CN100460353C - Multifunctional impervious microcrystal waterproof agent for concrete - Google Patents
Multifunctional impervious microcrystal waterproof agent for concrete Download PDFInfo
- Publication number
- CN100460353C CN100460353C CNB2007100378867A CN200710037886A CN100460353C CN 100460353 C CN100460353 C CN 100460353C CN B2007100378867 A CNB2007100378867 A CN B2007100378867A CN 200710037886 A CN200710037886 A CN 200710037886A CN 100460353 C CN100460353 C CN 100460353C
- Authority
- CN
- China
- Prior art keywords
- orders
- concrete
- microcrystal
- impervious
- multifunctional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/65—Water proofers or repellants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a multifunctional water-tight microcrystal concrete water-proof additive in building material technical domain. The component and mass percent of this invention is: 25-35% industrial SiO2, 4-15% industrial AL2O3, 15-25% ultra-fine slag, 34-45% jevigating quartz sand, 0.2-0.4% polyacrylic fiber and 0.6-0.80% high efficiency water reducing agent. This invention reach the purpose of water proof through blending gel, which generated by reacting active mineral and cement hydrated matter.
Description
Technical field
What the present invention relates to is a kind of concrete impervious water-proof material, specifically, relates to a kind of multifunctional impervious microcrystal waterproof agent for concrete.Belong to building material technical field.
Background technology
Concrete is as the widespread use in civil engineering work of a kind of main material of construction; but concrete material is because the characteristic of self structure; in use especially occur the seepage phenomenon for those underground and aouatic structure engineerings through regular meeting, this has had a strong impact on and has restricted the application of concrete material.Therefore, about the various additives that improve and improve the impervious ability of concrete material constantly are suggested, expand with inorganic water-proof agents such as the calcium chloride that improves the impervious ability of concrete anticracking, iron(ic) chloride by producing as early stage some, also have some organic classes in addition, as organosilicon, lipid acid etc.But waterproof ability is limited on the one hand for these water-resisting agents, can not be lasting, it is important reinforcing bars rusting in addition, so some novel more effective waterproof additive expectations are developed and use to concrete structure inside.Wherein be typically a kind of cement penetrant crystalline water-proof material the most.
Find through literature search prior art, Chinese patent publication number: CN1261385C, patent name: cementitious capillary waterproofing material and production technique thereof and constructional method, this patent mainly with cement as main base material, mix a certain amount of activeconstituents and levigate quartz sand outward, excite to react and generate micro crystal and play block pores and improve impervious waterproof ability thereby enter concrete structure inner utilization activeconstituents, but its price is very expensive with the inside concrete hydrated product by osmosis.Also find in the retrieval, patent name is " concrete waterproofer " (Chinese patent publication number: CN1115312C), this invention has proposed a kind of employing sylvic acid, polyvinyl alcohol, diethanolamine, trimeric cyanamide and 12 tabernaemontanus bulrush sodium sulfonates etc. and has heated compound formulated by a certain percentage, its product mixes in the concrete to improve concrete impervious ability with liquid state, the main mechanism of action is to improve concrete density by diminishing, but in actual applications, its barrier performance is very ineffective.
Summary of the invention
The objective of the invention is at having deficiency and defective in the prior art, provide a kind of efficiently, persistent, cheap, multi-functional impervious microcrystal waterproof agent for concrete, suitably adjust the prescription and the production technique of this material, it can be used as the mending-leakage patching material and uses.
The present invention is achieved by the following technical solutions, and each component and weight percent thereof that the present invention comprises are:
Industrial SiO
225～35%
Industrial Al
2O
34～15%
Ultrafine slag 15～25%
Levigate quartz sand 34～45%
Polyacrylic fibre 0.2～0.5%
High efficiency water reducing agent 0.5～0.8%
Described industrial SiO
2, its purity 〉=99% is more than fineness 800 orders.
Described industrial Al
2O
3, its purity 〉=95%, more than fineness 1000 orders.
