CN104714189A - Method for predicting cycle life of battery pack for electric car - Google Patents

Method for predicting cycle life of battery pack for electric car Download PDF

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Publication number
CN104714189A
CN104714189A CN201510155755.3A CN201510155755A CN104714189A CN 104714189 A CN104714189 A CN 104714189A CN 201510155755 A CN201510155755 A CN 201510155755A CN 104714189 A CN104714189 A CN 104714189A
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test
battery
capacity
cycle life
voltage
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王建
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Chery Automobile Co Ltd
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SAIC Chery Automobile Co Ltd
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Abstract

The invention relates to a method for predicting the cycle life of a battery pack for an electric car. The method comprises the following steps: step I, carrying out standard capacity test on the battery pack at normal temperature, and recording a real standard capacity of the battery pack; step II, carrying out dynamic stress working condition circulating test on the battery pack, returning to the step I after multiple times of working condition circulating test is ended, recording the test times of the standard capacity, ending the circulating test at the temperature if the real capacity of the standard capacity test for continuous 4 to 6 times is less than 80 percent of the rated capacity, wherein the test times of the standard capacity indicate the cycle life of the battery pack; step III, repeating the step I and the step II, and testing the cycle life of the battery pack under multiple temperature points. According to the method, the battery pack cycle life data at the grouped time is collected, a fitted equation is obtained by virtue of data processing, and the cycle life of a lithium ion battery at present can be predicted.

