CN104694243B - A kind of preparation method of giving off a strong fragrance rapeseed oil - Google Patents

A kind of preparation method of giving off a strong fragrance rapeseed oil Download PDF

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CN104694243B
CN104694243B CN201510079377.5A CN201510079377A CN104694243B CN 104694243 B CN104694243 B CN 104694243B CN 201510079377 A CN201510079377 A CN 201510079377A CN 104694243 B CN104694243 B CN 104694243B
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rapeseed oil
vegetable seed
tempering
strong fragrance
giving
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CN104694243A (en
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满时勇
王晓平
樊思信
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Anhui Jiaqi Grain & Oil Engineering And Technology Co Ltd
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Anhui Jiaqi Grain & Oil Engineering And Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/06Production of fats or fatty oils from raw materials by pressing
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/02Pretreatment
    • C11B1/04Pretreatment of vegetable raw material
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/001Refining fats or fatty oils by a combination of two or more of the means hereafter
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/16Refining fats or fatty oils by mechanical means

Abstract

The invention discloses a kind of preparation methods of giving off a strong fragrance rapeseed oil.It includes the following steps:(1) tempering is soaked:Vegetable seed is sent into fogger, spray moisture content wetting is delivered to tempering in tempering device;(2) cigarette is raised in frying, except desulfuration glucoside decomposition product;(3) it squeezes and crude rapeseed oil is made;(4) crude rapeseed oil crystallized, filtered, obtain giving off a strong fragrance rapeseed oil.The preparation method of the present invention is simple to operation, does not need to add any chemical addition agent in preparation process, no waste water and gas pollution, giving off a strong fragrance rapeseed oil aromatic flavour obtained, total glucosinolate content is extremely low, and Residual oil is low in rape cake, and vegetable seed oil yield efficiency is high.

Description

A kind of preparation method of giving off a strong fragrance rapeseed oil
Technical field
The present invention relates to edible oil and fat processing technique field more particularly to a kind of preparation methods of giving off a strong fragrance rapeseed oil.
Background technology
Contain 4% or so glucosinolate in vegetable seed.Glucosinolate is under wet, heat condition, in myrosase Effect is lower to degrade, and resolves into isothiocyanates, thiocyanates, oxazolidine thione and nitrile compounds, is referred to as total sulfur glucoside, These decomposition products can inhibit the thyroid gland of animal to the absorption of iodine, lead to metabolic disorder, and have the smell for the people that chokes, therefore, Giving off a strong fragrance rape oil-pressing technique should remove above-mentioned decomposition product, make in the rapeseed oil after squeezing that total glucosinolate content is small, have The fragrance of pure, strong rapeseed oil.Giving off a strong fragrance rapeseed oil is in light brown yellow, clear, and aromatic flavour is pure expressed oil, and Refining process is not added with any chemical addition agent, and intrinsic liposoluble vitamin and other physiological activators are able in rapeseed oil Retain, nutrient component damages are small, to ensureing people's safe edible vegetable oil, meet the needs of people are to healthy edible grease, have It is significant.
At present, the production method of domestic giving off a strong fragrance rapeseed oil is that the vegetable seed after cleaning is directly fried seed in coal-fired directly fiery roller Frying, oil expression or the embryo piece for the vegetable seed after cleaning being rolled into 0.4mm thickness in machine enter back into directly fiery roller seeds frying machine Interior frying, oil expression, the giving off a strong fragrance rapeseed oil produced have the smell of one strong people that chokes, and the purpose of aromatic flavour is not achieved, Some harmful ingredients do not remove, and Residual oil height, oil yield efficiency are low in cake, cause the wasting of resources, in particular by The mode of heating of coal-fired directly fire generates exhaust emission environment, do not meet safely, the modern production code requirement carried out production strictly in line with rules and regulations.
A kind of simple Degumming method of giving off a strong fragrance rapeseed oil is disclosed in the prior art, but is covered and taken off using addition in this method The degummings such as soil, silicate, modified alta-mud adsorbent carries out degumming, has used chemical addition agent;It discloses again in the prior art A kind of novel rapeseed oil fumet and its application process in giving off a strong fragrance rapeseed oil is prepared use a variety of chemistry in this application method Substance synthesizes fumet with rapeseed oil mixing preparation into giving off a strong fragrance rapeseed oil, is equally added to chemical addition agent, belongs to chemical method; Therefore, at present, the prior art need it is a kind of it is new, harmful components can be removed and do not add chemical addition agent, physiological activity object Matter be able to retain, strong fragrance can be generated, non-environmental-pollution prepare giving off a strong fragrance rapeseed oil method replacement.