Described ultrafine slag, its specific surface area are 5000～8000cm
2/ g.
Described levigate quartz sand, it should meet following particle diameter and grating requires:
8～20 orders 15～20% (weight ratio)
20～40 orders 20～30% (weight ratio)
40～60 orders 30～35% (weight ratio)
60～80 orders 15～20% (weight ratio)
80～100 orders 10～15% (weight ratio)
〉=100 orders 5～10% (weight ratio).
Described polypropylene fibre, its length should be controlled to be 5～15mm, and diameter is 30～50um.
Described high efficiency water reducing agent is an admixture naphthalenesulfonate series high-efficiency water-reducing agent powder, and addition content is 0.20～0.40%.
The preparation method of the above-mentioned additive of the present invention is: claim required industrial SiO by formula rate
2, industrial Al
2O
3, ultrafine slag, levigate quartz sand, polyacrylic fibre and high efficiency water reducing agent, in stirrer, stir, form product, pack.During on-the-spot the use, be that 8～10% of cement consumption is advisable as its volume of a kind of cement additire.
Compared with prior art, product of the present invention has following special character: the present invention adopts the high reactivity industry SiO of some amount
2And Al
2O
3Adding water with cement mixes and is hydrolyzed into colloidal sol when stirring, these colloidal sol molecules may penetrate in the pore of cement slurry inside, block and the cut-out capillary-size pore, the calcium hydroxide of ultrafine slag and hydrated cementitious product generation simultaneously reacts, generate Calucium Silicate powder and cement stone and form integral body, unhydrolysed crystallite of part and levigate quartz sand fill concrete hole, the density of increase cement stone.At industrial SiO
2, industrial Al
2O
3Under the mutual common physics chemical action of ultrafine slag, along with the continuous aquation of cement, make the density of cement stone constantly strengthen, seem more lasting.The present invention does not exist aging and inefficacy to the effect of reinforcing bar non-corroding, is a kind of very excellent dual-purpose water-proof material.
Embodiment
Below embodiments of the invention are elaborated: present embodiment is being to implement under the prerequisite with the technical solution of the present invention, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Claim required industrial SiO by formula rate
2, industrial Al
2O
3, ultrafine slag, levigate quartz sand, polyacrylic fibre and high efficiency water reducing agent, in stirrer, stir, form the multifunctional impervious microcrystal waterproof agent for concrete product, pack.According to the engineering application need,, can obtain needed performance by adjusting prescription.In specific implementation process, each weight percentages of components is:
Said components gets multifunctional impervious microcrystal waterproof agent for concrete by aforementioned prepared.Adding the waterproof additive of embodiment 1 preparation to proportioning by 8% of cement consumption is: cement: yellow ground is in the mortar of 1:3, is used to repair a roof that leaks for many years, and through the observation more than 1 year, not seeing has the infiltration phenomenon.Adding the waterproof additive of embodiment 2 preparation to proportioning by 10% of cement consumption is: cement: yellow ground is in the mortar of 1:3, be used to repair a moist for many years vault, through one month time, it is very dry that vault ground becomes, and free from dampness and general damp phenomenon occur.To add the design strength grade respectively to by 10% of cement consumption be 15MPa with the waterproof additives of embodiment 3 and 4 preparations, anti-penetration grade is in the concrete of S4, after 60 days, test, during the normal concrete impermeability test, when permeable pressure reaches 0.4MPa, test specimen is all permeable, and the concrete impermeability test pressure of admixture embodiment 3 yet there are no permeable when reaching 3.0MPa; And admixture embodiment's 4 have only 1 test specimen permeable, and remaining does not all have permeable phenomenon.