Description

A kind of Forecasting Methodology of battery for electric automobile group cycle life
Technical field
The invention belongs to electric vehicle battery system technical field, be specifically related to a kind of Forecasting Methodology of battery for electric automobile group cycle life.
Background technology
Along with socioeconomic growing, energy demand improves further, the cry of new energy technology is more and more higher, lithium ion battery because of its have that voltage is high, energy density is large, good cycle, self discharge are little and the outstanding advantages such as memory-less effect, are widely used in electric automobile field as drive energy.
Primary Study is carried out to battery life both at home and abroad, achieved interim achievement.Such as: based on the refined cell model of difference equation; Based on the analytic model of diffusion theory, can to any given load accurately predicting lithium-ions battery life-span.The current research to battery service life model is also in the elementary step, does not have systematic theory support, does not also produce the universal battery life model having and be generally worth.
Compare patent CN201410186038.2, introduction be the life prediction of monomer lithium ion battery, using with reality is all power brick difference to some extent in groups.In above disclosed patent, all that life prediction is carried out to cell, because batteries of electric automobile group has hundreds of or thousands of monomers to form, the aging effects factor of electric battery depends on the monomer that the performance of component units is the poorest, so simple cell life prediction can not on the battery pack.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of Forecasting Methodology of battery for electric automobile group cycle life, based on the test data of the Li-ion batteries piles of practical application, provide Life Prediction Model, can life-span of Accurate Prediction electric battery, greatly save the test period under the different test condition of car load or battery producer and expense, and the Li-ion batteries piles of same type all can according to this Forecasting Methodology.Employing high temperature circulation is tested, and accelerates the aging of battery, fast and effeciently can assess the cycle life performance of power brick, have very large using value.
Technical scheme of the present invention is: a kind of Forecasting Methodology of battery for electric automobile group cycle life, comprises the steps: step one: carry out normal capacity test to electric battery at normal temperatures, the actual standard capacity of record electric battery; Step 2: the test of dynamic stress Operation mode cycle is carried out to electric battery, after every 40-60 Operation mode cycle test terminates, return step one and carry out a normal capacity test, record standard volume test number of times K, if the actual capacity of 4-6 standard volume test continuously is all less than 80% of rated capacity C, then terminate to the loop test at temperature, normal capacity testing time K represents the battery cyclic life-span; Step 3: repeating step one to two, test the battery cyclic life-span under multiple temperature spot respectively, by being captured in the number of times K of testing standard capacity under condition of different temperatures, making T -1/ 10 -3-lnK curve, is extrapolated the cycle life of power battery pack at other temperature by fit equation.The concrete steps of described step one are: the first step, 1/3C steady current are discharged to battery power discharge cut-off voltage, leave standstill on request; Second step, 0.2C constant current charge are to cut-off voltage, then constant-voltage charge to electric current is 0.05C cut-off, leaves standstill on request; 3rd step, 1/3C steady current are discharged to cut-off voltage, leave standstill on request; Wherein, C is the rated capacity of electric battery.Described electric battery is ferrous phosphate lithium battery group, and the rated capacity of electric battery is 60Ah, and rated voltage is 330V.In described step 2 dynamic stress Operation mode cycle test have by condition: depth of discharge is 80%DOD, and the discharge cut-off voltage of electric battery is 295V, and charge cutoff voltage is 367V.In described step 2, a normal capacity test is carried out in every 50 dynamic stress Operation mode cycles test, and when the actual capacity of continuous 5 standard volume tests is all less than 80% of rated capacity C, loop test terminates.In described step 3, test temperature 10 DEG C, the cycle life of electric battery at 15 DEG C, 25 DEG C, 35 DEG C, 45 DEG C, fit equation is: lnKi=-7.453+3940/Ti (308K≤Ti < 333K), lnKi=12.25-1947/T (273K≤Ti < 308K), wherein: Ki is the battery cyclic life-span, Ti is the absolute temperature of working temperature.Also comprise step: utilize fit equation to estimate cycle life at 5 DEG C, 55 DEG C and actual test, and compare the validity determining evaluation method.
The present invention has following good effect: by acquisition time power brick cycle life data in groups, pass through data processing, obtain fit equation, can to current actual right Li-ion batteries piles Cycle life prediction, employing high temperature circulation is tested, accelerate the aging of battery, fast and effeciently can assess the cycle life performance of electric battery.
Accompanying drawing explanation
Fig. 1 is specific embodiment of the invention electric battery ambulatory stress test Operation mode cycle figure;
Fig. 2 is specific embodiment of the invention T -1/ 10 -3-lnK linear relationship chart.
Embodiment
Contrast accompanying drawing below, by the description to embodiment, the specific embodiment of the present invention is as the effect of the mutual alignment between the shape of involved each component, structure, each several part and annexation, each several part and principle of work, manufacturing process and operation using method etc., be described in further detail, have more complete, accurate and deep understanding to help those skilled in the art to inventive concept of the present invention, technical scheme.
The invention provides a kind of electric automobile power battery group Cycle life prediction method, comprise the following steps:
Step one: the Li-ion batteries piles of a rated voltage (> 300V), (25 ± 2 DEG C) carry out normal capacity test at normal temperatures:
The first step, 1/3C steady current are discharged to battery power discharge cut-off voltage, leave standstill on request;
Second step, 0.2C constant current charge are to cut-off voltage, then constant-voltage charge to electric current is 0.05C cut-off, leaves standstill on request;
3rd step, 1/3C steady current are discharged to cut-off voltage, leave standstill on request;
Wherein, C is the rated capacity of electric battery, the 3rd step release charge value be when time normal capacity, be designated as Ck (k is expressed as standard cycle number of times, k=0,1,2 ...).Electric battery is ferrous phosphate lithium battery group, and be made up of some cell connection in series-parallel, the rated capacity of electric battery is preferably 60Ah, and rated voltage is preferably 330V.
Step 2: respectively under different temperature environments, carry out dynamic stress working condition measurement (DST) to above-mentioned electric battery, testing procedure and operating mode are as table 1 and table 2:
Table 1:
Table 2:
DST operating mode has 20 steps, carries out loop test, be provided with cut-off condition by Variable power discharge and recharge: BMS (battery management system) monomer voltage, temperature protection, and electric battery stagnation pressure is protected, and depth of discharge is 80%DOD, till arriving first protection point.Described monomer discharge cut-off voltage is preferably 2.0V, and charge cutoff voltage is preferably 3.65V; Temperature < 60 DEG C; The discharge cut-off voltage of electric battery is preferably 295V, and charge cutoff voltage is preferably 367V.
Step 3: after every 50 DST Operation mode cycles, carry out normal capacity test, so circulate.If the discharge capacity of continuous 5 standard loop tests is all less than 80% of rated capacity, then loop test terminates, record standard volume test number of times, i.e. cycle life.
Step 4: test 10 DEG C respectively, 15 DEG C, 20 DEG C, 25 DEG C, 35 DEG C, the cycle life of electric battery under 45 DEG C of environment temperatures.Loop-around data is processed, in table 3:
Under table 3 different temperatures, cycle life
T,℃ Cycle index, K T —1(k)/10 -3 lnK
10 210 3.534 5.347
15 250 3.472 5.521
25 300 3.356 5.704
35 240 3.247 5.481
45 130 3.145 4.867
According to formula lnKi=a+b/Ti, make the linear relationship chart of lnK and 1/T, see Fig. 2, wherein a, b are coefficient.According to the operating characteristic of lithium ion battery, when low temperature or high temperature, charge-discharge performance impact is comparatively large, and life time decay accelerates.Therefore to the cycle life of the electric battery of 35 DEG C and above temperature, sectional linear fitting is carried out.Fit equation is as follows:
lnKi=-7.453+3940/Ti (308K≤Ti<333K)
lnKi=12.25-1947/Ti (273K≤Ti<308K)
Wherein: Ki is cycle life (number of times) under different temperatures, and Ti is the absolute temperature of working temperature.
Fit equation is utilized to estimate cycle life at 5 DEG C, 55 DEG C and actual test, and to compare the validity determining evaluation method, in table 4:
T,℃ Estimation cycle index, K Actual cycle number of times, K Error %
5 189 186 1.61%
55 95 93 2.15%
Table 4 estimates that cycle index and actual cycle number of times contrast
The cycle life calculated by above equation and actual test value very close, predict the outcome good, demonstrate the accuracy of Life Calculating Methods.Therefore to the estimation of power brick cycle life under different temperatures and can compare, also provide Data support for BMS (battery management system) control strategy simultaneously.Tested by power battery pack high-temperature cycle life, accelerate the aging of battery, fast and effeciently can assess the cycle life performance of electric battery.
Cycle life data provided by the invention, from the electric battery of practical application, can be directly used in and instruct BMS control strategy, have very great practical significance.
Above content is in conjunction with concrete embodiment further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deductions can also be made or replace, all should be considered as belonging to protection scope of the present invention.

