CN104724356B - Environment-friendly ceramic whiteware imitated glass bottle - Google Patents
Environment-friendly ceramic whiteware imitated glass bottle Download PDFInfo
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- CN104724356B CN104724356B CN201410253781.5A CN201410253781A CN104724356B CN 104724356 B CN104724356 B CN 104724356B CN 201410253781 A CN201410253781 A CN 201410253781A CN 104724356 B CN104724356 B CN 104724356B
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- glass bottle
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- ceramic whiteware
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Abstract
The invention provides an environment-friendly ceramic whiteware imitated glass bottle. Cleaning treatment must be carried out on the glass bottle before coating, and drying is carried out; water-based glass white primer is sprayed to the cleaned glass bottle, and the thickness of a dry film is controlled to be between eight micrometers and 10 micrometers; water-based glass white finish paint is sprayed, and the thickness of a dry film is controlled to be between eight micrometers and 10 micrometers; water-based glass coating varnish is sprayed, the thickness of a dry film is controlled between five micrometers and 10 micrometers, and the glass bottle is hung in a drying oven to be baked at 120 DEG C to 180 DEG C for 10 min to 25 min after spraying. The environment-friendly ceramic whiteware imitated glass bottle is free of heavy metal and alkylphenol and is environmentally friendly. The coated films are high in adhesive force, good in flexibility, high in hardness, and excellent in abrasion resistance, water resistance, alcohol resistance and salt fog resistance. The environment-friendly ceramic whiteware imitated glass bottle is high in stereoscopic impression and has the simulated effect the same as that of ceramic whiteware. The manufactured ceramic whiteware imitated glass bottle can be used for packaging white wine, perfume, tea and other food.
Description
Technical field
The invention belongs to container package field of material technology, is related to a kind of preparation method of environment-friendly imitation ceramic whiteware vial.
Background technology
Since reform and opening-up, glass packaging container industry has obtained quickly, constantly developing.Glass packaging container in 1997
Yield be 5,850,000 tons, 1,370,000 tons than 1978 increase 426%, and annual is incremented by 8.66%；Ratio 1999 in 2004
Increase by 33.96%, yield reaches 7,850,000 tons, annual is incremented by 6.02%；It is predicted that annual from now on be also incremented by with 5～6%.
Packaging industry, the never defeated selection in packaging material of importance of package design, popular product of today are intended to using tradition
Package design.Why attractive glass material is, is, because of its transparent pure speciality, can independently to open with figure, meet ring
Border requires.In markets such as Chinese liquor, cosmetic industries, the Packaging Value of vial is constantly deeply excavated.
2012, the yield of national Chinese liquor (65 degree of folding, commodity amount) increased by 30.70% on a year-on-year basis up to 112.56 hundred million liters.So
Many packing containers of Chinese liquor 90%, first-selected vial in packing container；Based on mark bottle (500ml) need to 18,500,000,000 bottles,
30% bottle is, using the packaging such as the ceramic whiteware of traditional culture, blue-and-white porcelain, ceramics, boccaro porcelain, Kuching's porcelain, to embody wine text according to investigations
Change intension, be easy to view and admire and preserve.And traditional porcelain vase and the disposable high-temperature firing of ceramics, use of can only banketing after breakage,
The wasting of resources, high cost, VOC emission are big, do not meet the requirement of modern life environment-friendly quality and sustainable development；And imitated porcelain
Device, glass-ceramic bottle have finishes genuine effect, and can be recycled after glass breakage, therefore a kind of imitative porcelain of exploitation,
Glass-ceramic bottle is very necessary for substituting traditional porcelain, ceramics.
The content of the invention
The present invention is intended to provide a kind of spray aqueous glass ceramic glaze agent on common white glass bottle by baking
Made by environment-friendly imitation ceramic whiteware vial.
