CN104649625A - Pre-cured alkali-activated inorganic coating material - Google Patents
Pre-cured alkali-activated inorganic coating material Download PDFInfo
- Publication number
- CN104649625A CN104649625A CN201310631603.7A CN201310631603A CN104649625A CN 104649625 A CN104649625 A CN 104649625A CN 201310631603 A CN201310631603 A CN 201310631603A CN 104649625 A CN104649625 A CN 104649625A
- Authority
- CN
- China
- Prior art keywords
- agent
- indication
- precuring
- sodium
- coating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a pre-cured alkali-activated inorganic coating material, which is applied to the repair and protection of outside surfaces of underground spaces and buildings, and particularly applicable to the surface repair and protection of exterior walls, basements, water conservancy projects, tunnels, bridges, highways, docks and pools. According to the invention, through a pre-curing process, the alkali-activated coating material is more convenient to use, and pre-cured more fully; and the pre-curing process refers to a step-by-step curing process, and in the first curing, an alkali-activator is not completely put, so that the pre-curing is performed at low alkalinity, therefore, the pre-curing can be gradually performed in two steps or multiple steps.
Description
Technical field
The present invention relates to a kind of precuring alkalis excited inorganic coating material, for reparation and the protection of the underground space, outer surface of building, be particularly useful for exterior wall, vault, hydro project, tunnel, bridge, highway, harbour, the surface reconditioning in pond and protection, belong to building material field.
Background technology
Soil polywater mud is the novel alkali-activated carbonatite gelling material of a class that eighties of last century is developed by French JDavidovits the end of the seventies, it refers to that by chainotte (metakaolin is main), industrial residue etc. be main raw material, is formed under the effect of alkali-activator.Sial oxygen compound in the mineral of the poly-cement raw material of soil experienced by one and defines the structure of some natural mineral in the similar earth's crust by the process of depolymerization to repolymerization, is the novel gelled material of excellent durability.Many mineral or mineral compound can have pozzolanic activity or latent hydraulicity after high-temperature calcination, such as kaolin has good activity after the calcining of 500-900 degree, and alkali-activated carbonatite and the gelling material based on alkali-activated carbonatite are referred to as alkali-activated carbonatite gelling material.The remarkable advantage of alkali-activated carbonatite gelling material is very firm and durable with the bonding of coagulation soil property matrix, therefore can not produce the problems such as disengaging, peeling, warpage, therefore may be used for reparation and the protection on coagulation soil property surface.
Application number be 201010299679.0 name be called that the patent of " a kind of bi-component environmental-protecting inorganic polymer coating material and preparation method thereof " is a kind of formula of typical alkali-activated carbonatite gelling material, two-part formulations in that patent, solid part is a component, liquid portion is another component, and its benefit is:
1, batching is convenient, directly solid part is mixed, then liquid and thickening material are mixed just.
2, almost there is no the restriction in storage time, because alkali-activator is separated with other material, therefore can not solidify because of mixed.
3, manufacturing technology is simple.
The shortcoming of this technology is:
1, mixing process before the use requires to stir very abundant, otherwise some does not have well-mixed metakaolin, accelerator for hardening to lump, and forms thicker particle, makes coating uneven.
2, the depolymehzation process of general metakaolin needs a few hours, and need slaking before therefore using, this waiting process wastes the working hour.
Current existing alkali-activated carbonatite coating material all adopts the technology of this disposable slaking, does not therefore need before a kind of use of exploitation to wait for and ensure that slaking sufficient alkali-activated material coating material is necessary.
Summary of the invention
The present invention is to improve prior art, by precuring process, make the use of alkali-activated carbonatite coating material convenient, and slaking is more abundant, so-called precuring process refers to the process of substep slaking, all alkali-activators are not dropped into during first time slaking, precuring is carried out at lower basicities, and precuring can even repeatedly progressively go forward one by one in two steps.
The present invention realizes in the following manner:
A kind of precuring alkalis excited inorganic coating material, is made up of precuring component, auxiliary material and secondary excitation agent, it is characterized in that:
The exceptionally precuring component that dewaters also comprises:
The alkali-activator (in solid content) of 1 ~ 50 part;
The gelling base material of 20 ~ 120 parts.
Secondary excitation agent comprises:
The alkali-activator (in solid content) of 1 ~ 50 part.
Accessory package contains:
The gelling base material of 0 ~ 60 part;
The hydrophober of 0 ~ 60 part;
The tinting material of 0 ~ 20 part;
The swelling agent of 0 ~ 80 part;
The accelerator for hardening of 0 ~ 50 part;
The filler of 5 ~ 250 parts;
The auxiliary agent of 0 ~ 50 part.
Precuring component and secondary excitation agent isolation are placed, the placement of auxiliary material one of in the following manner:
(1) place separately;
(2) all mix with precuring component;
(3) all mix with secondary excitation agent;
(4) part mixes with precuring component;
(5) part mixes with secondary excitation agent.
