CN104621123B - A kind of bactericidal composition containing prothioconazoles and fluopicolide and application thereof - Google Patents
A kind of bactericidal composition containing prothioconazoles and fluopicolide and application thereof Download PDFInfo
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- CN104621123B CN104621123B CN201310571249.3A CN201310571249A CN104621123B CN 104621123 B CN104621123 B CN 104621123B CN 201310571249 A CN201310571249 A CN 201310571249A CN 104621123 B CN104621123 B CN 104621123B
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- fluopicolide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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Abstract
The invention discloses a kind of bactericidal composition containing prothioconazoles and fluopicolide and application thereof.This bactericidal composition is with prothioconazoles and fluopicolide for principle active component.This bactericidal composition can be applicable to preventing and treating Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the Drug resistance of pathogenic bacteria, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention may be used for the fungal disease on preventing and treating crops, being particularly useful for preventing and treating powdery mildew, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease, gray mold, melasma, brown spot, balck shank, rice blast and epidemic disease, effect is better than single dose and uses.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of with prothioconazoles and fluopicolide be main active bactericidal composition and application.
Background technology:
Prothioconazoles (Prothioconazole), it it is the New-type wide-spectrum triazolinthione series bactericidal agent developed by Beyer Co., Ltd, chemical name: 2-(2-(1-chlorine cyclopropyl)-3-(2-chlorphenyl)-2-hydroxypropyl-1-2-dihydro-3-1,2,4-triazole-3-sulfo-, molecular formula: C14H15Cl2N3OS.Structural formula is as follows:
The mechanism of action of prothioconazoles is to suppress the demethylation effect on the precursor lanosterol of sterol in fungus or the liquor-saturated l4 position of 24-methylene dihydro Mi hair, i.e. demethylation inhibitors (DMIs).Not only there is good systemic activity, excellent protection, treat and root out activity, and the lasting period is long.By substantial amounts of field control effectiveness test, result shows that crop is not only had good safety by prothioconazoles, and preventing disease theraping effect is good, and increases production substantially, compares with triazole type biocide agent, and prothioconazoles has broader spectrum of bactericidal activity.It is mainly used in numerous diseases such as preventing and treating cereal crop such as Semen Tritici aestivi, Fructus Hordei Vulgaris, Brassica campestris L, Semen arachidis hypogaeae, Oryza sativa L. and legume crop.Almost all wheat and barley diseases there is good prevention effect, such as Semen Tritici aestivi and the powdery mildew of Fructus Hordei Vulgaris, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease etc..Oil Lay and the soil-borne disease of Semen arachidis hypogaeae can also be prevented and treated, such as sclerotiniose, and main foliage disease, such as gray mold, melasma, brown spot, balck shank, sclerotiniose and rust etc..
Fluopicolide (Fluopicolide), molecular formula: C14H8Cl3F3N2O.The chloro-N-{ of chemical name: 2,6-bis-[3-chloro-5-(trifluoromethyl)-2-pyridine] methyl } Benzoylamide.Structural formula:
Fluopicolide is the new pyridine acid amide fungicides with its particular mechanism developed by Beyer Co., Ltd.It is mainly used in preventing and treating oomycetes diseases such as downy mildew, epidemic disease etc., in addition also rice blast, gray mold, powdery mildew etc. is had certain preventive effect, with other compounds no interactions resistances.
The industrial crops cultivated areas such as the difficulty of prevention and cure of current phytopathogen is increasing, on the one hand, along with the change of pattern of farming, melon fruits and vegetables progressively expand, and disease occurrence degree, occur quantity all to increase, and in preventing and treating, difficulty strengthens；On the other hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, plant bactericidal composition containing prothioconazoles Yu fluopicolide that cost is low, effective for above-mentioned technical problem.
It is a still further object of the present invention to provide this bactericidal composition and cause the application of fungal disease medicine as preparation preventing and treating plant epiphyte, prevent and treat the application of powdery mildew, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease, gray mold, melasma, brown spot, balck shank, rice blast and epidemic disease medicine especially as preparation.
It is an object of the invention to be realized by following measures:
A kind of bactericidal composition containing prothioconazoles and fluopicolide, described prothioconazoles and fluopicolide weight ratio are 1～70:1～50, it is preferred to 1～35:1～25, more preferably 1～10:1～20, it is most preferred that for 1:2～6.
In the compositions of the present invention, the percentage by weight accounting for compositions both prothioconazoles and fluopicolide is 2～80%, it is preferable that 10～40%.
Described bactericidal composition, the dosage form that wherein prothioconazoles and fluopicolide and known auxiliary agent and excipient are re-dubbed on pesticide to allow.These known auxiliary agents have dispersant, diffusant, defoamer, wetting agent, disintegrating agent etc., calcium dodecyl benzene sulfonate can be adopted, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, one or more mixing in quaternary etc., excipient includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
The described bactericidal composition containing prothioconazoles and fluopicolide has the application of preventing and treating resistance plant fungal disease medicine as preparation.
The described bactericidal composition containing prothioconazoles and fluopicolide prevents and treats the application of powdery mildew, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease, gray mold, melasma, brown spot, balck shank, rice blast and epidemic disease medicine as preparation.
Beneficial effects of the present invention:
Compared with prior art beneficial effects of the present invention: (1) is compared with single dose, said composition antagonism fungal disease such as powdery mildew, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease, gray mold, melasma, brown spot, balck shank, rice blast and epidemic disease have obvious synergistic function, overcome and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost reduces；(5) suppressing the drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention:
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, and " % " of the present invention is mass percent.
Two kinds of reactive compounds can be processed into any one dosage form of permission, with specific embodiment, the preparation that two kinds of effective ingredient are processed into is described below, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:
By prothioconazoles 5g, fluopicolide 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
Embodiment 2:
By prothioconazoles 3g, fluopicolide 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
Embodiment 3:
By prothioconazoles 2g, fluopicolide 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 14% wettable powder.
Embodiment 4:
Weigh 5g prothioconazoles, 50g fluopicolide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 55% prothioconazoles-fluopicolide aqueous emulsion.
Embodiment 5:
Weigh 2g prothioconazoles, 30g fluopicolide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 32% prothioconazoles-fluopicolide microemulsion.
Embodiment 6:
Weigh 1g prothioconazoles, 5g fluopicolide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 6% prothioconazoles-fluopicolide aqueous emulsion.
Embodiment 7:
Weighing 50g prothioconazoles, 20g fluopicolide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 70% prothioconazoles-fluopicolide cream.
Embodiment 8:
Weighing 2g prothioconazoles, 40g fluopicolide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 42% prothioconazoles-fluopicolide cream.
Embodiment 9:
Weigh 5g prothioconazoles, 20g fluopicolide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 25% prothioconazoles-fluopicolide microemulsion.
Embodiment 10:
Weighing 5g prothioconazoles, 0.5g fluopicolide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 5.5% prothioconazoles-fluopicolide cream.
Embodiment 11:
Weighing 5g prothioconazoles, 30g fluopicolide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 35% prothioconazoles-fluopicolide cream.
Embodiment 12:
Weigh 10g prothioconazoles, 10g fluopicolide, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 20% prothioconazoles-fluopicolide suspending agent.
Embodiment 13:
Weigh 30g prothioconazoles, 12g fluopicolide, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 42% prothioconazoles-fluopicolide suspending agent.
Embodiment 14:
Weigh 2g prothioconazoles, 5g fluopicolide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and by water dispersible granular agent method, above raw material is formed with effect Ingredients Weight percentage composition is 7% prothioconazoles-fluopicolide water dispersion granule.
Embodiment 15:
Weigh 4g prothioconazoles, 13g fluopicolide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complements to 100g, and by water dispersible granular agent method, above raw material is formed with effect Ingredients Weight percentage composition is 17% prothioconazoles-fluopicolide water dispersion granule.
Embodiment 16:
Weigh 5g prothioconazoles, 15g fluopicolide, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 20% prothioconazoles-fluopicolide suspending agent.
Field control effectiveness test:
1. test process: the difference of each composition of this experimental evidence sets three dosings respectively, dosing be effective ingredient prothioconazoles (A) and effective ingredient fluopicolide (B) quality with.Comparison medicament is pesticide single dose 25% fluopicolide ME and 5% prothioconazoles ME and blank clean water experiment respectively.
2. test method: each plot area is 66.7m2, repeat 3 times；Investigation drug effect method after investigating before dispenser and preventing and treating is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.Result of the test is shown in following table:
Table 1 field control effectiveness test result
, the present composition has obvious synergistic function by field efficacy it is shown that as shown in Table 1, and the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has using value in agricultural is applied.
Claims (3)
1. the wettable powder containing prothioconazoles and fluopicolide, it is characterized in that: this wettable powder be by prothioconazoles 5g, fluopicolide 10g, to methoxyl group fatty acid amido benzene sulfonic acid sodium salt 2g, sodium methylene bis-naphthalene sulfonate 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
2. the wettable powder containing prothioconazoles and fluopicolide, it is characterized in that: this wettable powder is by prothioconazoles 3g, fluopicolide 12g, sodium lauryl sulphate 3g, sodium methylene bis-naphthalene sulfonate 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
3. the wettable powder containing prothioconazoles and fluopicolide, it is characterized in that: this wettable powder is by prothioconazoles 2g, fluopicolide 12g, sodium lauryl sulphate 3g, sodium methylene bis-naphthalene sulfonate 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 14% wettable powder.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310571249.3A CN104621123B (en) | 2013-11-15 | 2013-11-15 | A kind of bactericidal composition containing prothioconazoles and fluopicolide and application thereof |
| PCT/CN2014/076332 WO2015070568A1 (en) | 2013-11-15 | 2014-04-28 | Prothioconazole and fluopicolide containing sterilization composition and uses thereof |
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| CN201310571249.3A CN104621123B (en) | 2013-11-15 | 2013-11-15 | A kind of bactericidal composition containing prothioconazoles and fluopicolide and application thereof |
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| CN104621123A CN104621123A (en) | 2015-05-20 |
| CN104621123B true CN104621123B (en) | 2016-07-27 |
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| CN106172420A (en) * | 2016-06-27 | 2016-12-07 | 美丰农化有限公司 | A kind of bactericidal composition and preparation thereof and application |
| GB2552695B (en) * | 2016-08-04 | 2020-03-04 | Rotam Agrochem Int Co Ltd | A synergistic fungicidal composition |
| CN115161133B (en) * | 2022-08-02 | 2023-12-01 | 晋江市盛星新材料科技有限公司 | Whitening and degreasing agent for cotton fabric, and preparation method and application method thereof |
| CN115943962B (en) * | 2023-01-05 | 2024-06-25 | 河南科技学院 | Sterilization composition for preventing and treating banded sclerotial blight of wheat |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101578041A (en) * | 2006-12-22 | 2009-11-11 | 拜尔农作物科学股份公司 | Pesticidal composition comprising a 2-pyrdilmethylbenzamide derivative and an insecticide compound |
| WO2010009822A1 (en) * | 2008-07-24 | 2010-01-28 | Bayer Cropscience Ag | Thickener for plant-compatible concentrates that can be dispersed in water |
| CN102395272A (en) * | 2009-04-15 | 2012-03-28 | 先正达参股股份有限公司 | Fungicidal mixtures |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103314968B (en) * | 2013-06-09 | 2014-09-17 | 江苏辉丰农化股份有限公司 | Bactericidal composition with synergistic effect |
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- 2013-11-15 CN CN201310571249.3A patent/CN104621123B/en active Active
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- 2014-04-28 WO PCT/CN2014/076332 patent/WO2015070568A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101578041A (en) * | 2006-12-22 | 2009-11-11 | 拜尔农作物科学股份公司 | Pesticidal composition comprising a 2-pyrdilmethylbenzamide derivative and an insecticide compound |
| WO2010009822A1 (en) * | 2008-07-24 | 2010-01-28 | Bayer Cropscience Ag | Thickener for plant-compatible concentrates that can be dispersed in water |
| CN102395272A (en) * | 2009-04-15 | 2012-03-28 | 先正达参股股份有限公司 | Fungicidal mixtures |
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| CN104621123A (en) | 2015-05-20 |
| WO2015070568A1 (en) | 2015-05-21 |
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