The present invention relates to a kind of environment-friendly imitation ceramic whiteware vial, including technical scheme below：Must be to vial before application
Process is cleaned, is dried；Aqueous glass white primer is sprayed on clean vial, control build is in 8～10 μ
Between m, in 25～110 DEG C of film forming, film-forming state is to place 0～0.5h in room temperature after just surface drying or surface drying；Secondary spraying aqueouss
Glass white finish paint, between 8～10 μm, in 25～110 DEG C of film forming, film-forming state is just surface drying or table to control build
0～0.5h is placed in room temperature after dry；Spray aqueous glass coating varnish again, control build between 5～10 μm, after spraying
Hang in baking oven 10～25min is toasted at 120～180 DEG C.
Wherein, described aqueous glass white primer selects aqueous epoxy resins, water soluble acrylic resin and amino tree
White water-borne glass ceramics glaze agent priming paint made by fat.
Described aqueous glass white finish paint is from white made by water soluble acrylic resin, containing silicone resin and amino resins
Color aqueous glass ceramic glaze agent finish paint.
Described aqueous glass coating varnish selects water made by water soluble acrylic resin, containing silicone resin and amino resins
Property glass coating varnish.
Obtained imitative ceramic whiteware vial of the invention, without heavy metal, without alkyl phenol, environmental protection；Film adhesive is strong, pliability
Good, hardness is high, excellent wearability, resistance to water, alcohol resistance and salt fog resistance；Third dimension is strong, with the emulation as ceramic whiteware
Effect；Can be recycled with imitative ceramic whiteware vial later, not waste of resource；Obtained imitative ceramic whiteware vial of the invention can be used for
The packaging of Chinese liquor, perfume, Folium Camelliae sinensis and other food.
Description of the drawings
Fig. 1 is a kind of imitative ceramic whiteware glass wine bottle structural representation of the present invention, wherein 1 is common white bottle, 2 is white water
Property glass ceramics glaze agent priming paint, 3 be white water-borne glass ceramics glaze agent finish paint, 4 be aqueous glass coating varnish.
Specific embodiment
A kind of imitative Maotai tradition ceramic whiteware bottle, comprises the following steps：Process is first cleaned to vial, is dried；By water
Property glass white primer spray on clean vial, control build between 8～10 μm, in 25～110 DEG C of film forming,
Film-forming state is to place 0～0.5h in room temperature after just surface drying or surface drying；Secondary spraying aqueous glass white finish paint, controls dried film thickness
Between 8～10 μm, in 25～110 DEG C of film forming, film-forming state is to place 0～0.5h in room temperature after just surface drying or surface drying for degree；
Spray aqueous glass coating varnish again, between 5～10 μm, spraying rear overhang is hung in baking oven 120～180 control build
DEG C baking 10～25min.
According to relevant national standard, the film performance of the imitative ceramic whiteware glass wine bottle of the present invention is detected, testing result
As shown in table 1.
Table 1 imitates ceramic whiteware glass wine bottle film performance testing result
| Detection project | Testing result | Examination criteria |
| Paint film appearance | It is white, smooth, plentiful | Range estimation |
| Pencil hardness | ≥3H | GB/T6739-2006 |
| Adhesive force, draws circle method | 1 grade | GB/T9286-1998 |
| Gloss | Meet the requirements of the customers | GB/T9754-1988 |
| Resistance to water | 120h is without exception | GB/T1733—1993 |
| Alkali resistance, 0.1%NaOH | 120h is without exception | GB9274 |
| Resistance to salt water, 3%NaCl | 120h is without exception | GB/T10834-1989 |
| Salt fog resistance | 96h is without exception | GB/T1771-1991 |
| It is resistance to alcohol repellency, 50%C2H5OH | 120h is without exception | GB/T1763—1979 |
| Wearability (back and forth) | ＞ 120 times | GB/T1768—1979 |
Although the present invention has been explained in detail and has been cited embodiment, for one of ordinary skill in the art, show
So can as specified above and make various schemes, modification and change, should be construed as being included within the scope of claim.