The alkali-activator of indication refers at least one in alkaline silicate, alkaline phosphate, alkalimetal oxide, alkali, carbonate, vitriol, villaumite, alkali-activator can be single, also can be that multiple exciting agent is combined with each other, compare single exciting agent, the stimulation effect of compound activator advantageously, vitriol and villaumite can promote stimulation effect, in system, add these materials makes itself and other alkali-activator acting in conjunction improve stimulation effect, alkali-activator can be liquid, also can be solid.A part for alkali-activator is used for precuring, and another part is used for secondary excitation agent, and this is the alkali concn in order to reduce precuring process.
The gelling base material of indication refers at least one had in pozzolanic activity material, latent hydraulicity material, amorphous silicon aluminum oxide.Gelling base material can be through calcining, also can without calcining.Gelling base material can whole precurings, also can part precuring, therefore the part gelling base material of not precuring are attributed in auxiliary material.
The hydrophober of indication refers to the lyophobic dust of dispersion low surface energy in the coating, and this lyophobic dust intercepts the approach of capillary percolation, and lyophobic dust derives from following one of two things: the reaction product of hydrophober self and hydrophober.
The tinting material of indication refers to the material with corresponding color.
The swelling agent of indication refers to the material producing volumetric expansion effect in process of setting.
The accelerator for hardening of indication refers to the material improving coating curing progress.
The filler of indication is packing volume, reduces the material shrinking, adjust surface tactile sensation.
The auxiliary agent of indication refers to the auxiliary agents improving coating serviceability.
Secondary excitation agent can be aqueous, also can be dry powder.
Above-mentioned component does not list moisture separately, mainly because the material such as water glass, sodium hydroxide is general all with moisture, can directly utilize, also consider that the denseness difference required for the difference of different application occasion and raw material granularity is very large, also consider that operator can be suitable when coating application interpolation moisture is with the surface of applicable different water-intake rate in addition, thus randomness is larger.
Precuring alkalis excited inorganic coating material of the present invention, the alkali-activator of indication can be at least one in water glass, potassium silicate, lithium silicate, sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium carbonate, salt of wormwood, Quilonum Retard, sodium phosphate, potassiumphosphate, Trilithium phosphate.
Precuring alkalis excited inorganic coating material of the present invention, the gelling base material of indication can be at least one in metakaolin, kaolin, flyash, coal gangue, slag, slag, blast furnace granulated slag, phosphorus slag, slag, cinder, pure aluminium silicate, calcined clay, red mud, industrial tailings.
Precuring alkalis excited inorganic coating material of the present invention, the hydrophober of indication can be at least one in potassium methyl silicate, sodium methyl silicate, methyl siliconic acid lithium, methyl-silicone oil, silicone oil, organosilicon moisture repellent, polysiloxane hydrophober, silylation hydrophober, NANOTHIXB1490 nano level hydrophober, Kind of Modified Polyvinyl Alcohol Based Waterborne Water-Repellent, HEA polymer hydrophober, powder hydrophober, emulsion-type hydrophober, calcium stearate.Except above-mentioned conventional hydrophober, on market, the kind of hydrophober is very many, is difficult to enumerate one by one, generally speaking select the standard of hydrophober be alkaline-resisting, good dispersity, good endurance, hydrophobic nature are strong.
Hydrophober can directly be added in coating, also can brush again on coating after coating application completes, it is made to penetrate into coat inside, preferably first directly be added in coating, if again at coatingsurface brushing one deck after coating is solidified, make it penetrate into coat inside, being fitted together between such molecule is more abundant, but cost also can be higher.
The kind of hydrophober is very complicated, and the addition of some material is very large, and effective adding proportion is about 15%, and effective adding proportion of some kind is about 0.005%, and the effect that reach must be determined according to the strain test of hydrophober.
Precuring alkalis excited inorganic coating material of the present invention, the tinting material of indication can be at least comprise the one in white pigment, black pigment, pigment dyestuff, mineral dye, high-visibility pigment, phosphorescent pigment, pearly pigment, dyestuff, nonferrous metal oxides pigment.
On market, the kind of tinting material is very many, can select on demand to adopt, because coating generally needs a point multilayer repeatedly to brush, therefore also can consider that bottom is without tinting material, uses tinting material at surface layer.
Precuring alkalis excited inorganic coating material of the present invention, the swelling agent of indication can be at least comprise the one in alumina, bauxite, dehydrated gyp-, aluminium hydroxide, aluminum oxide, zinc oxide, magnesium oxide, alumite plumping agent, sulphoaluminate expander, calcium oxide one calcium sulphoaluminate composite expanding agent, HEA swelling agent, UEA swelling agent, phosphogypsum.
Precuring alkalis excited inorganic coating material of the present invention, the accelerator for hardening of indication can be at least comprise the one in carbonate, metal oxide, calcium cpd, fluorine cpd, gypsum, light calcium carbonate, water-ground limestone, unslaked lime, white lime, sierozem power, calcium sulfate, condensation of aluminum phosphate, silicon phosphate, wollastonite, Sodium Silicofluoride, calcium phosphate.