Invention content
In view of this, the present invention provides a kind of preparation method of giving off a strong fragrance rapeseed oil, and the preparation method is simple and practicable, prepares It is not required to add any chemical addition agent, no waste water, exhaust emission, giving off a strong fragrance rapeseed oil aromatic flavour obtained, oil yield efficiency in journey Height, total glucosinolate content is extremely low, and Residual oil is low in rape cake.
The present invention uses following technical scheme:
A kind of preparation method of giving off a strong fragrance rapeseed oil, includes the following steps:
1st, a kind of preparation method of giving off a strong fragrance rapeseed oil, which is characterized in that include the following steps:
(1) tempering is soaked:Vegetable seed is sent into fogger, spray moisture content wetting is delivered to tempering in tempering device;
(2) cigarette is raised in frying, except desulfuration glucoside decomposition product;
(3) it squeezes and crude rapeseed oil is made;
(4) crude rapeseed oil crystallized, filtered, obtain giving off a strong fragrance rapeseed oil.
Preferably, step (1) detailed process is:Vegetable seed is sent by screw conveyor in fogger, spray accounts for vegetable seed The moisture content of quality 5~18% is soaked, and the vegetable seed after wetting is delivered to 15~60min of tempering in tempering device, tempering temperature Be 30~60 DEG C, protein and phosphatide fully absorb moisture content in vegetable seed, after tempering the control of vegetable seed water content 15~ 20%.
Preferably, step (2) detailed process is:Vegetable seed after wetting tempering is delivered in horizontal seeds frying machine in damp and hot item Frying is heated under part makes vegetable seed generate strong fragrance, and the vegetable seed after frying is had the sulphur glucoside of penetrating odor using smoke machine removing is raised Decomposition product, the vegetable seed water content of Yang Yanhou is 2~3%.
Preferably, horizontal seeds frying machine uses conduction oil as heat medium, and the heating frying temperature is 130~180 DEG C, is added The time processed is propagandized hotly as 50~60min.
Present invention heating frying temperature can be 130 DEG C, 140 DEG C, 150 DEG C, 160 DEG C, 170 DEG C, 180 DEG C etc., and heating is fried Time processed can be 50min, 52min, 54min, 56min, 58min, 60min etc., and present invention heating frying temperature and time closes It is suitable, it not only improves vegetable seed and generates strong fragrance, improves oil yield efficiency and reduce total glucosinolate content, and reduce the energy to greatest extent Consumption.
Preferably, step (3) detailed process is:Frying is raised the vegetable seed after cigarette be delivered in 4 grades of squeezers squeeze be made Rape cake and crude rapeseed oil, rape cake resid amount≤6.0%, oil yield efficiency >=90%, Residual oil is low in rape cake, oil yield efficiency Crude rapeseed oil is isolated the dregs of fat by filter, isolates water content≤0.2% in the crude rapeseed oil of the dregs of fat by height, Impurity mass fraction≤0.2%, peroxide value≤5.0mmol/Kg.
Preferably, step (4) detailed process is:Crude rapeseed oil is pumped into crystallizing tank and is stirred, is passed through cooling water temperature, is tied Brilliant and progress first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water temperature, is crystallized, and is carried out Second of filtering, is made giving off a strong fragrance rapeseed oil.
Preferably, step (4) detailed process is:Crude rapeseed oil is pumped into crystallizing tank and is carried out by 10~15r/min rates Stirring is passed through cooling water and is cooled to 20~25 DEG C by 1.5~2 DEG C/min rates, growing the grain 8~for 24 hours with carry out first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water by 1 DEG C/min rates It is cooled to 10~15 DEG C, growing the grain 12~for 24 hours carries out second and filter that giving off a strong fragrance rapeseed oil, giving off a strong fragrance vegetable seed Water in oil quality is made Score≤0.2%, impurity mass fraction≤0.05%, acid value≤3.0mgKOH/g, peroxide value≤5.0mmol/Kg, phosphatide contain Amount≤50ppm, total glucosinolate content≤120ppm.
