CN104671830B - A kind of preparation method of water solublity red ceramic glaze - Google Patents
A kind of preparation method of water solublity red ceramic glaze Download PDFInfo
- Publication number
- CN104671830B CN104671830B CN201510125384.4A CN201510125384A CN104671830B CN 104671830 B CN104671830 B CN 104671830B CN 201510125384 A CN201510125384 A CN 201510125384A CN 104671830 B CN104671830 B CN 104671830B
- Authority
- CN
- China
- Prior art keywords
- ceramic glaze
- water solublity
- red ceramic
- red
- glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The preparation method that the invention discloses a kind of water solublity red ceramic glaze, it is characterized in that, the method has following processing step: in the reactor, the hexafluoro adding 8% ~ 18% by mass percentage closes zirconic acid ammonium, 1.0% ~ 2.0% sodium tripolyphosphate, 35% ~ 45% Zinc Fluosilicate, 10% ~ 20% ammonium fluoroborate, 10% ~ 24% cadmium sulfate, 6% ~ 16% sodium sulfide, 0.5% ~ 3% selenium powder, each component sum is absolutely, and ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof.The using method of water solublity red ceramic glaze: this water solublity red ceramic glaze is dissolved in temperature between 70 ~ 80 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 800 ~ 950 DEG C to finished product.
Description
Technical field
The invention belongs to ceramic technology field, particularly to the preparation method of a kind of water solublity red ceramic glaze, it belongs to ceramic paint, and it includes solubility auxiliary agent and toner.
Background technology
In China's magnificent art culture in several thousand, ceramic art is always in occupation of important status.And for ceramic art, glaze therein is again and the part of key.Generally, so-called ceramic glaze is a kind of homogeneous nature of glass thin layer covering ceramic body surface.For ceramic, ceramic glaze can improve serviceability, play decoration function etc..Redness signifies the ardent jump with life, and redness has significantly high decorative value, people can be allowed warmly to obtain, passion, hope, upwards, excitement, vivaciously, advance, luckiness, happy expression, bold and unrestrained, fighting will, revolution, magnificent, lucid and lively, beautiful impression.Redness enjoys people to like with gorgeous, luxurious, natural, the simple and unsophisticated sentiment of its uniqueness.Therefore, pure ' the red ceramic glaze that chemical stability is good is always up the heat subject of ceramic paint industry research to exploitation tone.Especially water miscible red ceramic glaze.
The domestic ceramics of China and construction sanitary ceramic product, from they yield, it is in No. 1 in the world, but major part product is still based on middle low gear, most important of which be exactly the decorative water product of product and material with international first water inlet condition than also having very big gap, be exactly as the colorant of ornament materials, glaze etc. specifically.Along with the development of Chinese national economy and going deep into of opening, the solution of people's problem of food and clothing, everybody to the quality of life it is also proposed that higher requirement, the environmental protection of ceramic product and be more exposed to problems such as Health Impacts pay attention to and pay close attention to.Glaze materials have high glaze unleaded, be that researcher is paid close attention to without cadmium frit, meet environment protection requirement.
Along with the raising day by day of people's living standard, the quality of ceramic ware for daily use, class are required also more and more higher, and ceramic glaze layer brightness is the main cause directly affecting product specification.Owing to current glaze formula and processing technology are all more outmoded, the ceramic ware for daily use surface fired is smooth not and bright, in order to improve domestic ceramics surface brightness, the exploitation kind of colour glaze covers all spectra of " red, orange, yellow, green, blue, blue, purple " with color, in addition, the colour glaze also constantly having multiple new application comes out.Low temperature pigment, middle temperature pigment and hard fire colour can be divided into according to the firing temperature difference that glaze materials is suitable for, be that product not only adaptability is wider, and rare talent is bright-colored.