Precuring alkalis excited inorganic coating material of the present invention, the filler of indication can be at least comprise metallic particles, inorganic particle, metal oxide, breeze, stone powder, mica, foliated glass powder, flaky pottery powder, quartz, industrial residue particle, coarse aggregate, cement, cement clinker, silicon ash, nanometer powder, rice hull ash, silt deposit, perlite, glass-cermic powder, zeolite, hollow ceramic microspheres, talcum powder, carbonate, calcium cpd, silicon powder, organosilicon, silane, siloxanes, resin monomer, resin, plastic grains, rubber, wax material, grease, emulsion, water soluble resin, latex powder, polyester fiber, polypropylene fibre, cellulosic fibre, steel fiber, glass fibre, monfil, PVA fiber, carbon fiber, mineral fibre, at least one in ceramic fiber.
Here indication fiber can be staple fibre, needle-like material, fiber dust, reticulin fiber, cloth, non-woven fabrics etc.
Appropriateness can be added with organic polymer in filler, except above-mentioned conventional organic polymer, on market also have countless organic polymer kind, but in general with alkali resistant, good dispersity for the most important condition.
The particle diameter of filler can determine the texture of coating, such as can make the coating of sand wall sense with coarse grained filler, can make the better coating of smooth finish with fine particle filler, and the organic water-insoluble filler of fusion can make art coatings.
Precuring alkalis excited inorganic coating material of the present invention, the auxiliary agent of indication at least comprises the one in flow agent, film coalescence aid, thickening material, retardant, accelerating chemicals, water-holding agent, softening agent, water reducer, defoamer, dispersion agent, tensio-active agent, air entrapment agent, whipping agent, coupling agent.
Precuring alkalis excited inorganic coating material of the present invention, the flow agent of indication can be at least the one in glassiness microballon powder, urethane flow agent;
Precuring alkalis excited inorganic coating material of the present invention, the film coalescence aid of indication can be at least the one in polyvinyl alcohol, EDTA tetra-sodium, EDETATE SODIUM, sodium salicylate, sodium polyacrylate, sodium hypophosphite, Seconary Alkane Sulphonate Sodium, sodium vinyl sulfonate, sodium methylate, sodium tert-butoxide, film coalescence aid can form very thin protective layer at coatingsurface, prevents the evaporation that moisture is too fast;
Precuring alkalis excited inorganic coating material of the present invention, the thickening material of indication can be at least the one in wilkinite, attapulgite, diatomite, red mud, Mierocrystalline cellulose, cellulosate;
Precuring alkalis excited inorganic coating material of the present invention, the retardant of indication can be at least the one in tartrate, citric acid, oxalic acid, acetic acid, lead nitrate, zinc nitrate, sodium-chlor, bariumchloride, Sodium Tetraborate, water-soluble hydramine, chromium cpd;
Precuring alkalis excited inorganic coating material of the present invention, the accelerating chemicals of indication can be calcium formiate;
Precuring alkalis excited inorganic coating material of the present invention, the water-holding agent of indication can be at least the one in carbohydrate, cellulosic fibre, sodium cellulose glycolate;
Precuring alkalis excited inorganic coating material of the present invention, the softening agent of indication can be molasses modifications;
Precuring alkalis excited inorganic coating material of the present invention, the water reducer of indication can be at least the one in sulfamate, naphthalene water reducer, polycarboxylate water-reducer;
Precuring alkalis excited inorganic coating material of the present invention, the defoamer of indication can be at least the one in mineral oil defoaming agent, silicone antifoam agent;
Precuring alkalis excited inorganic coating material of the present invention, the dispersion agent of indication can be at least the one in polyacrylic dispersion agent, organosilicone spreading agent;
Precuring alkalis excited inorganic coating material of the present invention, the tensio-active agent of indication can be Dodecyl trimethyl ammonium chloride;
Precuring alkalis excited inorganic coating material of the present invention, the air entrapment agent of indication can be aluminium powder;
Precuring alkalis excited inorganic coating material of the present invention, the whipping agent of indication can be at least the one in hydrogen peroxide, peroxide water;
Precuring alkalis excited inorganic coating material of the present invention, the coupling agent of indication can be at least the one in silane coupling agent, organo-silicon coupling agent, powder silane coupling agent, boric acid ester coupler.
Above-mentioned different auxiliary agent can select several use, also can all use, and even can not make used additives in some occasion.
Precuring component can start packing soon in firm mixing, also can the packing again of ageing for some time, and after its tangible packing, it still can continue natural ageing, and the auxiliary material adding precuring component can add at the very start, also can add later.
Precuring alkalis excited inorganic coating material can be bi-component package, also can be polycomponent packaging, also can on-the-spotly before construction modulate, on-the-spot precuring.
Precuring alkalis excited inorganic coating material of the present invention, can also comprise the secondary excitation agent being no less than two parts, and in manufacture and use procedure, gradation adds, and can realize repeatedly preexciting like this.
Present invention also offers a kind of manufacture method of precuring alkalis excited inorganic coating material, comprise the following steps:
(1) precuring component is prepared: by batching each in precuring component by proportioning mixing, stir, carry out precuring, then packing.
Precuring is mainly for the gelling base material in precuring component, and the auxiliary material added in precuring component can add together, also can add later.
(2) secondary excitation agent is prepared: by each component in secondary excitation agent by proportioning mixing, stir, packing.