Beneficial effects of the present invention:The preparation method of giving off a strong fragrance rapeseed oil provided by the invention includes:(1) tempering is soaked:It will Vegetable seed is sent into fogger, and spray moisture content wetting is delivered to tempering in tempering device;(2) cigarette is raised in frying, is produced except desulfuration glucoside decomposes Object;(3) it squeezes and crude rapeseed oil is made;(4) crude rapeseed oil crystallized, filtered, obtain giving off a strong fragrance rapeseed oil.The present invention is used Wetting tempering and frying raise the synergistic effect of cigarette technique so that glucosinolate under wet heat condition, in the work of myrosase Isothiocyanates, thiocyanates, oxazolidine thione and nitrile compounds are resolved under, are separated raising cigarette process, are pressed It dissolves that total glucosinolate content in the oil is extremely low after squeezing, makes the rapeseed oil for finally squeezing out that there is pure, strong fragrance and flavour; Rapeseed is after wetting tempering fully absorbs moisture, and protein denaturation is thorough during frying so that intracellular emulsus knot Structure destroys, and protein reduces the compatibility of grease, and the channel of grease outflow increases, and Residual oil is down to≤6% in cake, oil yield efficiency High >=90%, the utilization of resources is abundant, and does not add chemical addition agent, polluted without waste water and gas.
Description of the drawings
Fig. 1 is the process flow chart of preparation method of the present invention.
Specific embodiment
The technical solution further illustrated the present invention in conjunction with the embodiments separately below.
Embodiment 1:The preparation method of the giving off a strong fragrance rapeseed oil of the present embodiment includes the following steps:
(1) tempering is soaked:The vegetable seed after cleaning is sent into fogger using screw conveyor, spray accounts for vegetable seed quality 5% moisture content is soaked, and the vegetable seed after wetting is delivered to tempering 20min in tempering device, tempering temperature is 30 DEG C, makes vegetable seed Middle protein and phosphatide fully absorb moisture content, and the vegetable seed water content after tempering is controlled 15~20%;
(2) cigarette is raised in frying:Vegetable seed after wetting tempering is delivered in horizontal conduction oil seeds frying machine, is warming up to 130 DEG C, Under wet heat condition, frying 60min is heated, vegetable seed generates strong fragrance, and the vegetable seed after frying is removed spinosity using smoke machine is raised Swash the sulphur glucoside decomposition product of smell, the vegetable seed water content of Yang Yanhou is 3%;
(3) liquefaction is squeezed:Frying is raised to the vegetable seed after cigarette and is delivered to the obtained rape cake of squeezing in 4 grades of squeezers and vegetable seed hair Crude rapeseed oil is isolated the dregs of fat by filter, isolates water content≤0.2% in the crude rapeseed oil of the dregs of fat by oil, Impurity mass fraction≤0.2%, peroxide value≤5.0mmol/Kg.
(4) crystallization filtering:Crude rapeseed oil is pumped into crystallizing tank and is stirred by 10r/min rates, be passed through cooling water by 1.5 DEG C/min rates are cooled to 20 DEG C, crystallize 8h and carry out first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water by 1 DEG C/min rates It is cooled to 10 DEG C, crystallizes 12h, carry out second and filter that giving off a strong fragrance rapeseed oil is made, water content in giving off a strong fragrance rapeseed oil≤ 0.2%, impurity mass fraction≤0.05%, acid value≤3.0mgKOH/g, peroxide value≤5.0mmol/Kg, content of phospholipid≤ 50ppm, total glucosinolate content≤120ppm.
Embodiment 2:The preparation method of the giving off a strong fragrance rapeseed oil of the present embodiment includes the following steps:
(1) tempering is soaked:Vegetable seed after cleaning is sent by screw conveyor in fogger, spray accounts for vegetable seed quality 10% moisture content is soaked, and the vegetable seed after wetting is delivered to tempering 40min in tempering device, tempering temperature is 50 DEG C, makes dish Protein and phosphatide fully absorb moisture content in seed, and vegetable seed water content is controlled 18~20%;
(2) cigarette is raised in frying:Vegetable seed after wetting tempering is delivered in horizontal conduction oil seeds frying machine, 150 DEG C is warming up to, adds Propagandize 55min processed hotly, vegetable seed generates strong fragrance, and the vegetable seed after frying is had the sulphur glucoside point of penetrating odor using smoke machine removing is raised Product is solved, the vegetable seed water content of Yang Yanhou is 2.5%;
(3) liquefaction is squeezed:Frying is raised to the vegetable seed after cigarette and is delivered to the obtained rape cake of squeezing in 4 grades of squeezers and vegetable seed hair Crude rapeseed oil is isolated the dregs of fat by filter, isolates water content≤0.2% in the crude rapeseed oil of the dregs of fat by oil, Impurity mass fraction≤0.2%, peroxide value≤5.0mmol/Kg.