Claims (4)
1. a multifunctional impervious microcrystal waterproof agent for concrete is characterized in that, each component and the weight percent thereof that comprise are:
Industrial SiO
225～35%
Industrial Al
2O
34～15%
Ultrafine slag 15～25%
Levigate quartz sand 34～45%
Polypropylene fibre 0.2～0.5%
High efficiency water reducing agent 0.5～0.8%;
Described levigate quartz sand, it should meet following particle diameter and grating requires:
8～20 orders, 15～20% weight ratios
20～40 orders, 20～30% weight ratios
40～60 orders, 30～35% weight ratios
60～80 orders, 15～20% weight ratios
80～100 orders, 10～15% weight ratios
〉=100 orders 5～10% weight ratios;
Described industrial SiO
2, its purity 〉=99% is more than fineness 800 orders;
Described industrial Al
2O
3, its purity 〉=95% is more than fineness 1000 orders.
2. multifunctional impervious microcrystal waterproof agent for concrete according to claim 1 is characterized in that, described ultrafine slag, and its specific surface area is 5000～8000cm
2/ g.
3. multifunctional impervious microcrystal waterproof agent for concrete according to claim 1 is characterized in that, described polypropylene fibre, and its length is 5～15mm, diameter is 30～50um.
4. multifunctional impervious microcrystal waterproof agent for concrete according to claim 1 is characterized in that, it is Powdered that described high efficiency water reducing agent is that naphthalenesulfonate is.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100378867A CN100460353C (en) | 2007-03-08 | 2007-03-08 | Multifunctional impervious microcrystal waterproof agent for concrete |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100378867A CN100460353C (en) | 2007-03-08 | 2007-03-08 | Multifunctional impervious microcrystal waterproof agent for concrete |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101041568A CN101041568A (en) | 2007-09-26 |
| CN100460353C true CN100460353C (en) | 2009-02-11 |
Family
ID=38807386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100378867A Expired - Fee Related CN100460353C (en) | 2007-03-08 | 2007-03-08 | Multifunctional impervious microcrystal waterproof agent for concrete |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100460353C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102705593A (en) * | 2012-06-29 | 2012-10-03 | 山东龙泉管道工程股份有限公司 | Embedded prestress steel cylinder concrete pipe subjected to comprehensive antiseptic treatment |
| CN104496323A (en) * | 2014-12-23 | 2015-04-08 | 苏州万盛混凝土有限公司 | Method for preparing high anti-permeability concrete |
| CN104446226A (en) * | 2014-12-23 | 2015-03-25 | 苏州万盛混凝土有限公司 | High-anti-permeability concrete |
| CN109734345A (en) * | 2019-03-22 | 2019-05-10 | 安徽信息工程学院 | A kind of penetrant crystalline material and preparation method |
| CN110482898A (en) * | 2019-08-13 | 2019-11-22 | 安徽朗凯奇建材有限公司 | A kind of conjunction of autogenous healing, which subtracts, seeps additive, preparation method and its application method |
| CN113045272B (en) * | 2021-03-23 | 2022-04-12 | 广州市长运预拌混凝土有限公司 | Green environment-friendly concrete and preparation method thereof |
| CN113831076A (en) * | 2021-07-16 | 2021-12-24 | 河南省龙岳抗渗科技有限公司 | Microcrystalline high-strength anti-permeability reinforcing grouting material |
| CN113620648B (en) * | 2021-08-20 | 2022-09-06 | 武汉理工大学 | Cement-based material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1223237A (en) * | 1998-10-30 | 1999-07-21 | 上海微晶工贸有限公司 | Permeability-resisting microcrystal cement additive agent |
| CN1090596C (en) * | 1999-08-20 | 2002-09-11 | 胡一平 | Trace-silicon high-effect cement mortar water-proofing agent |
| CN1121357C (en) * | 1999-08-20 | 2003-09-17 | 胡一平 | Trace-silicon high-effect cement mortar and concrete alkali-proofing agent |
| CN1261385C (en) * | 2004-08-20 | 2006-06-28 | 姜哲 | Cement base permetration crystal type water-proof material and its producing process and construction method |
-
2007