Step 3 is entered when there being the auxiliary material of packaging separately,
(3) auxiliary material is prepared: mixed by proportioning by each component of the auxiliary material packed separately, stir, packing.
(4) in ratio according to claim 1, all components are mixed before using, stir.
Precuring alkalis excited inorganic coating material of the present invention can make the use of alkali-activated carbonatite coating material convenient, and slaking is more abundant, and quality of forming film is stablized.
Embodiment
Embodiment 1
The sodium silicate solution (concentration 30%, modulus 2.5) of 45 grams, 3.5 grams of sodium hydroxide, 55 grams of metakaolins, 20 grams of mica powders, 3 grams of short glass fibers, 10 grams of silica sands, 2 grams of methyl siliconic acid potassium solutions (content 20%), 3 grams of redispersable latex powders.
Precuring component has: sodium silicate solution, methyl siliconic acid potassium solution, 1 gram of sodium hydroxide, metakaolin.
Secondary excitation agent has: 2.5 grams of sodium hydroxide.
Accessory package contains: mica powder, short glass fiber, silica sand, redispersable latex powder.
Said ratio can by two component packing:
First component: precuring component.
Component B: secondary excitation agent, auxiliary material.
Manufacturing processed:
(1) precuring component is prepared: by mixing of respectively preparing burden in precuring component, stir, carry out precuring, then packing.
(2) secondary excitation agent is prepared: by the sodium hydroxide in secondary excitation agent and whole supplementary material mixing, stir, packing.
(3) by the first and second component mixing before using, stir.
Said ratio also can by three component packing:
First component: precuring component.
Component B: auxiliary material.
Third component: secondary excitation agent.
This three component can be contained in same pail pack, first component is placed on bottom, component B is placed on centre, third component is placed on topmost, owing to there being component B to isolate, the third component can be packed separately, above directly piling up, can certainly use the packing of small packages mode, this Method compare is applicable to market sale.
Its manufacturing processed:
(1) precuring component is prepared: by mixing of respectively preparing burden in precuring component, stir, carry out precuring, then packing.
(2) secondary excitation agent is prepared: by independent for the sodium hydroxide in secondary excitation agent packing.
(3) auxiliary material is prepared: by each component of auxiliary material by proportioning mixing, stir, packing.
(4) by the first and second the third each component mixing before using, stir.
Above-mentioned coating can be used as the protective coating of exterior wall and concrete surface, is particularly useful for the surfacecti proteon in bridge, tunnel.
Embodiment 2
The potassium silicate solution (concentration 35%, modulus 2.0) of 42 grams, 4.2 grams of sodium carbonate, 30 grams of metakaolins, 2 grams of slags, 5 grams of flyash, 18 grams of mica powders, 3 grams of calcium carbonate, 5 grams of glass fibre, 1 gram of organosilicon moisture repellent, 1 gram of redispersable latex powder, 2 grams of sodium hydroxide.
Precuring component has: potassium silicate solution, metakaolin, flyash.
Secondary excitation agent has: sodium carbonate, sodium hydroxide.
The accessory package mixed with precuring component contains: mica powder, machine silicon hydrophober.
The accessory package mixed with secondary excitation agent contains: calcium carbonate, glass fibre, redispersable latex powder, slag.
Said ratio can by two component packing:
First component: precuring component, the auxiliary material mixed with precuring component.
Component B: secondary excitation agent, the auxiliary material mixed with secondary excitation agent.
Manufacturing processed:
(1) precuring component is prepared: by batching each in precuring component and corresponding auxiliary material mixing, stir, carry out precuring, then packing.
(2) secondary excitation agent is prepared: by secondary excitation agent and the mixing of corresponding auxiliary material, stir, packing.
(3) by the first and second component mixing before using, stir.
Said ratio just secondary excitation agent can also be divided into two parts, and manufactures in the following manner:
(1) precuring component is prepared: by batching each in precuring component and corresponding auxiliary material mixing, stir, carry out precuring, add first part of secondary excitation agent again after 24 hours, stir, then packing.
(2) secondary excitation agent is prepared: by second part of secondary excitation agent and the mixing of corresponding auxiliary material, stir, packing.
(3) by the first and second component mixing before using, stir.
In like manner, the mixing before also two parts of secondary excitation agent all can being used for using, namely adds secondary excitation agent, 30 minutes timed intervals of interpolation before the use at twice.
Above-mentioned coating can be used as the protective coating of metope, also may be used for concrete protection.
Above-described embodiment is only present pre-ferred embodiments; not limit to the present invention with this; therefore; feature all and of the present invention, formula etc. are approximate, identical; i.e. all equivalent replacements of doing according to patent claim of the present invention or modification etc., within the scope that all still should belong to patent application of the present invention protection.
