CN104779315A - Graphene/indium phosphide photoelectric detector and preparation method thereof - Google Patents

Graphene/indium phosphide photoelectric detector and preparation method thereof Download PDF

Info

Publication number
CN104779315A
CN104779315A CN201510162728.9A CN201510162728A CN104779315A CN 104779315 A CN104779315 A CN 104779315A CN 201510162728 A CN201510162728 A CN 201510162728A CN 104779315 A CN104779315 A CN 104779315A
Authority
CN
China
Prior art keywords
graphene
layer
indium
surface electrode
indium phosphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510162728.9A
Other languages
Chinese (zh)
Inventor
林时胜
王朋
李晓强
章盛娇
徐志娟
吴志乾
徐文丽
陈红胜
骆季奎
李尔平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang University ZJU
Original Assignee
Zhejiang University ZJU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang University ZJU filed Critical Zhejiang University ZJU
Priority to CN201510162728.9A priority Critical patent/CN104779315A/en
Publication of CN104779315A publication Critical patent/CN104779315A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/09Devices sensitive to infrared, visible or ultraviolet radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/0304Inorganic materials including, apart from doping materials or other impurities, only AIIIBV compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Light Receiving Elements (AREA)

Abstract

The invention discloses a graphene/indium phosphide photoelectric detector. The photoelectric detector sequentially comprises an indium phosphide layer, a graphene layer and a surface electrode from bottom to top or sequentially comprises an indium phosphide layer, an insulation layer and a surface electrode from bottom to top as well as a graphene layer arranged on the indium phosphide layer and contacted with the surface electrode. A preparation method of the photoelectric detector comprises steps as follows: transferring graphene to a clean indium phosphide sheet, and then producing the surface electrode on the graphene layer; or growing the insulation layer on the clean indium phosphide sheet, then producing the surface electrode on the insulation layer, finally, transferring the graphene to indium phosphide, and enabling the graphene to be contacted with the surface electrode. The graphene/indium phosphide photoelectric detector uses the high carrier mobility and the good photoelectric response of the graphene material, combines excellent semiconductor photoelectric properties of the indium phosphide, and is sensitive in photoresponse, high in responsivity and simple in preparation process.