(4) crystallization filtering:Crude rapeseed oil is pumped into crystallizing tank and is stirred by 12r/min rates, is passed through cooling water by 2 DEG C/min rates are cooled to 25 DEG C, growing the grain 16h and carry out first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water by 1 DEG C/min rates It is cooled to 12 DEG C, growing the grain 16h, carries out second and filter that giving off a strong fragrance rapeseed oil is made, water content in giving off a strong fragrance rapeseed oil≤ 0.2%, impurity mass fraction≤0.05%, acid value≤3.0mgKOH/g, peroxide value≤5.0mmol/Kg, content of phospholipid≤ 50ppm, total glucosinolate content≤115ppm.
Embodiment 3:The preparation method of the giving off a strong fragrance rapeseed oil of the present embodiment includes the following steps:
(1) tempering is soaked:Vegetable seed after cleaning is sent by screw conveyor in fogger, spray accounts for vegetable seed quality 18% moisture content is soaked, and the vegetable seed after wetting is delivered to tempering 60min in tempering device, tempering temperature is 60 DEG C, makes dish Protein and phosphatide fully absorb moisture content in seed, and vegetable seed water content is controlled 18~20%;
(2) cigarette is raised in frying:Vegetable seed after wetting tempering is delivered in horizontal conduction oil seeds frying machine, 180 DEG C is warming up to, adds Propagandize 50min processed hotly, vegetable seed generates strong fragrance, and the vegetable seed after frying is had the sulphur glucoside point of penetrating odor using smoke machine removing is raised Product is solved, the vegetable seed water content of Yang Yanhou is 2%;
(3) liquefaction is squeezed:Frying is raised to the vegetable seed after cigarette and is delivered to the obtained rape cake of squeezing in 4 grades of squeezers and vegetable seed hair Crude rapeseed oil is isolated the dregs of fat by filter, isolates water content≤0.2% in the crude rapeseed oil of the dregs of fat by oil, Impurity mass fraction≤0.2%, peroxide value≤5.0mmol/Kg.
(4) crystallization filtering:Crude rapeseed oil is pumped into crystallizing tank and is stirred by 15r/min rates, is passed through cooling water by 2 DEG C/min rates are cooled to 25 DEG C, crystallization for 24 hours with carry out first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water by 1 DEG C/min rates It is cooled to 15 DEG C, crystallization for 24 hours, carries out second and filters that giving off a strong fragrance rapeseed oil is made, water content in giving off a strong fragrance rapeseed oil≤ 0.2%, impurity mass fraction≤0.05%, acid value≤3.0mgKOH/g, peroxide value≤5.0mmol/Kg, content of phospholipid≤ 50ppm, total glucosinolate content≤110ppm.
Performance test:Examples 1 to 3 and common process are subjected to total glucosinolate content test, as a result such as following table.
Project Total glucosinolate content in rapeseed oil Total glucosinolate content in rape cake Leach total glucosinolate content in rapeseed dregs
Embodiment 1 120ppm 0.8% 0.3%
Embodiment 2 115ppm 0.7% 0.4%
Embodiment 3 110ppm 0.6% 0.3%
Common process 300~400ppm 1.5% 0.8%
As can be seen from the above table:Total glucosinolate content≤120ppm in giving off a strong fragrance rapeseed oil produced by the present invention, it is total in rape cake Glucosinolate content≤0.8% leaches total glucosinolate content≤0.4% in rapeseed dregs, far below glucosinolate content total in common process.
