CN1047688A

CN1047688A - Coal gasification reactor

Info

Publication number: CN1047688A
Application number: CN90103807A
Authority: CN
Inventors: 汉约安·哈西耐克; 皮汉威马·达弗费尔德
Original assignee: Shell Internationale Research Maatschappij BV
Current assignee: Shell Internationale Research Maatschappij BV
Priority date: 1989-05-30
Filing date: 1990-05-28
Publication date: 1990-12-12
Anticipated expiration: 2005-05-28
Also published as: EP0400740A1; AU618195B2; DE69011216D1; CN1025345C; GB8912316D0; DK0400740T3; ES2058754T3; DE69011216T2; JP2932198B2; JPH0324195A; ZA904064B; EP0400740B1; AU5602290A; CA2017635A1; CA2017635C

Abstract

By tangentially burning with Small angle and between reactor outlet and expander inlet, the vapor pipe of specific length-to-diameter ratio being arranged and the slagging efficient of coal gasification process is improved by harness.Prevented in such a way in the enter the mouth scum silica frost effect and the slag effect of carrying secretly at an exhaust outlet place of expander.

Description

Coal gasification reactor

The present invention relates to the solid carbon fuel and the oxygenant of abundant pulverizing are carried out the reactor that partial oxidation is operated.

Fully the solid carbon fuel of pulverizing is used to prepare among each technological process of synthetic gas, in these processes, utilize oxygen-containing gas to make solid carbon fuel partial combustion in reactor of said abundant pulverizing, wherein the liquid slag that forms in said partial combustion process is removed by the outlet of said reactor bottom, by among the slag discharging device feeding water-bath or among the slag quench vessel, slag is solidified by gravity.

The solid carbon fuel of fully pulverizing with purified oxygen (as said oxygen-containing gas) partial combustion basically produces the synthetic gas of mainly being made up of carbon monoxide and hydrogen.The synthetic gas that forms when oxygen-containing gas is air or oxygen-rich air also contains a large amount of nitrogen certainly.The so-called solid carbon fuel of fully pulverizing generally refers to coal or other solid fuel, and for example brown coal, mud coal, timber, coke and carbon black or the like also can be the mixtures of liquid or gas and granular solids fuel still.

It is useful adding negative catalyst in said reactor again.The purpose of said negative catalyst is to relax the effect of temperature to reactor, and the reactant of preparation synthetic gas and/or the thermo-negative reaction between product and the said negative catalyst are guaranteed this mitigate effects.The negative catalyst that is suitable for is water vapor and carbonic acid gas.

Said pneumatolysis is preferably in 1200～1700 ℃ of temperature ranges and in 1～200 bar pressure scope carries out.

The reactor that the preparation synthetic gas is used can have any suitable shape.

Supply with solid carbon fuel and the oxygen-containing gas of fully pulverizing to reactor, can carry out, will not describe in detail about this point according to any this purpose mode that is suitable for.

After the liquid slag that forms in the partial combustion reaction drips, discharge by the outlet that is located at reactor bottom.

Carry out in the partial oxidation process at the solid carbon fuel to abundant pulverizing, when for example coal gasification was reacted, said fuel was infeeded in the gasifier by feed device by means of suitable carrier band fluid.

This hot product gas contains some tackiness particles usually, its tackiness of this particle looses during cooling.

These tackiness particles in the hot product gas can produce some problems in the equipment of further handling said product gas, because the undesirable settling that occurs in for example wall, valve or outlet can have a negative impact to this technology.And such settling is difficult to remove.These adhesive granular deposits may partly or entirely be in molten state, and wherein may comprise metal, salt or ash, and generally are being lower than these particle looses tackinesss under about 800 ℃ of temperature.

Therefore, above the outlet of reactor head product, quench section is set, makes hot product gas quenching therein.For example feeding in this quench section, suitable quenching medium processing product gas such as water or gas makes it cooling.

People know, in partial oxidation technology, some tangential flame burners have been adopted to the solid carbon fuel of abundant pulverizing, promptly around the reactor vessel wall, on some spaced points of same level attitude a plurality of tangential orientation burners are set, make and produce eddy current in the reactor.

As if but those present reactor design still have some shortcomings: slagging efficient very little (40～50%) may produce the scum silica frost phenomenon at reactor exit, and may occur from the phenomenon that the hot synthesis gas short circuit that reactor comes out enters expander.

The object of the invention is to provide a kind of slagging efficient to reach 90～95% reactor design.

Another object of the present invention is to provide a kind of scum silica frost effect and slag of preventing to drip the reactor design that the effect of carrying secretly takes place.

Another purpose of the present invention is to provide a kind of synthetic gas that prevents that the reactor design of said short circuit effect takes place.

Therefore, the invention provides a kind of reactor that the solid carbon fuel and the oxygenant of abundant pulverizing are carried out the partial oxidation operation, said reactor comprises that has a product gas outlet at the top, slag notch is arranged at the bottom, the reactor vessel that most burner ports are arranged on sidewall, on all points of circumferentially-spaced, be provided with a plurality of tangential orientation burners with the angle that catches fire for a short time in same level attitude, said reactor is provided with expander above its outlet, wherein one is arranged between said reactor outlet and the expander inlet by the vapor pipe of predetermined length/diameter than design.

Term " angle catches fire " is defined as: the symmetry axis of said burner nozzle and by angle between the straight line of reactor center on said burner center and the same sea line.

Below, the present invention is being illustrated in greater detail with reference to following accompanying drawing by embodiment, wherein:

Fig. 1 is vertical synoptic diagram of a kind of traditional reactor and quench section;

Fig. 2 is vertical synoptic diagram of a kind of reactor design of the present invention;

Fig. 3 a is the cross section view along Fig. 1 I-I line;

Fig. 3 b is the cross section view along Fig. 2 II-II line.

With reference to Fig. 1, reactor vessel 1 is described.This reactor vessel 1 bottom is provided with a slag notch 2, and a plurality of tangential flame burners 3 are positioned at the pneumatic outlet 4 and a quench system 5 at top, and this quench system 5 comprises an expander inlet 5a who is in said reactor outlet 4 tops.Around said tangential orientation burner 3 is arranged on the same sea line in all spaced points place, and makes in the said reactor vessel 1 and produce eddy current.

Said quench system 5 its export 6 places be connected to further processing synthetic gas with equipment on.This equipment is that affiliated technical field those of ordinary skill is known, thereby does not elaborate.In Fig. 2, use with Fig. 1 in identical ginseng colon.

In Fig. 2, said reactor 1 exports extension tube of 4 places equipment or vapor pipe 4a at it, and this extension tube is located between reactor outlet 4 and the expander inlet 5a and has predetermined length-to-diameter ratio Ls/Ds.

Said quench system 5 is located at the distant place apart from reactor outlet.Ls/Ds is preferably 5(as shown in Figure 2 with 4～6 for well).

In addition, in Fig. 2, said quench system 5 length-to-diameter ratio Lg/Dg=3, and the length-to-diameter ratio Lr/Dr=3 of said reactor 1.

Fig. 3 a represents that tangentially the burner of configuration is arranged, comprising four burner A, B, C, D; Horizontal and the centering adjustment point E of these burners this means that the angle that catches fire is 0 degree.

Fig. 3 b represents arranging of tangential-firing burner of the present invention, and comprising four burner A ', B ', C ' and D ', the said angle that catches fire is 5 degree.Be advisable with 3～5 degree in the angle that catches fire of the present invention.These burners point to the central circular area E ' with definite area.

When adopting reactor design of the present invention, big centrifugal force in said vapor pipe inside can produce big settling velocity, thereby has high slagging efficient, will be because most slags will sink in the bottom of said extension tube, so can be by by the dress hair cross or by making the narrower turbulent flow that reduces product gas of vapor pipe.Can prevent then that so cold synthetic gas from entering said reactor again.

Said vapor pipe also can reduce the turbulent flow of synthetic gas.This turbulent reduce and just the exhaust wall under said expander inlet be vertical and than Fig. 1 in this steeper fact of reactor top, will help preventing that the effect of carrying secretly of scum silica frost effect or slag from taking place.

Said vapor pipe can also reduce mobile short circuit phenomenon.Therefore the central bay that penetrates to reactor outlet increases.Transformation efficiency improves as a result, and temperature out can reduce.

From top description and accompanying drawing, various modification of the present invention are conspicuous for those of ordinary skill in the field of doing, so some such modification should be considered as within claim scope of the present invention.

Claims

1, a kind of reactor that ground solid carbon fuel and oxygenant is carried out the partial oxidation operation, said reactor comprises a reactor vessel, said container top has the product gas outlet, slag notch is arranged at the bottom, sidewall has a plurality of burner ports, and the same level attitude in all points of circumferentially-spaced place is provided with the little burner in the angle that catches fire of a plurality of tangential orientation; Above said reactor outlet, be provided with expander, the vapor pipe of predetermined length-to-diameter ratio is wherein arranged between said reactor outlet and said expander inlet.

2, according to the described reactor of claim 1, wherein said vapor pipe length-to-diameter ratio is 4～6.

3, according to the described reactor of claim 2, wherein said vapor pipe length-to-diameter ratio is 5.

4, according to any one said reactor in the claim 1～3, the wherein said angle that catches fire is 3～5 degree.

5, a kind of reactor that ground solid carbon fuel and oxygenant are carried out the partial oxidation operation is basically as described in Fig. 2 and 36 in the reference accompanying drawing in the specification sheets.