Claims (12)
1. a precuring alkalis excited inorganic coating material, is made up of precuring component, auxiliary material and secondary excitation agent, it is characterized in that:
The exceptionally precuring component that dewaters also comprises:
The alkali-activator (in solid content) of 1 ~ 50 part;
The gelling base material of 20 ~ 120 parts;
Secondary excitation agent comprises:
The alkali-activator (in solid content) of 1 ~ 50 part;
Accessory package contains:
The gelling base material of 0 ~ 60 part;
The hydrophober of 0 ~ 60 part;
The tinting material of 0 ~ 20 part;
The swelling agent of 0 ~ 80 part;
The accelerator for hardening of 0 ~ 50 part;
The filler of 5 ~ 250 parts;
The auxiliary agent of 0 ~ 50 part;
Precuring component and secondary excitation agent isolation are placed, the placement of auxiliary material one of in the following manner:
(1) place separately;
(2) all mix with precuring component;
(3) all mix with secondary excitation agent;
(4) part mixes with precuring component;
(5) part mixes with secondary excitation agent;
The alkali-activator of indication refers at least one in alkaline silicate, alkaline phosphate, alkalimetal oxide, alkali, carbonate, vitriol, villaumite;
The gelling base material of indication refers at least one had in pozzolanic activity material, latent hydraulicity material, amorphous silicon aluminum oxide;
The hydrophober of indication refers to the lyophobic dust of dispersion low surface energy in the coating, and this lyophobic dust intercepts the approach of capillary percolation, and lyophobic dust derives from following one of two things: the reaction product of hydrophober self and hydrophober;
The tinting material of indication refers to the material with corresponding color;
The swelling agent of indication refers to the material producing volumetric expansion effect in process of setting;
The accelerator for hardening of indication refers to the material improving coating curing progress;
The filler of indication is packing volume, reduces the material shrinking, adjust surface tactile sensation;
The auxiliary agent of indication refers to the auxiliary agents improving coating serviceability.
2., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the alkali-activator of indication is at least one in water glass, potassium silicate, lithium silicate, sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium carbonate, salt of wormwood, Quilonum Retard, sodium phosphate, potassiumphosphate, Trilithium phosphate.
3., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the gelling base material of indication is at least one in metakaolin, kaolin, flyash, coal gangue, slag, slag, blast furnace granulated slag, phosphorus slag, slag, cinder, pure aluminium silicate, calcined clay, red mud, industrial tailings.
4., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the hydrophober of indication is at least one in potassium methyl silicate, sodium methyl silicate, methyl siliconic acid lithium, methyl-silicone oil, silicone oil, organosilicon moisture repellent, polysiloxane hydrophober, silylation hydrophober, NANOTHIXB1490 nano level hydrophober, Kind of Modified Polyvinyl Alcohol Based Waterborne Water-Repellent, HEA polymer hydrophober, powder hydrophober, emulsion-type hydrophober, calcium stearate.
5., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the tinting material of indication at least comprises the one in white pigment, black pigment, pigment dyestuff, mineral dye, high-visibility pigment, phosphorescent pigment, pearly pigment, dyestuff, nonferrous metal oxides pigment.
6., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the swelling agent of indication at least comprises the one in alumina, bauxite, dehydrated gyp-, aluminium hydroxide, aluminum oxide, zinc oxide, magnesium oxide, alumite plumping agent, sulphoaluminate expander, calcium oxide-calcium sulphoaluminate composite expanding agent, HEA swelling agent, UEA swelling agent, phosphogypsum.
7., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the accelerator for hardening of indication at least comprises the one in carbonate, metal oxide, calcium cpd, fluorine cpd, gypsum, light calcium carbonate, water-ground limestone, unslaked lime, white lime, sierozem power, calcium sulfate, condensation of aluminum phosphate, silicon phosphate, wollastonite, Sodium Silicofluoride, calcium phosphate.
8. according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the filler of indication at least comprises metallic particles, inorganic particle, metal oxide, breeze, stone powder, mica, foliated glass powder, flaky pottery powder, quartz, industrial residue particle, coarse aggregate, cement, cement clinker, silicon ash, nanometer powder, rice hull ash, silt deposit, perlite, glass-cermic powder, zeolite, hollow ceramic microspheres, talcum powder, carbonate, calcium cpd, silicon powder, organosilicon, silane, siloxanes, resin monomer, resin, plastic grains, rubber, wax material, grease, emulsion, water soluble resin, latex powder, polyester fiber, polypropylene fibre, cellulosic fibre, steel fiber, glass fibre, monfil, PVA fiber, carbon fiber, mineral fibre, at least one in ceramic fiber.
9., according to precuring alkalis excited inorganic coating material according to claim 1, it is characterized in that the auxiliary agent of indication at least comprises the one in flow agent, film coalescence aid, thickening material, retardant, accelerating chemicals, water-holding agent, softening agent, water reducer, defoamer, dispersion agent, tensio-active agent, air entrapment agent, whipping agent, coupling agent.