Also comparing of glaze materials research is many, a kind of overglaze cobalt blue pigment for ceramic and preparation method disclosed in Chinese patent CN1151989C, it is characterised in that have the body pigment of 100 parts of weight and the compound colour generation auxiliary agent mixed grinding of 0.1 ~ 10 part of weight to form；The pigment tone dark of the present invention, Blues are big, chemical stability good, thermal coefficient of expansion is suitable, fired temperature 750 ~ 850 DEG C, glossiness 85 ~ 110；A kind of high-temp-resistant cadmium sulfoselenide crimson pigment for ceramic glaze and manufacture method thereof disclosed in Chinese patent CN1183205C, it is characterized in that, the percentage by weight that this cadmium sulfoselenide crimson pigment comprises raw material is: lithium fluoride 0.5 ~ 3.0%, sodium chloride 0.5 ~ 3.0%, tantalum pentoxide 0.1 ~ 30%, sodium hydroxide 0.5 ~ 3.0%, cadmium sulfoselenide 15 ~ 35%, zirconium oxychloride 10 ~ 35%, silicic acid 10 ~ 35%.The microwave sintering method of a kind of coated superfine sulphide selenide cadmium red pigment for ceramic glaze disclosed in Chinese patent CN102167624B, it is characterized in that adopting by the cadmium sulfoselenide split of Silica-coated, and add 0.02 ~ 0.05% sodium hexameta phosphate or OP-10 dispersant or dodecylbenzene sodium sulfonate before sintering, adopt microwave sintering.A kind of high glaze domestic ceramics glaze and preparation method thereof disclosed in Chinese patent CN102515860B, it is characterized in that the component that described high glaze domestic ceramics glaze is counted by weight percentage by down forms: potash feldspar 37 ~ 38%, Kaolin 15 ~ 16%, brium carbonate 4.5 ~ 6%, lanthanum carbonate 1.5 ~ 2.0% lithium carbonate 1.6 ~ 18%, zinc oxide 8 ~ 10%, zirconium oxide 3 ~ 4%, phosphorus pentoxide 3 ~ 4%, quartz 22 ~ 24%.In each raw material co-grinding of component formula ratio, carry out wet ball mill, obtain glaze slip；Then deironing, sieves, and old obtains.Traditional ceramic glaze is formed into slurry mostly, then uniformly imposes on biscuit and is sintered, and this method is complex process when preparing the slurry of glaze, is coated onto on biscuit to require visibly homogeneous, and technique is also more complicated.The application prepare a kind of glaze materials be can dissolve with in water, uniformly spray with aerosol apparatus and biscuit is sintered, can forming bright and clean one layer of beautiful enamel at ceramic surface, using method is simple, chemical stability good, changes the technical process of the slurry of original ceramic glaze.
Summary of the invention
The order of the present invention is to provide the water miscible red ceramic glaze of a kind of energy, the hardness improving glaze and glossiness, improves preparation method and the technique of the water solublity red ceramic glaze of pottery glossiness；
The purpose of the present invention is achieved through the following technical solutions.
A kind of preparation method of water solublity red ceramic glaze, it is characterised by that the method has following processing step: in the reactor, the hexafluoro adding 8% ~ 18% by mass percentage closes zirconic acid ammonium, 1.0% ~ 2.0% sodium tripolyphosphate, 35% ~ 45% Zinc Fluosilicate, 10% ~ 20% ammonium fluoroborate, 10% ~ 24% cadmium sulfate, 6% ~ 16% sodium sulfide, 0.5% ~ 3% selenium powder, each component sum is absolutely, ground and mixed is uniform, obtaining water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof.
In the preparation method of a kind of water solublity red ceramic glaze, described sodium sulfide is the sodium sulfide containing 9 water of crystallization.
In the preparation method of a kind of water solublity red ceramic glaze, described sodium sulfide: cadmium sulfate: the mol ratio of selenium powder optimum is 3:5:1.
The using method of a kind of water solublity red ceramic glaze that the present invention is obtained: this water solublity red ceramic glaze is dissolved in temperature between 70 ~ 80 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 800 ~ 950 DEG C to finished product.
The present invention compared with the prior art, has the advantage that and beneficial effect:
(1) present invention obtains water solublity red ceramic glaze, be characterized in that water miscible spraying is convenient, it is to avoid traditional ceramic glaze is formed into the loaded down with trivial details technical process of slurry mostly.
