CN104629481A - Natural dye extraction and processing method - Google Patents
Natural dye extraction and processing method Download PDFInfo
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- CN104629481A CN104629481A CN201310555334.0A CN201310555334A CN104629481A CN 104629481 A CN104629481 A CN 104629481A CN 201310555334 A CN201310555334 A CN 201310555334A CN 104629481 A CN104629481 A CN 104629481A
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- natural dye
- extracts
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- natural dyestuff
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- 238000000605 extraction Methods 0.000 title abstract description 8
- 229930182559 Natural dye Natural products 0.000 title abstract 7
- 239000000978 natural dye Substances 0.000 title abstract 7
- 238000003672 processing method Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000000284 extract Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000000975 dye Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 238000002137 ultrasound extraction Methods 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000010828 elution Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 230000008961 swelling Effects 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 3
- 239000004663 anionic softener Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 229960004025 sodium salicylate Drugs 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 241000209639 Biancaea sappan Species 0.000 abstract 1
- 235000015162 Caesalpinia sappan Nutrition 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- WZUVPPKBWHMQCE-UHFFFAOYSA-N Haematoxylin Chemical compound C12=CC(O)=C(O)C=C2CC2(O)C1C1=CC=C(O)C(O)=C1OC2 WZUVPPKBWHMQCE-UHFFFAOYSA-N 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000389 extracts by organism Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cosmetics (AREA)
- Coloring (AREA)
Abstract
The invention discloses a natural dye extraction and processing method, which is characterized by comprising the following steps: 1)pretreating raw materials, 2)performing supersonic wave extraction; 3)eluting, and 4)adding an additive. The method can effectively use sappan wood for extracting the natural dye, the obtained extract product is safe and has sterilization efficacy, the natural dye has good compatibility with ecological environment and is biodegradable. Partial chemical component is added for good color fastness of the natural dye, and long-term preservation can be realized, The natural dye can keep permeability, flexibility, elastic force and luster of original fabric after usage, hand feeling, moisture absorption and strength performance are good, and the natural dye is virtually harmless to humans. The method has the advantages of simple extraction technology, high extraction efficiency, low cost and wide market prospect.
Description
Technical field
The invention belongs to fuel manufacture technology field, be specifically related to a kind of natural dyestuff and extract and the method for processing.
Background technology
Bush is that dry heartwood is cylindrical, some connection roots, in irregular slightly bending strip.Surface burgundy or yellowish brown, visible red yellow alternate vertical walk striped, have cutter sheeter lines and tiny recessed oilhole.There is the annual ring shown in transverse section, sometimes the marrow of the visible yellow-white of central authorities, and the flash of light of tool point-like.Matter is fine and close, hard and weigh, odorless, and taste is micro-puckery.This product dropped in hot water, water dyes bright-coloured pink, then becomes yellow with vinegar, then adds alkali and become redness again.Be good with thick, solid, look reddish yellow person.
What long ago people used is all natural dyestuff, and main what utilize is the juice of plant, and what have also uses the dyeing such as the blood of insect.For thousands of years, our people to the application of vegetable dye widely.Have accumulated many experiences, such as can propose curcumine from ginger juice, rouge can be proposed refer to red from cochineal, can hematoxylin be proposed from bush, etc.
Natural dyestuff is mainly used in natural fiber (hair, fiber crops, silk, cotton) and most of regenerated fiber (milk fibre, soybean fibers, bamboo fibers, Modal etc.) textiles, and clothes, on dress ornament.Also can be used on artwork, leatherware, bamboo and wood products, makeup.While use natural dyestuff, do not use additive synthesis as far as possible, ensure environmental protection and the sky metachromia of product.
Along with the continuous enhancing of mankind's environmental consciousness and the growing interest to own health, the harm that partial synthesis dyestuff produces human health and ecotope is more and more noticeable.Under global Green Revolution tide, natural dyestuff starts again as people are paid attention to.In natural dyestuff, animals and plants dyestuff extracts by organism, good with Environmental compatibility, biodegradable.Natural dyestuff also has the several functions such as medicine, spices, makes the fabric after dyeing have special medicinal health-care function to human body.How extracting and post-treatment natural dyestuff, the efficient performance realizing dyestuff is the technical problem to be solved in the present invention.
Summary of the invention
The invention provides a kind of natural dyestuff to extract and the method for processing, technique is simple, and extraction efficiency is high, and cost is low, the Product Green environmental protection obtained, and easy to use, colour fastness is good, can preserve for a long time, wide market.
The technical scheme that the present invention takes:
Natural dyestuff extracts and a method of processing, and it is characterized in that, carries out according to following step:
(1) raw materials pretreatment: bush is added sodium hydroxide and regulate pH=7-8, be heated to 40-50 DEG C of reaction 30-40 min, wash, after naturally drying, mechanical disintegration is to 50-60 order;
(2) ultrasonic extraction: select concentration be the ethanol of 95% as solvent, be 1: 30-40 according to solid-liquid ratio, control ultrasonic power is 800-900W, ultrasonic extraction 70-80 min under temperature is 60 DEG C of conditions, filter;
(3) wash-out: by the filtrate deionized water rinsing obtained, then use pH=3-5, the ethanol elution of 95%;
(4) add additive: in elutriant, add the Benzoyl chloride 10-15% of 8%, modifying agent 3-4%, swelling agent 2-3%, solubilizing agent 0.5-0.8%, adjusts pH=7-8 with sodium hydroxide, stirs, be warming up to 45-50 DEG C of insulation 20min.
Modifying agent in above-mentioned steps (4) is one or more in organic silicon emulsion, anionic softener WML, NON IONIC SOFTNER FD-200, H-N100 NON IONIC SOFTNER.
Swelling agent in above-mentioned steps (4) is glycerol or polyoxyethylene glycol.
Solubilizing agent in above-mentioned steps (4) is one or more in urea, sodium salicylate, Sodium Benzoate.
The beneficial effect of the invention:
The present invention can effectively utilize bush extract natural dyestuff, the extract obtained safety and there is the effects such as sterilization, good with ecotope consistency, biodegradable.Adding some chemical properties makes dyestuff colour fastness good, and can preserve for a long time, can keep source textile ventilation property, flexibility, elastic force and gloss etc. after using, the performances such as feel, moisture absorption and brute force are good, and harmless.Extraction process of the present invention is simple, and extraction efficiency is high, and cost is low, wide market.
Embodiment
Embodiment 1
Natural dyestuff extracts and a method of processing, and it is characterized in that, carries out according to following step:
(1) raw materials pretreatment: bush is added sodium hydroxide and regulate pH=7-8, is heated to 40 DEG C of reaction 40 min, washes, after naturally drying, and mechanical disintegration to 60 order;
(2) ultrasonic extraction: select concentration be the ethanol of 95% as solvent, be 1: 30 according to solid-liquid ratio, control ultrasonic power is 800W, ultrasonic extraction 70min under temperature is 60 DEG C of conditions, filter;
(3) wash-out: by the filtrate deionized water rinsing obtained, then use pH=3-5, the ethanol elution of 95%;
(4) add additive: in elutriant, add the Benzoyl chloride 10% of 8%, organic silicon emulsion, anionic softener WML 3%, glycerol 2%, sodium salicylate 0.8%, adjusts pH=7-8 with sodium hydroxide, stirs, and is warming up to 50 DEG C of insulation 20min.
Embodiment 2
Natural dyestuff extracts and a method of processing, and it is characterized in that, carries out according to following step:
(1) raw materials pretreatment: bush is added sodium hydroxide and regulate pH=7-8, is heated to 50 DEG C of reaction 30 min, washes, after naturally drying, and mechanical disintegration to 60 order;
(2) ultrasonic extraction: select concentration be the ethanol of 95% as solvent, be 1: 35 according to solid-liquid ratio, control ultrasonic power is 900W, ultrasonic extraction 80 min under temperature is 60 DEG C of conditions, filter;
(3) wash-out: by the filtrate deionized water rinsing obtained, then use pH=3-5, the ethanol elution of 95%;
(4) add additive: in elutriant, add Benzoyl chloride 12%, the H-N100 NON IONIC SOFTNER 4% of 8%, glycerol or polyoxyethylene glycol 3%, Sodium Benzoate 0.8%, adjusts pH=7-8 with sodium hydroxide, stirs, be warming up to 50 DEG C of insulation 20min.
Claims (4)
1. natural dyestuff extracts and a method of processing, and it is characterized in that, carries out according to following step:
(1) raw materials pretreatment: bush is added sodium hydroxide and regulate pH=7-8, be heated to 40-50 DEG C of reaction 30-40 min, wash, after naturally drying, mechanical disintegration is to 50-60 order;
(2) ultrasonic extraction: select concentration be the ethanol of 95% as solvent, be 1: 30-40 according to solid-liquid ratio, control ultrasonic power is 800-900W, ultrasonic extraction 70-80 min under temperature is 60 DEG C of conditions, filter;
(3) wash-out: by the filtrate deionized water rinsing obtained, then use pH=3-5, the ethanol elution of 95%;
(4) add additive: in elutriant, add the Benzoyl chloride 10-15% of 8%, modifying agent 3-4%, swelling agent 2-3%, solubilizing agent 0.5-0.8%, adjusts pH=7-8 with sodium hydroxide, stirs, be warming up to 45-50 DEG C of insulation 20min.
2. a kind of natural dyestuff according to claim 1 extracts and the method for processing, it is characterized in that, the modifying agent in described step (4) is one or more in organic silicon emulsion, anionic softener WML, NON IONIC SOFTNER FD-200, H-N100 NON IONIC SOFTNER.
3. a kind of natural dyestuff according to claim 1 extracts and the method for processing, and it is characterized in that, the swelling agent in described step (4) is glycerol or polyoxyethylene glycol.
4. a kind of natural dyestuff according to claim 1 extracts and the method for processing, and it is characterized in that, the solubilizing agent in described step (4) is one or more in urea, sodium salicylate, Sodium Benzoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310555334.0A CN104629481A (en) | 2013-11-11 | 2013-11-11 | Natural dye extraction and processing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310555334.0A CN104629481A (en) | 2013-11-11 | 2013-11-11 | Natural dye extraction and processing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104629481A true CN104629481A (en) | 2015-05-20 |
Family
ID=53208742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310555334.0A Pending CN104629481A (en) | 2013-11-11 | 2013-11-11 | Natural dye extraction and processing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104629481A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349737A (en) * | 2016-08-10 | 2017-01-25 | 姚树明 | Preparation method of Salvia japonica Thunb. vegetable dye |
| CN107151925A (en) * | 2017-06-15 | 2017-09-12 | 兴化市大地蓝绢纺有限公司 | A kind of production method of the clear mesh pillowcase of ecological dyeing soothing the liver |
| CN108948782A (en) * | 2018-07-08 | 2018-12-07 | 杭州彩润科技有限公司 | The method of vegetable colour is produced using red sawdust |
| CN109181351A (en) * | 2018-08-09 | 2019-01-11 | 苏州品旺电子科技有限公司 | A kind of natural textile dyestuff for bamboo fibre |
-
2013
- 2013-11-11 CN CN201310555334.0A patent/CN104629481A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349737A (en) * | 2016-08-10 | 2017-01-25 | 姚树明 | Preparation method of Salvia japonica Thunb. vegetable dye |
| CN107151925A (en) * | 2017-06-15 | 2017-09-12 | 兴化市大地蓝绢纺有限公司 | A kind of production method of the clear mesh pillowcase of ecological dyeing soothing the liver |
| CN108948782A (en) * | 2018-07-08 | 2018-12-07 | 杭州彩润科技有限公司 | The method of vegetable colour is produced using red sawdust |
| CN109181351A (en) * | 2018-08-09 | 2019-01-11 | 苏州品旺电子科技有限公司 | A kind of natural textile dyestuff for bamboo fibre |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150520 |