10., according to precuring alkalis excited inorganic coating material according to claim 9, it is characterized in that:
The flow agent of indication is at least the one in glassiness microballon powder, urethane flow agent:
The film coalescence aid of indication is at least the one in polyvinyl alcohol, EDTA tetra-sodium, EDETATE SODIUM, sodium salicylate, sodium polyacrylate, sodium hypophosphite, Seconary Alkane Sulphonate Sodium, sodium vinyl sulfonate, sodium methylate, sodium tert-butoxide;
The thickening material of indication is at least the one in wilkinite, attapulgite, diatomite, red mud, Mierocrystalline cellulose, cellulosate;
The retardant of indication is at least the one in tartrate, citric acid, oxalic acid, acetic acid, lead nitrate, zinc nitrate, sodium-chlor, bariumchloride, Sodium Tetraborate, water-soluble hydramine, chromium cpd;
The accelerating chemicals of indication is calcium formiate;
The water-holding agent of indication is at least the one in carbohydrate, cellulosic fibre, sodium cellulose glycolate;
The softening agent of indication is molasses modifications;
The water reducer of indication is at least the one in sulfamate, naphthalene water reducer, polycarboxylate water-reducer;
The defoamer of indication is at least the one in mineral oil defoaming agent, silicone antifoam agent;
The dispersion agent of indication is at least the one in polyacrylic dispersion agent, organosilicone spreading agent;
The tensio-active agent of indication is Dodecyl trimethyl ammonium chloride;
The air entrapment agent of indication is aluminium powder;
The whipping agent of indication is at least the one in hydrogen peroxide, peroxide water;
The coupling agent of indication is at least the one in silane coupling agent, organo-silicon coupling agent, powder silane coupling agent, boric acid ester coupler.
11., according to precuring alkalis excited inorganic coating material according to claim 1, is characterized in that comprising the secondary excitation agent being no less than two parts.
The manufacture method of the precuring alkalis excited inorganic coating material described in 12. 1 kinds of claims 1 to 10, comprises the following steps:
(1) precuring component is prepared: by batching each in precuring component by proportioning mixing, stir, carry out precuring, then packing;
(2) secondary excitation agent is prepared: by each component in secondary excitation agent by proportioning mixing, stir, packing;
Step 3 is entered when there being the auxiliary material of packaging separately,
(3) auxiliary material is prepared: mixed by proportioning by each component of the auxiliary material packed separately, stir, packing;
(4) in ratio according to claim 1, all components are mixed before using, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310631603.7A CN104649625A (en) | 2013-11-22 | 2013-11-22 | Pre-cured alkali-activated inorganic coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310631603.7A CN104649625A (en) | 2013-11-22 | 2013-11-22 | Pre-cured alkali-activated inorganic coating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104649625A true CN104649625A (en) | 2015-05-27 |
Family
ID=53241336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310631603.7A Pending CN104649625A (en) | 2013-11-22 | 2013-11-22 | Pre-cured alkali-activated inorganic coating material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104649625A (en) |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987027A (en) * | 2015-06-10 | 2015-10-21 | 中国铁路总公司 | High-speed rail ballastless track concrete roadbed slab crack restoration material and preparation and application thereof |
| CN105130219A (en) * | 2015-07-09 | 2015-12-09 | 黄恒 | Formula of cement |
| CN105254262A (en) * | 2015-08-17 | 2016-01-20 | 霍山华凯环保科技有限公司 | Environment-friendly building material |
| CN105482516A (en) * | 2015-12-05 | 2016-04-13 | 刘传新 | Attapulgite interior wall coating drier and production method thereof |
| CN105884295A (en) * | 2016-04-11 | 2016-08-24 | 苏州甫众塑胶有限公司 | High-strength foam concrete material for floor heating and preparation method thereof |
| CN106145813A (en) * | 2016-06-28 | 2016-11-23 | 蚌埠市方阵商品混凝土有限公司 | A kind of high-temperature-resistant thermal-insulation concrete |
| CN106431080A (en) * | 2016-09-18 | 2017-02-22 | 广西棕海园林工程有限公司 | Diatomaceous earth plastering material for internal walls and preparation method of material |
| CN106431081A (en) * | 2016-09-18 | 2017-02-22 | 广西棕海园林工程有限公司 | Diatomaceous earth plastering material for outdoor walls and preparation method of material |
| CN107098630A (en) * | 2017-06-03 | 2017-08-29 | 合肥慧林建材有限公司 | A kind of mosquito proof pavior brick and preparation method thereof |
| CN107986706A (en) * | 2017-11-27 | 2018-05-04 | 柳州市闽贵砖厂 | A kind of porous brick and preparation method thereof |
| CN108164192A (en) * | 2017-12-12 | 2018-06-15 | 华南理工大学 | A kind of ground polymers base adhesive and its preparation method and application |