(2) present invention obtains water solublity red ceramic glaze, form owing to water solublity red ceramic glaze is closed the chemical compositions such as zirconic acid ammonium, ammonium fluoroborate and Zinc Fluosilicate by the hexafluoro of fluoride ion, molten can being integrated with the silicate in the biscuit of pottery, so enamel has, glossiness is good, chemical stabilization, lovely luster.
(3) present invention obtains water solublity red ceramic glaze, and preparation technology is simple, and condition is easily controllable, and production cost is low, it is easy to industrialized production.
Detailed description of the invention
Embodiment 1
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 12g hexafluoro and closes zirconic acid ammonium, 1.0g sodium tripolyphosphate, 40g Zinc Fluosilicate, 15g ammonium fluoroborate, 18g cadmium sulfate, 12g sodium sulfide, 2g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 75 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 850 DEG C to finished product.
Embodiment 2
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 8g hexafluoro and closes zirconic acid ammonium, 2g sodium tripolyphosphate, 45g Zinc Fluosilicate, 20g ammonium fluoroborate, 15g cadmium sulfate, 9g sodium sulfide, 1g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 70 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 800 DEG C to finished product.
Embodiment 3
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 11g hexafluoro and closes zirconic acid ammonium, 1.0g sodium tripolyphosphate, 36g Zinc Fluosilicate, 10g ammonium fluoroborate, 24g cadmium sulfate, 16g sodium sulfide, 2g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 80 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 900 DEG C to finished product.
Embodiment 4
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 18g hexafluoro and closes zirconic acid ammonium, 2.0g sodium tripolyphosphate, 44g Zinc Fluosilicate, 20g ammonium fluoroborate, 10g cadmium sulfate, 6g sodium sulfide, 0.5g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 75 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 950 DEG C to finished product.
Embodiment 5
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 10g hexafluoro and closes zirconic acid ammonium, 1.5g sodium tripolyphosphate, 42g Zinc Fluosilicate, 18g ammonium fluoroborate, 16g cadmium sulfate, 11g sodium sulfide, 1.5g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 80 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 900 DEG C to finished product.
Embodiment 6
The preparation method of a kind of water solublity red ceramic glaze, in the reactor, is separately added into 15g hexafluoro and closes zirconic acid ammonium, 1.0g sodium tripolyphosphate, 38g Zinc Fluosilicate, 16g ammonium fluoroborate, 20g cadmium sulfate, 8g sodium sulfide, 2g selenium powder, ground and mixed is uniform, obtains water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and wants sealed damp-proof；Its using method: this water solublity red ceramic glaze is dissolved in temperature between 70 DEG C in hot water, saturated solution, with aerosol apparatus by the solution even spraying of water solublity red ceramic glaze to the biscuit of pottery, through the high-temperature firings of 880 DEG C to finished product.
Embodiment 7
The finished product that water solublity red ceramic glaze prepared by embodiment 1 to embodiment 6 is applied on biscuit of ceramics preparation carries out technical specification test, and result is as follows:
(1) sintering temperature: 800 ~ 950 DEG C；
(2) glossiness: between 100 ~ 110；
(3) chemical stability:
Acid resistance test: finished product at 25 ± 2 DEG C, mass percentage concentration be 4% acetum in soak 48 hours, thing corrode vestige；
Alkali resistance test: finished product at 50 ± 2 DEG C, mass percentage concentration be 1% sodium carbonate liquor in soak 48 hours, thing corrode vestige；
(4) heat stability experiment: be placed in circuit by finished product, be raised to 200 DEG C from room temperature, be incubated 20 minutes, puts into rapidly in 25 DEG C of water, takes out and dry after 10 minutes, and color lump is without temperature shock crackle；
(5) linear expansion coefficient: 6.0 ~ 7.0 × 10-6/℃。
Claims (3)
1. the preparation method of a water solublity red ceramic glaze, it is characterized in that, the method has following processing step: in the reactor, the hexafluoro adding 8%～18% by mass percentage closes zirconic acid ammonium, 1.0%～2.0% sodium tripolyphosphate, 35%～45% Zinc Fluosilicate, 10%～20% ammonium fluoroborate, 10%～24% cadmium sulfate, 6%～16% sodium sulfide, 0.5%～3% selenium powder, each component sum is absolutely, ground and mixed is uniform, obtain water solublity red ceramic glaze, obtained water solublity red ceramic glaze plastic is packed, and want sealed damp-proof.
