CN104610608A - 电缆用阻燃丁苯橡胶套及其制备方法 - Google Patents
电缆用阻燃丁苯橡胶套及其制备方法 Download PDFInfo
- Publication number
- CN104610608A CN104610608A CN201510011657.2A CN201510011657A CN104610608A CN 104610608 A CN104610608 A CN 104610608A CN 201510011657 A CN201510011657 A CN 201510011657A CN 104610608 A CN104610608 A CN 104610608A
- Authority
- CN
- China
- Prior art keywords
- butadiene rubber
- sbr
- fire
- preparation
- cable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 83
- 229920003048 styrene butadiene rubber Polymers 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 25
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000004073 vulcanization Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- BUPRYTFTHBNSBD-UHFFFAOYSA-N (2,3,4-tribromophenyl) prop-2-enoate Chemical compound BrC1=CC=C(OC(=O)C=C)C(Br)=C1Br BUPRYTFTHBNSBD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 11
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001971 elastomer Polymers 0.000 claims description 27
- 239000005060 rubber Substances 0.000 claims description 27
- -1 clorafin Chemical compound 0.000 claims description 15
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 14
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 14
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 238000005987 sulfurization reaction Methods 0.000 claims description 9
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 6
- 230000008774 maternal effect Effects 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 235000015393 sodium molybdate Nutrition 0.000 abstract 1
- 239000011684 sodium molybdate Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/247—Heating methods
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | |
自熄性时间/s | 6 | 4 | 5 | 3 | 2 | 25 | 20 | 31 | 28 |
极限氧指数/% | 26 | 27 | 25 | 29 | 30 | 17 | 20 | 19 | 18 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510011657.2A CN104610608B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃丁苯橡胶套及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510011657.2A CN104610608B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃丁苯橡胶套及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104610608A true CN104610608A (zh) | 2015-05-13 |
CN104610608B CN104610608B (zh) | 2016-05-25 |
Family
ID=53145272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510011657.2A Active CN104610608B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃丁苯橡胶套及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104610608B (zh) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040147659A1 (en) * | 2002-10-16 | 2004-07-29 | Nabaltec Nabwerk Aluminiumhydroxid Technologie GmbH | Flame retardant polymer composition |
CN103524933A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种阻燃电缆料及其制备方法 |
CN103525072A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种无卤阻燃聚苯醚电缆料 |
CN103525075A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种高阻燃高耐热无卤阻燃热塑性电缆料 |
-
2015
- 2015-01-09 CN CN201510011657.2A patent/CN104610608B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040147659A1 (en) * | 2002-10-16 | 2004-07-29 | Nabaltec Nabwerk Aluminiumhydroxid Technologie GmbH | Flame retardant polymer composition |
CN103524933A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种阻燃电缆料及其制备方法 |
CN103525072A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种无卤阻燃聚苯醚电缆料 |
CN103525075A (zh) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | 一种高阻燃高耐热无卤阻燃热塑性电缆料 |
Also Published As
Publication number | Publication date |
---|---|
CN104610608B (zh) | 2016-05-25 |
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C06 | Publication | ||
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CB02 | Change of applicant information |
Address after: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant after: WUHU SPACEFLIGHT SPECIAL CABLE FACTORY CO., LTD. Address before: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant before: Wuhu Aerospace Special Cable Factory |
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COR | Change of bibliographic data | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhu Lixiang Inventor before: She Chen Inventor before: He Chenglong Inventor before: He Yuan Inventor before: Yang Chenfen |
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CB03 | Change of inventor or designer information | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171120 Address after: 236800, 3, 207 crystal mansion, Qiaocheng District, Anhui, Bozhou Patentee after: Bozhou Woye Intellectual Property Service Co. Ltd. Address before: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Patentee before: WUHU SPACEFLIGHT SPECIAL CABLE FACTORY CO., LTD. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190709 Address after: 402360 No. 174, Shuangta Road, Longgang Street, Dazu District, Chongqing, 2-18-18 Patentee after: Chongqing Huicheng Hengya Biotechnology Co., Ltd. Address before: 236800 3 building 207, Hai Jing building, Qiaocheng District, Bozhou, Anhui Patentee before: Bozhou Woye Intellectual Property Service Co. Ltd. |
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Effective date of registration: 20200924 Address after: Tongxiang City, Jiaxing City, Zhejiang province 314500 Fengqi Road Economic Development Zone on the south side Patentee after: JIAXING TOSUN RUBBER&PLASTIC Co.,Ltd. Address before: 402360 No. 174, Shuangta Road, Longgang Street, Dazu District, Chongqing, 2-18-18 Patentee before: Chongqing Huicheng Hengya Biotechnology Co.,Ltd. |
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