Claims (7)

1. a Forecasting Methodology for battery for electric automobile group cycle life, is characterized in that, comprises the steps:
Step one: at normal temperatures normal capacity test is carried out to electric battery, the actual standard capacity of record electric battery;
Step 2: the test of dynamic stress Operation mode cycle is carried out to electric battery, after every 40-60 Operation mode cycle test terminates, return step one and carry out a normal capacity test, record standard volume test number of times K, if the actual capacity of 4-6 standard volume test continuously is all less than 80% of rated capacity C, loop test then at this temperature terminates, and normal capacity testing time K represents the battery cyclic life-span;
Step 3: repeating step one to two, test the battery cyclic life-span under multiple temperature spot respectively, by being captured in the number of times K of testing standard capacity under condition of different temperatures, making T -1/ 10 -3-lnK curve, is extrapolated the cycle life of power battery pack at other temperature by fit equation.
2. Forecasting Methodology according to claim 1, is characterized in that, the concrete steps of described step one are:
The first step, 1/3C steady current are discharged to battery power discharge cut-off voltage, leave standstill on request;
Second step, 0.2C constant current charge are to cut-off voltage, then constant-voltage charge to electric current is 0.05C cut-off, leaves standstill on request;
3rd step, 1/3C steady current are discharged to cut-off voltage, leave standstill on request;
Wherein, C is the rated capacity of electric battery.
3. Forecasting Methodology according to claim 2, is characterized in that, described electric battery is ferrous phosphate lithium battery group, and the rated capacity of electric battery is 60Ah, and rated voltage is 330V.
4. Forecasting Methodology according to claim 2, is characterized in that, in described step 2, the cut-off condition of dynamic stress Operation mode cycle test has: depth of discharge is 80%DOD, and the discharge cut-off voltage of electric battery is 295V, and charge cutoff voltage is 367V.
5. Forecasting Methodology according to claim 1, it is characterized in that, in described step 2, a normal capacity test is carried out in every 50 dynamic stress Operation mode cycles test, when the actual capacity of continuous 5 standard volume tests is all less than 80% of rated capacity C, loop test terminates.
6. Forecasting Methodology according to claim 1, it is characterized in that, in described step 3, test temperature 10 DEG C, the cycle life of electric battery at 15 DEG C, 25 DEG C, 35 DEG C, 45 DEG C, fit equation is: lnKi=-7.453+3940/Ti (308K≤Ti < 333K)
lnKi=12.25-1947/Ti (273K≤Ti<308K)
Wherein: Ki is the battery cyclic life-span, Ti is the absolute temperature of working temperature.
7. Forecasting Methodology according to claim 6, is characterized in that, also comprises step: utilize fit equation to estimate cycle life at 5 DEG C, 55 DEG C and actual test, compare the validity determining evaluation method.
CN201510155755.3A 2015-04-02 2015-04-02 Method for predicting cycle life of battery pack for electric car Pending CN104714189A (en)