Description

A kind of Graphene/indium phosphide photodetector and preparation method thereof
Technical field
The present invention relates to a kind of photodetector and preparation method thereof, especially a kind of Graphene/indium phosphide photodetector and preparation method thereof, belongs to photoelectric device technical field.
Background technology
Graphene tow-dimensions atom material to be found and after preparing for 2004 first, more research shows that grapheme material has excellent electricity, optics and engineering properties, as the photoresponse in high carrier mobility, very wide wave-length coverage, high Young's modulus and pliability etc.The character of these uniquenesses makes Graphene likely be widely used in photoelectron technical field, comprises photodetector, solar cell etc.In recent years, many researchers carry out the application study of graphene optical detector, and its advantage to realize ultrafast and more broadband spectral response.But because Graphene only has the thickness of atomic size, the light ratio of absorption is less (~ 2.3%), have impact on the responsiveness of optical detection.Find suitable material be combined with Graphene or design new structure, strengthening its optical detection response, is the emphasis of investigation and application.
Summary of the invention
The object of the present invention is to provide a kind of responsiveness high, preparation technology's simple Graphene/indium phosphide photodetector and preparation method thereof.
Graphene of the present invention/indium phosphide photodetector can adopt the following two kinds technical scheme to realize:
Technical scheme one
Graphene of the present invention/indium phosphide photodetector, has the phosphorization phosphide indium layer of p-type or N-shaped doping, graphene layer and surface electrode from bottom to top successively;
The method preparing this photodetector is: be transferred to by Graphene in clean p-type or N-shaped doping phosphatization indium sheet and obtain graphene layer, then make surface electrode on graphene layer.
Technical scheme two
Graphene of the present invention/indium phosphide photodetector, there are the phosphorization phosphide indium layer of p-type or N-shaped doping, insulating barrier and surface electrode from bottom to top successively, insulating barrier area accounts for the 5-90% of phosphorization phosphide indium layer area, surface electrode area is less than insulating barrier area, described photodetector is also provided with graphene layer, graphene layer is arranged on phosphorization phosphide indium layer, and contacts with surface electrode.
The method preparing this photodetector is: in the p-type or N-shaped doping phosphatization indium sheet of cleaning, grow insulating barrier, and the reserved area making graphene layer, surface electrode is made again on above-mentioned insulating barrier, finally Graphene is transferred to above-mentioned reserved area place, and Graphene is contacted with surface electrode.
In the technical program, described insulating barrier can be silica, silicon nitride, silicon oxynitride, aluminium oxide or boron nitride, and its thickness is generally 1-200nm.
In above-mentioned two kinds of technical schemes, in described graphene layer, Graphene is generally 1 layer to 10 layers.
Described surface electrode is generally one or several the combination electrode in gold, palladium, silver, titanium, chromium, nickel, platinum and aluminium.
Traditional semiconductor material body, especially Ⅲ-Ⅴ compound semiconductor, have excellent photoelectric property.Graphene is combined with semi-conducting material, if both Fermi levels exist larger difference, can form schottky junction.Under illumination, photon absorbs primarily of semi-conducting material and produces electron hole pair, and under the effect of junction barrier, electronics or hole are injected in Graphene.Graphene carriers quantity changes thereupon, and its resistivity also can change.Extraneous light intensity changes, and injected electrons or hole concentration also change.The resistance change of Graphene can reflect the probe response situation of illumination to external world.
In addition, the Fermi level of Graphene can be regulated by doping or applied voltage, and the potential barrier also corresponding change of Schottky, the photodetection performance of device also can regulate.In Ⅲ-Ⅴ compound semiconductor, indium phosphide is direct band gap material, and its energy gap, closest to the optimal value (1.34ev) of solar spectrum energy, has good spectral absorption and response.
In sum, the beneficial effect that the present invention has is: compared with traditional photodetector, Graphene of the present invention/indium phosphide photodetector utilizes the excellent photoelectric property of the high carrier mobility of Graphene and good photoelectric respone and indium phosphide, has better light absorption and optical detection response performance; And its preparation technology is simple, be easy to realize.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of a kind of structure of Graphene/indium phosphide photodetector;
Fig. 2 is the schematic diagram of the another kind of structure of Graphene/indium phosphide photodetector;
Fig. 3 is the curent change curve of Graphene/indium phosphide photodetector under optical switch status that embodiment 1 obtains.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention will be further described.
With reference to Fig. 1, Graphene of the present invention/indium phosphide photodetector, has the phosphorization phosphide indium layer 1 of p-type or N-shaped doping, graphene layer 2 and surface electrode 3 from bottom to top successively; Or as shown in Figure 2, there are the phosphorization phosphide indium layer 1 of p-type or N-shaped doping, insulating barrier 4 and surface electrode 3 from bottom to top successively, insulating barrier 4 area accounts for the 5-90% of phosphorization phosphide indium layer 1 area, surface electrode 3 area is less than insulating barrier 4 area, described photodetector is also provided with graphene layer 2, graphene layer 2 is arranged on phosphorization phosphide indium layer 1, and contacts with surface electrode 3.
Embodiment 1
1) p-type phosphatization indium sheet sample is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) single-layer graphene is transferred in the phosphatization indium sheet of cleaning;
3) on Graphene, utilize thermal evaporation process to deposit 100nm gold electrode, obtain Graphene/indium phosphide photodetector.
Making alive between two surface electrodes, by the change of testing photoelectronic detector electric current under different light, can reflect its response to different spectrum and light intensity.When the photodetector that namely Fig. 3 obtains this example adds 5V voltage, do not adding the current value change curve of interval follow-on test under illumination and the illumination of 1 standard sunlight, can find out that the photodetector photoresponse that this example obtains is sensitive, responsiveness is high.
Embodiment 2
1) N-shaped phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) 10 layer graphenes are transferred in the phosphatization indium sheet of cleaning;
3) on Graphene, utilize thermal evaporation process to deposit 200nm nickel/gold electrode, obtain Graphene/indium phosphide photodetector.
Embodiment 3
1) N-shaped phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) 3 layer graphenes are transferred in the phosphatization indium sheet of cleaning;
3) silk screen printing 500nm silver electrode on Graphene, obtains Graphene/indium phosphide photodetector.
Embodiment 4
1) p-type phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) 6 layer graphenes are transferred in the phosphatization indium sheet of cleaning;
3) magnetron sputtering 20nm titanium/nickel electrode on Graphene, obtains Graphene/indium phosphide photodetector.
Embodiment 5
1) p-type phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) mask electron-beam evaporation silica 80nm in phosphatization indium sheet, it is 5% in surface of indium phosphide area coverage ratio;
3) electron-beam evaporation 40nm gold electrode on silica, gold electrode area is less than silica area;
4) single-layer graphene is transferred in the phosphatization indium sheet of evaporation electrode, and Graphene contacts with gold electrode, obtain Graphene/indium phosphide photodetector.
Embodiment 6
1) N-shaped phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) mask electron-beam evaporation silicon nitride 1nm in phosphatization indium sheet, it is 80% in surface of indium phosphide area coverage ratio;
3) electron-beam evaporation 20nm silver electrode on silicon nitride, silver electrode area is less than silicon nitride area;
4) 8 layer graphenes are transferred in the phosphatization indium sheet of evaporation electrode, and Graphene contacts with silver electrode, obtain Graphene/indium phosphide photodetector.
Embodiment 7
1) p-type phosphatization indium sheet is successively immersed in acetone, aqueous isopropanol carry out surface clean;
2) mask electron-beam evaporation aluminium oxide 200nm in phosphatization indium sheet, it is 90% in surface of indium phosphide area coverage ratio;
3) electron-beam evaporation 40nm gold/palladium electrode on alumina, the area of gold/palladium electrode is less than the area of aluminium oxide;
4) 3 layer graphenes are transferred in the phosphatization indium sheet of evaporation electrode, and Graphene contacts with gold/palladium electrode, obtain Graphene/indium phosphide photodetector.