| CN108164222A (en) * | 2018-02-01 | 2018-06-15 | 天津诚顺达建筑材料检测有限公司 | Cement-based grouting material and grout and mortar |
| CN108249789A (en) * | 2018-01-15 | 2018-07-06 | 三峡大学 | A kind of phosphorus slag base compound cementitious matter of no first-hand datum and preparation method thereof |
| CN108409215A (en) * | 2018-05-16 | 2018-08-17 | 江南大学 | A kind of ductility mud geo-polymer and preparation method thereof |
| CN109437688A (en) * | 2018-12-06 | 2019-03-08 | 湖南易兴建筑有限公司 | Nano inorganic mineral material and preparation method thereof and concrete |
| CN109437812A (en) * | 2018-12-05 | 2019-03-08 | 武汉鑫奥捷新型建材有限公司 | A kind of thermal insulation coatings and preparation method thereof |
| CN109608088A (en) * | 2019-01-12 | 2019-04-12 | 沈继锋 | A kind of compound concrete alkali-activator and preparation method thereof |
| CN109865794A (en) * | 2017-12-01 | 2019-06-11 | 宁夏共享化工有限公司 | A kind of production method preparing cast paint by industrial dust |
| CN110015869A (en) * | 2019-04-22 | 2019-07-16 | 河海大学 | A kind of resistant abrasion water conservancy project armour and preparation method thereof |
| CN110079130A (en) * | 2019-05-28 | 2019-08-02 | 广西福宝信科技有限公司 | Coating changed red mud and preparation method thereof |
| CN110183133A (en) * | 2019-05-09 | 2019-08-30 | 常熟理工学院 | A kind of rapid hardening preparation of batch method |
| CN110304846A (en) * | 2019-07-12 | 2019-10-08 | 浙江三力建筑材料有限公司 | King's material and preparation method thereof is repaired in a kind of lifting of inspection well cover |
| CN112551996A (en) * | 2020-12-14 | 2021-03-26 | 重庆市能容建筑科技有限公司 | Solid water-resistant permeable material for building and preparation method thereof |
| CN115594999A (en) * | 2022-12-12 | 2023-01-13 | 甘肃省交通规划勘察设计院股份有限公司（Cn） | Breathable mineral coating special for ultralow VOC concrete and preparation method thereof |
| CN116355446A (en) * | 2023-04-14 | 2023-06-30 | 郑州高聚粉体科技有限公司 | Surface coating manufacturing process for improving fire resistance limit of steel |
| CN116396038A (en) * | 2023-06-09 | 2023-07-07 | 河北天明七星装配式建筑科技有限公司 | Energy-saving environment-friendly inorganic rapid hardening molding A-level fireproof heat-insulating plate and preparation method thereof |
-
2013
- 2013-11-22 CN CN201310631603.7A patent/CN104649625A/en active Pending
Cited By (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987027A (en) * | 2015-06-10 | 2015-10-21 | 中国铁路总公司 | High-speed rail ballastless track concrete roadbed slab crack restoration material and preparation and application thereof |
| CN105130219A (en) * | 2015-07-09 | 2015-12-09 | 黄恒 | Formula of cement |
| CN105254262A (en) * | 2015-08-17 | 2016-01-20 | 霍山华凯环保科技有限公司 | Environment-friendly building material |
| CN105254262B (en) * | 2015-08-17 | 2017-11-07 | 霍山华凯环保科技有限公司 | A kind of environmental protection meets construction material |
| CN105482516A (en) * | 2015-12-05 | 2016-04-13 | 刘传新 | Attapulgite interior wall coating drier and production method thereof |
| CN105884295B (en) * | 2016-04-11 | 2018-06-22 | 舟山市大昌预拌混凝土有限公司 | A kind of floor heating high-strength foamed concrete material and preparation method thereof |
| CN105884295A (en) * | 2016-04-11 | 2016-08-24 | 苏州甫众塑胶有限公司 | High-strength foam concrete material for floor heating and preparation method thereof |
| CN106145813A (en) * | 2016-06-28 | 2016-11-23 | 蚌埠市方阵商品混凝土有限公司 | A kind of high-temperature-resistant thermal-insulation concrete |
| CN106431080A (en) * | 2016-09-18 | 2017-02-22 | 广西棕海园林工程有限公司 | Diatomaceous earth plastering material for internal walls and preparation method of material |
| CN106431081A (en) * | 2016-09-18 | 2017-02-22 | 广西棕海园林工程有限公司 | Diatomaceous earth plastering material for outdoor walls and preparation method of material |
| CN107098630A (en) * | 2017-06-03 | 2017-08-29 | 合肥慧林建材有限公司 | A kind of mosquito proof pavior brick and preparation method thereof |
| CN107986706A (en) * | 2017-11-27 | 2018-05-04 | 柳州市闽贵砖厂 | A kind of porous brick and preparation method thereof |
| CN109865794A (en) * | 2017-12-01 | 2019-06-11 | 宁夏共享化工有限公司 | A kind of production method preparing cast paint by industrial dust |
| CN108164192A (en) * | 2017-12-12 | 2018-06-15 | 华南理工大学 | A kind of ground polymers base adhesive and its preparation method and application |
| CN108249789A (en) * | 2018-01-15 | 2018-07-06 | 三峡大学 | A kind of phosphorus slag base compound cementitious matter of no first-hand datum and preparation method thereof |
| CN108164222A (en) * | 2018-02-01 | 2018-06-15 | 天津诚顺达建筑材料检测有限公司 | Cement-based grouting material and grout and mortar |
| CN108409215B (en) * | 2018-05-16 | 2021-02-02 | 江南大学 | Ductile sludge geopolymer and preparation method thereof |
| CN108409215A (en) * | 2018-05-16 | 2018-08-17 | 江南大学 | A kind of ductility mud geo-polymer and preparation method thereof |
| CN109437812B (en) * | 2018-12-05 | 2021-11-05 | 武汉鑫奥捷新型建材有限公司 | Heat-insulating coating and preparation method thereof |