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CN104991195A (en) * 2015-06-25 2015-10-21 中国电子科技集团公司第十八研究所 High-temperature accelerated storage test method for zinc-silver battery
CN105425156A (en) * 2015-11-06 2016-03-23 安徽江淮汽车股份有限公司 Cycle life testing method for power battery
CN105842630A (en) * 2016-05-05 2016-08-10 超威电源有限公司 Urban condition life detection formulating method for lead-acid battery used for electric vehicle
CN106093794A (en) * 2016-08-01 2016-11-09 深圳市电科电源股份有限公司 The high temperature service life accelerated test method of ferric phosphate lithium cell
CN106199445A (en) * 2016-07-14 2016-12-07 安徽轰达电源有限公司 Quickly charging battery cycle life detection method
CN106526486A (en) * 2016-08-30 2017-03-22 郑州轻工业学院 Construction method for lithium battery health life model
CN106950507A (en) * 2017-05-12 2017-07-14 国家电网公司 A kind of intelligent clock battery high reliability lifetime estimation method
CN107544033A (en) * 2016-09-05 2018-01-05 北京航空航天大学 Digital-analog fusion prediction method for remaining service life of lithium ion battery
WO2018054166A1 (en) * 2016-09-21 2018-03-29 蔚来汽车有限公司 Environment temperature-based battery cycle life test method
CN108732499A (en) * 2017-04-13 2018-11-02 中国电力科学研究院 A kind of method and system of detection cycle life of lithium ion battery
CN109904533A (en) * 2017-12-11 2019-06-18 奥动新能源汽车科技有限公司 The battery life analysis system and method for battery for electric automobile packet
CN109991557A (en) * 2018-11-30 2019-07-09 常州车之翼动力科技有限公司 Dynamic lithium battery cycle life detection method
CN110068409A (en) * 2019-04-11 2019-07-30 蜂巢能源科技有限公司 Lithium battery stress prediction method and apparatus
CN110244234A (en) * 2019-07-24 2019-09-17 中国科学院电工研究所 A kind of battery accelerating lifetime testing method
CN110416647A (en) * 2019-06-28 2019-11-05 国网天津市电力公司电力科学研究院 It is a kind of to enter network detecting method suitable for distribution terminal lead-acid accumulator
CN110470991A (en) * 2019-08-23 2019-11-19 江西优特汽车技术有限公司 A kind of power battery cycle life evaluating method
CN110658463A (en) * 2019-10-31 2020-01-07 上海派能能源科技股份有限公司 Method for predicting cycle life of lithium ion battery
CN111044927A (en) * 2019-12-25 2020-04-21 中国第一汽车股份有限公司 Power battery service life evaluation method and system
CN111366863A (en) * 2020-03-13 2020-07-03 上海应用技术大学 Lithium ion battery service life acceleration pre-judging method based on low-temperature circulation
CN112098113A (en) * 2020-08-28 2020-12-18 奇瑞新能源汽车股份有限公司 Method for testing protection capability of each system of electric automobile in high-temperature environment
CN112305439A (en) * 2019-07-31 2021-02-02 比亚迪股份有限公司 Battery life testing method and device and readable storage medium
CN112462275A (en) * 2019-09-09 2021-03-09 河南森源重工有限公司 Battery pack cycle life testing method
CN112599876A (en) * 2020-12-22 2021-04-02 江苏双登富朗特新能源有限公司 Regulation and control method for prolonging service life of lithium ion battery pack
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CN113761716A (en) * 2021-08-12 2021-12-07 惠州市豪鹏科技有限公司 Lithium ion battery cycle life prediction method and application thereof
CN117434453A (en) * 2023-12-21 2024-01-23 南昌大学 Method for detecting service life abnormality of lithium ion battery
CN112462275B (en) * 2019-09-09 2024-05-31 河南森源重工有限公司 Method for testing cycle life of battery pack

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Application publication date: 20150617