CN104781353B - 荧光体油墨组合物及其制备方法 - Google Patents
荧光体油墨组合物及其制备方法 Download PDFInfo
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- CN104781353B CN104781353B CN201380058703.3A CN201380058703A CN104781353B CN 104781353 B CN104781353 B CN 104781353B CN 201380058703 A CN201380058703 A CN 201380058703A CN 104781353 B CN104781353 B CN 104781353B
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Abstract
本发明涉及为了使用于光学材料上而空前改善了光损耗和雾度值的粘接性清漆(adhesive varnish)组合物及制备该组合物的方法。具体来讲,通过根据本发明的方法而制备的粘接性清漆,示出高透光率且以高粘度能够维持填充剂的稳定的分散,从而能够防止黄变现象。另外,根据本发明的粘接性清漆具有能够适用于硅薄膜、扩散片、反射片、反射器、发光二极管(LED)、发光二极管封装件(LED PACKAGE)、板上芯片(COB)等多个领域的优点。
Description
技术领域
本发明涉及含有荧光填充剂的粘接性清漆(adhesive varnish)组合物及其制备方法。
背景技术
为了得到多种形状的烧结体而在使用在粘合剂树脂中分散有导电性粉末、陶瓷粉末等的无机颗粒的无机颗粒糊剂组合物。尤其,在粘合剂树脂中分散有作为无机颗粒的荧光体的荧光体糊剂组合物使用于发光二极管(LED)或有机电致发光(有机EL)等,且最近对于荧光体糊剂组合物的需求在增加。
就上述荧光体糊剂组合物而言,通过丝网印刷、使用了刮刀等的涂布法、用于加工成片状的浇铸法等而加工成预定的形状之后,进行烧结就能够使用。
作为使用于荧光体糊剂组合物的粘合剂树脂,通常使用具有触变性的乙基纤维素等纤维素类树脂。然而,就纤维素类树脂中分散有荧光体的荧光体糊剂组合物而言,若不是在高温下进行烧结就不会被热分解。因此,存在导致在生产工艺中需要较多能量或烧结时间被拉长之类的问题。
针对这种问题,在研讨使用与纤维素类树脂相比能够在低温下脱脂的丙烯酸类树脂的方法。例如,日本公开专利公报平9-012979号中公开有使用了丙烯酸类树脂的荧光体糊剂组合物。然而,这种荧光体糊剂组合物由于丙烯酸类树脂所引起的粘接性非常强劲,因而难以处理。虽然调节丙烯酸类树脂的添加量即可降低粘接性,但由此荧光体糊剂组合物的粘度明显下降,因此,若使比重高的荧光体分散,则存在荧光体沉淀或凝聚的所谓储存稳定性下降的问题。
为此,通过提高丙烯酸类树脂的分子量,即可减少丙烯酸类树脂的添加量,且提高荧光体糊剂组合物的粘度,从而能够维持储存稳定性,但若提高丙烯酸类树脂的分子量,则存在剧烈产生丝线或丝网印刷起来困难之类的问题。
在日本公开专利公报2003-257314号中公开有为了提高荧光体的分散性而在荧光体糊剂组合物添加硬脂酸等具有1个以上羧基的化合物的方法。所公开的方法如下:添加具有1个以上羧基的化合物,使得羧基吸附于荧光体的表面而中和表面的电位或使氢键结合位钝化,并利用羧基以外的部分的立体效应而抑制凝聚,从而提高荧光体的分散性。然而,利用该方法则难以维持长期储存稳定性,且还存在荧光体沉淀或凝聚的情况。另外,粘度低的荧光体糊剂组合物存在粘度变化明显的问题。这样,实际状况是,需要确保荧光体的分散性而示出透光率和雾度特性,并且改善荧光体糊剂组合物的长期储存稳定性。
发明内容
技术问题
本发明其目的在于提供一种作为光学材料的、能够减少光损耗并提高透过率的粘接性清漆(adhesive varnish)及其制备方法。
具体来讲,本发明其目的在于提供一种空前提高了透光率并且能够使荧光填充剂稳定地分散的粘接性清漆。
另外,本发明其目的在于提供一种有用于光源涂层而示出优良的抗变色性和耐候性,且分散稳定性和长期储存稳定性优良的粘接性清漆。
本发明其目的在于提供一种适用于扩散片、反射片、LED、反射器等而具有高透光率和低雾度且能够使光效率极大化的粘接性清漆及其制备方法。