Claims (2)
1. a kind of environment-friendly imitation ceramic whiteware vial, it is characterised in that：On the vial of cleaning treatment, bottom is sprayed successively
Layer, middle level and surface layer；Described bottom is aqueous glass white primer, controls build for 8～10 μm；Described middle level is
Aqueous glass white finish paint, control build be 8～10 μm；Described surface layer is aqueous glass coating varnish, control dry film
Thickness is 5～10 μm；
Wherein, described aqueous glass white primer is made up of aqueous epoxy resins, water soluble acrylic resin and amino resins
Aqueous white glass ceramics glaze agent priming paint；Described aqueous glass white finish paint is water soluble acrylic resin, containing silicone resin
With white water-borne glass ceramics glaze agent finish paint made by amino resins；Described aqueous glass coating varnish is water-soluble acrylic
Aqueous glass coating varnish made by resin, containing silicone resin and amino resins.
2. a kind of a kind of coating process of environment-friendly imitation ceramic whiteware vial as claimed in claim 1, it is characterised in that：Including with
Lower step：
A. process must be cleaned before application to vial, be dried；
B. bottom：Aqueous glass white primer is sprayed on clean vial, the film forming at 25～110 DEG C, film-forming state
0～0.5h to be placed in room temperature after just surface drying or surface drying, control build for 8～10 μm；
C. middle level：Aqueous glass white finish paint is sprayed on bottom, the film forming at 25～110 DEG C, film-forming state are just table
0～0.5h is placed in room temperature after dry or surface drying, build is controlled for 8～10 μm；
D. surface layer：Aqueous glass coating varnish is sprayed on middle level, is then hung in baking oven, toasted at 120～180 DEG C
10～25min, controls build for 5～10 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410253781.5A CN104724356B (en) | 2013-10-30 | 2014-06-09 | Environment-friendly ceramic whiteware imitated glass bottle |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320682203 | 2013-10-30 | ||
| CN2013206822034 | 2013-10-30 | ||
| CN201410253781.5A CN104724356B (en) | 2013-10-30 | 2014-06-09 | Environment-friendly ceramic whiteware imitated glass bottle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104724356A CN104724356A (en) | 2015-06-24 |
| CN104724356B true CN104724356B (en) | 2017-04-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410253781.5A Expired - Fee Related CN104724356B (en) | 2013-10-30 | 2014-06-09 | Environment-friendly ceramic whiteware imitated glass bottle |
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| CN (1) | CN104724356B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961333A (en) * | 2015-06-29 | 2015-10-07 | 山东晶峰玻璃科技有限公司 | Manufacturing technology of new glass bottle |
| CN106009990A (en) * | 2016-06-12 | 2016-10-12 | 深圳市莱莉雅环保科技有限公司 | Micromolecular anionic waterborne glaze and preparation method thereof |
| CN115368029A (en) * | 2022-08-22 | 2022-11-22 | 四川华翔玻陶制品有限公司 | Glazing method for gold-sandwiched glaze of glass container |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863190A (en) * | 2010-06-29 | 2010-10-20 | 乔伯华 | Making process of high-porcelain-imitating craft gourd |
| CN102585633A (en) * | 2012-01-17 | 2012-07-18 | 东莞市利通化工实业有限公司 | Coating composition with ceramic imitation effect |
| CN102585634A (en) * | 2012-01-17 | 2012-07-18 | 东莞市利通化工实业有限公司 | Coating with imitative ceramic effect and spraying process thereof |
| CN103351801A (en) * | 2013-06-07 | 2013-10-16 | 浙江佑谦特种材料有限公司 | Glass substrate-use coating with ceramic imitation effect and coating method thereof |
-
2014
- 2014-06-09 CN CN201410253781.5A patent/CN104724356B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863190A (en) * | 2010-06-29 | 2010-10-20 | 乔伯华 | Making process of high-porcelain-imitating craft gourd |
| CN102585633A (en) * | 2012-01-17 | 2012-07-18 | 东莞市利通化工实业有限公司 | Coating composition with ceramic imitation effect |
| CN102585634A (en) * | 2012-01-17 | 2012-07-18 | 东莞市利通化工实业有限公司 | Coating with imitative ceramic effect and spraying process thereof |
| CN103351801A (en) * | 2013-06-07 | 2013-10-16 | 浙江佑谦特种材料有限公司 | Glass substrate-use coating with ceramic imitation effect and coating method thereof |
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| Publication number | Publication date |
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| CN104724356A (en) | 2015-06-24 |
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Granted publication date: 20170412 Termination date: 20180609 |