2. the preparation method of a kind of water solublity red ceramic glaze according to claim 1, it is characterised in that described sodium sulfide is the sodium sulfide containing 9 water of crystallization.
3. the water solublity red ceramic glaze prepared by preparation method of a kind of water solublity red ceramic glaze according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510125384.4A CN104671830B (en) | 2015-03-23 | 2015-03-23 | A kind of preparation method of water solublity red ceramic glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510125384.4A CN104671830B (en) | 2015-03-23 | 2015-03-23 | A kind of preparation method of water solublity red ceramic glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104671830A CN104671830A (en) | 2015-06-03 |
| CN104671830B true CN104671830B (en) | 2016-06-29 |
Family
ID=53307483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510125384.4A Expired - Fee Related CN104671830B (en) | 2015-03-23 | 2015-03-23 | A kind of preparation method of water solublity red ceramic glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104671830B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN102584342A (en) * | 2012-01-13 | 2012-07-18 | 南京工业大学 | Efficient energy-saving preparation method of ceramic coating pigment |
-
2015
- 2015-03-23 CN CN201510125384.4A patent/CN104671830B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN102584342A (en) * | 2012-01-13 | 2012-07-18 | 南京工业大学 | Efficient energy-saving preparation method of ceramic coating pigment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104671830A (en) | 2015-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101759441B (en) | Ceramic glaze and preparation process thereof | |
| CN101786904B (en) | Color-changing glaze for metallic luster ceramics and preparation method thereof | |
| CN104130024B (en) | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile | |
| CN102936156B (en) | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof | |
| CN106830681B (en) | A kind of compound furnace transmutation glaze glaze, compound furnace transmutation glaze pottery and preparation method thereof | |
| CN101372422B (en) | In-glaze decoration method for bright red glazed ceramic | |
| CN106082656B (en) | The preparation method of bluish white glaze under a kind of oxidizing atmosphere | |
| CN106145733B (en) | A kind of burning colorful sand and its preparation process | |
| CN101973788B (en) | Preparation method of phase-separation peacock blue glaze | |
| CN103896634A (en) | High-temperature domestic porcelain metallic bright glaze and product decorated by same | |
| CN106064888B (en) | The preparation method of pottery celeste glaze is imitated under a kind of oxidizing atmosphere | |
| CN106565092A (en) | Lightweight low-temperature fancy golden silk white glazed porcelain and manufacturing process | |
| CN105776861A (en) | Bright red nanometer glaze slip for ceramic sanitary wares as well as preparation method and application of bright red nanometer glaze slip | |
| CN107032832A (en) | A kind of Ceramic Tiles with color changeable effect and preparation method thereof | |
| CN105130193A (en) | Low-temperature matte reaction glaze and production method thereof | |
| CN103980005B (en) | Preparation method of blue-and-white material with Kangxi blue-and-white color development effect and blue-and-white porcelain product decorated by blue-and-white material | |
| CN106396740A (en) | Black gold sand glaze porcelain, and preparation method thereof | |
| CN101973787B (en) | Method for preparing split-phase coloring iron black glaze | |
| CN102515864A (en) | Gold crystal glaze domestic ceramic glaze material | |
| CN102617188B (en) | Method for preparing split-phase black fancy glaze by utilizing industrial slag | |
| CN108892381A (en) | A kind of preparation method of seven color pearl glaze and seven color pearl glazes | |
| CN104671831B (en) | A kind of preparation method of water-soluble black ceramic glaze | |
| CN104671830B (en) | A kind of preparation method of water solublity red ceramic glaze | |
| CN102010232A (en) | Building ceramic aventurine glaze and preparation method thereof | |
| CN104944906B (en) | A kind of color porcelain and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160629 Termination date: 20200323 |