解决问题方案
旨在达到上述目的的本发明能够提供一种粘接性清漆组合物,该粘接性清漆组合物包含粘合剂树脂混合物、荧光填充剂、以及溶剂,其中,上述粘合剂树脂混合物含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂。
在本发明中,作为粘合剂树脂混合物,以同时使用上述聚酯类树脂、丙烯酸类树脂、以及纤维素类树脂的方式制成,竟而能够提高荧光填充剂的分散稳定性,并能够使长期储存稳定性极大化,在涂敷到涂膜上时,即便厚度厚也能够保持低雾度并提高透光率,从而能够空前提高光效率。这一点能够通过上述组成成分的组合来实现,若逸出上述组成成分的组合,则透光率和雾度特性下降且长期储存稳定性降低,从而由于荧光填充剂的沉淀、相分离、凝聚或粘度上升而有可能导致分散性下降。
根据本发明的一实施例的组合物能够包含粘合剂树脂混合物25~60重量%、荧光填充剂30~70重量%、以及溶剂5~20重量%。
在根据本发明的一实施例的组合物中,粘合剂树脂混合物能够包含聚酯类树脂5~40重量%、丙烯酸类树脂10~45重量%、纤维素类树脂5~30重量%、以及稀释剂5~20重量%。
在根据本发明的一实施例的组合物中,组合物的粘度可以是5,000~30,000cP。
在根据本发明的一实施例的组合物中,纤维素类树脂其重均分子量可以是30,000至40,000g/mol。
在根据本发明的一实施例的组合物中,纤维素类树脂可以是选自由醋酸纤维素(cellulose acetate)、丙酸纤维素(cellulose propionate)、丁酸纤维素(cellulosebutyrate)、醋酸丙酸纤维素(cellulose acetate propionate)、醋酸丁酸纤维素(cellulose acetate butyrate)、邻苯二甲酸乙酸纤维素(cellulose acetatephthalate)、以及邻苯二甲酸纤维素(cellulose phthalate)组成的组中的一种或两种以上的化合物。
在根据本发明的一实施例的组合物中,丙烯酸类树脂能够包含选自丙烯酸类多元醇、丙烯酸(acrylic acid)共聚物、改性丙烯酸共聚物、以及聚丙烯酸酯(poly acrylate)中的一种或两种以上的混合物。
根据本发明的一实施例的组合物能够进一步包含硅系化合物。
本发明能够提供一种粘接性清漆组合物的制备方法,该方法包括:(a)将含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂的粘合剂树脂混合物在80至180℃进行搅拌的粘合剂树脂混合物制备步骤;以及,(b)将荧光填充剂和溶剂放入在上述(a)步骤所制备的粘合剂树脂混合物中并在25至100℃的温度范围进行搅拌的荧光体油墨制备步骤。
在根据本发明的一实施例的粘接性清漆组合物的制备方法中,上述组合物能够包含粘合剂树脂混合物25~60重量%、荧光填充剂30~70重量%、以及溶剂5~20重量%。
在根据本发明的一实施例的粘接性清漆组合物的制备方法中,上述粘合剂树脂混合物能够包含聚酯类树脂5~40重量%、丙烯酸类树脂10~45重量%、纤维素类树脂5~30重量%、以及稀释剂5~20重量%。
在根据本发明的一实施例的粘接性清漆组合物的制备方法中,上述粘合剂树脂混合物的粘度可以是5,000~15,000cP。
在根据本发明的一实施例的粘接性清漆组合物的制备方法中,溶剂可以是选自二甲基环己胺(dimethylcyclohexylamine)、甲基乙基甲酮(methylethylketone)、环己酮(cyclohexanone)、丙二醇单甲醚(propyleneglycolmonomethylether)、乙二醇单丁醚醋酸酯(ethyleneglycolmonobutylether acetate)、二甲苯(xylene)、乙酸乙酯(ethylacetate)、一缩二丙二醇单甲醚(dipropyleneglycolmonomethylether)、乙酸正丁酯(n-butyl acetate)、丁基乙二醇(butylglycol)、以及它们的混合物中的任一种。
在根据本发明的一实施例的粘接性清漆组合物的制备方法中,在(b)步骤的搅拌可以采用选自通过快速搅拌的分散、通过辊研磨机(roll mill)的分散、以及通过分散剂的分散中的任一以上的方法。
本发明能够提供一种包含上述粘接性清漆组合物的发光元件或LED封装件。
发明效果
根据本发明的粘接性清漆空前减少光损耗,并且使透光率极大化,从而能够拓宽可商用并应用于光学材料的范围。另外,提高透光率而使发光效率极大化,并且有用于光源涂层以应对黄变且具有高粘度,因而具有能够稳定地分散填充剂且能够容易地适用于扩散片、反射片、LED、反射器等的好处。
具体实施方式
下面详细说明本发明。
本发明能够包含:粘合剂树脂混合物、荧光填充剂、以及溶剂,其中,上述粘合剂树脂混合物含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂。
上述组合物能够包含粘合剂树脂混合物25~60重量%、荧光填充剂30~70重量%、以及溶剂5~20重量%。
此时,上述粘合剂树脂混合物能够包含聚酯类树脂5~40重量%、丙烯酸类树脂10~45重量%、纤维素类树脂5~30重量%、以及稀释剂5~20重量%。
另外,在本发明中,上述组合物包含聚酯而提高与其它成分的反应性从而提高熔融性、相容性(Miscibility),且为了示出提高耐候性、光效率等物性效果能够进一步包含硅系化合物。
上述硅系化合物可以在末端或侧链具有两个以上的不饱和反应基团,优选地、能够使用末端部存在有机物质的有机化合物。例如,能够使用末端具有二甲基乙烯基的二甲基硅氧烷(dimethylsiloxane)、二甲基乙烯基化二氧化硅(dimethylvinylated silica)或三甲基化二氧化硅(trimethylated silica)、以甲基丙烯酰氧基丙基三甲氧基硅烷(methacryloxypropyltrimethoxysilane)进行了表面处理的二氧化硅(silica)等,但未必限定于此。
上述聚酯类树脂能够使用将多元酸和多元醇缩聚而制备的树脂。作为一例,上述多元酸能够使用:邻苯二甲酸酐、间苯二甲酸、对苯二甲酸等芳香族类饱和二元酸;马来酸酐、富马酸、衣康酸、柠康酸等不饱和二元酸;以及,偏苯三甲酸酐等三元酸等。另外,能够使用己二酸、壬二酸、癸二酸、四氢邻苯二甲酸酐、六氢邻苯二甲酸酐、四氯邻苯二甲酸酐等脂肪族类饱和二元酸以及上述多元酸衍生物。上述多元醇能够混合具有侧链的二醇或三元以上的多元醇(polyol)而使用。作为一例,具有侧链的二醇是新戊二醇(Neo-pentylglycol)、1,4-丁二醇(1,4-butanediol)、丙二醇(Propyleneglycol)等,作为三元以上的多元醇能够使用三羟甲基丙烷(Trimethyrolpropane)、季戊四醇(Pentaerythritol)、甘油(glycerin)等。
对于粘合剂树脂混合物总量,上述聚酯类树脂能够包含5~40重量%,优选包含5~30重量%。
上述聚酯类树脂其重均分子量可以是10,000至100,000,优选为20,000至50,000。另外,上述聚酯类树脂优选使用丙烯酸类改性聚酯。若处于上述范围,则与其它成分的相容性良好且容易调节粘度,并在形成涂膜时,平滑性、分散性、以及均匀性优良。
上述丙烯酸类树脂能够包含选自丙烯酸类多元醇、丙烯酸共聚物、改性丙烯酸共聚物、以及聚丙烯酸酯中的一种或两种以上的混合物。
作为一例,能够使用对选自丙烯酸(acrylic acid)、甲基丙烯酸(methacrylicacid)、乙基缩水甘油醚丙烯酸酯(ethylglycidylether acrylate)、乙基缩水甘油醚甲基丙烯酸酯(ethylglycidylether methacrylate)、丙基缩水甘油醚丙烯酸酯(propylglycidylether acrylate)、丙基缩水甘油醚甲基丙烯酸酯(propylglycidylethermethacrylate)、丁基缩水甘油醚甲基丙烯酸酯(butylglycidylether methacrylate)等碳原子数为2~8的烷基缩水甘油醚丙烯酸酯(alkylglycidylether acrylate);苯并咪唑(Benzimidazole)、甲基丙烯酸甲酯(methyl methacrylate)、甲基醇丙烯酸酯(methylalcohol acrylate)、甲基丙烯酸缩水甘油酯(glycidyl methacrylate)、苯基缩水甘油醚丙烯酸酯(phenylglycidylether acrylate)、苯基缩水甘油醚甲基丙烯酸酯(phenylglycidylether methacrylate);以及,三环癸基甲基丙烯酸酯(Tricyclodecylmethacrylate)、苯基丙烯酸酯(phenyl acrylate)、苯基甲基丙烯酸酯(phenylmethacrylate)、苄基丙烯酸酯(benzyl acrylate)、苄基甲基丙烯酸酯(benzylmethacrylate)、2或4-甲氧基苯基丙烯酸酯(2or 4-methoxyphenyl acrylate)、2或4-甲氧基苯基甲基丙烯酸酯(2or 4-methoxyphenyl methacrylate)、2或4-甲氧基苄基丙烯酸酯(2or 4-methoxybenzyl acrylate)、2或4-甲氧基苄基甲基丙烯酸酯(2or 4-methoxybenzyl methacrylate)、2或4-乙氧基苯基丙烯酸酯(2or 4-ethoxyphenylacrylate)、2或4-乙氧基苯基甲基丙烯酸酯(2or4-ethoxyphenyl methacrylate)、2或4-乙氧基苄基丙烯酸酯(2or 4-ethoxybenzyl acrylate)、2或4-乙氧基苄基甲基丙烯酸酯(2or4-ethoxybenzyl methacrylate)、2或4-氯苯基丙烯酸酯(2or 4-chlorophenylacrylate)、2或4-氯苯基甲基丙烯酸酯(2or 4-chlorophenyl methacrylate)、2或4-氯苄基丙烯酸酯(2or4-chlorobenzyl acrylate)、2或4-氯苄基甲基丙烯酸酯(2or 4-chlorobenzyl methacrylate)、2或4-溴苯基丙烯酸酯(2or 4-bromophenyl acrylate)、2或4-溴苯基甲基丙烯酸酯(2or 4-bromophenyl methacrylate)、2或4-溴苄基丙烯酸酯(2or 4-bromobenzyl acrylate)、以及2或4-溴苄基甲基丙烯酸酯(2or4-bromobenzylmethacrylate)中的单体添加引发剂并利用通常的方法进行聚合而制备的丙烯酸类树脂。
上述丙烯酸类树脂能够优选使用丙烯酸类多元醇树脂。为了使光学特性极大化而能够使用上述丙烯酸类多元醇树脂。该丙烯酸类多元醇树脂能够使用利用引发剂对于单乙烯基单体和二乙烯基单体的混合物进行了聚合的丙烯酸类共聚物,更优选地、非挥发性组分的含量为40~70重量%,加德纳气泡粘度为N~Z5,酸值为0~10,色相为0~3。此时,能够使用二乙烯基甲基丙烯酸酯单体而作为上述二乙烯基单体。在与具有丁酸酯基(butyrategroup)和丙酸酯基(propionate group)的纤维素类树脂混合时,优选使用烃类化合物的个数多的长链的二乙烯基(甲基)丙烯酸酯。
对于粘合剂树脂混合物总量,上述丙烯酸类树脂能够包含10~45重量%,优选包含10~40重量%。
上述非挥发性组分的含量,若低于40重量%则导致挥发溶剂含量增加且涂膜形成时间拉长而有可能光泽和触感下降,若超过70重量%则以高粘度进行合成或有可能降低与纤维素类树脂的相容性。另外,上述加德纳气泡粘度,若低于N则有可能粘性和分子量降低,若超过Z5则由于高粘度而需要追加稀释溶剂,由此导致有机挥发溶剂增加。
另外,从物理特性和耐化学性特性角度来讲,上述丙烯酸类多元醇树脂其羟基含量对于树脂组合物中非挥发性组分优选为1~3重量%,且分子量分布系数为1.0~6.0。
上述纤维素类树脂可以是纤维素酯、烷基纤维素或硝化纤维素,优选地、能够使用选自由醋酸纤维素、丙酸纤维素、丁酸纤维素、醋酸丙酸纤维素、醋酸丁酸纤维素、邻苯二甲酸乙酸纤维素、以及邻苯二甲酸纤维素组成的组中的一种或两种以上的纤维素酯。
上述纤维素类树脂使用重均分子量(Mw)为30,000至40,000的树脂,从相容性、组合物的分散稳定性、以及抑制黄变角度来讲,最好对于丙烯酸类树脂以1:1.5至1:5的混合重量比来混合上述纤维素类树脂。
上述稀释剂能够使用选自二甲基环己胺、甲基乙基甲酮、环己酮、丙二醇单甲醚、乙二醇单丁醚醋酸酯、二甲苯、乙酸乙酯、一缩二丙二醇单甲醚、乙酸正丁酯、丁基乙二醇、以及它们的混合物中的溶剂。
上述荧光填充剂能够使用通常的荧光体。例如,能够使用烟台希尔德新材料有限公司(YANTAI SHIELD ADVANCED MATERIALS)的产品型号为SDY555-7、R625等的荧光体,但并不限定于此。
在本发明中,粘接性清漆组合物其粘度可以是5,000~30,000cP。满足上述粘度范围的组合物因荧光填充剂的稳定的分散而能够减少光损耗并使透光率极大化。
本发明能够提供一种粘接性清漆组合物的制备方法,该方法包括:
(a)将含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂的粘合剂树脂混合物在80至180℃进行搅拌的粘合剂树脂混合物制备步骤;以及,
(b)将荧光填充剂和溶剂放入在上述(a)步骤所制备的粘合剂树脂混合物中并在25至100℃的温度范围进行搅拌的荧光体油墨制备步骤。
在上述(a)步骤,粘合剂树脂混合物能够使用前面所述的粘合剂树脂混合物,这样一来,利用稀释剂而调节粘度,使得组合物内的流动性增大,从而能够提高各组成成分的相容性,并且提高分散稳定性。
此时,上述粘度调节工艺最好在25℃至100℃的温度范围实施以使相容性良好。另外,上述粘度优选调节成5,000至15,000cP。
上述溶剂能够使用选自二甲基环己胺、甲基乙基甲酮、环己酮、丙二醇单甲醚、乙二醇单丁醚醋酸酯、二甲苯、乙酸乙酯、一缩二丙二醇单甲醚、乙酸正丁酯、丁基乙二醇、以及它们的混合物中的任一种,但并不限定于此。
上述粘度得到调节的粘合剂树脂混合物在放入荧光填充剂之后,利用选自通过快速搅拌的分散、通过辊研磨机的分散、以及通过分散剂的分散中的任一以上的方法来实施搅拌,最好实施通过使用了均化器(homogenizer)等的快速搅拌的分散或并行通过辊研磨机的分散。此时,搅拌速度优选为500至2,000rpm以能够防止荧光体的碳化。此后,包括静置上述所搅拌的混合物的步骤以使其稳定化。
上述混合有荧光填充剂的粘接组合物的粘度最好为5,000至30,000cps。
根据本发明的粘接性清漆组合物由于具有优良的透光率和填充剂的分散稳定性的优点,因而能够容易地适用于扩散片、反射片、LED、反射器等。
作为一种实施方式,利用丝网印刷法在钢化玻璃、金属、聚碳酸酯(PC)、聚甲基丙烯酸甲酯(PMMA)、聚对苯二甲酸乙二醇酯(PET)材料等的基板上涂布根据本发明的粘接性清漆组合物之后,附着具备电极的多个LED芯片而提供形成有荧光层的LED封装件,从而不仅能够使透光率极大化,而且防止黄变现象,因而具有能够增进长期使用寿命特性和耐久性的好处。
本发明能够提供包含上述粘接性清漆组合物的发光元件。
本发明能够提供包含上述粘接性清漆组合物的LED封装件。
本发明能够提供包含上述粘接性清漆组合物的蓝色激光二极管。
本发明能够提供包含上述粘接性清漆组合物的板上芯片(chip on board,COB)。
下面基于实施例而具体说明本发明。
实施例1
将混合了丙烯酸类改性聚酯(韩国NOKWON C&I公司产品,产品型号为PKI HF,重均分子量为35,000g/mol)25重量%、丙烯酸类多元醇(acrylic polyol)(韩国爱敬化学公司产品,产品型号为A-811)35重量%、纤维素树脂(美国伊士曼化工有限公司(EASTMAN)产品,产品型号为CBA-381-20)25重量%、以及丙二醇单甲醚15重量%的粘合剂树脂混合物在50℃搅拌了10分钟之后,每分钟升温2℃而在120℃以1000rpm搅拌了6个小时。搅拌完毕,将混合了上述粘合剂树脂混合物为60重量%、丙二醇单甲醚15重量%、以及荧光填充剂(烟台希尔德新材料有限公司(YANTAI SHIELD ADVANCED MATERIALS)产品,产品型号为R625)30重量%的混合物在包括了3/4比率的叶轮的反应器中在50℃以800rpm搅拌了1个小时。此后,利用三辊研磨机(3-ROLL-MILL)进行搅拌而制备了粘接性清漆组合物。所制备的组合物的粘度示出为6,560cP(美国博力飞(brookfield)旋转粘度计(产品型号:DV II pro+),主轴号(spindleNo.)为64,转速为50rpm,温度为25℃)。
实施例2
除了对于组合物总量使用了上述粘合剂树脂混合物50重量%、荧光体40重量%、以及丙二醇单甲醚10重量%以外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为6,563cP。
实施例3
除了对于组合物总量使用了上述粘合剂树脂混合物40重量%、荧光体50重量%、以及丙二醇单甲醚10重量%以外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为6,575cP。
实施例4
除了对于组合物总量使用了上述粘合剂树脂混合物30重量%、荧光体60重量%、以及丙二醇单甲醚10重量%以外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为7,498cP。
实施例5
除了对于组合物总量使用了上述粘合剂树脂混合物20重量%、荧光体60重量%、以及丙二醇单甲醚20重量%以外,实施了与实施例1相同的方法。组合物的粘度示出为1,920cP。
比较例1
未使用丙烯酸类改性聚酯和丙烯酸类多元醇,而是使用纤维素树脂80重量%和丙二醇单甲醚20重量%而用作粘合剂树脂混合物,除此之外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为2,478cP。
比较例2
未使用丙烯酸类多元醇,而是使用丙烯酸类改性聚酯10重量%、纤维素树脂80重量%、以及丙二醇单甲醚10重量%而用作粘合剂树脂混合物,除此之外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为9,530cP。
比较例3
未使用丙烯酸类改性聚酯,而是使用丙烯酸类多元醇10重量%、纤维素树脂80重量%、以及丙二醇单甲醚10重量%而用作粘合剂树脂混合物,除此之外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为5,520cP。
比较例4
在制备粘合剂树脂混合物时,将温度范围调节为50℃,除此之外,实施与实施例1相同的方法而制备了粘接性清漆组合物。所制备的组合物的粘度示出为1,110cP。
评价
在聚甲基丙烯酸甲酯(PMMA,poly(methyl methacrylate))材料的塑料试样上丝网印刷(Silk screen print)实施例或比较例的粘接性清漆组合物并在60℃干燥30分钟而得到了涂膜。对于包含上述涂膜的试样,利用分光光度计(SpectroPhotometer,产品型号为CM-3700d)并按照JIS(日本工业标准)K7105方法测定了雾度值(Haze Value)和透光率,并利用低真空扫描电子显微镜(Low Vacuum Scanning Electron Microscope,产品型号为Quanta 400)测定了涂膜厚度。
关于长期储存稳定性,将上述粘接性清漆组合物在23℃下保管了30天之后,肉眼确认了有否溶液的相分离、荧光填充剂的沉淀,并按照下述基准进行了评价。
O:未确认出溶液的相分离、荧光填充剂的沉淀等。
X:组合物相分离,从而观察到荧光填充剂的沉淀或颗粒层,且上清液的粘度下降。
表1
测定了对于上述涂膜的透光率和雾度值的结果,与比较例的涂膜相比,根据本发明的实施例的涂膜示出透光率高且雾度值低,从而能够确认出光损耗少且能够提高光效率。
如上所述,在本发明中,虽然通过限定的实施例来进行了说明,但这只是为了有助于更为全盘地理解本发明而提供的,本发明并不限定于上述的实施例,本领域普通技术人员根据这些描述能够进行多种修改和变形。
因此,可谓本发明的思想不得由所说明的实施例而定,不仅是所付的权利要求,而且与该权利要求等同或等价的变形均属于本发明思想的范畴。
Claims (13)
1.一种粘接性清漆组合物,其包含粘合剂树脂混合物、荧光填充剂、以及溶剂,其中,上述粘合剂树脂混合物含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂;
上述组合物包含粘合剂树脂混合物25~60重量%、荧光填充剂30~70重量%、以及溶剂5~20重量%;
上述粘合剂树脂混合物包含聚酯类树脂5~40重量%、丙烯酸类树脂10~45重量%、纤维素类树脂5~30重量%、以及稀释剂5~20重量%;
所述溶剂是选自二甲基环己胺、甲基乙基甲酮、环己酮、丙二醇单甲醚、乙二醇单丁醚醋酸酯、二甲苯、乙酸乙酯、一缩二丙二醇单甲醚、乙酸正丁酯、丁基乙二醇、以及它们的混合物中的任一种溶剂;
所述粘接性清漆组合物是通过如下方法制备的:
(a)将粘合剂树脂混合物在80至180℃进行搅拌的粘合剂树脂混合物制备步骤;以及,
(b)将荧光填充剂和溶剂放入在上述(a)步骤所制备的粘合剂树脂混合物中并在25至100℃的温度范围进行搅拌的荧光体油墨制备步骤;
其中,上述组合物的粘度是5,000~30,000cP。
2.根据权利要求1所述的粘接性清漆组合物,其中,上述纤维素类树脂其重均分子量是30,000至40,000g/mol。
3.根据权利要求1所述的粘接性清漆组合物,其中,上述纤维素类树脂是选自由醋酸纤维素、丙酸纤维素、丁酸纤维素、醋酸丙酸纤维素、醋酸丁酸纤维素、邻苯二甲酸乙酸纤维素、以及邻苯二甲酸纤维素组成的组中的一种或两种以上的化合物。
4.根据权利要求1所述的粘接性清漆组合物,其中,上述丙烯酸类树脂包含选自丙烯酸类多元醇、丙烯酸共聚物、改性丙烯酸共聚物、以及聚丙烯酸酯中的一种或两种以上的混合物。
5.根据权利要求1所述的粘接性清漆组合物,其中,上述组合物进一步包含硅系化合物。
6.一种粘接性清漆组合物的制备方法,其包括:
(a)将含有聚酯类树脂、丙烯酸类树脂、纤维素类树脂、以及稀释剂的粘合剂树脂混合物在80至180℃进行搅拌的粘合剂树脂混合物制备步骤;以及,
(b)将荧光填充剂和溶剂放入在上述(a)步骤所制备的粘合剂树脂混合物中并在25至100℃的温度范围进行搅拌的荧光体油墨制备步骤;
上述组合物包含粘合剂树脂混合物25~60重量%、荧光填充剂30~70重量%、以及溶剂5~20重量%;
上述粘合剂树脂混合物包含聚酯类树脂5~40重量%、丙烯酸类树脂10~45重量%、纤维素类树脂5~30重量%、以及稀释剂5~20重量%;
所述溶剂是选自二甲基环己胺、甲基乙基甲酮、环己酮、丙二醇单甲醚、乙二醇单丁醚醋酸酯、二甲苯、乙酸乙酯、一缩二丙二醇单甲醚、乙酸正丁酯、丁基乙二醇、以及它们的混合物中的任一种溶剂;
上述组合物的粘度是5,000~30,000cP。
7.根据权利要求6所述的粘接性清漆组合物的制备方法,其中,上述粘合剂树脂混合物的粘度是5,000~15,000cP。
8.根据权利要求6所述的粘接性清漆组合物的制备方法,其中,在上述(b)步骤进一步包含硅系化合物。
9.根据权利要求6所述的粘接性清漆组合物的制备方法,其中,在上述(b)步骤的搅拌利用选自通过快速搅拌的分散、通过辊研磨机的分散、以及通过分散剂的分散中的任一以上的方法来实施。
10.一种发光元件,其包含选自权利要求1至5所述的组合物和利用权利要求6至9所述的制备方法所制备的组合物中的任一组合物。
11.一种LED封装件,其包含选自权利要求1至5所述的组合物和利用权利要求6至9所述的制备方法所制备的组合物中的任一组合物。
12.一种蓝色激光二极管,其包含选自权利要求1至5所述的组合物和利用权利要求6至9所述的制备方法所制备的组合物中的任一组合物。
13.一种COB封装件,其包含选自权利要求1至5所述的组合物和利用权利要求6至9所述的制备方法所制备的组合物中的任一组合物。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5132045A (en) * | 1988-03-16 | 1992-07-21 | Mitsubishi Rayon Co., Ltd. | Acrylic phosphor paste compositions and phosphor coatings obtained therefrom |
US20070092758A1 (en) * | 2005-10-20 | 2007-04-26 | Lee Eun S | Dispersant having silane head and phosphor paste composition comprising the same |
CN1966160A (zh) * | 2005-11-15 | 2007-05-23 | 厦门华联电子有限公司 | 荧光胶涂覆工艺 |
CN101175833A (zh) * | 2005-04-07 | 2008-05-07 | 住友化学株式会社 | 荧光体、荧光体糊及发光元件 |
US20080230748A1 (en) * | 2007-03-21 | 2008-09-25 | Samsung Electronics Co., Ltd. | Dispersant having multifunctional head and phosphor paste composition comprising the same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0912979A (ja) | 1995-06-28 | 1997-01-14 | Toray Ind Inc | 感光性蛍光体ペースト |
JP2878204B2 (ja) | 1996-09-27 | 1999-04-05 | 鹿児島日本電気株式会社 | 蛍光体ペーストおよびこれを用いた蛍光表示管 |
JP2003025314A (ja) | 2001-07-17 | 2003-01-29 | Eidai Co Ltd | 木質繊維板の製造方法 |
KR100497260B1 (ko) | 2002-05-07 | 2005-06-28 | 삼성에스디아이 주식회사 | 플라즈마 디스플레이 패널용 형광체 페이스트 조성물 및이의 제조 방법 |
KR101271273B1 (ko) | 2005-03-31 | 2013-06-04 | 세키스이가가쿠 고교가부시키가이샤 | 바인더 수지 조성물 및 무기 미립자 분산 페이스트 조성물 |
JP2008050594A (ja) | 2006-07-26 | 2008-03-06 | Sekisui Chem Co Ltd | バインダー樹脂組成物 |
DE102012222045A1 (de) * | 2012-12-03 | 2014-06-05 | Cht R. Beitlich Gmbh | Beschichtung von Luminophoren |
-
2013
- 2013-11-14 KR KR1020130138283A patent/KR101537516B1/ko active IP Right Grant
- 2013-11-14 US US14/440,360 patent/US9481779B2/en active Active
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5132045A (en) * | 1988-03-16 | 1992-07-21 | Mitsubishi Rayon Co., Ltd. | Acrylic phosphor paste compositions and phosphor coatings obtained therefrom |
CN101175833A (zh) * | 2005-04-07 | 2008-05-07 | 住友化学株式会社 | 荧光体、荧光体糊及发光元件 |
US20070092758A1 (en) * | 2005-10-20 | 2007-04-26 | Lee Eun S | Dispersant having silane head and phosphor paste composition comprising the same |
CN1966160A (zh) * | 2005-11-15 | 2007-05-23 | 厦门华联电子有限公司 | 荧光胶涂覆工艺 |
US20080230748A1 (en) * | 2007-03-21 | 2008-09-25 | Samsung Electronics Co., Ltd. | Dispersant having multifunctional head and phosphor paste composition comprising the same |
Non-Patent Citations (1)
Title |
---|
Effects of two cellulose binders on the luminous properties of phosphor pastes;Yun Young-Hoon et al;《Ceramics International》;20120331;第38卷(第2期);第1599-1603页 * |
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