- 2007-03-08 CN CNB2007100378867A patent/CN100460353C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1223237A (en) * | 1998-10-30 | 1999-07-21 | 上海微晶工贸有限公司 | Permeability-resisting microcrystal cement additive agent |
| CN1090596C (en) * | 1999-08-20 | 2002-09-11 | 胡一平 | Trace-silicon high-effect cement mortar water-proofing agent |
| CN1121357C (en) * | 1999-08-20 | 2003-09-17 | 胡一平 | Trace-silicon high-effect cement mortar and concrete alkali-proofing agent |
| CN1261385C (en) * | 2004-08-20 | 2006-06-28 | 姜哲 | Cement base permetration crystal type water-proof material and its producing process and construction method |
Non-Patent Citations (2)
| Title |
|---|
| 水泥基渗透结晶型防水材料性能研究. 陈兵等.新型建筑材料，第12期. 2000 |
| 水泥基渗透结晶型防水材料性能研究. 陈兵等.新型建筑材料，第12期. 2000 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101041568A (en) | 2007-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100460353C (en) | Multifunctional impervious microcrystal waterproof agent for concrete | |
| CN101538139B (en) | Dry-mixed mortar with waste stone dust in stone mining and processing plant as aggregate and filler | |
| CN102060460B (en) | Inorganic cement capillary crystalline waterproofing agent and production process thereof | |
| AU2019200497B2 (en) | Metal oxide cement | |
| CN102898114B (en) | Plant root puncture resistance environment-friendly self-healing waterproof adhesive and preparation method of adhesive | |
| CN104649626A (en) | Highly dense alkali-activated coating material | |
| CN102875082A (en) | Cement-based permeable crystalline core master batch and its application | |
| CN104649625A (en) | Pre-cured alkali-activated inorganic coating material | |
| CN105777040A (en) | Novel ceramic tile adhesive and preparation method thereof | |
| CN105110730A (en) | Modified organic silicon reinforced cement-based permeable crystallization type waterproof coating and preparation method therefor | |
| CN102875053B (en) | construction method of compound type powder waterproof agent | |
| CN1982254B (en) | Antiseptic concrete air-tight agent composition and its production | |
| CN107337408A (en) | A kind of wear-resisting antiseepage composite mortar of cracking resistance and preparation method thereof | |
| CN105733382A (en) | Micro-nano reinforcing steel bar anti-rusting agent for autoclaved aerated concrete slab and preparation method of micro-nano reinforcing steel bar anti-rusting agent | |
| JP2000109833A (en) | Solidification and hydrophobicizing of soil substance | |
| KR101033652B1 (en) | Manufacturing method of liquid composition for water-proof in concrete and concrete composition using the same | |
| CN101786826B (en) | Ready-mixed mortar thickening plasticity-maintaining agent | |
| Kazemian et al. | Effect of calcium chloride and kaolinite on shear strength and shrinkage of cement grout | |
| US10273187B2 (en) | Metal oxide activated cement | |
| CN107021706B (en) | Self-waterproof concrete | |
| CN111606599B (en) | Polymer modifier for concrete, preparation method and impervious waterproof concrete | |
| CN108911572A (en) | Modified penetrant crystalline waterproofing agent of organosilicon | |
| US10752548B2 (en) | Metal oxide activated cement | |
| CN107010863A (en) | Concrete waterproofer | |
| KR100622062B1 (en) | Liquid water-Proof agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANGHAI ZHONGJIN CONSTRUCTION GROUP CO., LTD. Free format text: FORMER OWNER: SHANGHAI JIAOTONG UNIVERSITY Effective date: 20120521 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 200240 MINHANG, SHANGHAI TO: 200060 PUTUO, SHANGHAI |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20120521 Address after: Xikang Road 200060 No. 1048 5 floor Patentee after: Shanghai Zhongjin Construction Group Co., Ltd. Address before: 200240 Dongchuan Road, Shanghai, No. 800, No. Patentee before: Shanghai Jiao Tong University |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090211 Termination date: 20160308 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |