CN104724356A - Environment-friendly ceramic whiteware imitated glass bottle - Google Patents

Environment-friendly ceramic whiteware imitated glass bottle Download PDF

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Publication number
CN104724356A
CN104724356A CN201410253781.5A CN201410253781A CN104724356A CN 104724356 A CN104724356 A CN 104724356A CN 201410253781 A CN201410253781 A CN 201410253781A CN 104724356 A CN104724356 A CN 104724356A
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China
Prior art keywords
glass
glass bottle
ceramic whiteware
environment
white
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Application number
CN201410253781.5A
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Chinese (zh)
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CN104724356B (en
Inventor
许钧强
李传才
付华
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SHENZHEN LAI LI YA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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SHENZHEN LAI LI YA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201410253781.5A priority Critical patent/CN104724356B/en
Publication of CN104724356A publication Critical patent/CN104724356A/en
Application granted granted Critical
Publication of CN104724356B publication Critical patent/CN104724356B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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  • Paints Or Removers (AREA)

Abstract

The invention provides an environment-friendly ceramic whiteware imitated glass bottle. Cleaning treatment must be carried out on the glass bottle before coating, and drying is carried out; water-based glass white primer is sprayed to the cleaned glass bottle, and the thickness of a dry film is controlled to be between eight micrometers and 10 micrometers; water-based glass white finish paint is sprayed, and the thickness of a dry film is controlled to be between eight micrometers and 10 micrometers; water-based glass coating varnish is sprayed, the thickness of a dry film is controlled between five micrometers and 10 micrometers, and the glass bottle is hung in a drying oven to be baked at 120 DEG C to 180 DEG C for 10 min to 25 min after spraying. The environment-friendly ceramic whiteware imitated glass bottle is free of heavy metal and alkylphenol and is environmentally friendly. The coated films are high in adhesive force, good in flexibility, high in hardness, and excellent in abrasion resistance, water resistance, alcohol resistance and salt fog resistance. The environment-friendly ceramic whiteware imitated glass bottle is high in stereoscopic impression and has the simulated effect the same as that of ceramic whiteware. The manufactured ceramic whiteware imitated glass bottle can be used for packaging white wine, perfume, tea and other food.

Description

A kind of environment-friendly imitation ceramic whiteware glass bottle
Technical field
The invention belongs to container package field of material technology, relate to a kind of preparation method of environment-friendly imitation ceramic whiteware glass bottle.
Background technology
Since reform and opening-up, glass packaging container industry obtains and develops fast, constantly.The output of glass packaging container in 1997 is 5,850,000 tons, and 1,370,000 tons than 1978 increase 426%, and annual increases progressively 8.66%; Within 2004, increased by 33.96% than 1999, output reaches 7,850,000 tons, and annual increases progressively 6.02%; It is predicted and also increase progressively with 5 ~ 6% every year from now on.In packaging industry, the importance of package design is never defeated in the selection of packing, and popular product of today trends towards adopting traditional package design.Why attractive glass material is, is because of its transparent pure speciality, independently can opens, meet environmental requirement with figure.In the market such as white wine, cosmetic industry, the Packaging Value of glass bottle is constantly deeply excavated.
2012, the output of national white wine (rolling over 65 degree, commodity amount) reached 112.56 hundred million liters, increases by 30.70% on a year-on-year basis.White wine 90% packing containers many like this, first-selected glass bottle in packing container; Need with 18,500,000,000 bottles by mark bottle (500ml), the bottle of 30% is the packaging such as ceramic whiteware, blue and white porcelain, pottery, boccaro porcelain, Kuching's porcelain of employing traditional culture according to investigations, and embodiment spirits culture intension, is convenient to view and admire and preserve.And traditional porcelain vase and the disposable high-temperature firing of pottery, use of can only banketing after breakage, the wasting of resources, cost is high, and VOC discharge is large, does not meet the requirement of modern life environment-friendly quality and sustainable development; And imitated porcelain, glass-ceramic bottle have complete genuine effect, and can be recycled after glasswork breakage, therefore develop a kind of imitative porcelain, glass-ceramic bottle is used for alternative traditional porcelain, pottery is very necessary.
Summary of the invention
The present invention aims to provide a kind of environment-friendly imitation ceramic whiteware glass bottle spraying the agent of aqueous glass ceramic glaze and make by toasting on common white glass bottle.
The present invention relates to a kind of environment-friendly imitation ceramic whiteware glass bottle, comprise following technical scheme: before application, clean must be carried out to glass bottle, dry; Aqueous glass white primer is sprayed on clean glass bottle, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Secondary spraying aqueous glass white finish paint, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Spray aqueous glass finish varnish again, control build between 5 ~ 10 μm, spraying rear overhang is hung in baking oven at 120 ~ 180 DEG C of baking 10 ~ 25min.
Wherein, the white water-borne glass ceramics glaze agent priming paint that described aqueous glass white primer selects aqueous epoxy resins, water soluble acrylic resin and amino resin to make.
The white water-borne glass ceramics glaze agent finish paint that described aqueous glass white finish paint selects water soluble acrylic resin, containing silicone resin and amino resin to make.
The aqueous glass finish varnish that described aqueous glass finish varnish selects water soluble acrylic resin, containing silicone resin and amino resin to make.
The imitative ceramic whiteware glass bottle that the present invention obtains, not containing heavy metal, without alkyl phenol, environmental protection; Film adhesive is strong, elasticity good, hardness is high, excellent resistance to abrasion, fastness to water, alcohol resistance and salt fog resistance; Three-dimension effect is strong, have the simulated effect the same with ceramic whiteware; Can be recycled with imitative ceramic whiteware glass bottle later, do not waste resource; The imitative ceramic whiteware glass bottle that the present invention obtains can be used for the packaging of white wine, perfume, tealeaves and other food.
Accompanying drawing explanation
Fig. 1 is that one of the present invention imitates ceramic whiteware glass wine bottle structural representation, and wherein 1 is common white bottle, and 2 is white water-borne glass ceramics glaze agent priming paint, and 3 is white water-borne glass ceramics glaze agent finish paint, and 4 is aqueous glass finish varnish.
Detailed description of the invention
A kind of imitative Maotai tradition ceramic whiteware bottle, comprises the following steps: first carry out clean to glass bottle, dries; Aqueous glass white primer is sprayed on clean glass bottle, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Secondary spraying aqueous glass white finish paint, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Spray aqueous glass finish varnish again, control build between 5 ~ 10 μm, spraying rear overhang is hung in baking oven at 120 ~ 180 DEG C of baking 10 ~ 25min.
According to relevant national standard, detect the film performance of imitative ceramic whiteware glass wine bottle of the present invention, testing result is as shown in table 1.
Ceramic whiteware glass wine bottle film performance testing result imitated by table 1
Test item Testing result Examination criteria
Paint film appearance White, smooth, plentiful Range estimation
Pencil hardness ≥3H GB/T6739-2006
Adhesive ability, draws circle method 1 grade GB/T9286-1998
Gloss Meet the requirements of the customers GB/T9754-1988
Fastness to water 120h is without exception GB/T1733—1993
Resistance to alkalis, 0.1%NaOH 120h is without exception GB9274
Resistance to salt water, 3%NaCl 120h is without exception GB/T10834-1989
Salt fog resistance 96h is without exception GB/T1771-1991
Resistance to alcohol repellency, 50%C 2H 5OH 120h is without exception GB/T1763—1979
Resistance to abrasion (back and forth) > 120 times GB/T1768—1979
Although the present invention has been explained in detail and has quoted embodiment as proof, for those of ordinary skill in the art, the various schemes obviously can made according to above-mentioned explanation, amendment and change, within the scope that all should be included in claim.