| CN109437812A (en) * | 2018-12-05 | 2019-03-08 | 武汉鑫奥捷新型建材有限公司 | A kind of thermal insulation coatings and preparation method thereof |
| CN109437688A (en) * | 2018-12-06 | 2019-03-08 | 湖南易兴建筑有限公司 | Nano inorganic mineral material and preparation method thereof and concrete |
| CN109608088A (en) * | 2019-01-12 | 2019-04-12 | 沈继锋 | A kind of compound concrete alkali-activator and preparation method thereof |
| CN110015869B (en) * | 2019-04-22 | 2021-03-19 | 河海大学 | Anti-abrasion hydraulic face protection block and preparation method thereof |
| CN110015869A (en) * | 2019-04-22 | 2019-07-16 | 河海大学 | A kind of resistant abrasion water conservancy project armour and preparation method thereof |
| CN110183133A (en) * | 2019-05-09 | 2019-08-30 | 常熟理工学院 | A kind of rapid hardening preparation of batch method |
| CN110183133B (en) * | 2019-05-09 | 2021-05-11 | 常熟理工学院 | Preparation method of quick-setting ingredient |
| CN110079130A (en) * | 2019-05-28 | 2019-08-02 | 广西福宝信科技有限公司 | Coating changed red mud and preparation method thereof |
| CN110304846A (en) * | 2019-07-12 | 2019-10-08 | 浙江三力建筑材料有限公司 | King's material and preparation method thereof is repaired in a kind of lifting of inspection well cover |
| CN110304846B (en) * | 2019-07-12 | 2021-10-29 | 浙江三力建筑材料有限公司 | Inspection well cover lifting repair material and preparation method thereof |
| CN112551996A (en) * | 2020-12-14 | 2021-03-26 | 重庆市能容建筑科技有限公司 | Solid water-resistant permeable material for building and preparation method thereof |
| CN115594999A (en) * | 2022-12-12 | 2023-01-13 | 甘肃省交通规划勘察设计院股份有限公司（Cn） | Breathable mineral coating special for ultralow VOC concrete and preparation method thereof |
| CN116355446A (en) * | 2023-04-14 | 2023-06-30 | 郑州高聚粉体科技有限公司 | Surface coating manufacturing process for improving fire resistance limit of steel |
| CN116396038A (en) * | 2023-06-09 | 2023-07-07 | 河北天明七星装配式建筑科技有限公司 | Energy-saving environment-friendly inorganic rapid hardening molding A-level fireproof heat-insulating plate and preparation method thereof |
| CN116396038B (en) * | 2023-06-09 | 2023-08-15 | 河北天明七星装配式建筑科技有限公司 | Energy-saving environment-friendly inorganic rapid hardening molding A-level fireproof heat-insulating plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104649625A (en) | Pre-cured alkali-activated inorganic coating material | |
| CN104649626A (en) | Highly dense alkali-activated coating material | |
| CN104291741A (en) | Hydrophobic modified alkali-activated inorganic polymer coating restoration material | |
| CN104291740A (en) | Waterproof alkali activated inorganic polymer coating | |
| KR101141347B1 (en) | Eco-friendly geopolymer mortar compound for restoring cross section and method for repairing cross section of concrete controlling corrosion, salt-attack and neutralization and using the same | |
| Vickers et al. | Fire-resistant geopolymers: role of fibres and fillers to enhance thermal properties | |
| CN104254504B (en) | The geopolymer formulation and method of dimensionally stable | |
| AU2010323416B2 (en) | Inorganic binder system for the production of chemically resistant construction chemistry products | |
| CN104245621A (en) | Print control device capable of generating image data using plurality of error matrices | |
| CN102596848A (en) | Geopolymer cement and use thereof | |
| CN107265937A (en) | Geopolymer composite material for ultra-high performance concrete | |
| CN110304872B (en) | Nano modified cement-based underwater non-dispersible material and preparation method thereof | |
| CN106904911A (en) | A kind of anti-corrosion maritime concrete of sea sand and preparation method thereof | |
| CN106904891A (en) | Carbonization preventing paint and preparation method thereof | |
| AU2017228691A1 (en) | A metal oxide activated cement | |
| CN104343122A (en) | Concrete structure protection method | |
| CN113135695A (en) | Anti-cracking anti-permeation high-durability concrete and preparation method thereof | |
| CN105384403A (en) | Composite floor tiles having good stain resistance capacity | |
| CN114213094B (en) | Regenerated ceramic powder geopolymer repair mortar and preparation method thereof | |
| CN107651893A (en) | A kind of radiation proof decoration cement | |
| CN100460353C (en) | Multifunctional impervious microcrystal waterproof agent for concrete | |
| CN105819760B (en) | A kind of ground polymers terrace base material | |
| CN115151517A (en) | Slag-based hydraulic binder, dry mortar composition comprising such a binder and activation system for a slag-based binder | |
| CN110183165A (en) | The concrete and its preparation process of fly ash base geopolymer concrete and normal concrete knot | |
| KR101877528B1 (en) | Cement composition having rapid hardening properties for runway reparing and runway repairing method using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150527 |
|
| WD01 | Invention patent application deemed withdrawn after publication |