Claims (6)

1. Graphene/indium phosphide photodetector, is characterized in that the phosphorization phosphide indium layer (1), graphene layer (2) and the surface electrode (3) that have p-type or N-shaped to adulterate successively from bottom to top; Or there are the phosphorization phosphide indium layer (1) of p-type or N-shaped doping, insulating barrier (4) and surface electrode (3) from bottom to top successively, insulating barrier (4) area accounts for the 5-90% of phosphorization phosphide indium layer (1) area, surface electrode (3) area is less than insulating barrier (4) area, described photodetector is also provided with graphene layer (2), graphene layer (2) is arranged on phosphorization phosphide indium layer (1), and contacts with surface electrode (3).
2. Graphene according to claim 1/indium phosphide photodetector, is characterized in that in described graphene layer (2), Graphene is 1 layer to 10 layers.
3. Graphene according to claim 1/indium phosphide photodetector, is characterized in that described insulating barrier (4) is silica, silicon nitride, silicon oxynitride, aluminium oxide or boron nitride.
4. Graphene according to claim 1/indium phosphide photodetector, is characterized in that the thickness of described insulating barrier (4) is 1-200nm.
5. Graphene according to claim 1/indium phosphide photodetector, is characterized in that described surface electrode (3) is one or several the combination electrode in gold, palladium, silver, titanium, chromium, nickel, platinum and aluminium.
6. the method for the Graphene/indium phosphide photodetector of preparation as described in any one of claim 1-5, is characterized in that comprising the steps:
Graphene is transferred on clean p-type or N-shaped doping phosphatization indium sheet (1) and obtains graphene layer (2), then make surface electrode (3) on graphene layer (2);
Or in the p-type or N-shaped doping phosphatization indium sheet (1) of cleaning, grow insulating barrier (4), and the reserved area making graphene layer (2), surface electrode (3) is made again on above-mentioned insulating barrier (4), finally Graphene is transferred to above-mentioned reserved area place, and Graphene is contacted with surface electrode (3).
CN201510162728.9A 2015-04-08 2015-04-08 Graphene/indium phosphide photoelectric detector and preparation method thereof Pending CN104779315A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510162728.9A CN104779315A (en) 2015-04-08 2015-04-08 Graphene/indium phosphide photoelectric detector and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510162728.9A CN104779315A (en) 2015-04-08 2015-04-08 Graphene/indium phosphide photoelectric detector and preparation method thereof

Publications (1)

Publication Number Publication Date
CN104779315A true CN104779315A (en) 2015-07-15

Family

ID=53620678

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510162728.9A Pending CN104779315A (en) 2015-04-08 2015-04-08 Graphene/indium phosphide photoelectric detector and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104779315A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106057961A (en) * 2016-06-28 2016-10-26 兰建龙 Titanium-oxide-nanoband-based heterojunction type photovoltaic detector and preparation method thereof
CN106505115A (en) * 2016-10-17 2017-03-15 浙江大学 Quantum dot light doped graphene/boron nitride/gallium nitride ultraviolet detector and preparation method thereof
CN107437568A (en) * 2016-05-26 2017-12-05 中国科学院物理研究所 A kind of photovoltaic devices and a kind of method for producing photovoltaic effect
CN108075009A (en) * 2016-11-09 2018-05-25 香港生产力促进局 Graphene infrared sensor based on photonic crystal photoresponse enhancing technology and preparation method thereof
CN110783423A (en) * 2019-09-09 2020-02-11 浙江大学 Graphene/aluminum oxide/gallium arsenide terahertz detector and manufacturing method thereof
CN114784125A (en) * 2022-03-25 2022-07-22 国科大杭州高等研究院 Asymmetric induction room-temperature high-sensitivity photoelectric detector and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102263144A (en) * 2011-07-29 2011-11-30 清华大学 Semiconductor heterojunction solar cell based on bionic moth eye and manufacturing method thereof
WO2013190128A2 (en) * 2012-06-21 2013-12-27 Norwegian University Of Science And Technology (Ntnu) Solar cells
CN104241415A (en) * 2014-09-10 2014-12-24 浙江大学 Graphene/gallium arsenide solar cell and manufacturing method thereof
CN104393093A (en) * 2014-11-13 2015-03-04 北京工业大学 High-detectivity gallium-nitride-based Schottky ultraviolet detector using graphene

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102263144A (en) * 2011-07-29 2011-11-30 清华大学 Semiconductor heterojunction solar cell based on bionic moth eye and manufacturing method thereof
WO2013190128A2 (en) * 2012-06-21 2013-12-27 Norwegian University Of Science And Technology (Ntnu) Solar cells
CN104241415A (en) * 2014-09-10 2014-12-24 浙江大学 Graphene/gallium arsenide solar cell and manufacturing method thereof
CN104393093A (en) * 2014-11-13 2015-03-04 北京工业大学 High-detectivity gallium-nitride-based Schottky ultraviolet detector using graphene