Giving off a strong fragrance rapeseed oil prepared by the present invention has the advantages that:
(1) aromatic flavour, harmful substance contents are few:The synergistic effect of cigarette technique is raised in used wetting tempering and frying, So that glucosinolate resolves into isothiocyanates, thiocyanates, oxazolidine under wet heat condition, under the action of myrosase Thioketones and nitrile compounds are separated raising cigarette process, and it is extremely low to dissolve total glucosinolate content in the oil after squeezing, makes finally to press The rapeseed oil come of squeezing out has pure, strong fragrance and flavour;
(2) Residual oil is low in rape cake, oil yield efficiency is high:After vegetable seed fully absorbs moisture, the albumen qualitative change during frying Property it is thorough so that intracellular creamy texture destroys, and protein reduces the compatibility of grease, and the channel of grease outflow increases, together When, the oil extruder gun pressure power of 4 grades of squeezings of use is high, reaches 28~30Mpa, down to≤6%, vegetable seed goes out Residual oil in rape cake Oily efficiency >=90%, the utilization of resources are abundant;
(3) good product quality:It is not added any chemical additives in preparation process, the giving off a strong fragrance rapeseed oil after refining is purer Just, total glucosinolate content≤120ppm;Total glucosinolate content≤0.8% of rape cake after squeezing, after routinely leaching, rapeseed dregs total sulfur Salidroside content≤0.4% reaches feed rapeseed dregs standard;
(4) no pollution, zero-emission:Production process does not have any discharge of wastewater, the colloidal substance after Polish filtration mainly into It is divided into phosphatide and grease, mixes with the rapeseed dregs after leaching and sold as feed, while improve the nutritive value of rapeseed dregs, do not have There is any solid waste.
It should be noted that and understand, in the spirit and scope for not departing from appended claims the claimed invention In the case of, various modifications and improvements can be made to the present invention of foregoing detailed description.It is therefore desirable to the technical solution of protection Range do not limited by given any specific exemplary teachings.
Applicant states that the present invention illustrates the detailed process equipment of the present invention and technological process by above-described embodiment, But the invention is not limited in above-mentioned detailed process equipment and technological processes, that is, it is above-mentioned detailed not mean that the present invention has to rely on Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, The addition of equivalence replacement and auxiliary element to each raw material of product of the present invention, selection of concrete mode etc. all fall within the present invention's Within protection domain and the open scope.

Claims (1)

1. a kind of preparation method of giving off a strong fragrance rapeseed oil, which is characterized in that include the following steps:
(1) tempering is soaked:Vegetable seed is sent into fogger, spray moisture content wetting is delivered to tempering in tempering device;
(2) cigarette is raised in frying, except desulfuration glucoside decomposition product;
(3) it squeezes and crude rapeseed oil is made;
(4) crude rapeseed oil crystallized, filtered, obtain giving off a strong fragrance rapeseed oil;
Step (1) detailed process is:By vegetable seed by screw conveyor be sent into fogger in, spray account for vegetable seed quality 5~ 18% moisture content is soaked, and the vegetable seed after wetting is delivered to 15~60min of tempering in tempering device, tempering temperature is 30~60 DEG C, the control of vegetable seed water content is 15~20% after tempering;
Step (2) detailed process is:Vegetable seed after wetting tempering is delivered in horizontal seeds frying machine and is added under wet heat condition The system propagandized hotly makes vegetable seed generate strong fragrance, and the sulphur glucoside that the vegetable seed after frying has penetrating odor using smoke machine removing is raised is decomposed production Object, the vegetable seed water content of Yang Yanhou is 2~3%;
The horizontal seeds frying machine uses conduction oil as heat medium, and the heating frying temperature is 130~180 DEG C, heats frying Time is 50~60min;
Step (3) detailed process is:Frying is raised the vegetable seed after cigarette be delivered in 4 grades of squeezers squeeze be made rape cake and Crude rapeseed oil is isolated the dregs of fat by crude rapeseed oil, rape cake resid amount≤6.0%, oil yield efficiency >=90% by filter, point Separate out water content≤0.2% in the crude rapeseed oil of the dregs of fat, impurity mass fraction≤0.2%, peroxide value≤ 5.0mmol/Kg;
Step (4) detailed process is:Crude rapeseed oil is pumped into crystallizing tank and is stirred by 10~15r/min rates, is led to Enter cooling water and be cooled to 20~25 DEG C by 1.5~2 DEG C/min rates, growing the grain 8~for 24 hours with carry out first time filtering;
Crude rapeseed oil after first time is filtered is pumped into again in secondary crystallization tank, is passed through cooling water and is cooled down by 1 DEG C/min rates To 10~15 DEG C, growing the grain 12~for 24 hours carries out second and filters that giving off a strong fragrance rapeseed oil is made, water content in giving off a strong fragrance rapeseed oil ≤ 0.2%, impurity mass fraction≤0.05%, acid value≤3.0mgKOH/g, peroxide value≤5.0mmol/Kg, content of phospholipid≤ 50ppm, total glucosinolate content≤120ppm.
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