer or poly-
Isobutene.
Further improved to be, detersive can be polyisobutene sulphur barium phosphate salt.
Further improved to be, antirust agent can be barium mahogany sulfonate or petroleum sodium sulfonate or zinc naphthenate.
Further improved to be, antioxidant can be diphenylamines or butylated hydroxy anisole or propylgallate.
A kind of preparation method of steel strand wires special anti-corrosion fat, its step is as follows:
A. 650SN mineral oil is filled with the saponification kettle added with boric acid, and is warming up to 55~75 DEG C;
B. 12- hydroxy stearic acids are then added, industrial stearic acid, lithium hydroxide, white lime, water plays pressure, perseverance after having added
Pressure, release, then temperature is increased between 150~190 DEG C, adds 650SN 100~500L of mineral oil, it is continuously heating to 220~
248 DEG C carry out chilling mixing and are transferred in mediation kettle, carry out circulation shear;
C. polymethacrylates is added, polyisobutene sulphur barium phosphate salt, barium mahogany sulfonate, diphenylamines passes through adjustment
650SN mineral oil measure cone penetration be 220-295 lubricating oil, after meeting the requirements, homogeneous, degassing.
Embodiment 2
A kind of steel strand wires special anti-corrosion fat, consisting of:12- hydroxy stearic acids 8%w, industrial stearic acid 2w, lithium hydroxide
4%w, white lime 0.5%w, water 10%w, polymethacrylates 0.5%w, polyisobutene sulphur barium phosphate salt 0.5%w, oil
Barium sulfonate 0.5%w, diphenylamines 0.5%w and 650SN73.5%w.
A kind of preparation method of steel strand wires special anti-corrosion fat, its step is as follows:650SN mineral oil is filled with saponification kettle, and
It is warming up to 65 DEG C;Then add 12- hydroxy stearic acids, industrial stearic acid, lithium hydroxide, white lime, water, add after rise press,
Constant pressure, release, then temperature are increased between 150~190 DEG C, are added 650SN 100~500L of mineral oil, are continuously heating to 220 and enter
Row chilling is mixed and is transferred in mediation kettle, carries out circulation shear;Addition polymethacrylates, polyisobutene sulphur barium phosphate salt,
Barium mahogany sulfonate, diphenylamines, by adjust 650SN mineral oil measure cone penetration be 220-295 anti-corrosion grease, meet the requirements
Afterwards, homogeneous, degassing.
The preparation method of this steel strand wires special anti-corrosion fat, mainly adds the glue that boric acid improves lubricating grease in saponification process
Body stability, and polymethacrylates is added in harmonic process enables filling oil firmly to wrap in soap fiber, Ke Yi great
Width improves the Stencil oil-dividing rate of anti-corrosion grease, solves current steel strand wires anti-corrosion grease condensate oil seriously, reaches effective protection to steel strand wires.
Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art,
It can still modify to the technical scheme described in foregoing embodiments, or which part technical characteristic is carried out etc.
With replacing, within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc. should be included in this
Within the protection domain of invention.
Claims (6)
1. a kind of steel strand wires special anti-corrosion fat, consisting of:5%~10%w of 12- hydroxy stearic acids;Industrial stearic acid 1%~
3%w;3%~5%w of lithium hydroxide;0.5%~1%w of white lime;8%~13%w of water;70%~75%w of 650SN mineral oil;
0.5%~1%w of viscosity index improver;0.5%~1%w of detersive;0.5%~1%w of antirust agent;Antioxidant 0.5%~
1%w.
2. a kind of steel strand wires special anti-corrosion fat according to claim 1, it is characterised in that:Described viscosity index improver
Can be polymethacrylates or ethylene propylene copolymer or polyisobutene.
3. a kind of steel strand wires special anti-corrosion fat according to claim 1, it is characterised in that:Described detersive can be poly-
Isobutene sulphur barium phosphate salt.
4. a kind of steel strand wires special anti-corrosion fat according to claim 1, it is characterised in that:Described antirust agent can be stone
Oily barium sulfonate or petroleum sodium sulfonate or zinc naphthenate.
5. a kind of steel strand wires special anti-corrosion fat according to claim 1, it is characterised in that:Described antioxidant can be two
Aniline or butylated hydroxy anisole or propylgallate.
6. a kind of preparation method of steel strand wires special anti-corrosion fat, its step is as follows:
A. 650SN mineral oil is filled with the saponification kettle added with boric acid, and is warming up to 55~75 DEG C;
B. and then add 12- hydroxy stearic acids, industrial stearic acid, lithium hydroxide, white lime, water, pressure after add, constant pressure,
Release, then temperature are increased between 150~190 DEG C, are added 650SN 100~500L of mineral oil, are continuously heating to 220~248 DEG C
Carry out chilling mixing and be transferred in mediation kettle, carry out circulation shear;
C. polymethacrylates, polyisobutene sulphur barium phosphate salt, barium mahogany sulfonate, diphenylamines, by adjusting 650SN are added
Mineral oil measure cone penetration be 220-295 anti-corrosion grease, after meeting the requirements, homogeneous, degassing.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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CN107794108A (en) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | A kind of round wires concentric gallows empty conductor conduction anti-corrosion grease and preparation method thereof |
CN108795546A (en) * | 2018-07-26 | 2018-11-13 | 郑州市欧普士科技有限公司 | A kind of degradable grass trimmer special grease and preparation method thereof |
CN110527581A (en) * | 2019-09-23 | 2019-12-03 | 上海鸿辉光通科技股份有限公司 | A kind of aerial condutor high-temperature anticorrosion rouge and preparation method thereof |
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CN107760427A (en) * | 2017-11-16 | 2018-03-06 | 郑州市欧普士科技有限公司 | A kind of extremely low point of oil cut rate aerial condutor anti-corrosion grease and preparation method thereof |
CN107794108A (en) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | A kind of round wires concentric gallows empty conductor conduction anti-corrosion grease and preparation method thereof |
CN108795546A (en) * | 2018-07-26 | 2018-11-13 | 郑州市欧普士科技有限公司 | A kind of degradable grass trimmer special grease and preparation method thereof |
CN110527581A (en) * | 2019-09-23 | 2019-12-03 | 上海鸿辉光通科技股份有限公司 | A kind of aerial condutor high-temperature anticorrosion rouge and preparation method thereof |
CN110527581B (en) * | 2019-09-23 | 2021-09-14 | 上海鸿辉光通科技股份有限公司 | High-temperature anti-corrosion grease for overhead conductor and preparation method thereof |
CN111269743A (en) * | 2020-03-17 | 2020-06-12 | 郑州市欧普士科技有限公司 | Wear-resistant high-temperature-resistant lubricating grease and preparation method and application thereof |
CN111269743B (en) * | 2020-03-17 | 2022-06-28 | 郑州市欧普士科技有限公司 | Wear-resistant high-temperature-resistant lubricating grease and preparation method and application thereof |
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Application publication date: 20170818 |