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107437568A (en) * 2016-05-26 2017-12-05 中国科学院物理研究所 A kind of photovoltaic devices and a kind of method for producing photovoltaic effect
CN107437568B (en) * 2016-05-26 2019-04-05 中国科学院物理研究所 A kind of photovoltaic devices and a kind of method for generating photovoltaic effect
CN106057961A (en) * 2016-06-28 2016-10-26 兰建龙 Titanium-oxide-nanoband-based heterojunction type photovoltaic detector and preparation method thereof
CN106505115A (en) * 2016-10-17 2017-03-15 浙江大学 Quantum dot light doped graphene/boron nitride/gallium nitride ultraviolet detector and preparation method thereof
CN108075009A (en) * 2016-11-09 2018-05-25 香港生产力促进局 Graphene infrared sensor based on photonic crystal photoresponse enhancing technology and preparation method thereof
CN110783423A (en) * 2019-09-09 2020-02-11 浙江大学 Graphene/aluminum oxide/gallium arsenide terahertz detector and manufacturing method thereof
CN114784125A (en) * 2022-03-25 2022-07-22 国科大杭州高等研究院 Asymmetric induction room-temperature high-sensitivity photoelectric detector and preparation method thereof
CN114784125B (en) * 2022-03-25 2024-04-02 国科大杭州高等研究院 Asymmetric induction room temperature high-sensitivity photoelectric detection device and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106505115B (en) Quantum dot light doped graphene/boron nitride/gallium nitride ultraviolet detector and preparation method thereof
CN104779315A (en) Graphene/indium phosphide photoelectric detector and preparation method thereof
Diao et al. 12.35% efficient graphene quantum dots/silicon heterojunction solar cells using graphene transparent electrode
Cao et al. Efficient screen printed perovskite solar cells based on mesoscopic TiO2/Al2O3/NiO/carbon architecture
Yang et al. Interface engineering for efficient and stable chemical-doping-free graphene-on-silicon solar cells by introducing a graphene oxide interlayer
Kushwaha et al. Defect induced high photocurrent in solution grown vertically aligned ZnO nanowire array films
CN103346199B (en) Based on the UV photodetector and preparation method thereof of single-layer graphene/nanometic zinc oxide rod array schottky junction
CN103280484B (en) P-type graphene film/n-type Ge schottky junction near infrared photodetector and preparation method thereof
Deo et al. Strong photo-response in a flip-chip nanowire p-Cu 2 O/n-ZnO junction
Bae et al. Carrier-selective p-and n-contacts for efficient and stable photocatalytic water reduction
Guo et al. High-performance WO 3− x-WSe 2/SiO 2/n-Si heterojunction near-infrared photodetector via a homo-doping strategy
Zhao et al. Self-driven visible-near infrared photodetector with vertical CsPbBr3/PbS quantum dots heterojunction structure
Liao et al. Strain-modulation and service behavior of Au–MgO–ZnO ultraviolet photodetector by piezo-phototronic effect
Xie et al. p-CdTe nanoribbon/n-silicon nanowires array heterojunctions: photovoltaic devices and zero-power photodetectors
Athira et al. SnO2-NiO heterojunction based self-powered UV photodetectors
Chen et al. Enhanced photoresponsivity in carbon quantum dots-coupled graphene/silicon Schottky-junction photodetector
CN103956402B (en) A kind of self-driven high speed schottky junction near infrared photodetector and preparation method thereof
Nguyen et al. Self-powered transparent photodetectors for broadband applications
CN105720127A (en) Multifunctional generator based on graphene/semiconductor heterojunction and manufacturing method thereof
CN109252179A (en) A kind of double absorption layer light anode and preparation method for photocatalytic water
Peng et al. UV-induced SiC nanowire sensors
Popoola et al. Fabrication of bifacial sandwiched heterojunction photoconductor–type and MAI passivated photodiode–type perovskite photodetectors
Kurt et al. Optical and electrical characterization of a ZnO/coronene-based hybrid heterojunction photodiode
Huang et al. Self-powered ultraviolet photodetector based on CuGaO/ZnSO heterojunction
Huang et al. Dual functional modes for nanostructured p-Cu2O/n-Si heterojunction photodiodes

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150715

WD01 Invention patent application deemed withdrawn after publication