Claims (4)

1. an environment-friendly imitation ceramic whiteware glass bottle, is characterized in that: comprise the following steps: must carry out clean to glass bottle before application, dries; Aqueous glass white primer is sprayed on clean glass bottle, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Secondary spraying aqueous glass white finish paint, controls build between 8 ~ 10 μm, 25 ~ 110 DEG C of film forming, film-forming state be just after surface drying or surface drying at room temperature placement 0 ~ 0.5h; Spray aqueous glass finish varnish again, control build between 5 ~ 10 μm, spraying rear overhang is hung in baking oven at 120 ~ 180 DEG C of baking 10 ~ 25min.
2. a kind of environment-friendly imitation ceramic whiteware glass bottle as claimed in claim 1, is characterized in that: the white water-borne glass ceramics glaze agent priming paint that described aqueous glass white primer selects aqueous epoxy resins, water soluble acrylic resin and amino resin to make.
3. a kind of environment-friendly imitation ceramic whiteware glass bottle as claimed in claim 1, is characterized in that: the white water-borne glass ceramics glaze agent finish paint that described aqueous glass white finish paint selects water soluble acrylic resin, containing silicone resin and amino resin to make.
4. a kind of environment-friendly imitation ceramic whiteware glass bottle as claimed in claim 1, is characterized in that: the aqueous glass finish varnish that described aqueous glass finish varnish selects water soluble acrylic resin, containing silicone resin and amino resin to make.
CN201410253781.5A 2013-10-30 2014-06-09 Environment-friendly ceramic whiteware imitated glass bottle Expired - Fee Related CN104724356B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410253781.5A CN104724356B (en) 2013-10-30 2014-06-09 Environment-friendly ceramic whiteware imitated glass bottle

Applications Claiming Priority (3)

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CN2013206822034 2013-10-30
CN201320682203 2013-10-30
CN201410253781.5A CN104724356B (en) 2013-10-30 2014-06-09 Environment-friendly ceramic whiteware imitated glass bottle

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CN104724356B CN104724356B (en) 2017-04-12

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104961333A (en) * 2015-06-29 2015-10-07 山东晶峰玻璃科技有限公司 Manufacturing technology of new glass bottle
CN106009990A (en) * 2016-06-12 2016-10-12 深圳市莱莉雅环保科技有限公司 Micromolecular anionic waterborne glaze and preparation method thereof
CN115368029A (en) * 2022-08-22 2022-11-22 四川华翔玻陶制品有限公司 Glazing method for gold-sandwiched glaze of glass container

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101863190B (en) * 2010-06-29 2012-08-15 乔伯华 Making process of high-porcelain-imitating craft gourd
CN102585633B (en) * 2012-01-17 2014-01-08 东莞市利通化工实业有限公司 Coating composition with ceramic imitation effect
CN102585634B (en) * 2012-01-17 2014-01-08 东莞市利通化工实业有限公司 Coating with imitative ceramic effect and spraying process thereof
CN103351801B (en) * 2013-06-07 2015-07-29 浙江佑谦特种材料有限公司 A kind of coating with imitative porcelain effect for glass baseplate and coating method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104961333A (en) * 2015-06-29 2015-10-07 山东晶峰玻璃科技有限公司 Manufacturing technology of new glass bottle
CN106009990A (en) * 2016-06-12 2016-10-12 深圳市莱莉雅环保科技有限公司 Micromolecular anionic waterborne glaze and preparation method thereof
CN115368029A (en) * 2022-08-22 2022-11-22 四川华翔玻陶制品有限公司 Glazing method for gold-sandwiched glaze of glass container

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